Russian Journal of Coordination Chemistry最新文献_第10页

Chiral Cobalt(III) Complexes Based on (1R,2R)-Cyclohexanediamine and 4-Bromo-5-methylsalicylaldehyde: Synthesis, Modification, and Application in Catalysis and Enantioselective Sensors 基于(1R,2R)-环己二胺和4-溴-5-甲基水杨醛的手性钴（III）配合物：合成、修饰及其在催化和对映选择性传感器中的应用

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601468

O. V. Khromova, A. F. Smol’yakov, R. A. Zil’berg, Yu. B. Teres, G. I. Ishmakaeva, V. I. Maleev, V. A. Larionov

{"title":"Chiral Cobalt(III) Complexes Based on (1R,2R)-Cyclohexanediamine and 4-Bromo-5-methylsalicylaldehyde: Synthesis, Modification, and Application in Catalysis and Enantioselective Sensors","authors":"O. V. Khromova, A. F. Smol’yakov, R. A. Zil’berg, Yu. B. Teres, G. I. Ishmakaeva, V. I. Maleev, V. A. Larionov","doi":"10.1134/S1070328424601468","DOIUrl":"10.1134/S1070328424601468","url":null,"abstract":"New chiral octahedral positively charged diastereomeric cobalt(III) complexes Λ(R,R)-1 and Δ(R,R)-1 with two asymmetric NNO-donor ligands (Schiff base of (1R,2R)-cyclohexanediamine and 4‑bromo-5-methylsalicylaldehyde) were synthesized. Single-crystal X-ray diffraction (XRD) analysis showed that the Δ(R,R)-1 complex is arranged in the crystal as a homochiral spiral with a “tube-in-tube” cavity, formed via hydrogen bonding between amino groups of the complex, water molecules, and the counterion. The bromo-containing complex Λ(R,R)-1 was further modified by a catalytic Suzuki–Miyaura cross-coupling reaction to give complexes Λ(R,R)-2 and Λ(R,R)-3 with introduced Ph and 4-CF3C6H4 groups. The structure of complex Λ(R,R)-2 was confirmed by XRD. The catalytic activity of the synthesized complexes was studied in asymmetric phase-transfer alkylation and trimethylsilylcyanation reactions. Cobalt(III) complexes were also tested as chiral selectors for enantioselective voltammetric sensors, and the effect of complex structure on sensor characteristics toward the enantiomers of naproxen and thyroxine was evaluated.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 3","pages":"200 - 210"},"PeriodicalIF":1.1,"publicationDate":"2025-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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cis- and trans-Isomerism in Manganese(II) Complexes with Acylpyrazolonepyridine 锰（II）与酰基吡唑啉配合物的顺式和反式异构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601547

I. A. Nikovskii, A. N. Sinel’nikov, A. S. Bogomyakov, A. V. Borodulina, Yu. V. Nelyubina

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Indium(III) Catecholates Based on Alkyl-Substituted o-Benzoquinones 基于烷基取代邻苯醌的邻苯二甲酸铟(III

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328425600172

I. V. Ershova, I. N. Meshcheryakova, A. V. Maleeva, N. O. Druzhkov, A. V. Cherkasov, A. V. Piskunov

{"title":"Indium(III) Catecholates Based on Alkyl-Substituted o-Benzoquinones","authors":"I. V. Ershova, I. N. Meshcheryakova, A. V. Maleeva, N. O. Druzhkov, A. V. Cherkasov, A. V. Piskunov","doi":"10.1134/S1070328425600172","DOIUrl":"10.1134/S1070328425600172","url":null,"abstract":"A series of dimeric indium(III) catecholates [(R-Cat)InI]2 (R = 3,6-cHex (I), 3,5-tOc (II), 4-tOc (III), and 3,5-C(Me)2Ph (IV)) is synthesized by the oxidative addition of indium(I) iodide to the following alkyl-substituted o-benzoquinones: 3,6-di-cyclo-hexyl-o-benzoquinone (3,6-cHex-Q), 3,5-di-tert-octyl-o-benzoquinone (3,5-tOc-Q), 4-tert-octyl-о-benzoquinone (4-tOc-Q), and 3,5-bis(2-phenylpropan-2-yl)-o-benzoquinone (3,5-C(Me)2Ph-Q). Compounds I–IV are stable in the crystalline state and in solution, and their structures are confirmed by NMR and IR spectroscopy and elemental analysis. The crystallization of complex II from THF gives crystals of two types, cis-II·4THF and trans-II·4THF, corresponding to the cis and trans orientations of the alkyl substituents relatively to the catecholate fragment plane. The reactions of compounds I–IV with 2,2'-bipyridyl afford heteroleptic derivatives (R-Cat)InI(Bipy) (R = 3,6-cHex (V), 3,5-tOc (VI), 4-tOc (VII), and 3,5-C(Me)2Ph (VIII)). Compounds V and VIII are isolated in the individual state and characterized by a set of physicochemical methods. Derivatives VI and VII are unstable and undergo further transformations to form a poorly separable mixture of products. The molecular structures of complexes cis-II·4THF and trans-II·4THF are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2404879 and 2404880, respectively).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 3","pages":"160 - 168"},"PeriodicalIF":1.1,"publicationDate":"2025-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Europium Coordination Compounds for the Design of a Polyethylene-Based Luminescent Composite Material 铕配位化合物用于设计聚乙烯基发光复合材料

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601432

D. M. Roitershtein, L. N. Puntus, E. A. Varaksina, M. E. Minyaev, I. E. Nifantiev

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Monovalent Lanthanide Compounds 单价镧系化合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601407

S. Yu. Bukhvalova, A. A. Fagin, M. N. Bochkarev

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Solid-Phase Cyclopalladation of Bis(thioamide) Pincer Ligands Based on m-Phenylenediamine 基于间苯二胺的双（硫酰胺）螯合配体固相环钯化

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-06-06 DOI: 10.1134/S1070328424601535

D. V. Aleksanyan, Yu. V. Nelyubina, Z. S. Klemenkova, V. A. Kozlov

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New 2D Coordination Polymer of Cobalt(II) Pivalate with 1,4-Diaminobutane: Synthesis and Thermal Properties 新型1,4-二氨基丁烷钴（II）私人酸酯配位聚合物的合成及热性能

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-05-26 DOI: 10.1134/S1070328424601456

V. A. Bushuev, D. S. Yambulatov, N. V. Gogoleva, F. M. Dolgushin, I. V. Skabitsky, S. S. Shapovalov, S. A. Nikolaevskii, M. A. Kiskin, I. L. Eremenko

{"title":"New 2D Coordination Polymer of Cobalt(II) Pivalate with 1,4-Diaminobutane: Synthesis and Thermal Properties","authors":"V. A. Bushuev, D. S. Yambulatov, N. V. Gogoleva, F. M. Dolgushin, I. V. Skabitsky, S. S. Shapovalov, S. A. Nikolaevskii, M. A. Kiskin, I. L. Eremenko","doi":"10.1134/S1070328424601456","DOIUrl":"10.1134/S1070328424601456","url":null,"abstract":"The reaction of cobalt(II) trimethyl acetate (pivalate) [Co(Рiv)2]n (HРiv = HO2CCMe3) with 1,4-diaminobutane (Dab) in powder XRD acetonitrile affords 2D coordination polymer [Co(Piv)2(Dab)2]n (I) with a coproduct impurity, but the addition of one equivalent of 2,2'-bipyridine to the reaction mixture makes it possible to isolate a single-phase sample of compound I (according to the powder XRD X-ray diffraction (XRD) data) in a yield of 78%. The crystal structure of compound I is determined by XRD (CIF file CCDC no. 2404406): the cobalt(II) atoms in the distorted octahedral environment (CoN4O2) of two monodentate carboxylate groups and four bridging Dab molecules form a layered coordination polymer with the honeycomb topology hcb. The thermal behavior of compound I is studied by simultaneous thermal analysis: the thermal decomposition of compound I leads to the formation of organic salt (H2Dab)(Piv)2, cobalt(II) pivalate, and octahedral complex [Co8O2(Piv)12]. The products are identified by powder XRD and NMR spectroscopy.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 2","pages":"112 - 118"},"PeriodicalIF":1.1,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144135379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis of Nickel(II) Complexes with 2,6-Dichlorophenyl-Substituted Pyridylpyrazole 2,6-二氯苯取代吡啶基吡唑镍配合物的合成

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-05-26 DOI: 10.1134/S1070328424601511

I. A. Nikovskii, E. S. Safiullina, Yu. V. Nelyubina

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Structures of Binuclear Fluorooxalatouranylates Rb5[(UO2)2(C2O4)4F]⋅2H2O and Ba5[(UO2)2(C2O4)4F]2⋅22H2O 双核氟草ouranyates Rb5[(UO2)2(C2O4)4F]⋅2H2O和Ba5[(UO2)2(C2O4)4F]2⋅22H2O的结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-05-26 DOI: 10.1134/S1070328424601353

V. N. Serezhkin, M. S. Grigoriev, M. V. Sukacheva, L. B. Serezhkina

{"title":"Structures of Binuclear Fluorooxalatouranylates Rb5[(UO2)2(C2O4)4F]⋅2H2O and Ba5[(UO2)2(C2O4)4F]2⋅22H2O","authors":"V. N. Serezhkin, M. S. Grigoriev, M. V. Sukacheva, L. B. Serezhkina","doi":"10.1134/S1070328424601353","DOIUrl":"10.1134/S1070328424601353","url":null,"abstract":"The structures of novel crystals of Rb5[(UO2)2(C2O4)4F]·2H2O (I) and Ba5[(UO2)2(C2O4)4F]2⋅22H2O (II) (CIF files CCDC nos. 2392480 (I) and 2392481 (II)) are studied by X‑ray diffraction (XRD). The uranyl-containing structural units are the binuclear complexes of the same composition [(UO2)2(C2O4)4F]5– but with different structures, which are described by the crystallochemical formulas ({{{text{A}}}_{{text{2}}}}{{{text{T}}}^{{11}}}{text{B}}_{{text{3}}}^{{{text{01}}}}{{{text{M}}}^{{text{1}}}}) (I) and ({{{text{A}}}_{{text{2}}}}{text{B}}_{{text{4}}}^{{{text{01}}}}{{{text{M}}}^{{text{2}}}}) (II) (A = ({text{UO}}_{{text{2}}}^{{{text{2 + }}}}), T11 or B01 = ({{{text{C}}}_{{text{2}}}}{text{O}}_{{text{4}}}^{{{text{2}} - }}), M1 or M2 = F–). The complexes contain crystallographically nonequivalent U(VI) atoms, which are components of the uranyl ions and implement the pentagonal bipyramidal coordination. In compound I, the U(VI) atoms form coordination polyhedra UO2FO4 and UO2O5, and only UO2FO4 are formed in compound II. In both structures, the binuclear [(UO2)2(C2O4)4F]5– complexes are linked into a 3D framework due to coordination bonds R–O and R–F (R = Rb or Ba). The water molecules involved in the formation of a set of hydrogen bonds are localized in voids of the 3D framework. The IR spectroscopy results for compounds I and II are consistent with the XRD data.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 2","pages":"104 - 111"},"PeriodicalIF":1.1,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144135520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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New Nickel Pincer Complexes Based on Pentamethylruthenocene 新型五甲基鲁二茂镍螯合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-05-26 DOI: 10.1134/S1070328424601559

S. V. Safronov, Yu. V. Nelyubina

{"title":"New Nickel Pincer Complexes Based on Pentamethylruthenocene","authors":"S. V. Safronov, Yu. V. Nelyubina","doi":"10.1134/S1070328424601559","DOIUrl":"10.1134/S1070328424601559","url":null,"abstract":"New nickel(II) pincer complexes based on the pentamethylruthenocene, NiCl[{2,5-(R2PCH2)2C5H2}Ru(Cp*)] (Cp* = C5Me5, Ia: R = tBu; Ib: R = iPr), were synthesized via a two-step route starting from the 1,3-functionally substituted diol {1,3-(HOCH2)C5H3}Ru(Cp*). In the first step, diol was reacted with dialkylphosphines (tBu2PH, iPr2PH) in acetic acid to give diphosphines{1,3-(R2PCH2)2C5H3}Ru(Cp*) (R = tBu; iPr), which were not isolated in a pure state, but after the removal AcOH, was immediately subjected to cyclometallation with nickel(II) chloride hexahydrate in the presence of pyridine. After all purification procedures, the yields of products Ia and Ib were 31 and 16%, respectively. The complexes were fully characterized by 1H, 31P{1H}, and 13C{1H} NMR spectroscopy data. The purity of the products was confirmed by elemental analysis. The structure of complex Ia was established by single crystal X-ray diffraction (CCDC no. 2408463).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 2","pages":"129 - 134"},"PeriodicalIF":1.1,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144135380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0