Russian Journal of Coordination Chemistry最新文献_第10页

Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties 含羧基的镉(II)有机配位聚合物：溶热合成、结构和性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S1070328423600316

B. Xu, W. Yao, X. Yu, D. G. Samsonenko, V. P. Fedin, E. Gao

引用次数: 0

Synthesis and Specific Features of the Molecular and Crystal Structures of Cp4Ru4(µ3-CO)4 Cluster Cp4Ru4(µ3-CO)4团簇的合成及其分子结构和晶体结构的具体特征

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S1070328423600249

S. V. Osintseva, O. V. Semeikin, F. M. Dolgushin, E. D. Tselukovskaya, I. V. Anan’ev

{"title":"Synthesis and Specific Features of the Molecular and Crystal Structures of Cp4Ru4(µ3-CO)4 Cluster","authors":"S. V. Osintseva, O. V. Semeikin, F. M. Dolgushin, E. D. Tselukovskaya, I. V. Anan’ev","doi":"10.1134/S1070328423600249","DOIUrl":"10.1134/S1070328423600249","url":null,"abstract":"Tetranuclear cluster [Ru(μ3-CO)Cp]4 (I) is synthesized as a minor product in the thermal reaction of cyclopentadiene with Ru3(CO)12 aimed at preparing ruthenium dimer [Ru(CO)2Cp]2. The spectral (13С and 1H NMR, IR) and structural studies are carried out for cluster I. Under different conditions, the crystallization of cluster I gives dark cherry-colored crystals of two types: cluster Ia and its tetrahydrate Ib. The structures of compounds Ia and Ib are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2241197 and 2241199, respectively). A comparative analysis of the cluster geometry shows that the distortion of the Ru4(CO)4 cage in compound I from the ideal Td symmetry in the structure of the pure compound is due to anisotropy of intermolecular contacts in the crystal. Specific features of chemical binding in the [Ru(μ3-CO)Cp]4 cluster and its iron-containing analog are studied by DFT calculations using topological analysis of the electron density comparing the energy characteristics and effective force constants of binding interactions. A necessity to use criteria of elastic deformations of interatomic interactions (force constants) for the correction description of such structural chemical phenomena as structural nonrigidity of the cage in transition metal clusters is demonstrated.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138742187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Trimethylammonium Dichlorohexachlorotellurate(IV): Crystal Structure and Specific Features of Noncovalent Cl···Cl Interactions 三甲基二氯六氯锡酸铵（IV）：晶体结构和 Cl-Cl 非共价相互作用的具体特征

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S1070328423600213

A. N. Usol’tsev, A. A. Sonina, N. A. Korobeinikov, S. A. Adonin

引用次数: 0

Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones 氯化钯（II）与单亚氨基苊酮的反应

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S1070328423601176

A. N. Lukoyanov, N. F. Romashev, V. I. Komlyagina, V. V. Kokovkin, A. V. Cherkasov, A. L. Gushchin

{"title":"Reactions of Palladium(II) Chloride with Monoiminoacenaphthenones","authors":"A. N. Lukoyanov, N. F. Romashev, V. I. Komlyagina, V. V. Kokovkin, A. V. Cherkasov, A. L. Gushchin","doi":"10.1134/S1070328423601176","DOIUrl":"10.1134/S1070328423601176","url":null,"abstract":"The reaction of PdCl2 with [2,6-diisopropylphenyl]iminoacenaphthenone (Dpp-mian) in dichloromethane affords compound [Pd(Dpp-mian)Cl2]2[Pd(Dpp-mian)2Cl2] (I). Complex I contains two structural units: [Pd(Dpp-mian)Cl2] in which Dpp-mian coordinates to Pd(II) via the bidentate-chelate mode by the nitrogen and oxygen atoms and [Pd(Dpp-mian)2Cl2] where two Dpp-mian molecules are linked with palladium only via the nitrogen atom. The reaction of PdCl2 with [4-methoxyphenyl]iminoacenaphthenone (4-MeOPh-mian) in dichloromethane is accompanied by the rearrangement of the ligand structure followed by the formation of the earlier described Pd(II) complex with 1,2-bis[4-methoxyphenyl]iminoacenaphthene (4-MeOPh-bian): [Pd(4-MeOPh-bian)Cl2] (II) (CIF file CCDC no. 2280529). Compound I is synthesized for the first time and characterized by X-ray diffraction (XRD) (CIF file CCDC no. 2280528 (I)), phase XRD, elemental analysis, IR spectroscopy, and cyclic voltammetry.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138741831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Mixed-Ligand Complex [Cu4(bpy)4(PO4)2(CO3)(H2O)2]: Synthesis, Crystal Structure, and Biological Properties 混合配体[Cu4(py)4(PO4)2(CO3)(H2O)2]：合成、晶体结构和生物学特性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S1070328423601073

K. A. Koshenskova, N. V. Makarenko, D. E. Baravikov, F. M. Dolgushin, O. B. Bekker, I. L. Eremenko, I. A. Lutsenko

{"title":"Mixed-Ligand Complex [Cu4(bpy)4(PO4)2(CO3)(H2O)2]: Synthesis, Crystal Structure, and Biological Properties","authors":"K. A. Koshenskova, N. V. Makarenko, D. E. Baravikov, F. M. Dolgushin, O. B. Bekker, I. L. Eremenko, I. A. Lutsenko","doi":"10.1134/S1070328423601073","DOIUrl":"10.1134/S1070328423601073","url":null,"abstract":"The reactions in the Cu(OAc)2⋅H2O–phytic acid–2,2'-bipyridine (bpy) system in aqueous methanol solutions resulted in the formation of a molecular different-ligand tetranuclear complex [(Cu4(bpy)4(PO4)2(CO3)(H2O)2]⋅13H2O (I), the structure of which was established from the X-ray diffraction data (CCDC no. 2262998). The molecule of complex I contains four non-equivalent Cu2+ cations, coordinating each two phosphate anions (({text{PO}}_{4}^{{3 - }}) remaining after the transformation of the phytate ring), four neutral bpy molecules, two water molecules, and one carbonate anion (({text{CO}}_{3}^{{2 - }})). The presence of a large number of solvate water molecules in the outer coordination sphere gives rise to a hydrogen-bonded framework involved in stabilization of the crystal packing. Study of the antimycobacterial activity of I against non-pathogenic Mycolicibacterium smegmatis strain revealed high biological efficacy.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138742632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Low-Temperature Behavior of the Heat Capacity and Photoluminescence of the Binuclear Pivalate Complex [Eu2(Bаth)2(Piv)6] 双核新戊酸盐配合物 [Eu2(Bаth)2(Piv)6]的热容量和光致发光的低温行为

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S107032842360105X

I. G. Fomina, A. V. Tyurin, Yu. S. Zavorotnyi, I. L. Eremenko

{"title":"Low-Temperature Behavior of the Heat Capacity and Photoluminescence of the Binuclear Pivalate Complex [Eu2(Bаth)2(Piv)6]","authors":"I. G. Fomina, A. V. Tyurin, Yu. S. Zavorotnyi, I. L. Eremenko","doi":"10.1134/S107032842360105X","DOIUrl":"10.1134/S107032842360105X","url":null,"abstract":"The low-temperature behavior of the heat capacity and photoluminescence of the earlier structurally characterized binuclear pivalate complex [Eu2(Bath)2(Piv)6] (monoclinic crystal system, I2/a) (I), where Bath = 4,7-diphenyl-1,10-phenanthroline, Piv = ({{{text{(C}}{{{text{H}}}_{{text{3}}}}{text{)}}}_{{text{3}}}}{text{CCO}}_{2}^{ - }), is studied. The temperature dependence of the heat capacity in a temperature range of 5.96–302.88 K is measured by adiabatic calorimetry, and the thermodynamic functions (C_{p}^{^circ })(T), S°(T), Ф°(Т), and Н°(Т) – Н°(0) are calculated. The absence of low-temperature phase transitions in complex I is shown. In a temperature range of 98–295 K, complex I demonstrates a high temperature stability of the integral photoluminescence intensity of the 5D0–7Fj (j = 0–6) transitions of the Eu3+ ion.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138741771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chemical Transformations of [Pd(OOCMe)4Mn] in the Reactions with 1,10-Phenanthroline and Pivalic Acid [Pd(OOCMe)4Mn]与 1,10-菲罗啉和特戊酸反应中的化学变化

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-12-19 DOI: 10.1134/S1070328423600754

E. A. Sosunov, A. D. Maksimova, I. A. Yakushev, N. K. Ogarkova, M. N. Vargaftik, A. S. Popova

{"title":"Chemical Transformations of [Pd(OOCMe)4Mn] in the Reactions with 1,10-Phenanthroline and Pivalic Acid","authors":"E. A. Sosunov, A. D. Maksimova, I. A. Yakushev, N. K. Ogarkova, M. N. Vargaftik, A. S. Popova","doi":"10.1134/S1070328423600754","DOIUrl":"10.1134/S1070328423600754","url":null,"abstract":"A series of new Pd–Mn bimetallic acetate and pivalate complexes were synthesized and structurally characterized. The starting [Pd(OOCMe)4Mn] complex reacts with N‑donor ligands such as 1,10-phenanthroline (phen) to give [Pd(OOCMe)4Mn(phen)]⋅MeCN (I) (CCDC no. 2217716). The replacement of acetate bridges in the heterometallic Pd–Mn carboxylate complexes with pivalate bridges was investigated. It was shown that complete replacement of all acetate bridges with pivalate ones can occur both in heterometallic complex I, which contains a ligand coordinated to the second metal atom, to give the compound [Pd(Piv)4Mn(phen)]⋅C6H6 (II) (CCDC no. 2217717), structurally related to the initial acetate complex, and in the acetate complex [Pd(OOCMe)4Mn]. The heterometallic co-crystallized pivalate [Pd(Piv)4Mn⋅2HPiv] (III) (CCDC no. 2217718) formed in the latter case can react with 5-nitro-1,10-phenanthroline to give the complex [Pd(Piv)4Mn(Nphen)] (IV) (CCDC no. 2217719).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138741772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Heterophase Synthesis of Silver Trifluoroacetate with Copper, Indium, and Zinc. Standard Enthalpy of Formation of Copper Trifluoroacetate 铜、铟、锌异相合成三氟乙酸银的研究。三氟乙酸铜的标准生成焓

IF 1.9 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-11-01 DOI: 10.1134/S1070328423600237

I. P. Malkerova, D. B. Kayumova, E. V. Belova, M. A. Shmelev, A. A. Sidorov, I. L. Eremenko, A. S. Alikhanyan

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Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of a Dinuclear Copper Complex with Pyrazole 吡唑双核铜配合物的合成、晶体结构和Hirschfeld表面分析

IF 1.9 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-11-01 DOI: 10.1134/S1070328422600498

Z. Q. Li, J. J. Guo, C. Feng

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Structure and Magnetic Properties of the Single Crystal of the Liquid-Crystalline Cu(II) Complex with β-Enaminoketone 液晶Cu（II）与β-烯酮配合物的单晶结构和磁性

IF 1.9 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2023-11-01 DOI: 10.1134/S1070328423600614

O. A. Turanova, A. T. Gubaidullin, A. A. Sukhanov, E. N. Frolova, V. N. Kovganko, A. F. Saifina, A. N. Turanov

引用次数: 0