Russian Journal of Coordination Chemistry最新文献

Influence of the Steric Factor on the Structure of Indium(III) Iodide Complexes Based on Substituted o-Iminobenzoquinones 位阻因子对取代邻亚胺苯醌类碘化铟配合物结构的影响

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600780

I. N. Meshcheryakova, N. O. Druzhkov, T. N. Kocherova, R. V. Rumyantcev, M. V. Arsenyev, N. M. Khamaletdinova, A. V. Piskunov

{"title":"Influence of the Steric Factor on the Structure of Indium(III) Iodide Complexes Based on Substituted o-Iminobenzoquinones","authors":"I. N. Meshcheryakova, N. O. Druzhkov, T. N. Kocherova, R. V. Rumyantcev, M. V. Arsenyev, N. M. Khamaletdinova, A. V. Piskunov","doi":"10.1134/S1070328425600780","DOIUrl":"10.1134/S1070328425600780","url":null,"abstract":"Based on a series of substituted o-iminobenzoquinones (6-((2,6-di-iso-propylphenyl)imino)-2,4-bis(2,4,4-trimethylpentan-2-yl)cyclohexa-2,4-dien-1-one (L1), 4-(tert-butyl)-6-((2,6-di-iso-propylphenyl)imino)-3-methoxycyclohexa-2,4-dien-1-one (L2), and 6-((2,6-di-iso-propylphenyl)imino)-3-methoxy-4-(2,4,4-trimethylpentan-2-yl)cyclohexa-2,4-dien-1-one (L3)), indium(III) iodide complexes were synthesized containing a redox-active ligand in the neutral form. The o-iminobenzoquinone L1 was synthesized for the first time. It was found that the structure of the obtained complexes depends on the degree of shielding of the carbonyl oxygen atom in the starting o-iminobenzoquinone. The sterically hindered L1 forms a 1 : 1 adduct with InI3 (complex (L1)InI3 (I)). The absence of a substituent at position 2 of the o-iminobenzoquinone ring promotes the formation of bisligand ionic derivatives {[(L2)2InI2]InI4} (II) and {[(L3)2InI2]InI4} (III). The molecular structure of L1 and complexes I·0.5 toluene, II·toluene·0.5 hexane was established by X-ray diffraction analysis (CCDC nos. 2440874 (L1), 2440875 (I·0.5 toluene), 2440876 (II·toluene·0.5 hexane)). The optical and electrochemical properties of the starting o-iminobenzoquinones and their indium(III) complexes were studied. It was shown that complexation significantly enhances the oxidative properties of L1, L2, and L3.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"402 - 413"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Rhenium(I) Carbonyl Isonitrile Complex Based on Menthol-Modified Phenanthroline: Synthesis and Luminescence Properties 基于薄荷醇修饰邻菲罗啉的羰基异腈铼配合物的合成及其发光性能

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600524

M. P. Davydova, A. M. Agafontsev, V. N. Yudin, M. I. Rakhmanova, A. V. Artem’ev

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Synthesis, Structure, and Optical Properties of Cyclometalated Iridium(III) Complexes with 2-Arylbenzimidazoles and Pyrazino[2,3-f][1,10]phenanthroline 环金属化铱（III）与2-芳基苯并咪唑和吡嗪[2,3-f][1,10]菲罗啉配合物的合成、结构和光学性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600573

E. A. Sholina, S. I. Bezzubov

{"title":"Synthesis, Structure, and Optical Properties of Cyclometalated Iridium(III) Complexes with 2-Arylbenzimidazoles and Pyrazino[2,3-f][1,10]phenanthroline","authors":"E. A. Sholina, S. I. Bezzubov","doi":"10.1134/S1070328425600573","DOIUrl":"10.1134/S1070328425600573","url":null,"abstract":"Two new iridium(III) complexes with benzimidazole ligands differing in the size of the aromatic system and an auxiliary N-donor ligand with an extended conjugated system were synthesized and studied by structural and spectroscopic methods. A comparison of the results of crystal packing analysis with the data of electronic absorption spectroscopy, diffuse reflectance spectroscopy, and luminescence spectroscopy shows that intermolecular π–π interactions between the benzimidazole ligands have little effect on the optical characteristics of the complexes. Both compounds exhibit light absorption in the 250–550 nm range (ε = 58 000–1000 M–1 cm–1) in solution and in the solid state (Eg = 2.14–2.16 eV) and emit in the orange region (λmax = 558–585 nm), with the maxima of solid-state emission systematically red-shifted by approximately 25 nm compared to emission in solution. The results of this work provide a better understanding of the extent to which crystal packing affects the optical properties of iridium(III) complexes and will be used in further development of crystal engineering approaches for designing iridium-based luminescent compounds in the long-wavelength region.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"455 - 463"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spin State of the pH-Sensitive Cobalt(II) Complex with the Bis(pyrazol-3-yl)pyridine-Based Ligand ph敏感性钴（II）配合物与双（吡唑-3-基）吡啶基配体的自旋态

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600743

E. S. Safiullina, I. A. Nikovskiy, Yu. V. Nelyubina

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Calcium Complexes with the Bulky Tris((2-N-piperidinomethyl)phenyl)methoxide Ligand. Synthesis and Catalytic Activity in the Dearomatization of N-Heterocycles 与大体积三（（2- n -哌啶甲基）苯基）甲氧基配体的钙配合物。n -杂环脱芳化反应的合成及其催化活性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S107032842560069X

A. N. Selikhov, Yu. V. Nelyubina, A. A. Trifonov

{"title":"Calcium Complexes with the Bulky Tris((2-N-piperidinomethyl)phenyl)methoxide Ligand. Synthesis and Catalytic Activity in the Dearomatization of N-Heterocycles","authors":"A. N. Selikhov, Yu. V. Nelyubina, A. A. Trifonov","doi":"10.1134/S107032842560069X","DOIUrl":"10.1134/S107032842560069X","url":null,"abstract":"The reaction of equimolar amounts of tris((2-N-piperidinomethyl)phenyl)methanol (2‑C5H10NCH2-o-C6H4)3COH and [(Me3Si)2N]2Ca(THF)2 (toluene, 23○C) resulted in the synthesis of mixed-ligand calcium alkoxide-amide complex [(2-C5H10NCH2C6H4)3CO]CaN(SiMe3)2 (I) in 70% yield. According to X-ray diffraction data, the monoanionic alkoxide ligand in I is coordinated to the metal in the κ3-O,N,N-mode. Complex I catalyzes the addition of PhSiH3 to annulated N-containing heterocycles: quinoline, 4-methylquinoline, 6-methylquinoline, and isoquinoline. The reactions are chemo- and regioselective and proceed over periods of 24 to 120 h. The reaction of I with PhSiH3 (molar ratio of 1 : 2) gives the bis(alkoxide) complex [κ2-O,N-(2-C5H10NCH2C6H4)3CO]2Ca (II) and CaH2 as a result of symmetrization of the intermediate calcium alkoxy hydride. In the crystalline state, complex II has a non-linear structure, with the OCa(1)O angle being 112.65(4)° and only one of the piperidine moieties in each ligand being involved in the coordination to the metal ion. The molecular structure of complexes I and II was determined using X-ray diffraction (CCDC nos. 2443979 (I), 2443980 (II)).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"522 - 530"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and Structure of Iron(II) Complexes with 1-Methyl-2-pyridin-2-yl-1H- and 1-Methyl-2-phenyliminomethyl-1H-benzimidazoles and Boron Cluster Anions [BnHn]2– (n = 10, 12) 1-甲基-2-吡啶-2-基- 1h -和1-甲基-2-苯基-甲基- 1h -苯并咪唑与硼簇阴离子[BnHn]2 - (n = 10,12)配合物的合成与结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600482

V. V. Avdeeva, A. S. Kubasov, S. E. Nikiforova, O. N. Belousova, E. A. Malinina, N. T. Kuznetsov

{"title":"Synthesis and Structure of Iron(II) Complexes with 1-Methyl-2-pyridin-2-yl-1H- and 1-Methyl-2-phenyliminomethyl-1H-benzimidazoles and Boron Cluster Anions [BnHn]2– (n = 10, 12)","authors":"V. V. Avdeeva, A. S. Kubasov, S. E. Nikiforova, O. N. Belousova, E. A. Malinina, N. T. Kuznetsov","doi":"10.1134/S1070328425600482","DOIUrl":"10.1134/S1070328425600482","url":null,"abstract":"The study addresses the complex formation reactions between iron(II) and benzimidazole (L) derivatives (L1 = C13N3H11, L2 = C15N3H13) in the presence of boron cluster anion salts [BnHn]2– (n = 10, 12). The prepared complexes [FeL3][BnHn] were characterized by elemental analysis and IR spectroscopy. The structure of [({text{FeL}}_{{text{3}}}^{{text{1}}})][B10H10] was established by single crystal X-ray diffraction (CCDC no. 2432134). The distorted octahedral environment of the Fe atom is formed by the imidazole and pyridine nitrogen atoms of the three ligand molecules. In the crystal, the ({{{text{[FeL}}_{{text{3}}}^{{text{1}}}{text{]}}}^{{{text{2 + }}}}}) complex has a meridional configuration. The Fe–N bond lengths for the imidazole nitrogen atoms are in the 1.954(8)–1.980(6) Å range, while for the pyridine nitrogen atoms, this range is 1.977(7)–2.011(8) Å.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"539 - 545"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis, Structure, and Optical and Electrochemical Properties of a Chromophoric Cyclometalated Iridium(III) Complex 一种显色环金属化铱（III）配合物的合成、结构、光学和电化学性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600561

D. E. Smirnov, S. I. Bezzubov

{"title":"Synthesis, Structure, and Optical and Electrochemical Properties of a Chromophoric Cyclometalated Iridium(III) Complex","authors":"D. E. Smirnov, S. I. Bezzubov","doi":"10.1134/S1070328425600561","DOIUrl":"10.1134/S1070328425600561","url":null,"abstract":"A new N-donor ligand, methyl 4-(1-methyl-1H-pyrimidin-2-yl)nicotinate, and an octahedral cationic iridium(III) complex based on it (I) have been synthesized. 1-Benzyl-2-phenyl[2,3]naphthimidazole was used as the cyclometalated ligand, and ({text{PF}}_{6}^{ - }) serves as the counterion. Compound I was characterized by 1H, 13C, 19F, 31P, 1H,1H–COSY, and 1H,1H–NOESY NMR spectroscopy, high-resolution mass spectrometry, and X-ray diffraction analysis. Due to the coordination of ligands with extended conjugated systems around the metal ion, the target complex absorbs light up to 700 nm (ε ~ 1000 M–1 cm–1), which accounts for its intense coloration. Complex I exhibits reversible electrochemical behavior in the positive potential range with E1/2 = 0.58 V vs. ({{E}_{{{{{text{F}}{{{text{c}}}^{ + }}} mathord{left/ {vphantom {{{text{F}}{{{text{c}}}^{ + }}} {{text{Fc}}}}} right. kern-0em} {{text{Fc}}}}}}}). Based on its key characteristics, the obtained compound surpasses most iridium analogs and appears promising for further evaluation in photovoltaic devices.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"514 - 521"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mononuclear Diphenyltin(IV) Complexes with Salicylaldimine Schiff Bases: Synthesis, Structures, and Electrochemical Properties 水杨醛二胺席夫碱单核二苯基锡配合物：合成、结构和电化学性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600639

P. G. Shangin, V. A. Klok, I. V. Krylova, M. E. Minyaev, E. V. Tretyakov, M. A. Syroeshkin, V. M. Pechennikov, M. P. Egorov, E. N. Nikolaevskaya

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Local Atomic Structure of Co(II), Ni(II), and Cu(II) Metal Chelates Based on 1-Phenyl-3-methyl-4-formyl-5-pyrazolone and 1-Aminobenzimidazole Derivatives 基于1-苯基-3-甲基-4-甲酰基-5-吡唑酮和1-氨基苯并咪唑衍生物的Co（II）、Ni（II）和Cu（II）金属螯合物的局部原子结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600676

A. A. Shiryaeva, V. G. Vlasenko, A. S. Burlov, T. A. Kuz’menko, V. V. Chesnokov, A. I. Uraev, A. L. Trigub

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Metallation of Ketazines: Reaction of Tetralone Azine with Methyllithium 氯他嗪的金属化：四酮嗪与甲基锂的反应

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600317

V. V. Sushev, N. V. Zolotareva, M. D. Grishin, R. V. Rumyantcev, G. K. Fukin, A. N. Kornev

引用次数: 0