Russian Journal of Coordination Chemistry最新文献

Copper(I) Thiocyanate Complexes with tert-Butylpyridylphosphine Ligands: Synthesis and Photophysical Properties 叔丁基吡啶膦配体硫氰酸铜配合物的合成及其光物理性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601426

A. Yu. Baranov, I. Yu. Bagryanskaya, A. V. Artem’ev

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Spin Crossover–Few-Layer Graphene Nanocomposites: Synthesis and Magnetic Properties of Fe(NH2trz)3A2@FLG (A = Cl–, Br–) 自旋交叉-少层石墨烯纳米复合材料Fe(NH2trz)3A2@FLG （A = Cl -, Br -）的合成与磁性能

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601244

L. G. Lavrenova, V. G. Makotchenko, E. V. Korotaev, E. Yu. Gerasimov, A. I. Bulavchenko, O. G. Shakirova

{"title":"Spin Crossover–Few-Layer Graphene Nanocomposites: Synthesis and Magnetic Properties of Fe(NH2trz)3A2@FLG (A = Cl–, Br–)","authors":"L. G. Lavrenova, V. G. Makotchenko, E. V. Korotaev, E. Yu. Gerasimov, A. I. Bulavchenko, O. G. Shakirova","doi":"10.1134/S1070328425601244","DOIUrl":"10.1134/S1070328425601244","url":null,"abstract":"Stable nanoparticles capable of experiencing spin crossover with hysteresis on curves of the µeff(T) dependence near ambient temperature have been synthesized. The earlier synthesized complexes [Fe(NH2trz)3]Cl2·H2O and [Fe(NH2trz)3]Br2·H2O exhibiting sharp spin crossover with hysteresis are used for the preparation of the nanocomposites. Few-layer graphene (FLG) formed by the microwave heating of the intercalated polydicarbonfluoride compound with acetone served as the basis. Nanoparticles Fe(NH2trz)3Cl2@FLG (SCO1-n) and Fe(NH2trz)3Br2@FLG (SCO2-n) (n = 1–3) have been prepared (n indicates time (h) of the treatment of the initial particles with ultrasound). The effective hydrodynamic diameter of particles of the complexes in ethanol is determined by photon correlation spectroscopy. The structures and microstructures of the samples are studied by high resolution transmission electron microscopy. The study of the µeff(T) dependence shows that all synthesized composites exhibit crossover with hysteresis on the µeff(T) curves. The temperature and character of the transition depend substantially on the particle size. The variation of the ultrasonication time during the preparation of the composites makes it possible to purposefully modify their magnetic properties.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1172 - 1186"},"PeriodicalIF":1.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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New Photochromic Zinc(II) Complexes with 1,2,4-Triazole-Containing Schiff Bases 新型含1,2,4-三唑希夫碱光致变色锌（II）配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601529

A. A. Bovkunova, A. A. Anisimov, V. E. Gontcharenko, E. S. Bazhina, I. V. Taydakov, I. L. Eremenko, I. V. Ananyev

{"title":"New Photochromic Zinc(II) Complexes with 1,2,4-Triazole-Containing Schiff Bases","authors":"A. A. Bovkunova, A. A. Anisimov, V. E. Gontcharenko, E. S. Bazhina, I. V. Taydakov, I. L. Eremenko, I. V. Ananyev","doi":"10.1134/S1070328425601529","DOIUrl":"10.1134/S1070328425601529","url":null,"abstract":"The reactions of zinc(II) bromide with Schiff bases, 4-(2-hydroxyphenyl)methyleneamino-1,2,4-triazole (HL1) and 4-(2-hydroxy-3-methoxyphenyl)methyleneamino-1,2,4-triazole (HL2), yielded the complexes [Zn(HL1)2Br2] (I) and [Zn(HL2)2Br2] (II). It was shown that I and II are also formed upon the addition of hydrobromic acid to a suspension of zinc(II) coordination compounds containing anionic [L1]– and [L2]– ligands in MeOH. The crystal structures of compounds I and II were determined by single-crystal X-ray diffraction (CIF files CCDC no. 2502710 (I), no. 2502711 (II)). It was found that upon complexation with Zn2+ ions, conformational changes occur in the HL1 and HL2 molecules. This facilitates intramolecular proton transfer, causing compounds I and II to exhibit a photochromic effect, which is confirmed by diffuse reflectance spectroscopy data.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1082 - 1094"},"PeriodicalIF":1.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Coordination Chemistry: Part 1. Electronic Structure, Stability, Reaction Mechanisms, Nonaqueous Solvents 配位化学：第1部分电子结构，稳定性，反应机理，非水溶剂

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601438

M. N. Sokolov, A. L. Gushchin, D. G. Samsonenko

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Synthesis, Study of the Structure, and Molecular Docking of Cu(II) Coordination Compounds with 3-Benzylidene-1-pyrrolines 铜（II）配位化合物与3-苄基吡咯啉的合成、结构及分子对接研究

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601268

O. V. Zvereva, M. A. Shmelev, E. S. Bazhina, Yu. K. Voronina, I. L. Eremenko

{"title":"Synthesis, Study of the Structure, and Molecular Docking of Cu(II) Coordination Compounds with 3-Benzylidene-1-pyrrolines","authors":"O. V. Zvereva, M. A. Shmelev, E. S. Bazhina, Yu. K. Voronina, I. L. Eremenko","doi":"10.1134/S1070328425601268","DOIUrl":"10.1134/S1070328425601268","url":null,"abstract":"A series of copper nitrate complexes with 3-benzylidene-1-pyrroline (LH) and its derivatives [3-(4-chlorobenzylidene)-1-pyrroline (LCl), 3-(4-bromobenzylidene)-1-pyrroline (LBr), and 3-(4-methoxybenzylidene)-1-pyrroline (LOMe)] was synthesized: [Cu(H2O)2(LH)2(NO3)2] (IH), [Cu(LCl)2(NO3)2] (IICl), [Cu(LBr)2(NO3)2] (IIBr), and [Cu(LOMe)2(NO3)2] (IIOMe). The obtained coordination compounds were characterized by X-ray diffraction, IR spectroscopy, and CHN analysis. UV/Vis spectra of the complexes in solutions were studied. The structure and crystal packing of the complexes were analyzed in detail, and the main structuring non-covalent interactions in the crystals were identified. The interaction of synthesized coordination compounds with the HER2 (human epidermal growth factor receptor) was investigated using molecular docking.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1125 - 1139"},"PeriodicalIF":1.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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First Copper(II) Indole Carboxylate Complexes: Features of Synthesis, Structural Organization, and Biological Activity 铜（II）吲哚羧酸盐配合物：合成、结构组织和生物活性的特点

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601463

K. A. Koshenskova, L. S. Razvorotneva, A. D. Filippova, F. M. Dolgushin, N. V. Gogoleva, O. B. Bekker, V. O. Shender, I. L. Eremenko, I. A. Lutsenko

{"title":"First Copper(II) Indole Carboxylate Complexes: Features of Synthesis, Structural Organization, and Biological Activity","authors":"K. A. Koshenskova, L. S. Razvorotneva, A. D. Filippova, F. M. Dolgushin, N. V. Gogoleva, O. B. Bekker, V. O. Shender, I. L. Eremenko, I. A. Lutsenko","doi":"10.1134/S1070328425601463","DOIUrl":"10.1134/S1070328425601463","url":null,"abstract":"Complexes [Cu2(ind)4(EtOH)2] (I), [Cu(ind)2bpy]·1.15MeCN·0.85MeOH (II), and [Cu(ind)(phen)2]+ ·ind–·0.5Hind·1.5H2O (III) were synthesized using slow diffusion of the starting solutions of copper(II) acetate, indole-2-carboxylic acid (Hind), and oligopyridines (2,2'-bipyridine (bpy)/1,10-phenanthroline (phen)). The structures of the complexes were established by single crystal X-ray diffraction and the phase purity was confirmed by powder X-ray diffraction. According to single-crystal X-ray diffraction data, I and II are molecular complexes, while III is an ionic complex comprising the cationic mononuclear [Cu(ind)(phen)2]+ moiety in the independent part of the unit cell and the ind– anion in the outer sphere. The coordination environment of copper(II) cation (C.N.Cu 5) is described by a square pyramid (I, III) or a planar square with C.N.Cu 4 (II). The supramolecular level involves both hydrogen bonds and non-covalent interactions, mainly of the π…π and C–H…π type. The stability of salt solutions of I–III was studied by spectrophotometry in comparison with the free ligands and over a period of 2 days. Complexes I–III were investigated for biological activity: the antimycobacterial activity was evaluated against the non-pathogenic Mycolicibacterium smegmatis strain and the cytotoxicity of III was assessed against the test human ovarian adenocarcinoma cells (SKOV3).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1159 - 1171"},"PeriodicalIF":1.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Template Synthesis of Functionalized o-Iminosemiquinones and o-Iminoquinones in the Coordination Sphere of Nickel(II) and Zinc(II) Ions 镍（II）和锌（II）离子配位球中功能化邻亚胺半醌和邻亚胺醌的模板合成

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601475

N. O. Druzhkov, T. N. Kocherova, I. N. Meshcheryakova, A. V. Cherkasov, I. A. Yakushev, S. V. Baryshnikova, P. V. Dorovatovskii, A. V. Piskunov

{"title":"Template Synthesis of Functionalized o-Iminosemiquinones and o-Iminoquinones in the Coordination Sphere of Nickel(II) and Zinc(II) Ions","authors":"N. O. Druzhkov, T. N. Kocherova, I. N. Meshcheryakova, A. V. Cherkasov, I. A. Yakushev, S. V. Baryshnikova, P. V. Dorovatovskii, A. V. Piskunov","doi":"10.1134/S1070328425601475","DOIUrl":"10.1134/S1070328425601475","url":null,"abstract":"New nickel(II) bis-o-iminobenzosemiquinolate complexes (L1)2Ni (I) and (L2)2Ni (II) were prepared by template synthesis using o- and m-phenylenediamine compounds with NiCl2 ((o-PDA)2NiCl2 and (m-PDA)2NiCl2) as precursors in the reaction with thallium(I) 3,5-di-tert-butyl-o-benzosemiquinolate. The o-phenylenediamine complex with ZnI2 ((o-PDA)ZnI2) was allowed to react with 4-(tert-butyl)-5-methoxy-o-benzoquinone to give L3ZnI2 (III) containing a neutrally coordinated molecule of new o-iminobenzoquinone. It was shown that the condensation of o(m)-phenylenediamine with o-benzosemiquinone/o-benzoquinone takes place in the coordination sphere of nickel(II) and zinc(II) ions, giving rise to new o-iminobenzosemiquinolate/o-iminobenzoquinone ligands functionalized with an amino group. The structure of complexes I and III was confirmed by X-ray diffraction.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1051 - 1059"},"PeriodicalIF":1.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Coordination Complexes of Arylimine Derivatives of Aceanthrylene-1,2-dione 乙炔-1,2-二酮芳胺衍生物的配位配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S107032842560130X

G. V. Markin, R. V. Rumyantsev, G. Yu. Zhigulin, A. A. Belikov, G. K. Fukin, S. Yu. Ketkov

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Coordination Compounds in High-Resolution Nuclear Magnetic Resonance Spectroscopy 高分辨率核磁共振波谱中的配位化合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-04-01 DOI: 10.1134/S1070328425601256

V. K. Voronov

{"title":"Coordination Compounds in High-Resolution Nuclear Magnetic Resonance Spectroscopy","authors":"V. K. Voronov","doi":"10.1134/S1070328425601256","DOIUrl":"10.1134/S1070328425601256","url":null,"abstract":"This review illustrates the broad potential of using nuclear magnetic resonance spectra transformed by complex formation to study the structure and dynamics of heteroatom ligands and their coordination compounds. Such transformations are considered separately for the formation of both paramagnetic and diamagnetic coordination complexes. A section discussing the features of nuclear magnetic resonance in paramagnetic systems precedes the discussion of the molecular structure of specific organic heteroatom compounds and their complexes. These features arise from hyperfine interactions between unpaired electrons localized on the coordinating ion and the resonating nuclei. This results in paramagnetic line broadening and contact and pseudocontact shifts of resonance lines in nuclear magnetic resonance spectra. These paramagnetic shifts and broadenings provide information on molecular structure. The main principles of the paramagnetic additive method are presented; their use enables overcoming difficulties associated with strong paramagnetic broadening of resonance lines in high-resolution nuclear magnetic resonance spectra. It is also shown that the transformation of nuclear magnetic resonance spectra during the formation of diamagnetic coordination compounds yields valuable information on the molecular structure of both ligands and the resulting complexes.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1140 - 1158"},"PeriodicalIF":1.1,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of Bis(4,4,4-trifluoro-1-(4-(triphenylsilyl)phenyl)butane-1,3-dionato)- and Bis(4,4,4-trifluoro-1-(4-(triphenylgermyl)phenyl)butane-1,3-dionato)(dipyridine)copper(II) 双（4,4,4-三氟-1-（4-（三苯基硅基）苯基）丁烷-1,3-二氮酮）和双（4,4,4-三氟-1-（4-（三苯基germyl）苯基）丁烷-1,3-二氮酮）铜的合成（II）

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2026-02-11 DOI: 10.1134/S1070328425601451

I. V. Taydakov, T. S. Stankevich, P. V. Dorovatovskii, A. V. Vologzhanina, V. E. Gontcharenko, M. M. Islamov, D. A. Metlina, A. A. Abramovich, E. A. Varaksina

{"title":"Synthesis of Bis(4,4,4-trifluoro-1-(4-(triphenylsilyl)phenyl)butane-1,3-dionato)- and Bis(4,4,4-trifluoro-1-(4-(triphenylgermyl)phenyl)butane-1,3-dionato)(dipyridine)copper(II)","authors":"I. V. Taydakov, T. S. Stankevich, P. V. Dorovatovskii, A. V. Vologzhanina, V. E. Gontcharenko, M. M. Islamov, D. A. Metlina, A. A. Abramovich, E. A. Varaksina","doi":"10.1134/S1070328425601451","DOIUrl":"10.1134/S1070328425601451","url":null,"abstract":"Two new diketone ligands containing tetraphenylsilyl and tetraphenylgermyl fragments were synthesized and thoroughly characterized. Their interaction with Cu(II) ions led to the formation of insoluble coordination compounds, which are assumed to possess polymeric structures. Reaction of these compounds with an excess of pyridine in dichloromethane solution afforded molecular complexes of the composition [Cu(L)2(Py)2]. The molecular structure of the tetraphenylsilyl-based complex (5a) was established by single-crystal X-ray diffraction. Although crystals of the germanium analogue (5b) were unsuitable for direct structural analysis, powder X-ray diffraction confirmed its phase purity and demonstrated its isostructural to the silicon complex. These results expand the coordination chemistry of silicon- and germanium-substituted diketone ligands and illustrate their potential for constructing new Cu(II) coordination architectures.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 12","pages":"1118 - 1124"},"PeriodicalIF":1.1,"publicationDate":"2026-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147588504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0