Thin Solid Films最新文献

{"title":"Mechanism of the local destruction of the amorphous Ta2O5 layer on the surface of a tantalum anode","authors":"B.E. Pushkarev,&nbsp;R.M. Nikonova,&nbsp;V.I. Lad'ynov","doi":"10.1016/j.tsf.2024.140564","DOIUrl":"10.1016/j.tsf.2024.140564","url":null,"abstract":"<div><div>In the present work, a mechanism of the destruction of amorphous tantalum oxide Ta₂O₅ on the tantalum anode surface is suggested based on high absorption properties of tantalum. The data of analysis of the morphological peculiarities of the defective areas of the surface layers show that the destruction of the amorphous film occurs due to the growth of a pyramid-shaped defect; the pyramidal defect is not coherent with amorphous surface Ta₂O₅, and it is not a product of its crystallization. The nucleation and growth of the “pyramid” occurs due to the directed movement of oxygen during the oxidation of the tantalum surface along the grain boundaries to the region of triple junctions of the tantalum matrix with the subsequent local formation of crystalline Ta₂O₅. The suggested mechanism offig destruction can be realized when high-purity tantalum powders are used.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140564"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of thermal annealing on the luminescent and structural properties of the SiOxCy thin films by organic catalytic chemical vapor deposition","authors":"M. Meneses ,&nbsp;M.F. Ávila Meza ,&nbsp;J.R. Ramos Serrano ,&nbsp;Y. Matsumoto","doi":"10.1016/j.tsf.2024.140568","DOIUrl":"10.1016/j.tsf.2024.140568","url":null,"abstract":"<div><div>Photoluminescent silicon oxycarbide (SiO_xC_y) thin films were deposited on n-type (100) silicon substrates using the organic catalytic chemical vapor deposition (O<img>Cat-CVD) technique employing tetra-ethyl orthosilicate (TEOS) as an organic-based precursor. These films were annealed at a temperature of 500, 800 and 1000 °C for 30 min in a nitrogen (N₂) environment. The as-deposited and annealed SiO_xC_y films were analyzed using optical and structural characterizations, such as photoluminescence (PL), Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), Secondary ion mass spectrometry (SIMS) and scanning electron microscopy (SEM). The PL spectrum of the as-deposited film showed emission in the blue-green region, while the annealed SiO_xC_y films showed strong emission from blue to near-infrared. The PL in all the films was attributed to different structural defects related to oxygen and carbon that act as radiative centers in the SiO_xC_y network. The annealed films showed an increase in the emission intensity, where the annealed film at 800 °C displayed the highest emission intensity. This is related to an increase in the amount of radiative defects in the films due to structural and compositional changes after the thermal annealing (TA). XPS and SIMS measurements showed an oxygen incorporation with the TA, increasing from 54.6 at % to 63.8 at % for the as-deposited and annealed at 1000 °C films, respectively. FTIR spectra showed an increase in the Si-O-C and Si-O-Si bonds and the hydrogen and other radicals desorption. These results support the creation of radiative centers due to structural changes in the films after the thermal annealing.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140568"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Phase evolution and surface analysis of electron beam evaporated calcium and yttria-stabilized zirconia thin films","authors":"Ankit Kumar ,&nbsp;Pravin Kumar ,&nbsp;A S Dhaliwal","doi":"10.1016/j.tsf.2024.140575","DOIUrl":"10.1016/j.tsf.2024.140575","url":null,"abstract":"<div><div>The manuscript investigates the structural and morphological characteristics of thin films of calcium stabilized zirconia (CSZ, 16 mol % CaO), synthesized through electron beam deposition on silicon wafers, with a focus on the phase evolution during annealing at 800 °C. The study compares these properties with yttria stabilized zirconia (YSZ, 8 mol % Y₂O₃) thin films. Rutherford backscattering spectrometry validates film composition, with thicknesses of ∼315 nm for CSZ and ∼285 nm for YSZ. X-ray diffraction initially identifies an amorphous structure, transitioning to a cubic phase post-annealing, with average crystallite sizes of 18.07 nm for CSZ and 16.22 nm for YSZ, corroborated by Raman spectroscopy. The lattice parameters are determined using Rietveld refinement. Surface morphology is investigated through field emission scanning electron microscope and atomic force microscopy shows a reduction in surface roughness from 6.05 nm to 1.34 nm for CSZ and from 4.54 nm to 1.64 nm for YSZ post-annealing, indicating enhanced homogeneity. Elemental distribution analysis using energy dispersive X-ray spectroscopy confirms film uniformity. The study provides insights into the structural evolution and morphological characteristics of calcium stabilized zirconia thin films, particularly at the nanoscale level, offering valuable contributions to its industrial applicability.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140575"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142707003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structure and hysteresis properties of Ni/Ta nanocomposite films modified by thermomagnetic treatment","authors":"V.O. Vas'kovskiy ,&nbsp;A.A. Bykova ,&nbsp;N.A. Kulesh ,&nbsp;A.N. Gorkovenko ,&nbsp;V.N. Lepalovskij ,&nbsp;P.A. Savin ,&nbsp;N.V. Selezneva","doi":"10.1016/j.tsf.2024.140576","DOIUrl":"10.1016/j.tsf.2024.140576","url":null,"abstract":"<div><div>This work presents the results of a study on the crystal structure and hysteresis properties of nickel films (glass/Ni) and their layered composites (glass/Ni/Ta, glass/Ta/Ni/Ta) modified by thermomagnetic treatment. Using analysis of angular dependencies of coercive force, it has been shown that in the initial state all types of samples exhibit biaxial magnetic anisotropy, which is likely a result of the superposition of the \"magnetostatic\" and \"magnetoelastic\" mechanisms. We show that the thermomagnetic treatment can result in the formation of uniaxial or isotropic magnetic states, depending on the sample design.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140576"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142707001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surface texturized graphene oxide coating on Ti6Al4V by integrated femtosecond laser","authors":"Jianwei Zhai ,&nbsp;Zhou Yu ,&nbsp;Jun Hu","doi":"10.1016/j.tsf.2024.140567","DOIUrl":"10.1016/j.tsf.2024.140567","url":null,"abstract":"<div><div>Graphene oxide (GO) coating has the advantages of high specific surface area and easy functional modification, and has great application prospects in orthopedic implants. However, its poor osteogenic properties limit its application and need to be further improved. Studies have shown that periodic nanostreaks on the surface of long bone during development are beneficial to improve osteogenic properties and promote periosteal tissue formation. Therefore, based on the idea of duplex modification combining surface coating and surface texture technology, this paper uses femtosecond laser to construct periodic structure on the surface of GO coating on titanium alloy substrate, and controls the surface micro-nano morphology and chemical composition of GO coating. The surface morphology, crystal structure and chemical composition were characterized and confirmed by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR) and three-dimensional laser confocal microscopy. Using this technique, a uniform and complete GO coating is prepared and periodic nanofringes (i.e. laser-induced periodic surface structures) are formed on its surface under laser action without damaging the substrate material. In the case of a scan speed of 0.005m/s, the period changes from 924 nm to 442 nm when the laser power is increased from 0.4 W to 8W. Raman spectrum results show that the degree of graphitization increases and the disorder decreases under laser action. XPS and FTIR confirmed the removal of oxygen-containing groups and the conversion of Csp³ to Csp² in the GO coating.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140567"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Optimization of titanium alloy bipolar plate performance in proton exchange membrane water electrolysis with Cr/W/diamond-like carbon coating","authors":"Xiaoyu Gong ,&nbsp;Shaolong Wang ,&nbsp;Xiejing Luo ,&nbsp;Anqing Fu ,&nbsp;Chaofang Dong","doi":"10.1016/j.tsf.2024.140580","DOIUrl":"10.1016/j.tsf.2024.140580","url":null,"abstract":"<div><div>The operating environment for bipolar plates in proton exchange membrane water electrolysis (PEMWE) systems is highly challenging, characterized by high electrical potential, acidic pH, and elevated temperatures. Bipolar plates must possess high corrosion resistance and electrical conductivity to ensure stable and efficient system perfomance. Therefore, surface coatings are essential to decelerate oxidation on the substrate surface, preventing a significant increase in interfacial contact resistance (ICR). This investigation applied a Cr/W/diamond-like carbon (DLC) coating to titanium alloy (Ti-6Al-4 V, also known as TC4) surfaces using magnetron sputtering. The multilayer coating system was designed to enhance electrical conductivity and corrosion resistance of the bipolar plate while ensuring good coating adhesion. At potentials of 1.2 V, 1.5 V, and 1.8 V, the current densities measured during potentiostatic polarization were 0.11 μA·cm^-2, 0.19 μA·cm^-2, and 0.4 μA·cm^-2, respectively, showing a significant reduction compared to the TC4 matrix and demonstrating long-term stability. The Cr/W/DLC-coated TC4 bipolar plates exhibited an ICR of 16.98 mΩ/cm² under a contact pressure of 1.4 MPa. These results suggest that the coating provides exceptional corrosion resistance under PEMWE operating conditions while retaining electrical conductivity.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140580"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142747723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of zinc hydroxyl acetate nanosheet-assembled honeycomb-like and flower-like structures by chemical bath deposition method for the construction of hydrophobic surfaces","authors":"Rulin Dong,&nbsp;Jingyu Tan,&nbsp;Yiyi Ji,&nbsp;Zhixin Qi,&nbsp;Zhidong Chen,&nbsp;Yukai Chen","doi":"10.1016/j.tsf.2024.140569","DOIUrl":"10.1016/j.tsf.2024.140569","url":null,"abstract":"<div><div>Layered zinc hydroxyl acetate (LZHA) nanosheet-assembled honeycomb-like and flower-like structures were synthesized by a chemical bath deposition method using aqueous zinc acetate solution as the bath solution and a porous ZnO coating as the substrate. The morphology of LZHA architectures growing on the surface of the substrate depends on the type of LZHA nucleation. The homogeneous nucleation facilitates the adsorption of crumpled LZHA nanosheets generated in the solution onto the substrate surface, whereas heterogeneous nucleation promotes the formation of flat LZHA nanosheets on the substrate surface. The crumpled and flat LZHA nanosheets serving as the seeds undergo cyclic “growth-division” processes to evolve into LZHA nanosheet-assembled honeycomb-like and flower-like structures, respectively. The hierarchical architecture features of the LZHA honeycombs and flowers can be topologically inherited without any crack and collapse when converted into ZnO by calcination. The LZHA honeycomb-like and Ag nanoparticle modified ZnO flower-like structures were characterized by a scanning electron microscope, field-emission scanning electron microscope, energy dispersive X-ray spectrometer and X-ray diffractometer. The synthesized ZnO honeycomb-like and flower-like structures show excellent hydrophobic properties owning to the appropriate roughness provided by the hierarchical structures. In particular, the surface assembled by ZnO honeycombs derived from their LZHA precursors with deposition time of 4 h shows a higher water contact angle of 162.3°. In addition, the Ag nanoparticle modification on the petals of ZnO flowers results in the formation of multi-scale rough surfaces, and thus increases the water contact angle. The synthesized superhydrophobic surfaces exhibit promising applications in fields such as anti-icing, anti-corrosion and reducing fluidic drag.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140569"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Increasing the adhesion of graphene on quartz through fluorination","authors":"Espen W. Selfors ,&nbsp;Ranveig Flatabø ,&nbsp;Peter James Thomas ,&nbsp;Bodil Holst","doi":"10.1016/j.tsf.2024.140571","DOIUrl":"10.1016/j.tsf.2024.140571","url":null,"abstract":"<div><div>Graphene was the first 2D-material ever discovered, and its unique properties open up for many applications. Due to its high mechanical resistance and transparency, it has been investigated as a coating for optical devices such as windows or lenses. A particular focus has been as an anti-icing coating where graphene functionalized with fluorine atoms, so-called fluorinated graphene, has been demonstrated to inhibit ice formation. However, to function as a durable coating the adhesion between graphene and the underlying substrate must be strong. Up till now it has not been possible to deposit graphene/functionalized graphene on a transparent substrate, such as SiO₂, with strong adhesion, without an intermediate metal layer (that gradually makes it opaque). Through optical and electron microscopy observation of surfaces scratched with a sapphire tip, we show how a transparent, functionalized graphene coating with improved adhesion can be created through fluorination of graphene transferred onto a quartz substrate (<span><math><mi>α</mi></math></span>-SiO₂). The fluorination leads to an increase in adhesion of approximately 3 times compared to unfluorinated graphene adhered to the same substrate. Comparing this with reported adhesion energies for graphene on SiO₂ gives an estimated adhesion energy between 0.03<!--> <!-->J/m² and 9<!--> <!-->J/m² for graphene fluorinated on SiO₂.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140571"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142707002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Corrigendum to “A structure zone diagram including plasma-based deposition and ion etching” [Thin Solid Films 518 (2010) 4087–4090]","authors":"André Anders","doi":"10.1016/j.tsf.2024.140574","DOIUrl":"10.1016/j.tsf.2024.140574","url":null,"abstract":"","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140574"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143131390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Conventional epitaxy of NiO thin films on muscovite mica and c-Al2O3 substrates","authors":"Faezeh A․F․ Lahiji ,&nbsp;Biplab Paul ,&nbsp;Arnaud le Febvrier ,&nbsp;Per Eklund","doi":"10.1016/j.tsf.2024.140566","DOIUrl":"10.1016/j.tsf.2024.140566","url":null,"abstract":"&lt;div&gt;&lt;div&gt;Fiber-textured and epitaxial NiO thin films were deposited on Si(100), c-Al&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;, and muscovite mica(001) substrates using reactive magnetron sputtering at substrate temperatures of 300 °C and 400 °C, to investigate the effect of film thickness and substrate temperature on epitaxial growth of NiO films. The as-deposited films exhibited a face-centered cubic structure with a larger lattice constant, attributed to strain induced during the sputtering process. With an increase in substrate temperature to 400 °C, the d-spacing decreased due to strain release, approaching the NiO bulk value for the thickest film. The NiO film grown on Si(100) displayed fiber texture. On c-plane sapphire, NiO thin films exhibited twin domains and three-fold symmetry, consistent with expected crystallographic orientation relationship for NaCl-structured materials on sapphire:&lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;111&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mrow&gt;&lt;mo&gt;∥&lt;/mo&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;0001&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;msub&gt;&lt;mi&gt;l&lt;/mi&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;/msub&gt;&lt;msub&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mrow&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;mtext&gt;and&lt;/mtext&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;¯&lt;/mo&gt;&lt;/mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;/mrow&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mo&gt;∥&lt;/mo&gt;&lt;/mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mrow&gt;&lt;mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;¯&lt;/mo&gt;&lt;/mover&gt;&lt;mn&gt;010&lt;/mn&gt;&lt;/mrow&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;mi&gt;l&lt;/mi&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mrow&gt;&lt;mn&gt;01&lt;/mn&gt;&lt;mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;¯&lt;/mo&gt;&lt;/mover&gt;&lt;/mrow&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mrow&gt;&lt;mo&gt;∥&lt;/mo&gt;&lt;/mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mrow&gt;&lt;mn&gt;10&lt;/mn&gt;&lt;mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;¯&lt;/mo&gt;&lt;/mover&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;/mrow&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;A&lt;/mi&gt;&lt;mi&gt;l&lt;/mi&gt;&lt;mn&gt;2&lt;/mn&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;mn&gt;3&lt;/mn&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;. On muscovite mica(001) substrates, the observed epitaxial shows that the mechanism is conventional epitaxy, rather than van der Waals epitaxy, consistent with the epitaxial growth of the non-layered non-van-der-Waals compound NiO. The epitaxial relationship was identified as of &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;111&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mrow&gt;&lt;mo&gt;∥&lt;/mo&gt;&lt;/mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;(&lt;/mo&gt;&lt;mn&gt;001&lt;/mn&gt;&lt;mo&gt;)&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;M&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;c&lt;/mi&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt; and &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mrow&gt;&lt;mn&gt;0&lt;/mn&gt;&lt;mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;mo&gt;¯&lt;/mo&gt;&lt;/mover&gt;&lt;mn&gt;1&lt;/mn&gt;&lt;/mrow&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;N&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;O&lt;/mi&gt;&lt;mspace&gt;&lt;/mspace&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;mrow&gt;&lt;mo&gt;∥&lt;/mo&gt;&lt;/mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mn&gt;010&lt;/mn&gt;&lt;mo&gt;]&lt;/mo&gt;&lt;/mrow&gt;&lt;mrow&gt;&lt;mi&gt;M&lt;/mi&gt;&lt;mi&gt;i&lt;/mi&gt;&lt;mi&gt;c&lt;/mi&gt;&lt;mi&gt;a&lt;/mi&gt;&lt;/mrow&gt;&lt;/msub&gt;&lt;/mrow&gt;&lt;/math&gt;&lt;/span&gt;, &lt;span&gt;&lt;math&gt;&lt;mrow&gt;&lt;msub&gt;&lt;mrow&gt;&lt;mo&gt;[&lt;/mo&gt;&lt;mro","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"808 ","pages":"Article 140566"},"PeriodicalIF":2.0,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142655633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}