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Quasi-1D NbTe4 for Broadband Pulse Generation from 1.0 to 3.0 μm: Bridging the Near- and Mid-Infrared.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-10 DOI: 10.3390/nano15060424
Zian Cai, Wenyao Zhang, Qi Kang, Hongfu Huang, Xin Xiang, Shunbin Lu, Qiao Wen
{"title":"Quasi-1D NbTe<sub>4</sub> for Broadband Pulse Generation from 1.0 to 3.0 μm: Bridging the Near- and Mid-Infrared.","authors":"Zian Cai, Wenyao Zhang, Qi Kang, Hongfu Huang, Xin Xiang, Shunbin Lu, Qiao Wen","doi":"10.3390/nano15060424","DOIUrl":"10.3390/nano15060424","url":null,"abstract":"<p><p>Quasi-one-dimensional (quasi-1D) transition metal chalcogenides (TMCs), a subclass of low-dimensional materials, have attracted significant attention due to their unique optical and electronic properties, making them promising candidates for nonlinear photonics. In this work, NbTe<sub>4</sub>, a quasi-1D transition metal tetrachalcogenide, was synthesized and employed for the first time as a broadband saturable absorber (SA) for pulsed laser applications. The nonlinear optical (NLO) properties of NbTe<sub>4</sub> were systematically characterized at 1.0 μm, 2.0 μm, and 3.0 μm, revealing saturation intensities of 59.53 GW/cm<sup>2</sup>, 14 GW/cm<sup>2</sup>, and 6.8 MW/cm<sup>2</sup>, with corresponding modulation depths of 17.4%, 5.3%, and 21.5%. Utilizing NbTe<sub>4</sub>-SA, passively Q-switched (PQS) pulses were successfully generated in the 1.0 μm and 2.0 μm bands, achieving pulse durations of 86 ns and 2 μs, respectively. Furthermore, stable mode-locked operation was demonstrated in an Er-doped fluoride fiber laser at 3.0 μm, yielding a pulse duration of 19 ps. These results establish NbTe<sub>4</sub> as a highly promising broadband SA material for next-generation ultrafast photonic devices and pave the way for the development of other quasi-1D materials in nonlinear optics.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11945161/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Chemical Deformation of a Thermally Cured Polyimide Film Surface into Neutral 1,2,4,5-Benzentetracarbonyliron and 4,4'-Oxydianiline to Remarkably Enhance the Chemical-Mechanical Planarization Polishing Rate.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-10 DOI: 10.3390/nano15060425
Man-Hyup Han, Hyun-Sung Koh, Il-Haeng Heo, Myung-Hoe Kim, Pil-Su Kim, Min-Uk Jeon, Min-Ji Kim, Woo-Hyun Jin, Kyoo-Chul Cho, Jinsub Park, Jea-Gun Park
{"title":"The Chemical Deformation of a Thermally Cured Polyimide Film Surface into Neutral 1,2,4,5-Benzentetracarbonyliron and 4,4'-Oxydianiline to Remarkably Enhance the Chemical-Mechanical Planarization Polishing Rate.","authors":"Man-Hyup Han, Hyun-Sung Koh, Il-Haeng Heo, Myung-Hoe Kim, Pil-Su Kim, Min-Uk Jeon, Min-Ji Kim, Woo-Hyun Jin, Kyoo-Chul Cho, Jinsub Park, Jea-Gun Park","doi":"10.3390/nano15060425","DOIUrl":"10.3390/nano15060425","url":null,"abstract":"<p><p>The rapid advancement of 3D packaging technology has emerged as a key solution to overcome the scaling-down limitation of advanced memory and logic devices. Redistribution layer (RDL) fabrication, a critical process in 3D packaging, requires the use of polyimide (PI) films with thicknesses in the micrometer range. However, these polyimide films present surface topography variations in the range of hundreds of nanometers, necessitating chemical-mechanical planarization (CMP) to achieve nanometer-level surface flatness. Polyimide films, composed of copolymers of pyromellitimide and diphenyl ether, possess strong covalent bonds such as C-C, C-O, C=O, and C-N, leading to inherently low polishing rates during CMP. To address this challenge, the introduction of Fe(NO<sub>3</sub>)<sub>3</sub> into CMP slurries has been proposed as a polishing rate accelerator. During CMP, this Fe(NO<sub>3</sub>)<sub>3</sub> deformed the surface of a polyimide film into strongly positively charged 1,2,4,5-benzenetetracarbonyliron and weakly negatively charged 4,4'-oxydianiline (ODA). The chemically dominant polishing rate enhanced with the concentration of the Fe(NO<sub>3</sub>)<sub>3</sub> due to accelerated surface interactions. However, higher Fe(NO<sub>3</sub>)<sub>3</sub> concentrations reduce the attractive electrostatic force between the positively charged wet ceria abrasives and the negatively charged deformed surface of the polyimide film, thereby decreasing the mechanically dominant polishing rate. A comprehensive investigation of the chemical and mechanical polishing rate dynamics revealed that the optimal Fe(NO<sub>3</sub>)<sub>3</sub> concentration to achieve the maximum polyimide film removal rate was 0.05 wt%.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11944291/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Efficiency SERS of 4-Mercaptobenzoic Acid and Biphenyl-4,4'-Dithiol via Nanoparticle-on-Mirror Plasmonic Nanocavities.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-09 DOI: 10.3390/nano15060421
Wangze Li, Yifan Zhu, Jinze Li, Lei Guo, Xilin Zhou, Xin Xie, Zhengkun Fu, Huan Chen, Hairong Zheng
{"title":"High-Efficiency SERS of 4-Mercaptobenzoic Acid and Biphenyl-4,4'-Dithiol via Nanoparticle-on-Mirror Plasmonic Nanocavities.","authors":"Wangze Li, Yifan Zhu, Jinze Li, Lei Guo, Xilin Zhou, Xin Xie, Zhengkun Fu, Huan Chen, Hairong Zheng","doi":"10.3390/nano15060421","DOIUrl":"10.3390/nano15060421","url":null,"abstract":"<p><p>Surface-enhanced Raman scattering (SERS) technology has important applications in many fields, such as biomedicine, environmental monitoring, and food safety. Plasmonic nanocavities have the ability to superdiffract localized light and enhance light-matter interactions. As a key SERS active substrate, research on plasmonic nanocavities has made significant progress regarding the enhancement mechanism, the utilization of hotspots for the detection of specific molecular groups, and practical applications. However, challenges related to improving the enhancement factor of nanocavity SERS, enhancing the stability and reproducibility of hotspots, and enabling the detection of single-molecule layers remain. In this study, we adopt a bottom-up approach to construct a silver microplate-molecule-multi-sized silver nanosphere nanoparticle-on-mirror (NPoM) nanocavity and achieve the efficient stable enhancement of Raman scattering from 4-mercaptobenzoic acid and biphenyl-4,4'-dithiol molecules via the electromagnetic mechanism. By characterizing the fabricated nanocavity using dark-field scattering and micro-confocal Raman scattering, we observed that the Raman scattering intensity in the NPoM nanocavity was enhanced by a factor of 10<sup>3</sup> compared to that of individual silver nanospheres. Furthermore, we achieved the efficient stabilization of SERS by precisely tuning the size of the silver nanospheres to match their resonance frequency with the Raman shift of the target molecules. This approach offers a valuable reference for the detection of various single-molecule layers and demonstrates significant potential for applications in biosensing and chemical analysis.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11945916/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative Assessment of the Impacts of Wildland-Urban Interface Fire Ash on Growth of the Diatom Thalassiosira weissflogii.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-09 DOI: 10.3390/nano15060422
Talal Alshehri, Amar Yasser Jassim, Bo Cai, Tammi L Richardson, Mohammed Baalousha
{"title":"Comparative Assessment of the Impacts of Wildland-Urban Interface Fire Ash on Growth of the Diatom <i>Thalassiosira weissflogii</i>.","authors":"Talal Alshehri, Amar Yasser Jassim, Bo Cai, Tammi L Richardson, Mohammed Baalousha","doi":"10.3390/nano15060422","DOIUrl":"10.3390/nano15060422","url":null,"abstract":"<p><p>Fires at the wildland-urban interface (WUI) result in the release of ash into the atmosphere that can be transported for long distances and deposited on land and in oceans. Wildfire ash has the potential to increase phytoplankton biomass in the open ocean by providing both major nutrients and trace metals. However, fires that originate at the WUI contain potentially toxic concentrations of metals such as Ti, Cr, Cu, Pb, and Zn, especially in coastal oceans close to WUI fires, where ash deposition rates are high. Here, we investigated the impact of fire ash from different sources originating from vegetation, structures, and vehicles on growth of the diatom <i>Thalassiosira weissflogii</i> (<i>T. weissflogii</i>). The diatom was exposed to ash suspensions containing equimolar concentrations of 10 and 50 µM Fe. The concentration of potentially toxic metals (e.g., Ti, Cu, and Zn) in the exposure suspensions decreased following the order vehicle ash suspension > structural ash suspension > vegetation ash suspension. Growth rates (GR) of <i>T. weissflogii</i> were between 0.44 d<sup>-1</sup> and 0.52 d<sup>-1</sup> in the controls, and varied with ash types, following the order vegetation (GR = 0.40 d<sup>-1</sup> to 0.48 d<sup>-1</sup>) > vehicle (GR = 0.06 d<sup>-1</sup> to 0.46 d<sup>-1</sup>) > structure (GR = 0.02 d<sup>-1</sup> to 0.31 d<sup>-1</sup>) ash. Two ash samples (A 131 and A136) completely inhibited the growth of <i>T. weissflogii</i>, possibly due to high Ti, Cu, and Zn concentrations in the form of (nano)particles. Overall, this study showed that structural and vehicle ash, with high concentrations of potentially toxic metals, significantly suppress the growth of <i>T. weissflogii</i>, whereas vegetation ash with high concentrations of Fe and Mn but low concentrations of potentially toxic metals had no significant beneficial or suppressive effect. High concentrations of the metals Ti, Cu, and Zn in the form of nano(particles) in structural and vehicle ash are possible sources of toxicity to diatom growth. This study provides valuable insights into the potential impacts of WUI fires on aquatic ecosystems and can inform management strategies aimed at reducing these impacts.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11944898/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polycarboxylate Superplasticizer-Modified Graphene Oxide: Dispersion and Performance Enhancement in Cement Paste.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-08 DOI: 10.3390/nano15060419
Haiming Zhang, Xingyu Gan, Zeyu Lu, Laibo Li, Lingchao Lu
{"title":"Polycarboxylate Superplasticizer-Modified Graphene Oxide: Dispersion and Performance Enhancement in Cement Paste.","authors":"Haiming Zhang, Xingyu Gan, Zeyu Lu, Laibo Li, Lingchao Lu","doi":"10.3390/nano15060419","DOIUrl":"10.3390/nano15060419","url":null,"abstract":"<p><p>Graphene oxide (GO) significantly enhances cement hydration at the nanoscale; however, its tendency to complex and agglomerate with Ca<sup>2</sup>⁺ in cement paste remains an unresolved issue. To improve the dispersibility and enhance the reinforcing effect of GO in cement paste, polycarboxylate (PC) superplasticizer was used to disperse GO (PC@GO). This study uniquely divided PC into two parts, with one modifying GO and the other acting as a water-reducing agent, to explore the effects on GO dispersion and analyze the rheological, carbon emission, mechanical, and hydration properties of cement paste. The experimental results show that the dispersion of GO modified by PC was improved, resulting in a significant enhancement in the performance of the cement paste containing PC@GO. The flexural and compressive strength of cement paste containing PC@GO<sub>4</sub> cured for 7 days increased by 23.7% and 12.6%, respectively, meanwhile, the carbon-to-strength ratio (CI) decreased by 14.8%. In addition, the hydration acceleration period shortened by 7.50%, and the water absorption and porosity of the cement paste containing PC@GO<sub>4</sub> decreased by 35.2% and 45.3%, respectively. Incorporating PC@GO into cement paste significantly enhances the dispersion of GO, substantially improves its mechanical properties, and positions it as a promising solution for the development of high-performance cementitious materials.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11946404/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Advances in Nanostructured Conversion-Type Cathodes: Fluorides and Sulfides.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-08 DOI: 10.3390/nano15060420
Mobinul Islam, Md Shahriar Ahmed, Sua Yun, Basit Ali, Hae-Yong Kim, Kyung-Wan Nam
{"title":"Recent Advances in Nanostructured Conversion-Type Cathodes: Fluorides and Sulfides.","authors":"Mobinul Islam, Md Shahriar Ahmed, Sua Yun, Basit Ali, Hae-Yong Kim, Kyung-Wan Nam","doi":"10.3390/nano15060420","DOIUrl":"10.3390/nano15060420","url":null,"abstract":"<p><p>This review paper explores the emerging field of conversion cathode materials, which hold significant promises for advancing the performance of lithium-ion (LIBs) and lithium-sulfur batteries (LSBs). Traditional cathode materials of LIBs, such as lithium cobalt oxide, have reached their limits in terms of energy density and capacity, driving the search for alternatives that can meet the increasing demands of modern technology, including electric vehicles and renewable energy systems. Conversion cathodes operate through a mechanism involving complete redox reactions, transforming into different phases, which enables the storage of more lithium ions and results in higher theoretical capacities compared to conventional intercalation materials. This study examines various conversion materials, including metal oxides, sulfides, and fluorides, highlighting their potential to significantly enhance energy density. Despite their advantages, conversion cathodes face numerous challenges, such as poor conductivity, significant volume changes during cycling, and issues with reversibility and stability. This review discusses current nanoengineering strategies employed to address these challenges, including nano structuring, composite formulation, and electrolyte optimization. By assessing recent research and developments in conversion cathode technology, this paper aims to provide a comprehensive overview of their potential to revolutionize lithium-ion batteries and contribute to the future of energy storage solutions.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11946122/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Mobility Tellurium Thin-Film Transistor: Oxygen Scavenger Effect Induced by a Metal-Capping Layer.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-08 DOI: 10.3390/nano15060418
Seung-Min Lee, Seong Cheol Jang, Ji-Min Park, Jaewon Park, Nayoung Choi, Kwun-Bum Chung, Jung Woo Lee, Hyun-Suk Kim
{"title":"High-Mobility Tellurium Thin-Film Transistor: Oxygen Scavenger Effect Induced by a Metal-Capping Layer.","authors":"Seung-Min Lee, Seong Cheol Jang, Ji-Min Park, Jaewon Park, Nayoung Choi, Kwun-Bum Chung, Jung Woo Lee, Hyun-Suk Kim","doi":"10.3390/nano15060418","DOIUrl":"10.3390/nano15060418","url":null,"abstract":"<p><p>With the ongoing development of electronic devices, there is an increasing demand for new semiconductors beyond traditional silicon. A key element in electronic circuits, complementary metal-oxide semiconductor (CMOS), utilizes both n-type and p-type semiconductors. While the advancements in n-type semiconductors have been substantial, the development of high-mobility p-type semiconductors has lagged behind. Recently, tellurium (Te) has been recognized as a promising candidate due to its superior electrical properties and the capability for large-area deposition via vacuum processes. In this work, an innovative approach involving the addition of a metal-capping layer onto Te thin-film transistors (TFTs) is proposed, which significantly enhances their electrical characteristics. In particular, the application of an indium (In) metal-capping layer has led to a dramatic increase in the field-effect mobility of Te TFTs from 2.68 to 33.54 cm<sup>2</sup>/Vs. This improvement is primarily due to the oxygen scavenger effect, which effectively minimizes oxidation and eliminates oxygen from the Te layer, resulting in the production of high-quality Te thin films. This progress in high-mobility p-type semiconductors is promising for the advancement of high-performance electronic devices in various applications and industries.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11945103/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the Current Conduction and Interface Passivation of Graphene-Insulator-Silicon Solar Cells.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-08 DOI: 10.3390/nano15060416
Hei Wong, Jieqiong Zhang, Jun Liu, Muhammad Abid Anwar
{"title":"On the Current Conduction and Interface Passivation of Graphene-Insulator-Silicon Solar Cells.","authors":"Hei Wong, Jieqiong Zhang, Jun Liu, Muhammad Abid Anwar","doi":"10.3390/nano15060416","DOIUrl":"10.3390/nano15060416","url":null,"abstract":"<p><p>Interface-passivated graphene/silicon Schottky junction solar cells have demonstrated promising features with improved stability and power conversion efficiency (PCE). However, there are some misunderstandings in the literature regarding some of the working mechanisms and the impacts of the silicon/insulator interface. Specifically, attributing performance improvement to oxygen vacancies and characterizing performance using Schottky barrier height and ideality factor might not be the most accurate or appropriate. This work uses Al<sub>2</sub>O<sub>3</sub> as an example to provide a detailed discussion on the interface ALD growth of Al<sub>2</sub>O<sub>3</sub> on silicon and its impact on graphene electrode metal-insulator-semiconductor (MIS) solar cells. We further suggest that the current conduction in MIS solar cells with an insulating layer of 2 to 3 nm thickness is better described by direct tunneling, Poole-Frenkel emission, and Fowler-Nordheim tunneling, as the junction voltage sweeps from negative to a larger forward bias. The dielectric film thickness, its band offset with Si, and the interface roughness, are key factors to consider for process optimization.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11944533/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On-Chip Electrochemical Sensor Based on 3D Graphene Assembly Decorated Ultrafine RuCu Alloy Nanocatalyst for In Situ Detection of NO in Living Cells.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-08 DOI: 10.3390/nano15060417
Haibo Liu, Kaiyuan Yao, Min Hu, Shanting Li, Shengxiong Yang, Anshun Zhao
{"title":"On-Chip Electrochemical Sensor Based on 3D Graphene Assembly Decorated Ultrafine RuCu Alloy Nanocatalyst for In Situ Detection of NO in Living Cells.","authors":"Haibo Liu, Kaiyuan Yao, Min Hu, Shanting Li, Shengxiong Yang, Anshun Zhao","doi":"10.3390/nano15060417","DOIUrl":"10.3390/nano15060417","url":null,"abstract":"<p><p>In this work, we developed 3D ionic liquid (IL) functionalized graphene assemblies (GAs) decorated by ultrafine RuCu alloy nanoparticles (RuCu-ANPs) via a one-step synthesis process, and integrated it into a microfluidic sensor chip for in situ electrochemical detection of NO released from living cells. Our findings have demonstrated that RuCu-ANPs on 3D IL-GA exhibit high density, uniform distribution, lattice-shaped arrangement of atoms, and extremely ultrafine size, and possess high electrocatalytic activity to NO oxidation on the electrode. Meanwhile, the 3D IL-GA with hierarchical porous structures can facilitate the efficient electron/mass transfer at the electrode/electrolyte interface and the cell culture. Moreover, the graft of IL molecules on GA endows it with high hydrophilicity for facile and well-controllable printing on the electrode. Consequently, the resultant electrochemical microfluidic sensor demonstrated excellent sensing performances including fast response time, high sensitivity, good anti-interference ability, high reproducibility, long-term stability, as well as good biocompatibility, which can be used as an on-chip sensing system for cell culture and real-time in situ electrochemical detection of NO released from living cells with accurate and stable characteristics in physiological conditions.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11946219/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Study on the Microstructure and Mechanical Properties of Improved 25Ni-20Cr Steel via in Situ Testing.
IF 4.4 3区 材料科学
Nanomaterials Pub Date : 2025-03-07 DOI: 10.3390/nano15060413
Penghui Lei, Xiaoyu Ji, Jiahao Chen, Yunhao Huang, Nan Lv, Yulin Fan, Yongchao Hou, Xinsheng Shi, Di Yun
{"title":"A Study on the Microstructure and Mechanical Properties of Improved 25Ni-20Cr Steel via in Situ Testing.","authors":"Penghui Lei, Xiaoyu Ji, Jiahao Chen, Yunhao Huang, Nan Lv, Yulin Fan, Yongchao Hou, Xinsheng Shi, Di Yun","doi":"10.3390/nano15060413","DOIUrl":"10.3390/nano15060413","url":null,"abstract":"<p><p>To meet the application requirements for structural components in Gen-IV nuclear reactors, it is essential to improve the high-temperature mechanical properties of 25Ni-20Cr (S35140) austenitic stainless steel. In this research, an improved austenitic stainless steel (N-S35140), derived from S35140 steel, was investigated. The scanning transmission electron microscopy (STEM) results indicate that the addition of titanium (Ti) microalloying elements to S35140 steel led to the precipitation of new strengthening nano phases, including M(C, N), MC, MN and Ti(C, N), in N-S35140. These precipitates effectively compensated for the loss of high-temperature strength resulting from the substantial reduction in carbon content. During the in situ transmission electron microscopy (TEM) compressive process at room temperature, the yield strength of N-S35140 steel is 618.4 MPa. At room temperature, the tensile strength of N-S35140 steel is 638.5 MPa, with a yield strength of 392.8 MPa and an elongation of 32.7%, which surpasses those of S35140 steel at room temperature. N-S35140 steel exhibits a tensile strength of 330.6 MPa, a yield strength of 228.2 MPa, and an elongation of 51.4% during the in situ scanning electron microscopy (SEM) tensile test conducted at 650 °C. As a consequence, the improved N-S35140 steel demonstrates significantly enhanced mechanical properties compared to the original S35140 steel, positioning it as a promising candidate for structural components in Gen-IV nuclear reactors.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11944395/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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