E. Abdeltwab, A. Atta, Nuha Al-Harbi, M. M. Abdelhamied
{"title":"Synthesis, characterization and dielectric properties of polymer nanocomposites for energy storage applications","authors":"E. Abdeltwab, A. Atta, Nuha Al-Harbi, M. M. Abdelhamied","doi":"10.1007/s13233-024-00298-y","DOIUrl":"10.1007/s13233-024-00298-y","url":null,"abstract":"<div><p>In this project, the oxidative chemical polymerization method is used to prepare polymer composite that consisting of polypyrrole polymer (PPy) and iron oxide nanoparticles (Fe<sub>2</sub>O<sub>3</sub>NPs). Then deposited this blend (PPy/Fe<sub>2</sub>O<sub>3</sub>) onto the PET substrate to creating flexible nanocomposite PET/(PPy/Fe<sub>2</sub>O<sub>3</sub>). Analyzing the samples using X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR) proves that the composite was effectively formed. With varying Fe<sub>2</sub>O<sub>3</sub> ratios, the dielectric parameters of PET polymer and PET/(PPy/Fe<sub>2</sub>O<sub>3</sub>) composite have been documented at frequencies of 40–5.6 MHz. The surface properties were significantly enhanced by irradiation. The surface free energy increases from 41.36 mJ/m<sup>2</sup> to 66.23 mJ/m<sup>2</sup> and water contact angle reduces from 58.36° for PET to 39.25°. The results demonstrated that the composite surface characteristics were enhanced as the concentration of Fe<sub>2</sub>O<sub>3</sub> changed. The obtained data showed that the fabricated samples have better properties than the PET films that can be utilized in many applications as capacitors and storage devices.</p><h3>Graphical abstract</h3><p><b>a</b> SEM of PET, <b>b</b> SEM of PPy/Fe<sub>2</sub>O<sub>3</sub>, <b>c</b> SEM of PET/(PPy/Fe<sub>2</sub>O<sub>3</sub>, <b>d</b> contact angle with ratios\u0000of Fe<sub>2</sub>O<sub>3</sub> and <b>e</b> surface free energy with ratios of Fe<sub>2</sub>O<sub>3</sub></p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 11","pages":"1113 - 1122"},"PeriodicalIF":2.8,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141777398","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Screen printing and electrical properties of silver paste using a robust biopolymer binder for fine line electrode in energy devices","authors":"Young Sil Lee, Ju Hwan An, Kwan Han Yoon","doi":"10.1007/s13233-024-00296-0","DOIUrl":"10.1007/s13233-024-00296-0","url":null,"abstract":"<div><p>The purpose of this study is to identify factors affecting the dispersion and printing properties of pastes that are required to form fine line width electrodes by controlling the rheological properties of pastes applied in various fields. In particular, to solve the problem of high cost and low efficiency of silver used in the front electrode of silicon solar cells, it is necessary to print uniform fine lines with high aspect ratio to achieve higher efficiency while reducing raw material consumption. In this study, ethyl cellulose (EC), a conventional general-purpose binder, and xanthan gum (XG), which is widely used as a thickener in the food industry and has excellent temperature stability and the advantage of having a high viscosity even with a small content, used as binders. An organic solution was prepared by completely dissolving the binder in a solvent, and then inorganic particles and glass flecks were added to prepare the final paste. The rheological properties of the paste were measured, and the aspect ratio and the electrical conductivity of the electrodes were assessed after screen printing and firing. The results indicated that the paste prepared with XG binder exhibited a higher overall viscosity compared to the paste with EC binder and demonstrated a superior shear-thinning behavior. The pastes with optimal printing properties were found to contain 12 wt% EC and 7 wt% XG, respectively. In the frequency sweep test, XG had higher G' and G'' than EC, showing relatively good sedimentation stability and high aspect ratio. Viscosity recovery through hysteresis test was also better for XG than EC. For the final electrical conductivity, both EC and XG showed a value of 10<sup>3</sup> Ω⋅m order. However, if the electrodes were formed from a paste made of XG, the final solar cell efficiency is expected to be higher due to the larger area receiving sunlight due to the high aspect ratio.</p><h3>Graphical Abstract</h3><p>This study investigates the rheological properties of pastes formulated with ethyl cellulose and xanthan gum for screen-printed electrodes in silicon solar cell fabrication. Xanthan gum-based pastes exhibit higher viscosity and better shear thinning behavior compared to ethyl cellulose-based pastes, with optimal printing properties observed at 7 wt% xanthan gum content. The findings suggest that utilizing xanthan gum-based pastes could lead to higher efficiency in silicon solar cells due to the potential for achieving larger aspect ratio electrodes\u0000</p><div><figure><div><div><picture><source><img></source></picture></div><div><p>Fine line widths and patterns of ethyl cellulose/silver and xanthan gum/silver pastes</p></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 11","pages":"1123 - 1133"},"PeriodicalIF":2.8,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Drug release and physical properties of double layers coated contact lenses using natural polymers","authors":"Hye Ji Kim, Hyun Mee Lee","doi":"10.1007/s13233-024-00289-z","DOIUrl":"10.1007/s13233-024-00289-z","url":null,"abstract":"<div><p>This study aims to develop contact lenses with improved drug-release duration time by layer-by-layer (LBL) coating with natural polymers on contact lenses containing the drug gatifloxacin. LBL coating was performed in single and double layers on contact lenses containing gatifloxaxin using natural polymers carrageenan and polylysine. The performance of contact lenses was evaluated based on various physical properties and antibacterial properties. As a result, contact lenses containing gatifloxacin have reduced physical properties compared to lenses without gatifloxacin. As the concentration of gatifloxacin increased, oxygen permeability and wettability decreased, and antibacterial properties increased. LBL coating improved the wettability and antibacterial properties of contact lenses and increased the drug-release duration. Double-layers coated lenses increased the duration of drug release more than single-coated lenses.</p><h3>Graphic Abstract</h3><p>Double layer-coating with poly-L-lysine and carrageenan on contact lenses</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 10","pages":"981 - 988"},"PeriodicalIF":2.8,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13233-024-00289-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141547766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Valeria G. Oyervides-Guajardo, Jesús A. Claudio-Rizo, Denis A. Cabrera-Munguía, Martín Caldera-Villalobos, Tirso E. Flores-Guia, Florentino Soriano-Corral, Adán Herrera-Guerrero
{"title":"BioZnMOFs dispersed in collagen-starch hydrogels: a stimulating approach for animal and plant tissue growth","authors":"Valeria G. Oyervides-Guajardo, Jesús A. Claudio-Rizo, Denis A. Cabrera-Munguía, Martín Caldera-Villalobos, Tirso E. Flores-Guia, Florentino Soriano-Corral, Adán Herrera-Guerrero","doi":"10.1007/s13233-024-00293-3","DOIUrl":"10.1007/s13233-024-00293-3","url":null,"abstract":"<div><p>The utilization of bio-derived zinc metal–organic frameworks (bioZnMOFs) as crystalline materials represents an advanced innovation with dual significance in both physicochemical and biological realms. BioZnMOFs based on essential amino acids such as <span>l</span>-phenylalanine, <span>l</span>-histidine, and <span>l</span>-tryptophan were dispersed in collagen–starch hydrogels (mass ratio 1%) to generate the materials ZnF, ZnH, and ZnT, respectively. Using solid-state <sup>13</sup>C NMR, the chemical components of these systems were identified. The surface structure of these biomatrices was inspected by SEM, indicating that ZnT generates the largest occluded clusters. EDS analysis revealed that Zn(II) ions are uniformly distributed in all the semi-IPN biomatrices. WAXS analysis demonstrated a semi-crystalline structure, while FTIR analysis revealed that the ZnH matrix shows the greatest physicochemical interaction processes, benefiting crosslinking (40 ± 5%), swelling (4900 ± 510%), storage modulus (1000 Pa at 35 Hz), and reduced gelation time (10 ± 1 min) in this biomatrix. These materials display slow degradation in collagenase-rich environments and vegetable substrate. ZnH and ZnT matrices stimulate monocyte metabolism, while ZnF and ZnH actively promote fibroblast metabolism, encouraging proliferation at 48 h. ZnT shows modulation of IL-10 and TNF-α cytokine secretion in monocytes, suggesting its potential in wound healing applications. Additionally, the ZnT matrix enhances tomato root cell metabolism and proliferation. After 30 days, plants growing on ZnT matrices exhibit larger stem diameters and more leaves, showcasing their agricultural potential. Overall, these bioZnMOF-based materials offer versatile solutions with promising applications in biomedicine and agriculture.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div><div><p>The incorporation of bioZnMOFs into collagen-starch hydrogels allows for the modulation of their structural, physicochemical, and biological properties. The chemical structure of the bioZnMOF determines the enhancement of functional applicability. BioZnMOF based on <span>l</span>-histidine significantly improves crosslinking, swelling, and gelation speed, while those based on <span>l</span>-tryptophan stimulate animal tissue growth with inflammation control and also promote the growth of tomato plants. These advanced materials represent versatile platforms for biomedical and agricultural applications</p></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 11","pages":"1097 - 1112"},"PeriodicalIF":2.8,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506015","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization of mechanical, thermal and rheological properties of silica-based nanocomposite filled thermoplastic polyurethane film","authors":"Sanghee Kim","doi":"10.1007/s13233-024-00286-2","DOIUrl":"10.1007/s13233-024-00286-2","url":null,"abstract":"<div><p>The objective of this study is to investigate the effects of incorporating negatively charged core–shell type SiO<i>x</i>/PS (silicate core/polystyrene shell) nanoparticles on the mechanical, thermal, and rheological properties of a non-commercial thermoplastic polyurethane (TPU, pristine 9094) film. TPU-SiO<i>x</i>/PS nanocomposites were fabricated by blending pristine 9094 TPU-based resin with SiO<i>x</i>/PS nanoparticles of 1, 2, and 3 wt% loading and prepared as sheet-type films via T-die extrusion. The dispersion of SiO<i>x</i>/PS nanoparticles within the TPU matrix was confirmed using FTIR (Fourier-Transform Infrared Spectroscopy) and zeta potential (<i>ζ</i>) analysis. Results showed peaks assigned to benzene ring (698 cm<sup>−1</sup>, 1638 cm<sup>−1</sup>) in the polystyrene structure, with a shift in zeta potential (<i>ζ</i>) from + 19.77 mV (pristine) to −13.30 mV (1 wt%) and −6.42 mV (2 wt%). At 2 wt%, the SiO<i>x</i>/PS-TPU film exhibited an increase of 13.2% in yield strength and 20.1% in Young’s modulus compared to pristine 9094 film. This loading also yielded the highest increases in storage modulus (<i>G′</i>) and complex viscosity (<i>η</i>). The decrease in the slope of G′ from G′ ~ ω<sup>1.67</sup> (pristine 9094) to G′ ~ ω<sup>1.62</sup> (2wt%) reflects the reinforcement of polymer chains and enhanced elasticity. Increases in <i>T</i><sub>g,SS</sub> (glass transition temperature of soft segment) and decreases in <i>T</i><sub>g,HS</sub> (glass transition temperature of hard segment) suggest enhanced interactions between SiO<i>x</i>/PS nanoparticles and polymer chains. Finally, a 2 wt% loading enables the mechanical and rheological properties of the pristine 9094 TPU film comparable to those of the commercial pristine 49,510 TPU film.</p><h3>Graphical abstract</h3><p>TPU-nanocomposite film through T-die extrusion process</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 7","pages":"727 - 743"},"PeriodicalIF":2.8,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141513579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermal conductivity of polyaniline reinforced epoxy resin","authors":"Youngwoo Cha, Munju Goh","doi":"10.1007/s13233-024-00288-0","DOIUrl":"10.1007/s13233-024-00288-0","url":null,"abstract":"<div><p>This study introduces the possibility of using polyaniline as a thermally conductive filler in the manufacturing process of composites using epoxy. Compared to conventional thermally conductive fillers, polyaniline is a material with a simple synthesis process and is cost-effective. In this experiment, among various types of polyaniline, polyaniline in the form of an emeraldine salt (ES) doped with protons and polyaniline in the form of a dedoped neutral emeraldine base (EB) were used as the thermally conductive filler. ES doped with protons show higher electrical and thermal conductivity than EB due to the conductive polymer characteristics in which the thermal conductivity increases as the electrical conductivity increases. We put both fillers into the widely commercially available diglycidyl ether of bisphenol A (DGEBA) epoxy composite, and analyzed the effect of the thermal conductivity of the filler increased by doping on the thermal conductivity of the composite, and analyzed the possibility of use as a thermally conductive filler. The epoxy resin without filler was measured to have the thermal conductivity of 0.21 W/m K, the thermal conductivity of the composite reinforced with EB filler was measured to be 0.27 W/m K, and the thermal conductivity of the composite reinforced with ES filler was measured to be 0.29 W/m K. The results confirmed that the input of polyaniline as a thermally conductive filler could improve the thermal conductivity of the composite, and also confirmed that the proton-doped ES filler showed higher thermal conductivity than the neutral EB filler. Through this study, we highlight the possibility that polyaniline can be used as a promising thermally conductive filler for various composite materials.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div><div><p>Proton-doped polyanilines, when used as thermally conductive fillers in epoxy composites, increase thermal conductivity more effectively than dedoped polyanilines</p></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 8","pages":"745 - 750"},"PeriodicalIF":2.8,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. M. R. Fattah, Zainab A. Farhan, Karolos J. Kontoleon, Ehsan kianfar, Salema K. Hadrawi
{"title":"Retraction Note: Hollow fiber membrane contactor based carbon dioxide absorption − stripping: a review","authors":"I. M. R. Fattah, Zainab A. Farhan, Karolos J. Kontoleon, Ehsan kianfar, Salema K. Hadrawi","doi":"10.1007/s13233-024-00294-2","DOIUrl":"10.1007/s13233-024-00294-2","url":null,"abstract":"","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 8","pages":"823 - 823"},"PeriodicalIF":2.8,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142413582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bridging the future: unveiling the latest innovations in ethylene vinyl acetate blends and composites through electron beam irradiation—a comprehensive review","authors":"Jawad Ahmed, Sidra Mushtaq","doi":"10.1007/s13233-024-00292-4","DOIUrl":"10.1007/s13233-024-00292-4","url":null,"abstract":"<div><p>High energy radiation processing has proven to be remarkably effective in enhancing the properties of polymeric materials. Specially, electron beam (E-beam) radiation stands out as a versatile technique for crosslinking, compatibilizing, and grafting polymer blends and composites. Its reputation for simplicity, high speed, environmental friendliness, and user-friendliness has made it the preferred method in industries such as automotive, electrical insulation, ink curing, surface modification, food packaging, medical sterilization, and healthcare. This review focuses on recent advancements in the application of E-beam irradiation to ethylene vinyl acetate (EVA) blends and composites, with a specific focus on incorporating partially nanoscale clay to achieve desired properties and the controlled crosslinking of blends and nanocomposites using high-energy radiation. Numerous studies have investigated the development and modification of EVA with various thermoplastic and elastomeric polymers, highlighting radiation-induced grafting of different monomers onto the polymer backbone. The review primarily examines the utilization of EVA blends and composites for the purpose of adjusting their physical, chemical, thermal, surface, and structural properties. Additionally, it investigates the formation of crosslinking by analyzing gel content and optimizing the dosage of crosslinking co-agents and fillers. Furthermore, the study explores the effect of E-beam irradiation on the tensile properties, specifically the enhancement of tensile strength resulting from crosslinking formation at varying E-beam radiation doses. Additionally, the diverse applications of high-energy radiation-modified polymers in industries such as automotive, wire and cable insulation, heat shrinkable tubes, sterilization, biomedical, nuclear, and space industries are discussed. These applications demonstrate the extensive potential and practicality of utilizing high-energy radiation processing to enhance the properties of polymeric materials in various industrial settings.</p><h3>Graphical abstract</h3><p>Effects of electron beam irradiation on ethylene vinyl acetate blends and composites.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 11","pages":"1049 - 1063"},"PeriodicalIF":2.8,"publicationDate":"2024-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141506009","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Multiscale acoustical study on graphene oxide impregnated polyurethane foam","authors":"Sung Soo Yang, Inhwa Jung, Yeon June Kang","doi":"10.1007/s13233-024-00281-7","DOIUrl":"10.1007/s13233-024-00281-7","url":null,"abstract":"<div><p>This study examines the multiscale acoustic properties of sound-absorbing polyurethane (PU) foam impregnated with graphene oxide (GO). GO impregnation into the PU foam was achieved through a vacuum-assisted process. The effects of GO impregnation on the macroscopic acoustic behavior, transport parameters, and sound absorption coefficients were investigated. Scanning electron microscopy images revealed that the impregnated GO enveloped the open pores within the porous structure. Geometric parameters derived from the microstructural observations were used to perform acoustic simulations. Models with partially open cells could be used to accurately predict the transport parameters and sound absorption coefficients of foams with low levels of GO impregnation. For foams with high levels of GO impregnation, it was necessary to incorporate closed cells into the model, which significantly enhanced the prediction accuracy for the transport parameters and sound absorption coefficients. This study advances our understanding of the acoustic properties of GO-impregnated PU foams and will be beneficial for developing more effective sound-absorbing materials.</p><h3>Graphical abstract</h3><p>Acoustical characterization of graphene oxide impregnated polyurethane foam</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 10","pages":"935 - 946"},"PeriodicalIF":2.8,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141513639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Youjin Song, Donghyeon Lee, Hyunjoo Seo, Jeewoo Lim, Byungjin Koo
{"title":"Amine detection via PDMS swelling in CNT/PDMS strain sensors","authors":"Youjin Song, Donghyeon Lee, Hyunjoo Seo, Jeewoo Lim, Byungjin Koo","doi":"10.1007/s13233-024-00290-6","DOIUrl":"10.1007/s13233-024-00290-6","url":null,"abstract":"<div><p>The amine sensing is of critical importance in food safety, environmental protection, and national security. We herein report our novel approach to amine detection based on swelling parameters and strain sensors. Specifically, we prepared strain sensors using poly(3-hexylthiophene) (P3HT), single-walled carbon nanotube (CNT), and polydimethylsiloxane (PDMS). P3HT-wrapped CNTs were produced in chloroform, and this solution was drop-casted onto PDMS pads, followed by attaching copper electrodes, resulting in CNT/PDMS strain sensors. It has been well documented that PDMS possesses matching solubility parameters with diisopropylamine, and we discovered that diisopropylamine caused the most significant swelling of the PDMS pad compared to the other seven solvents/chemicals used in this study. The swelling of PDMS induced by diisopropylamine resulted in a large increase in electrical resistance (R/R<sub>0</sub> ~ 2.21, wherein R and R<sub>0</sub> represent the resistances before and after swelling, respectively), probably due to the transmitted stress/strain from PDMS swelling and thus the perturbation of the CNT networks. This study offers a new method for fabricating chemical sensors utilizing strain based on polymer swelling.</p><h3>Graphical Abstract</h3><p>The swelling of PDMS induced by various solvents/chemicals was recorded as changes in resistivity, leading to the fabrication of strain-based chemical sensors.</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"32 8","pages":"751 - 756"},"PeriodicalIF":2.8,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141513640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}