Nanomaterials最新文献

{"title":"Folic Acid-Conjugated Magnetic Oleoyl-Chitosan Nanoparticles for Controlled Release of Doxorubicin in Cancer Therapy.","authors":"Banendu Sunder Dash, Yi-Chian Lai, Jyh-Ping Chen","doi":"10.3390/nano15060415","DOIUrl":"10.3390/nano15060415","url":null,"abstract":"<p><p>To develop an efficient drug delivery system, we co-entrapped superparamagnetic Fe₃O₄ and the chemotherapeutic drug doxorubicin (DOX) in oleoyl-chitosan (OC) to prepare DOX-entrapped magnetic OC (DOX-MOC) nanoparticles (NPs) through ionic gelation of OC with sodium tripolyphosphate (TPP). The NPs provide magnetically targeted delivery of DOX in cancer therapy. Using folic acid (FA)-grafted OC, FA-conjugated DOX-entrapped magnetic OC (FA-DOX-MOC) NPs were prepared similarly for FA-mediated active targeting of cancer cells with overexpressed folate receptors. Considering DOX loading and release, the best conditions for preparing DOX-MOC NPs were an OC:TPP mass ratio = 1:4 and OC concentration = 0.2%. These spherical NPs had a particle size of ~250 nm, 87.9% Fe₃O₄ content, 53.1 emu/g saturation magnetization, 83.1% drug encapsulation efficacy, and 2.81% drug loading efficiency. FA did not significantly change the physico-chemical characteristics of FA-DOX-MOC compared to DOX-MOC, and both NPs showed pH-dependent drug release behaviors, with much faster release of DOX at acidic pH values found in endosomes. However, FA could enhance the intracellular uptake of the NPs and DOX accumulation in the nucleus. This active targeting effect led to significantly higher cytotoxicity towards U87 cancer cells. These results suggest that FA-DOX-MOC NPs can efficiently deliver DOX for controlled drug release in cancer therapy.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11944324/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multilayer Core-Sheath Structured Nickel Wire/Copper Oxide/Cobalt Oxide Composite for Highly Sensitive Non-Enzymatic Glucose Sensor.","authors":"Yuxin Wu, Zhengwei Zhu, Xinjuan Liu, Yuhua Xue","doi":"10.3390/nano15060411","DOIUrl":"10.3390/nano15060411","url":null,"abstract":"<p><p>The development of micro glucose sensors plays a vital role in the management and monitoring of diabetes, facilitating real-time tracking of blood glucose levels. In this paper, we developed a three-layer core-sheath microwire (NW@CuO@Co₃O₄) with nickel wire as the core and copper oxide and cobalt oxide nanowires as the sheath. The unique core-sheath structure of microwire enables it to have both good conductivity and excellent electrochemical catalytic activity when used as an electrode for glucose detecting. The non-enzymatic glucose sensor base on a NW@CuO@Co₃O₄ core-sheath wire exhibits a high sensitivity of 4053.1 μA mM^-1 cm^-2, a low detection limit 0.89 μM, and a short response time of less than 2 s.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11946131/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigating the Effects of Long-Term Ambient Air Storage on the Sliding Properties of N-Alloyed MoSe₂ Coatings.","authors":"Talha Bin Yaqub, Irfan Nadeem, Muhammad Aneeq Haq, Muhammad Yasir, Albano Cavaleiro, Mitjan Kalin","doi":"10.3390/nano15060414","DOIUrl":"10.3390/nano15060414","url":null,"abstract":"<p><p>Transition metal dichalcogenide coatings have emerged as potential candidates for terrestrial and aerospace mobility applications. Among these, the alloyed MoSe₂ coatings have displayed promising results while sliding in diverse environments. N-alloyed Mose₂ coatings provide the additional benefit of overcoming the impact of PVD compositional variations on dry sliding, making them promising solid lubricants for mobility-sector applications. However, the impact of long-term storage has never been investigated for this rarely studied solid-lubricant system. This study investigates the tribological performance of direct current magnetron sputtered MoSeN coatings after 40 months of storage in an ambient atmosphere. Sliding tests were conducted under conditions consistent with pre-storage conditions. The results showed that coatings with 0 at. %, 22 at. %, 33 at. %, and 35 at. % N-alloying exhibited COF values nearly identical to the pre-storage results, with only a negligible increase in ~0.01. Similarly, all coatings displayed specific wear rates in the range of 10^-7, aligning with earlier findings. The obtained results show that the sliding performance of MoSeN coatings does not deteriorate over time, highlighting their suitability for critical aerospace applications, where components and assembled parts may be stored for years before launching into space or in actual applications.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11945098/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Facile Two-Step High-Throughput Screening Strategy of Advanced MOFs for Separating Argon from Air.","authors":"Xiaoyi Xu, Bingru Xin, Zhongde Dai, Chong Liu, Li Zhou, Xu Ji, Yiyang Dai","doi":"10.3390/nano15060412","DOIUrl":"10.3390/nano15060412","url":null,"abstract":"<p><p>Metal-organic frameworks (MOFs) based on the pressure swing adsorption (PSA) process show great promise in separating argon from air. As research burgeons, the number of MOFs has grown exponentially, rendering the experimental identification of materials with significant gas separation potential impractical. This study introduced a high-throughput screening through a two-step strategy based on structure-property relationships, which leveraged Grand Canonical Monte Carlo (GCMC) simulations, to swiftly and precisely identify high-performance MOF adsorbents capable of separating argon from air among a vast array of MOFs. Compared to traditional approaches for material development and screening, this method significantly reduced both experimental and computational resource requirements. This research pre-screened 12,020 experimental MOFs from a computationally ready experimental MOF (CoRE MOF) database down to 7328 and then selected 4083 promising candidates through structure-performance correlation. These MOFs underwent GCMC simulation assessments, showing superior adsorption performance to traditional molecular sieves. In addition, an in-depth discussion was conducted on the structural characteristics and metal atoms among the best-performing MOFs, as well as the effects of temperature, pressure, and real gas conditions on their adsorption properties. This work provides a new direction for synthesizing next-generation MOFs for efficient argon separation in labs, contributing to energy conservation and consumption reduction in the production of high-purity argon gas.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 6","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11945806/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143730832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Thermally Controlled Ultra-Wideband Wide Incident Angle Metamaterial Absorber with Switchable Transmission at the THz Band.","authors":"Liansheng Wang, Fengkai Xin, Quanhong Fu, Dongyan Xia","doi":"10.3390/nano15050404","DOIUrl":"10.3390/nano15050404","url":null,"abstract":"<p><p>We demonstrate a thermally controlled ultra-wideband wide incident angle metamaterial absorber with switchable transmission at the THz band in this paper. The underlying hybrid structure of FSS-VO₂ thin films make them switchable between absorption mode and transmission mode by controlling the temperature. It can achieve ultra-wideband absorption with above 90% absorption from 1 THz to 10 THz and exhibits excellent absorption performance under a wide range of incident and polarization angles at a high temperature (80 °C). At room temperature (27 °C), it acts in transmission mode with a transmission coefficient of up to 60% at 3.1278 THz. The transmission region is inside the absorption band, which is very important for practical applications. The metamaterial absorber has the advantage of easy fabrication, an ultra-wideband, a wide incident angle, switchable multi-functions, and passivity with wide application prospects on terahertz communication and radar devices.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 5","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11901589/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143605309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Catalytic Activity of Water-Soluble Palladium Nanoparticles with Anionic and Cationic Capping Ligands for Reduction, Oxidation, and C-C Coupling Reactions in Water.","authors":"Jan W Farag, Ragaa Khalil, Edwin Avila, Young-Seok Shon","doi":"10.3390/nano15050405","DOIUrl":"10.3390/nano15050405","url":null,"abstract":"<p><p>The availability of water-soluble nanoparticles allows catalytic reactions to occur in highly desirable green environments. The catalytic activity and selectivity of water-soluble palladium nanoparticles capped with 6-(carboxylate)hexanethiolate (C6-PdNP) and 5-(trimethylammonio)pentanethiolate (C5-PdNP) were investigated for the reduction of 4-nitrophenol, the oxidation of α,β-conjugated aldehydes, and the C-C coupling of phenylboronic acid. The study showed that between the two PdNPs, C6-PdNP exhibits better catalytic activity for the reduction of 4-nitrophenol to 4-aminophenol in the presence of sodium borohydride and the selective oxidation of conjugated aldehydes to conjugated carboxylic acids. For the latter reaction, molecular hydrogen (H₂) and H₂O act as oxidants for the surface palladium atoms on PdNPs and conjugated aldehyde substrates, respectively. The results indicated that the competing addition activities of Pd-H and H₂O toward the π-bond of different unsaturated substrates promote either reduction or oxidation reactions under mild conditions in organic solvent-free environments. In comparison, C5-PdNP exhibited higher catalytic activity for the C-C coupling of phenylboronic acid. Gas chromatography-mass spectrometry (GC-MS) was mainly used as an analytical technique to examine the products of catalytic reactions.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 5","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11901881/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143605415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microwave Absorption Properties of Graphite Nanosheet/Carbon Nanofiber Hybrids Prepared by Intercalation Chemical Vapor Deposition.","authors":"Yifan Guo, Junhua Su, Qingfeng Guo, Ling Long, Jinlong Xie, Ying Li","doi":"10.3390/nano15050406","DOIUrl":"10.3390/nano15050406","url":null,"abstract":"<p><p>Carbon-based microwave absorption materials have garnered widespread attention as lightweight and efficient wave absorbers, emerging as a prominent focus in the field of functional materials research. In this work, FeNi₃ nanoparticles, synthesized in situ within graphite interlayers, were employed as catalysts to grow carbon nanofibers in situ via intercalation chemical vapor deposition (CVD). We discovered that amorphous carbon nanofibers (CNFs) can exfoliate and separate highly conductive graphite nanosheets (GNS) from the interlayers. Meanwhile, the carbon nanofibers eventually intertwine and encapsulate the graphite nanosheets, forming porous hybrids. This process induces significant changes in the electrical conductivity and electromagnetic parameters of the resulting GNS/CNF hybrids, enhancing the impedance matching between the hybrids and free space. Although this process slightly reduces the microwave loss capability of the hybrids, the balance between these effects significantly enhances their microwave absorption performance, particularly in the K_u band. Specifically, the optimized GNS/CNF hybrids, when mixed with paraffin at a 30 wt% ratio, exhibit a maximum microwave reflection loss of -44.1 dB at 14.6 GHz with a thickness of 1.5 mm. Their effective absorption bandwidth, defined as the frequency range with a reflection loss below -10 dB, spans the 12.5-17.4 GHz range, covering more than 80% of the K_u band. These results indicate that the GNS/CNF hybrids prepared via intercalation CVD are promising candidates for microwave absorption materials.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 5","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11901750/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143605734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Various Nanofillers on Piezoelectric Nanogenerator Performance of P(VDF-TrFE) Nanocomposite Thin Film.","authors":"Sangkwon Park, Hafiz Muhammad Abid Yaseen","doi":"10.3390/nano15050403","DOIUrl":"10.3390/nano15050403","url":null,"abstract":"<p><p>Flexible polymer-based piezoelectric nanogenerators (PENGs) have gained significant interest due to their ability to deliver clean and sustainable energy for self-powered electronics and wearable devices. Recently, the incorporation of fillers into the ferroelectric polymer matrix has been used to improve the relatively low piezoelectric properties of polymer-based PENGs. In this study, we investigated the effect of various nanofillers such as titania (TiO₂), zinc oxide (ZnO), reduced graphene oxide (rGO), and lead zirconate titanate (PZT) on the PENG performance of the nanocomposite thin films containing the nanofillers in poly(vinylidene fluoride-co-trifluoro ethylene) (P(VDF-TrFE)) matrix. The nanocomposite films were prepared by depositing molecularly thin films of P(VDF-TrFE) and nanofiller nanoparticles (NPs) spread at the air/water interface onto the indium tin oxide-coated polyethylene terephthalate (ITO-PET) substrate, and they were characterized by measuring their microstructures, crystallinity, β-phase contents, and piezoelectric coefficients (<i>d</i>₃₃) using SEM, FT-IR, XRD, and quasi-static meter, respectively. Multiple PENGs incorporating various nanofillers within the polymer matrix were developed by assembling thin film-coated substrates into a sandwich-like structure. Their piezoelectric properties, such as open-circuit output voltage (<i>V_OC</i>) and short-circuit current (<i>I_SC</i>), were analyzed. As a result, the PENG containing 4 wt% PZT, which was named P-PZT-4, showed the best performance of <i>V_OC</i> of 68.5 V with the <i>d</i>₃₃ value of 78.2 pC/N and β-phase content of 97%. The order of the maximum <i>V_OC</i> values for the PENGs of nanocomposite thin films containing various nanofillers was PZT (68.5 V) > rGO (64.0 V) > ZnO (50.9 V) > TiO₂ (48.1 V). When the best optimum PENG was integrated into a simple circuit comprising rectifiers and a capacitor, it demonstrated an excellent two-dimensional power density of 20.6 μW/cm² and an energy storage capacity of 531.4 μJ within 3 min. This piezoelectric performance of PENG with the optimized nanofiller type and content was found to be superior when it was compared with those in the literature. This PENG comprising nanocomposite thin film with optimized nanofiller type and content shows a potential application for a power source for low-powered electronics such as wearable devices.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 5","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11901528/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143605726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Emission Enhancement of ZnO Thin Films in Ultraviolet Wavelength Region Using Au Nano-Hemisphere on Al Mirror Structures.","authors":"Shogo Tokimori, Kai Funato, Kenji Wada, Tetsuya Matsuyama, Koichi Okamoto","doi":"10.3390/nano15050400","DOIUrl":"10.3390/nano15050400","url":null,"abstract":"<p><p>Using a heterogeneous metal Nano Hemisphere on Mirror (NHoM) structure, composed of an Al₂O₃ thin film and Au nano-hemispheres formed on a thick Al film, we successfully generated two distinct surface plasmon resonance (SPR) peaks: one in the ultraviolet (UV) wavelength range below 400 nm and another in the visible range between 600 and 700 nm. This NHoM structure can be fabricated through a straightforward process involving deposition, sputtering, and annealing, enabling rapid, large-area formation. By adjusting the thickness of the Al₂O₃ spacer layer in the NHoM structure, we precisely controlled the localized surface plasmon resonance (LSPR) wavelength, spanning a wide range from the UV to the visible spectrum. Through this tuning, we enhanced the band-edge UV emission of the ZnO thin film by a factor of 35. Temperature-dependent measurements of emission intensity revealed that the NHoM structure increased the internal quantum efficiency (IQE) of the ZnO thin film from 8% to 19%. The heterometallic NHoM structure proposed in this study enables wide-ranging control of SPR wavelengths and demonstrates significant potential for applications in enhancing luminescence in the deep ultraviolet (DUV) region, where luminescence efficiency is typically low.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 5","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11901977/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143605773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ferroelectric and Non-Linear Optical Nanofibers by Electrospinning: From Inorganics to Molecular Crystals.","authors":"Rosa M F Baptista, Etelvina de Matos Gomes, Michael Belsley, Bernardo Almeida","doi":"10.3390/nano15050409","DOIUrl":"10.3390/nano15050409","url":null,"abstract":"<p><p>In recent decades, substantial progress has been made in embedding molecules, nanocrystals, and nanograins into nanofibers, resulting in a new class of hybrid functional materials with exceptional physical properties. Among these materials, functional nanofibers exhibiting ferroelectric, piezoelectric, pyroelectric, multiferroic, and nonlinear optical characteristics have attracted considerable attention and undergone substantial improvements. This review critically examines these developments, focusing on strategies for incorporating diverse compounds into nanofibers and their impact on enhancing their physical properties, particularly ferroelectric behavior and nonlinear optical conversion. These developments have transformative potential across electronics, photonics, biomaterials, and energy harvesting. By synthesizing recent advancements in the design and application of nanofiber-embedded materials, this review seeks to highlight their potential impact on scientific research, technological innovation, and the development of next-generation devices.</p>","PeriodicalId":18966,"journal":{"name":"Nanomaterials","volume":"15 5","pages":""},"PeriodicalIF":4.4,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11901488/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143605780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}