Thin Solid Films最新文献

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Crossed sprays forming composite thin films and heterogeneous structures for the fabrication of an organic solar cell
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-13 DOI: 10.1016/j.tsf.2025.140627
Chin-Tai Chen, Ya-Han Lee
{"title":"Crossed sprays forming composite thin films and heterogeneous structures for the fabrication of an organic solar cell","authors":"Chin-Tai Chen,&nbsp;Ya-Han Lee","doi":"10.1016/j.tsf.2025.140627","DOIUrl":"10.1016/j.tsf.2025.140627","url":null,"abstract":"<div><div>Nanomaterials and composite thin films at nanometer scales have been studied over decades as electron/hole transport layers and heterogeneous structures of organic solar cells using different manufacturing methods such as blade coating, spin coating, inkjet printing, and spray coating. The optoelectronic performances for fabricating thin-film devices on glass substrates involve the solid nanofilms' electrical and optical properties. Recently, research on composite nanofilms has progressed in pursuit of further enhancing these properties. This paper reports a crossed-spray deposition method to implement it using two atomizers. With the crossed sprays of hole transport layers (HTL) and photoactive layers (PL), the structured nanofilms with multiple components were produced with a higher electrical conductivity and optical absorptance than that formed by a single spray only. The experimental results showed that an organic solar cell comprising the HTL and PL from the crossed sprays was produced with better performances than the single spray. Using crossed sprays employing the composite deposition method, the layer interfaces of the spray deposition films with a high series resistance still need to be reduced to improve the device performance, posing a challenge to the uniform film-forming process.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"814 ","pages":"Article 140627"},"PeriodicalIF":2.0,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143427712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of pulse width on the mechanical properties and high-temperature steam oxidation resistance of Cr coatings deposited by high-power impulse magnetron sputtering
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-11 DOI: 10.1016/j.tsf.2025.140626
Ding Chen , Wei Dai , Daoxuan Liang , Qimin Wang , Jun Yan
{"title":"Effect of pulse width on the mechanical properties and high-temperature steam oxidation resistance of Cr coatings deposited by high-power impulse magnetron sputtering","authors":"Ding Chen ,&nbsp;Wei Dai ,&nbsp;Daoxuan Liang ,&nbsp;Qimin Wang ,&nbsp;Jun Yan","doi":"10.1016/j.tsf.2025.140626","DOIUrl":"10.1016/j.tsf.2025.140626","url":null,"abstract":"<div><div>This study investigates the influence of pulse width parameters on the structural characteristics, mechanical properties, and high-temperature steam oxidation resistance of Cr coatings deposited on Zr-4 alloy using high-power impulse magnetron sputtering (HiPIMS). The findings reveal that all Cr coatings deposited by HiPIMS exhibit a (200) crystal plane preferential growth. Cr coatings deposited with narrow pulse widths possess dense structures with minimal columnar growth. As pulse width increases, the fiber texture of the coating becomes more pronounced, leading to a gradual decrease in hardness and scratch resistance. During steam oxidation at 1200 °C, Cr coatings deposited with wider pulse widths facilitate O diffusion due to enhanced columnar growth. This results in complete oxidation at an early stage, forming a dense oxide layer that impedes further inward O diffusion and outward Zr diffusion. In contrast, Cr coatings deposited with narrower pulse widths effectively slow down internal O diffusion owing to their denser structure. Consequently, a dense oxide layer forms on the surface, further restricting oxygen ingress. However, the remaining Cr layer fails to prevent the outward diffusion of Zr, resulting in the formation of ZrO<sub>2</sub> channels in a lattice pattern, which exacerbates the oxidation of the Zr substrate.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"814 ","pages":"Article 140626"},"PeriodicalIF":2.0,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143422701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Raman spectra and Seebeck coefficient of Cu2ZnSnS4 nanocrystals/PEDOT:PSS composite films
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-11 DOI: 10.1016/j.tsf.2025.140618
Yevhenii Havryliuk , Volodymyr Dzhagan , Oleksandra Ivakhno-Tsehelnyk , Anatolii Karnaukhov , Julia Hann , Oleksandr Selyshchev , Dietrich R.T. Zahn
{"title":"Raman spectra and Seebeck coefficient of Cu2ZnSnS4 nanocrystals/PEDOT:PSS composite films","authors":"Yevhenii Havryliuk ,&nbsp;Volodymyr Dzhagan ,&nbsp;Oleksandra Ivakhno-Tsehelnyk ,&nbsp;Anatolii Karnaukhov ,&nbsp;Julia Hann ,&nbsp;Oleksandr Selyshchev ,&nbsp;Dietrich R.T. Zahn","doi":"10.1016/j.tsf.2025.140618","DOIUrl":"10.1016/j.tsf.2025.140618","url":null,"abstract":"<div><div>Cu<sub>2</sub>ZnSnS<sub>4</sub> (CZTS), especially in the form of nanocrystals (NCs), is very promising as absorber material for thin-film solar cells. Recent studies on CZTS showed thermoelectric (TE) properties as well, making this material attractive for hybrid energy harvesting applications. Here, we investigate composites of CZTS NCs with poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), a widely used conductive polymer with TE properties, which potentially may help to improve the inherently low electrical conductivity of NC films. We focus on the investigation of the Seebeck coefficient of pure PEDOT:PSS and CZTS NCs/PEDOT:PSS composites subject to thermal or flash lamp annealing (FLA). The surface morphology of the obtained films was studied using atomic force microscopy, while structural changes in both the CZTS NCs and the polymer were monitored simultaneously using Raman spectroscopy. For both FLA and thermal annealing, the composite films show improved Seebeck coefficients (20–200 μV/K) compared to pure PEDOT:PSS films (10–18 μV/K) or NCs films (10–30 μV/K).</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"815 ","pages":"Article 140618"},"PeriodicalIF":2.0,"publicationDate":"2025-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143480364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization and comparison of hydrogenated and unhydrogenated amorphous boron carbon nitride films deposited via radio frequency magnetron sputtering
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-10 DOI: 10.1016/j.tsf.2025.140624
Ryu Taniguchi, Yusuke Hayashi, Tatsuya Nishida, Yoshiharu Enta, Yushi Suzuki, Yasuyuki Kobayashi, Hideki Nakazawa
{"title":"Characterization and comparison of hydrogenated and unhydrogenated amorphous boron carbon nitride films deposited via radio frequency magnetron sputtering","authors":"Ryu Taniguchi,&nbsp;Yusuke Hayashi,&nbsp;Tatsuya Nishida,&nbsp;Yoshiharu Enta,&nbsp;Yushi Suzuki,&nbsp;Yasuyuki Kobayashi,&nbsp;Hideki Nakazawa","doi":"10.1016/j.tsf.2025.140624","DOIUrl":"10.1016/j.tsf.2025.140624","url":null,"abstract":"<div><div>We have prepared amorphous boron carbon nitride (BCN) and hydrogenated amorphous BCN (BCN:H) films via radio frequency magnetron sputtering without and with H<sub>2</sub> and investigated the effects of hydrogen on the properties of the BCN and BCN:H films. The carbon content of the BCN:H films increased slightly with increasing H<sub>2</sub> flow ratio. Raman measurements clarified that the hydrogen dilution prevented the formation of sp<sup>2</sup> carbon clusters. The Fourier transform infrared absorption peaks corresponding to C<img>H<sub>n</sub> stretching vibration modes increased gradually with the hydrogen flow ratio. The optical bandgap and electrical resistivity of the BCN:H films were larger than those of the BCN films. Additionally, the optical bandgap and electrical resistivity of the BCN:H films increased as the H<sub>2</sub> flow ratio increased, probably due to a decrease in sp<sup>2</sup> C<img>C bonding caused by the introduction of hydrogen during deposition, as shown by X-ray photoelectron spectroscopy. It was found that the BCN:H film exhibited a higher resistivity than the BCN film under almost the same optical bandgap. This result suggests that introducing hydrogen reduces defect density in the BCN:H film. The critical load decreased with the H<sub>2</sub> flow ratio owing to increased internal stress. The tribological properties of the BCN:H films were improved with the H<sub>2</sub> flow ratio. The root-mean-square roughness of the films, as estimated from atomic force microscope images, decreased with an increase in the hydrogen flow ratio.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"813 ","pages":"Article 140624"},"PeriodicalIF":2.0,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143403645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of the tribological behavior of diamond-like carbon coatings applied to AISI M2 high-speed steel
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-09 DOI: 10.1016/j.tsf.2025.140622
Jorge Wanderson Barbosa , Paulo Sérgio Martins , Ernane Rodrigues da Silva , Elhadji Cheikh Talibouya Ba , Pedro Miraglia Firpe , Rubens Lucas de Freitas Filho , Soraia Sandra Pires , Pedro Américo Almeida Magalhães Júnior , André Barros de Mello Oliveira
{"title":"Analysis of the tribological behavior of diamond-like carbon coatings applied to AISI M2 high-speed steel","authors":"Jorge Wanderson Barbosa ,&nbsp;Paulo Sérgio Martins ,&nbsp;Ernane Rodrigues da Silva ,&nbsp;Elhadji Cheikh Talibouya Ba ,&nbsp;Pedro Miraglia Firpe ,&nbsp;Rubens Lucas de Freitas Filho ,&nbsp;Soraia Sandra Pires ,&nbsp;Pedro Américo Almeida Magalhães Júnior ,&nbsp;André Barros de Mello Oliveira","doi":"10.1016/j.tsf.2025.140622","DOIUrl":"10.1016/j.tsf.2025.140622","url":null,"abstract":"<div><div>Amorphous carbon coatings, known as Diamond-like Carbon (DLC), are thin coatings comprising amorphous carbon with sp<sup>2</sup> (graphite) and sp<sup>3</sup> (diamond) bonds in varying proportions. These coatings are characterized by their high hardness and chemical inertness. Their application aims to effectively enhance the chemical, physical, and mechanical properties of conventional metals used as substrates, providing protection against abrasive and adhesive wear. The development of other DLC coatings is being studied for application under various conditions and on different non-ferrous metal alloys. This study proposes to evaluate and characterize DLC (Type A) and DLC with CrN interlayer (Type B) coatings using techniques such as Raman spectroscopy, X-ray Diffraction, Rockwell C adhesion test, and micro-abrasive wear test. Results showed that the total thickness of the Type B coating was approximately twice that of the Type A coating. Both showed a DLC layer of the a-C:H class. Comparing the crystallinity spectra, a higher level of amorphization was observed in the Type B DLC. In the adhesion test, classes HF2 and HF1, based on VDI 3198 standard, were assigned to the Type A and Type B coatings, respectively. Analyzing the cutting tools, changes in the surface texture on the rake face were observed, where the feed marks were completely covered when the Type B coating was applied. In the micro-abrasive wear test, it was found that the wear coefficients obtained with the coatings represented only 27 % of the value obtained on the high-speed steel substrate, which shows a difference of 63 % in the wear coefficient.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"813 ","pages":"Article 140622"},"PeriodicalIF":2.0,"publicationDate":"2025-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143388388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The comparative study of citrate-sulphate bath with and without ammonium ion and its effect on electrodeposition and selected properties of ternary Zn-Fe-Mo alloy coatings for corrosion protection
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-08 DOI: 10.1016/j.tsf.2025.140623
Hafiz Muhammad Shoaib , Anna Mazur-Nowacka , Katarzyna Winiarska , Agnieszka Laszczyńska , Andrzej Żak , Juliusz Winiarski
{"title":"The comparative study of citrate-sulphate bath with and without ammonium ion and its effect on electrodeposition and selected properties of ternary Zn-Fe-Mo alloy coatings for corrosion protection","authors":"Hafiz Muhammad Shoaib ,&nbsp;Anna Mazur-Nowacka ,&nbsp;Katarzyna Winiarska ,&nbsp;Agnieszka Laszczyńska ,&nbsp;Andrzej Żak ,&nbsp;Juliusz Winiarski","doi":"10.1016/j.tsf.2025.140623","DOIUrl":"10.1016/j.tsf.2025.140623","url":null,"abstract":"<div><div>This study evaluates Zn-Fe-Mo alloy coatings, electrodeposited from citrate-sulphate baths with ammonium ions, focusing on how current density correlates with coating properties for protecting carbon steel from corrosion. Electroplating in a bath containing (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> salt takes place under less negative reduction potentials which resulted in higher content of Fe (up to 12 wt.%) and Mo (up to 5 wt.%). Regardless of the presence or absence of ammonium ions, Fe and Mo contents decreased with rising deposition current density. Deposits from both types of baths were grayish and powdery on the surface at lower current densities (10–15 mA cm<sup>−2</sup>) while at the higher ones (20–25 mA cm<sup>−2</sup>) they were smooth and fine. It was accompanied by a reduction of surface roughness from 0.8 to 0.04 µm. Coatings deposited at 20 mA cm<sup>−2</sup> were built of columnar beads formed by 20–40 nm crystallites. Deposits were highly textured in the presence of (NH<sub>4</sub>)<sub>2</sub>SO<sub>4</sub> while those obtained in Na<sub>2</sub>SO<sub>4</sub> containing bath were not. Besides pure Zn and Fe phases, possible iron-zinc intermetallic with stoichiometry close to Fe<sub>22</sub>Zn<sub>78</sub>, Fe<sub>11</sub>Zn<sub>40</sub> or FeZn<sub>10.98</sub> were found. Increasing the electrodeposition current density from 10 to 25 mA cm<sup>−2</sup> caused a rise in the corrosion resistance for both types of coatings. More specifically, ammonium ions favour the fabrication of more noble deposits with the lowest corrosion current densities and the highest charge transfer resistances after 24 h exposure in 0.5 M solution of NaCl.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"813 ","pages":"Article 140623"},"PeriodicalIF":2.0,"publicationDate":"2025-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143378379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wafer-scale aluminium nitride nanostructures for solar-blind ultra-violet detection
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-08 DOI: 10.1016/j.tsf.2025.140619
Wusi Zhang , Feijie Chen , Difei Xue , Chang Liu , Kai Peng , Chenlong Chen , Peiwen Lv
{"title":"Wafer-scale aluminium nitride nanostructures for solar-blind ultra-violet detection","authors":"Wusi Zhang ,&nbsp;Feijie Chen ,&nbsp;Difei Xue ,&nbsp;Chang Liu ,&nbsp;Kai Peng ,&nbsp;Chenlong Chen ,&nbsp;Peiwen Lv","doi":"10.1016/j.tsf.2025.140619","DOIUrl":"10.1016/j.tsf.2025.140619","url":null,"abstract":"<div><div>Ultra-wide bandgap semiconductor aluminum nitride (AlN) detectors have attracted much attention in recent years. As a next-generation semiconductor material, AlN crystals have shown advantages in many fields, attracting several teams to investigate preparation methods to prepare high-quality crystals. In this paper, Solar-blind photodetectors (SBPDs) based on metal-semiconductor-metal single-crystal AlN films were prepared by nitriding on c-plane sapphire using chemical vapor deposition (CVD). The prepared AlN SBPDs showed a responsivity of 11 mA/W, a fast-rising and falling response time, and a detective of 2.53 × 10<sup>11</sup> Jones. Nitriding through sapphire is a cost-effective way to grow AlN at high temperatures and can grow wafer-scale AlN, demonstrating the advantages of AlN growth.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"813 ","pages":"Article 140619"},"PeriodicalIF":2.0,"publicationDate":"2025-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143394753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molybdenum nitride thin films synthesized by microwave electron cyclotron resonance – Assisted reactive pulsed laser deposition
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-07 DOI: 10.1016/j.tsf.2025.140621
Enrique Camps , E. Campos-González , C. Rivera-Rodríguez , G. Quiñones-Galván , A. Conde-Gallardo
{"title":"Molybdenum nitride thin films synthesized by microwave electron cyclotron resonance – Assisted reactive pulsed laser deposition","authors":"Enrique Camps ,&nbsp;E. Campos-González ,&nbsp;C. Rivera-Rodríguez ,&nbsp;G. Quiñones-Galván ,&nbsp;A. Conde-Gallardo","doi":"10.1016/j.tsf.2025.140621","DOIUrl":"10.1016/j.tsf.2025.140621","url":null,"abstract":"<div><div>Molybdenum nitride thin films were deposited using a hybrid plasma system. This system results from the combination of a stationary continuous plasma, created by a microwave electron cyclotron resonance discharge in nitrogen atmosphere and a pulsed plasma produced by the laser ablation of a molybdenum metallic target. The plasma parameters were measured by Langmuir probes, and the type of chemically excited species were detected by optical emission spectroscopy. The results indicate that the hybrid plasma is more efficient than the laser ablation or microwave discharge processes alone. X-ray diffraction showed the presence of the δ-MoN (hexagonal) phase with a preferred orientation that changes depending on the experimental conditions. Films deposited using the laser ablation process without the presence of the microwave plasma were mainly composed by metallic molybdenum, as seen by X-Ray Diffraction. X-ray photoelectron spectra measurements showed that the nitrogen content in the samples grown by the hybrid plasma process is significantly higher than in those grown with the conventional laser ablation process. The hardness values ​​of the MoN films grown by the hybrid system increased from 19 to 24 GPa as a function of the mean kinetic energy of the ions formed in the laser ablation plasma. All the films show superconductivity, with a Tc-onset from 5.1 to 7.2 K, depending on the nitrogen content.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"813 ","pages":"Article 140621"},"PeriodicalIF":2.0,"publicationDate":"2025-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143377459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SiC thin films: Nanosecond pulsed laser-deposition via Digital Twin approach and atom probe tomography characterizations
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-05 DOI: 10.1016/j.tsf.2025.140620
H G Prashantha Kumar , Sree Harsha Choutapalli , Nilesh J Vasa , Tiju thomas , Srinivasa Rao Bakshi
{"title":"SiC thin films: Nanosecond pulsed laser-deposition via Digital Twin approach and atom probe tomography characterizations","authors":"H G Prashantha Kumar ,&nbsp;Sree Harsha Choutapalli ,&nbsp;Nilesh J Vasa ,&nbsp;Tiju thomas ,&nbsp;Srinivasa Rao Bakshi","doi":"10.1016/j.tsf.2025.140620","DOIUrl":"10.1016/j.tsf.2025.140620","url":null,"abstract":"<div><div>This research presents the synthesis of silicon carbide (SiC) thin films using a nanosecond pulsed laser deposition method, combined with a Level -2 Digital Twin approach for real-time process optimization. Various target precursors were employed to fabricate SiC thin films, and the influence of these precursors on the material properties was investigated. The Digital Twin model provided dynamic real-time feedback, allowing precise control over the deposition parameters, improving consistency and identical windows throughout. Such deposited thin film exhibited an average surface roughness (Ra) and nanoindentation hardness measured in the range of 2 nm to 5 nm and range of 32 to 41 GPa for the SiC thin film respectively. Transmission Electron Microscopic (TEM) characterisations on lamellar thin film specimens revealed 558.9 ± 10 nm and 593.62 ± 10 nm thick film deposition for Spark Plasma Sintered (SPS) and Reaction Bonded (RB) SiC thin films followed by average of Si ∼ 50 at. %, C ∼ 48. at. % with the traces of O ∼ 0.43 at.% elemental composition distributions for both films analysed through Atom Probe Tomography (APT) reconstructions and reveals the impurities concentrations aluminium (Al), Nitrogen (N), Vanadium (V) &amp; Potassium (P) in both films with additional B at.% elements in reaction bonded SiC alone. Further, the impact of laser irradiation was witnessed in terms of change in resistance values attributed to laser assist activation of inherited and substitutional impurities in thin films with a scale of respective impurity concentrations.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"813 ","pages":"Article 140620"},"PeriodicalIF":2.0,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143351382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of wettability and antimicrobial activity of Ti-Cu and Ti-Ag thin film metallic glasses coated on the surface of 316L, CoCrW, Ti6Al4V alloy substrates produced by selective laser melting
IF 2 4区 材料科学
Thin Solid Films Pub Date : 2025-02-01 DOI: 10.1016/j.tsf.2025.140605
Çetin Çimen , Mehmet Karakan , Didem Özgür , Ezgi Pelin Yıldız
{"title":"Investigation of wettability and antimicrobial activity of Ti-Cu and Ti-Ag thin film metallic glasses coated on the surface of 316L, CoCrW, Ti6Al4V alloy substrates produced by selective laser melting","authors":"Çetin Çimen ,&nbsp;Mehmet Karakan ,&nbsp;Didem Özgür ,&nbsp;Ezgi Pelin Yıldız","doi":"10.1016/j.tsf.2025.140605","DOIUrl":"10.1016/j.tsf.2025.140605","url":null,"abstract":"<div><div>This study includes examining the production of 316 L, CoCrW and Ti6Al4 V base materials using the selective laser melting method and investigating the properties of Ti-Cu and Ti-Ag thin film metallic glasses (TFMG) coated on the surfaces of these samples. Ti-Cu and Ti-Ag coatings were prepared by co-sputtering Ti-Cu and Ti-Ag targets in Argon gas plasma. Characterization of TFMG is focused on examining surface microstructure and physicochemical properties. Optical profilometry, X-ray Diffraction, Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy and Atomic Force Microscopy analyzes were performed to determine structural features. Wettability and antimicrobial activity were also evaluated. The results demonstrated that Ti-Cu coatings, with a water contact angle ranging from 27.6° to 30.31°, and Ti-Ag coatings, with a contact angle between 7.62° and 9.68°, exhibit hydrophilic surfaces. Furthermore, they show high antimicrobial activity against various bacterial species, consistent with previous studies. However, variations in effect were observed among yeast strains, with <em>Candida non-albicans</em> species showing greater resistance due to their biofilm formation and resistance to metal ions. In contrast, Ti-Cu and Ti-Ag coatings displayed strong antifungal activity against <em>Candida albicans</em>, indicating potential suitability for clinical applications such as catheters and surgical implants. Despite their high antimicrobial efficacy, the limited effects on certain microorganisms underscore the need for more comprehensive evaluations under various conditions and long-term in vivo studies.</div></div>","PeriodicalId":23182,"journal":{"name":"Thin Solid Films","volume":"811 ","pages":"Article 140605"},"PeriodicalIF":2.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143154236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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