Russian Journal of Coordination Chemistry最新文献_第5页

Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions 含2,2'-二碘多联苯-4,4'-二羧酸阴离子的钠和钙金属有机框架的结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-10 DOI: 10.1134/S1070328425600147

M. A. Bondarenko, N. A. Korobeinikov, A. S. Zaguzin, R. V. Red’kin, E. A. Pilyukova, A. V. Zaitsev, S. A. Adonin

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Lanthanum Bis(amidinate) Amido Complex {2-[Ph2Р(O)]C6H4NC(But)N(2,6-Me2C6H3)}2LaN(SiMe3)2: Synthesis, Structure, and Catalytic Activity in Ring-Opening Polymerization of rac-Lactide and ε-Caprolactone 双（氨基酸）氨基配合物{2-[Ph2Р(O)]C6H4NC(But)N(2,6- me2c6h3)}2LaN(SiMe3)2: racc -丙交酯和ε-己内酯开环聚合的合成、结构和催化活性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-02 DOI: 10.1134/S107032842560041X

A. O. Tolpygin, A. V. Cherkasov, G. K. Fukin, A. A. Trifonov

{"title":"Lanthanum Bis(amidinate) Amido Complex {2-[Ph2Р(O)]C6H4NC(But)N(2,6-Me2C6H3)}2LaN(SiMe3)2: Synthesis, Structure, and Catalytic Activity in Ring-Opening Polymerization of rac-Lactide and ε-Caprolactone","authors":"A. O. Tolpygin, A. V. Cherkasov, G. K. Fukin, A. A. Trifonov","doi":"10.1134/S107032842560041X","DOIUrl":"10.1134/S107032842560041X","url":null,"abstract":"The La(III) bis(amidinate) amido complex {2-[Ph2Р(O)]C6H4NC(But)N(2,6-Me2C6H3)}2LaN(SiMe3)2 (I) was synthesized by the reaction of 2-[Ph2Р(O)]C6H4NHC(But)=N(2,6-Me2C6H3) (HL) and La[N(SiMe3)2]3 in 2 : 1 molar ratio and isolated in 74% yield. X-ray analysis revealed that in I both monoanionic amidinate ligands are κ3-N,N,O-coordinated to La(III) ion. Complex I demonstrates high catalytic activity in ring-opening polymerization of cyclic esters and enables 100% conversion of 100–300 equiv of rac-lactide in 30 min or 100–500 equiv of ε-caprolactone in 1 min providing highly controlled polymerization. The obtained polymeric samples feature linear dependence of molecular weight vs. the monomer loading and rather narrow polydispersity (Mw/Mn = 1.36–1.88).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 5","pages":"374 - 380"},"PeriodicalIF":1.1,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis, Structures, and Thermal Behavior of Calcium, Strontium, Barium Bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato) Complexes with Crown-Ethers 钙、锶、钡与冠醚配合物（1-二茂铁-4,4,4-三氟丁烷-1,3-dionato）的合成、结构和热行为

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-02 DOI: 10.1134/S1070328425600184

T. S. Pochekutova, B. I. Petrov, N. M. Lazarev, G. K. Fukin, E. V. Baranov, N. M. Khamaletdinova, A. A. Zolotukhin, A. A. Belikov, T. I. Lopatina, R. S. Kovylin

{"title":"Synthesis, Structures, and Thermal Behavior of Calcium, Strontium, Barium Bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato) Complexes with Crown-Ethers","authors":"T. S. Pochekutova, B. I. Petrov, N. M. Lazarev, G. K. Fukin, E. V. Baranov, N. M. Khamaletdinova, A. A. Zolotukhin, A. A. Belikov, T. I. Lopatina, R. S. Kovylin","doi":"10.1134/S1070328425600184","DOIUrl":"10.1134/S1070328425600184","url":null,"abstract":"The new ferrocenyl-containing β-diketonate complexes with crown-ethers [Ca(Fctfa)2(15-crown-5)] (I), [Sr(Fctfa)2(18-crown-6)] (II), [Sr(Fctfa)2(18-crown-6)](CH2Cl2) (III), [Ba(Fctfa)2(18-crown-6)] (IV) and [Ba(Fctfa)2(18-crown-6)](CH2Cl2) (V) (Fctfa = 1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato), 15-crown-5 = 1,4,7,10,13-pentanoxacyclopentadecane; 18-crown-6 = 1,4,7,10,13,16-hexaoxacyclooctadecane) have been synthesized. The compounds are characterized by infrared and 1H NMR spectroscopy and X-ray diffraction analysis. The thermal behavior of complexes I, II, IV was investigated by thermal analysis. It was found that complexes are thermally stable up to 150°C for I, 215°C for II 180°C for IV. The decomposition behavior of I, II, IV studied by 1H nuclear magnetic resonance investigation of substances, formed at decomposition of I, II, IV in dynamic vacuum. It was found, that the heating of I, II, IV in the ranges 150–800°C for I, 215–800°C for II, 180–800°C for IV affords the solid substances, containing alkaline-earth metals fluorides and iron oxides. Using topological analysis of the electron density distribution in I, III, V, intra- and intermolecular interactions were quantitatively estimated within the framework of Bader’s atoms in molecules theory. According to Espinosa–Mollins–Lecomte correlation, energies of the intermolecular interactions for I, III, V are close to the experimentally measured enthalpies of sublimation of related complexes published previously.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 5","pages":"348 - 362"},"PeriodicalIF":1.1,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145160913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Estimating Strength of Cu–O Bonds in Cu(II) β-Diketonates from Electron Density Topology 从电子密度拓扑估计Cu(II) β-二酮酸酯中Cu - o键的强度

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-02 DOI: 10.1134/S1070328425600226

R. E. Afaunov, I. V. Mirzaeva, S. G. Kozlova

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Coordination Compounds of Cobalt(II) and Zinc(II) with N,N'-((Hydrazine-1,2-diylidene-bis(methanylylidene))bis(2,1-phenylene))bis(4-methylbenzenesulfonamide): Synthesis and Properties 钴（II）和锌（II）与N，N'-（（肼-1,2-二乙基-双（甲基乙基））双（2,1-苯基））双（4-甲基苯磺酰胺）配位化合物的合成及性能

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601638

A. A. Kolodina, O. P. Demidov, N. I. Vikrishchuk, A. S. Galkina, N. N. Efimov, A. V. Chernyshev, L. D. Popov, A. V. Metelitsa, A. S. Burlov

{"title":"Coordination Compounds of Cobalt(II) and Zinc(II) with N,N'-((Hydrazine-1,2-diylidene-bis(methanylylidene))bis(2,1-phenylene))bis(4-methylbenzenesulfonamide): Synthesis and Properties","authors":"A. A. Kolodina, O. P. Demidov, N. I. Vikrishchuk, A. S. Galkina, N. N. Efimov, A. V. Chernyshev, L. D. Popov, A. V. Metelitsa, A. S. Burlov","doi":"10.1134/S1070328424601638","DOIUrl":"10.1134/S1070328424601638","url":null,"abstract":"N,N'-((Hydrazine-1,2-diylidene-bis(methanylylidene))bis(2,1-phenylene))bis(4-methylbenzene-sulfonamide) (H2L) and its binuclear complexes Zn2L2 and Co2L2 are synthesized. The compositions and structures of H2L and its complexes are determined by elemental analysis and IR and 1H NMR spectroscopy (for Zn2L2). The structures of H2L and Co2L2 are determined by XRD (CIF files CCDC no. 2405868 for H2L and no. 2390599 for Co2L2·4DMSO). The magnetic properties of Co2L2 and photoluminescence properties of H2L and Zn2L2 are studied. The Zn(II) complex exhibits the photoluminescence properties in an acetonitrile solution and in the solid state ((lambda _{{{text{max}}}}^{{{text{fl}}}}) = 584 and 532 nm) with quantum yields of 0.06 and 0.68, respectively. The Co(II) complex exhibits the properties of slow magnetic relaxation.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 3","pages":"175 - 183"},"PeriodicalIF":1.1,"publicationDate":"2025-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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New Tetraiodomanganate(II) with Highly Efficient Short-Lived Phosphorescence 具有高效短寿命磷光的新型四锰酸盐（II）

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328425600123

M. P. Davydova, I. Yu. Bagryanskaya, A. S. Berezin, V. A. Kuimov, A. V. Artem’ev

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Yttrium Polyphenylcyclopentadienyl Complexes with 1,3,5-Trimethyl-1,3,5-triazacyclohexane 与1,3,5-三甲基-1,3,5-三氮杂环己烷的钇聚苯基环戊二烯配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601444

D. A. Bardonov, K. A. Lysenko, I. E. Nifantiev, M. E. Minyaev, D. M. Roitershtein

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Chiral Cobalt(III) Complexes Based on (1R,2R)-Cyclohexanediamine and 4-Bromo-5-methylsalicylaldehyde: Synthesis, Modification, and Application in Catalysis and Enantioselective Sensors 基于(1R,2R)-环己二胺和4-溴-5-甲基水杨醛的手性钴（III）配合物：合成、修饰及其在催化和对映选择性传感器中的应用

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601468

O. V. Khromova, A. F. Smol’yakov, R. A. Zil’berg, Yu. B. Teres, G. I. Ishmakaeva, V. I. Maleev, V. A. Larionov

{"title":"Chiral Cobalt(III) Complexes Based on (1R,2R)-Cyclohexanediamine and 4-Bromo-5-methylsalicylaldehyde: Synthesis, Modification, and Application in Catalysis and Enantioselective Sensors","authors":"O. V. Khromova, A. F. Smol’yakov, R. A. Zil’berg, Yu. B. Teres, G. I. Ishmakaeva, V. I. Maleev, V. A. Larionov","doi":"10.1134/S1070328424601468","DOIUrl":"10.1134/S1070328424601468","url":null,"abstract":"New chiral octahedral positively charged diastereomeric cobalt(III) complexes Λ(R,R)-1 and Δ(R,R)-1 with two asymmetric NNO-donor ligands (Schiff base of (1R,2R)-cyclohexanediamine and 4‑bromo-5-methylsalicylaldehyde) were synthesized. Single-crystal X-ray diffraction (XRD) analysis showed that the Δ(R,R)-1 complex is arranged in the crystal as a homochiral spiral with a “tube-in-tube” cavity, formed via hydrogen bonding between amino groups of the complex, water molecules, and the counterion. The bromo-containing complex Λ(R,R)-1 was further modified by a catalytic Suzuki–Miyaura cross-coupling reaction to give complexes Λ(R,R)-2 and Λ(R,R)-3 with introduced Ph and 4-CF3C6H4 groups. The structure of complex Λ(R,R)-2 was confirmed by XRD. The catalytic activity of the synthesized complexes was studied in asymmetric phase-transfer alkylation and trimethylsilylcyanation reactions. Cobalt(III) complexes were also tested as chiral selectors for enantioselective voltammetric sensors, and the effect of complex structure on sensor characteristics toward the enantiomers of naproxen and thyroxine was evaluated.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 3","pages":"200 - 210"},"PeriodicalIF":1.1,"publicationDate":"2025-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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cis- and trans-Isomerism in Manganese(II) Complexes with Acylpyrazolonepyridine 锰（II）与酰基吡唑啉配合物的顺式和反式异构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601547

I. A. Nikovskii, A. N. Sinel’nikov, A. S. Bogomyakov, A. V. Borodulina, Yu. V. Nelyubina

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Indium(III) Catecholates Based on Alkyl-Substituted o-Benzoquinones 基于烷基取代邻苯醌的邻苯二甲酸铟(III

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328425600172

I. V. Ershova, I. N. Meshcheryakova, A. V. Maleeva, N. O. Druzhkov, A. V. Cherkasov, A. V. Piskunov

{"title":"Indium(III) Catecholates Based on Alkyl-Substituted o-Benzoquinones","authors":"I. V. Ershova, I. N. Meshcheryakova, A. V. Maleeva, N. O. Druzhkov, A. V. Cherkasov, A. V. Piskunov","doi":"10.1134/S1070328425600172","DOIUrl":"10.1134/S1070328425600172","url":null,"abstract":"A series of dimeric indium(III) catecholates [(R-Cat)InI]2 (R = 3,6-cHex (I), 3,5-tOc (II), 4-tOc (III), and 3,5-C(Me)2Ph (IV)) is synthesized by the oxidative addition of indium(I) iodide to the following alkyl-substituted o-benzoquinones: 3,6-di-cyclo-hexyl-o-benzoquinone (3,6-cHex-Q), 3,5-di-tert-octyl-o-benzoquinone (3,5-tOc-Q), 4-tert-octyl-о-benzoquinone (4-tOc-Q), and 3,5-bis(2-phenylpropan-2-yl)-o-benzoquinone (3,5-C(Me)2Ph-Q). Compounds I–IV are stable in the crystalline state and in solution, and their structures are confirmed by NMR and IR spectroscopy and elemental analysis. The crystallization of complex II from THF gives crystals of two types, cis-II·4THF and trans-II·4THF, corresponding to the cis and trans orientations of the alkyl substituents relatively to the catecholate fragment plane. The reactions of compounds I–IV with 2,2'-bipyridyl afford heteroleptic derivatives (R-Cat)InI(Bipy) (R = 3,6-cHex (V), 3,5-tOc (VI), 4-tOc (VII), and 3,5-C(Me)2Ph (VIII)). Compounds V and VIII are isolated in the individual state and characterized by a set of physicochemical methods. Derivatives VI and VII are unstable and undergo further transformations to form a poorly separable mixture of products. The molecular structures of complexes cis-II·4THF and trans-II·4THF are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2404879 and 2404880, respectively).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 3","pages":"160 - 168"},"PeriodicalIF":1.1,"publicationDate":"2025-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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