E. V. Gorbachuk, M. A. Mikhaylov, D. G. Sheven, M. N. Sokolov, D. G. Yakhvarov
{"title":"Rhenium Iodide Cluster Re3I9 as a Precursor in the Synthesis of [Re(CO)5I] and ((n-C4H9)4N)2[Re2Cl8]","authors":"E. V. Gorbachuk, M. A. Mikhaylov, D. G. Sheven, M. N. Sokolov, D. G. Yakhvarov","doi":"10.1134/S1070328424600463","DOIUrl":null,"url":null,"abstract":"<p>The reduction of rhenium iodide cluster Re<sub>3</sub>I<sub>9</sub> to [Re(CO)<sub>5</sub>I] (55% yield) was observed in the presence of concentrated HCl and HCOOH at 130°C. In a dimethylammonium chloride [(CH<sub>3</sub>)<sub>2</sub>NH<sub>2</sub>]Cl melt, the triangular cluster polymer Re<sub>3</sub>I<sub>9</sub> is transformed into the dianionic binuclear cluster complex [Re<sub>2</sub>-Cl<sub>8</sub>]<sup>2–</sup>, which was isolated as the tetrabutylammonium salt ((<i>n</i>-C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N)<sub>2</sub>[Re<sub>2</sub>Cl<sub>8</sub>] in 46% yield. The structure of the complex [Re(CO)<sub>5</sub>I] was confirmed by powder X-ray diffraction, energy dispersive spectroscopy, IR, and Raman spectroscopy. ((<i>n</i>-C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N)<sub>2</sub>[Re<sub>2</sub>Cl<sub>8</sub>] was identified using elemental analysis, energy dispersive spectroscopy, and IR and Raman spectroscopy. An acetonitrile solution of ((<i>n</i>-C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N)<sub>2</sub>[Re<sub>2</sub>Cl<sub>8</sub>] was characterized by the mass spectrum and characteristic UV−Vis spectrum.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 9","pages":"715 - 720"},"PeriodicalIF":1.1000,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328424600463","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The reduction of rhenium iodide cluster Re3I9 to [Re(CO)5I] (55% yield) was observed in the presence of concentrated HCl and HCOOH at 130°C. In a dimethylammonium chloride [(CH3)2NH2]Cl melt, the triangular cluster polymer Re3I9 is transformed into the dianionic binuclear cluster complex [Re2-Cl8]2–, which was isolated as the tetrabutylammonium salt ((n-C4H9)4N)2[Re2Cl8] in 46% yield. The structure of the complex [Re(CO)5I] was confirmed by powder X-ray diffraction, energy dispersive spectroscopy, IR, and Raman spectroscopy. ((n-C4H9)4N)2[Re2Cl8] was identified using elemental analysis, energy dispersive spectroscopy, and IR and Raman spectroscopy. An acetonitrile solution of ((n-C4H9)4N)2[Re2Cl8] was characterized by the mass spectrum and characteristic UV−Vis spectrum.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
