Russian Journal of Coordination Chemistry最新文献_第9页

Simple Catalyst Based on Zinc(II) Iodide for the Synthesis of Cyclic Carbonates 基于碘化锌的简单催化剂合成环状碳酸盐

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-11-18 DOI: 10.1134/S1070328425600731

M. D. Tugushev, D. D. Strunin, A. A. Dan’shina, Yu. V. Nelyubina, I. A. Nikovskii

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Supramolecular Lanthanide Complexes with Cucurbituril: Luminescence and Logical Devices 瓜脲类超分子镧系配合物：发光和逻辑器件

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-11-18 DOI: 10.1134/S1070328425600810

M. I. Rakhmanova, T. S. Sukhikh, E. A. Kovalenko

{"title":"Supramolecular Lanthanide Complexes with Cucurbituril: Luminescence and Logical Devices","authors":"M. I. Rakhmanova, T. S. Sukhikh, E. A. Kovalenko","doi":"10.1134/S1070328425600810","DOIUrl":"10.1134/S1070328425600810","url":null,"abstract":"Complexes [{DyxLn(2 – x)(H2O)5(NO3)}2CB[6]](NO3)4·HNO3·6H2O (x = 1, Ln = Eu; x = 0.8, Gd, Ho) (I–III) are synthesized from a mixture of lanthanide nitrates and cucurbit[6]uril (C36H36N24O16, CB[6]) in nitric acid on heating to 100°С. According to the X-ray diffraction (XRD) data, in compounds I–III the lanthanide cation coordinates two oxygen atoms of the CB[6] molecule, H2O molecules, and nitrate ions. Compounds I–III are characterized by XRD, IR spectroscopy, ICP-OES spectroscopy, and elemental analysis. The coordinates of chromaticity points are determined from the luminescence spectra, and their values are very close to the white light coordinates. This specific feature is a consequence of the presence of two Dy3+-centered emission bands with comparable intensities. One of these bands is the hypersensitive transition 4F9/2 → 6H13/2 caused by a relatively high symmetry of the coordination lanthanide environment close to C4v. In addition, a peculiarity of compounds I–III is a strong dependence of the luminescence spectrum on the excitation wavelength. Models of molecular logical devices with a possibility of switching over luminescent signal of irradiation with different wavelengths are proposed on the basis of this phenomenon.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 8","pages":"740 - 748"},"PeriodicalIF":1.1,"publicationDate":"2025-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145537771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Antimicrobial Applications of Fe(II) and Fe(III) Schiff Base Complexes: Role of Complexation in Activity Enhancement: A Review (2020–2025) 铁（II）和铁（III）希夫碱配合物的抗菌应用：络合作用在活性增强中的作用：综述（2020-2025）

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-11-10 DOI: 10.1134/S1070328425600974

M. S. Alhussaini, A. A. I. Alyahya, A. A. Al-Ghanayem

{"title":"Antimicrobial Applications of Fe(II) and Fe(III) Schiff Base Complexes: Role of Complexation in Activity Enhancement: A Review (2020–2025)","authors":"M. S. Alhussaini, A. A. I. Alyahya, A. A. Al-Ghanayem","doi":"10.1134/S1070328425600974","DOIUrl":"10.1134/S1070328425600974","url":null,"abstract":"Schiff base ligands and their coordination complexes with transition metals have garnered significant interest in medicinal chemistry due to their diverse biological activities, particularly antimicrobial properties. Among them, Fe(II) and Fe(III) complexes have shown remarkable potential as antimicrobial agents against a broad spectrum of pathogens. This review highlights recent advances (2020 to 2025) in the antimicrobial evaluation of Fe(II) and Fe(III) Schiff base complexes. Key studies reporting improved efficacy against bacterial and fungal strains are examined, with a focus on structural variations of ligands, coordination geometries, and the influence of metal oxidation states on bioactivity. A central theme of this review is the role of complexation in enhancing antimicrobial activity. The process of forming metal–ligand complexes has been shown to improve membrane permeability, increase reactive oxygen species (ROS) generation, and inhibit essential microbial enzymes. Additionally, the electronic and steric properties of the Schiff base framework significantly affect metal chelation and, in turn, biological performance. By correlating molecular design with antimicrobial outcomes, this review offers valuable insights into structure–activity relationships and highlights future directions for developing iron-based metallopharmaceuticals with enhanced therapeutic potential.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 9","pages":"829 - 841"},"PeriodicalIF":1.1,"publicationDate":"2025-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145772113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Scandium(III) 1,1,1-Trifluorohexane-2,4-dionate Complex: Synthesis, Structure, and Thermal Properties 钪（III） 1,1,1-三氟己烷-2,4-二酸配合物：合成、结构和热性能

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S1070328425600536

A. V. Sartakova, S. V. Sysoev, A. M. Makarenko, N. V. Kurat’eva, D. P. Pishchur, K. V. Zherikova

{"title":"Scandium(III) 1,1,1-Trifluorohexane-2,4-dionate Complex: Synthesis, Structure, and Thermal Properties","authors":"A. V. Sartakova, S. V. Sysoev, A. M. Makarenko, N. V. Kurat’eva, D. P. Pishchur, K. V. Zherikova","doi":"10.1134/S1070328425600536","DOIUrl":"10.1134/S1070328425600536","url":null,"abstract":"A new scandium(III) 1,1,1-trifluorohexane-2,4-dionate complex [Sc(5Htfac)3] was synthesized, purified, and characterized by elemental analysis, NMR spectroscopy, and mass spectrometry. Its structure was determined at 150 K by X-ray diffraction analysis (CCDC no. 2433044). The complex has a molecular structure in which the bidentate cyclic ligands are arranged according to the os-isomer. Shortened H…F interactions were identified in the structure. The thermal properties were studied by TGA and DSC, and the fusion temperature (309.3 ± 0.5 K), enthalpy (ΔfusH°(Tfus) = 36.0 ± 1.4 kJ mol–1), and entropy (ΔfusS°(Tfus) = 116.5 ± 4.5 J mol–1 K–1) were determined. The temperature dependence of the saturated vapor pressure was measured by the flow method (343–433 K) and the static method with a membrane null manometer (410–470 K). On this basis, the thermodynamic characteristics of vaporization at average and standard temperatures were calculated (ΔvapH°(298.15 K) = 100.2 ± 1.3 kJ mol–1, ΔvapS°(298.15 K) = 201.8 ± 2.8 J mol–1 K–1). From these data, the sublimation parameters of the complex were obtained (ΔsubH°(298.15 K) = 135.3 ± 1.9 kJ mol–1, ΔsubS°(298.15 K) = 315.3 ± 5.4 J mol–1 K–1). The structure and thermal properties of [Sc(5Htfac)3] were compared with those of two scandium(III) β-diketonates bearing methyl and tert-butyl substituents in the ligand.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 7","pages":"628 - 636"},"PeriodicalIF":1.1,"publicationDate":"2025-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145327631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Template Synthesis of the Copper(II) Complex with the Pyridylpyrazolone Ligand 吡啶基吡唑酮配体铜配合物的模板合成

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S1070328424601493

D. D. Strunin, I. A. Nikovskii, T. M. Aliev, Yu. V. Nelyubina

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Synthesis of the Cobalt(II) Aqua Complex with Acetylpyridylpyrazolone 乙酰吡啶基吡唑酮与钴（II）水配合物的合成

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S107032842460150X

M. D. Tugushev, I. A. Nikovskii, S. A. Solov’eva, Yu. V. Nelyubina

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Complexes of Pivaloyltrifluoroacetonates of Potassium and Rubidium with 18-Crown-6 Ether: Synthesis, Structure, Thermal Properties 18-冠-6醚钾铷二戊酰三氟丙酮酸配合物的合成、结构和热性能

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S1070328425600494

D. V. Kochelakov, E. S. Vikulova

{"title":"Complexes of Pivaloyltrifluoroacetonates of Potassium and Rubidium with 18-Crown-6 Ether: Synthesis, Structure, Thermal Properties","authors":"D. V. Kochelakov, E. S. Vikulova","doi":"10.1134/S1070328425600494","DOIUrl":"10.1134/S1070328425600494","url":null,"abstract":"<div>In a search for volatile fluorinated compounds of potassium and rubidium, new complexes of the corresponding pivaloyltrifluoroacetonates (Ptac) with 18-crown-6 ether, [K(18C6)(Ptac)] (I) and [Rb(18C6)(Ptac)] (II), were synthesized. The compounds were characterized by elemental analysis, IR spectroscopy, and X-ray fluorescence analysis, and their structures were studied by single-crystal X-ray diffraction (SCXRD) in the range of 100–400 K (CCDC nos. 2429226–2429232 (I), 2429233–2429239 (II)). The complexes are isostructural and have an molecular mononuclear structure, with M…H and M…C contacts involving the tert-butyl group between fragments, forming chains. The thermal expansion tensors are elongated along this direction. X-ray diffraction analysis showed that the rubidium cation in such a complex can complete its coordination sphere with a solvent molecule (chloroform, CCDC no. 2429240 (IIs)). For I, II, and IIs, Hirshfeld surface were analyzed and a search for pseudoperiodicity in the crystal packings was carried out using the translational sublattice method. Thermogravimetric analysis showed that, unlike the initial pivaloyltrifluoroacetonates, complexes I and II are volatile and promising for testing in gas-phase processes of thin-film material deposition.</div>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 7","pages":"595 - 606"},"PeriodicalIF":1.1,"publicationDate":"2025-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145327633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Structural Characteristics of (N-Thiocyanato)chromates(III) of Lanthanides(III) with Pyridine-3-carboxylic Acid 含吡啶-3-羧酸镧系元素（III）（n -硫氰酸酯）铬酸盐（III）的结构特征

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S1070328425600366

E. V. Cherkasova, N. V. Pervukhina, N. V. Kuratieva, T. G. Cherkasova

{"title":"Structural Characteristics of (N-Thiocyanato)chromates(III) of Lanthanides(III) with Pyridine-3-carboxylic Acid","authors":"E. V. Cherkasova, N. V. Pervukhina, N. V. Kuratieva, T. G. Cherkasova","doi":"10.1134/S1070328425600366","DOIUrl":"10.1134/S1070328425600366","url":null,"abstract":"To complete the studies of double complex compounds, (N-thiocyanato)chromates(III) of lanthanide complexes with pyridine-3-carboxylic acid, new compounds of the compositions [LnL3(H2O)2][Cr(NCS)6]·nH2O were synthesized from aqueous solutions (Ln = Pr (I), n = 1.5; Sm (II), Gd (III), Tb (IV), n = 2; L = C6H5NO2). The substances were studied by chemical analysis, IR spectroscopy, and PXRD (CCDC nos. 2427051–2427054). In the crystal structures of complexes I–IV, the cation has a chain structure due to the bidentate-bridging function of pyridine-3-carboxylic (nicotinic) acid molecules. The coordination environment of the lanthanide atoms consists of eight oxygen atoms belonging to six nicotinic acid molecules and two coordinated H2O molecules, located at the vertices of a distorted square antiprism. In the isolated [Cr(NCS)6]3– anions, the Cr coordination polyhedron consists of the N atoms of six thiocyanate ions and is close to a regular octahedron. In the structures of complexes I–IV, the space between polymeric cations is filled with complex anions and crystallization water molecules. Additionally, the structure is stabilized by intermolecular hydrogen bonds.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 7","pages":"579 - 585"},"PeriodicalIF":1.1,"publicationDate":"2025-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145327629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Structure and Properties of Magnesium Complexes with Bulky β-Diketones: 2,2,6,6-Tetramethylheptane-3,5-dione and Its Methoxy-Substituted Derivative 含大体积β-二酮：2,2,6,6-四甲基庚烷-3,5-二酮及其甲氧基取代衍生物的镁配合物的结构和性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S1070328425600408

E. A. Rikhter, E. S. Vikulova, T. S. Sukhikh, A. V. Strigunovskaya, N. B. Morozova

{"title":"Structure and Properties of Magnesium Complexes with Bulky β-Diketones: 2,2,6,6-Tetramethylheptane-3,5-dione and Its Methoxy-Substituted Derivative","authors":"E. A. Rikhter, E. S. Vikulova, T. S. Sukhikh, A. V. Strigunovskaya, N. B. Morozova","doi":"10.1134/S1070328425600408","DOIUrl":"10.1134/S1070328425600408","url":null,"abstract":"In order to study the effect of bulky terminal substituents in the β-diketonate ligand on the structure and properties of volatile magnesium compounds, complexes with 2,2,6,6-tetramethylheptane-3,5-dione (HThd) and, for the first time, with 2-methoxy-2,6,6-trimethylheptane-3,5-dione (HZis) were obtained. The complexes [Mg2(L)4] (L = Thd (I), Zis (II)), the synthesis intermediates [Mg(H2O)2(L)2] (L = Thd (III), Zis (IV)), and aqua derivative [Mg2(H2O)(Zis)4] (V) were characterized by elemental analysis and IR spectroscopy. The structures of binuclear complexes and the synthesis by-product [Mg7(Zis)6(μ-OH)6]Cl2·5CHCl3 (VI) were established by X-ray diffraction (CCDC nos. 2424128 (Ia, a new polymorph), 2424130 (II), 2424129 (V), 2424126 (V·1/2CHCl3), 2424127 (VI) ). Both [Mg2(L)4] molecules are characterized by asymmetric environment of metal centers (the Mg coordination number (C.N.) is 5, 6), but in I, three μ,κ2:1-ligands occupy bridging positions, while in II, two ligands have different coordinations (μ,κ2:κ1 and μ,κ2(O,O'):κ2(O',OOMe)). The inclusion of water in II to give V is not associated with any significant structural rearrangement, but C.N. of the unsaturated metal center changes from 5 to 6. Thermogravimetric analysis showed that complex I is more volatile and low-melting than II.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 7","pages":"615 - 627"},"PeriodicalIF":1.1,"publicationDate":"2025-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145327535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis and Crystal Structure of Cobalt Complexes with Cucurbit[6]uril 瓜bbbbil钴配合物的合成及晶体结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-10-20 DOI: 10.1134/S1070328425600469

I. V. Andrienko, D. G. Samsonenko, E. A. Kovalenko

{"title":"Synthesis and Crystal Structure of Cobalt Complexes with Cucurbit[6]uril","authors":"I. V. Andrienko, D. G. Samsonenko, E. A. Kovalenko","doi":"10.1134/S1070328425600469","DOIUrl":"10.1134/S1070328425600469","url":null,"abstract":"Four cobalt complexes with cucurbit[6]uril (CB[6]), [Co(H2O)6](Bdc)·CB[6]·14.5H2O (I), 2(H2NMe2)2[CoCl4]·CB[6]·12H2O (II), [{Co(H2O)4Cl}4(CB[6])]Cl4·9H2O (III), and [Co(H2O)6]-[Co(H2O)5(Dmf)][CoCl4]2·CB[6]·6H2O (IV), were prepared by evaporation of the reaction solution containing cobalt chloride and cucurbit[6]uril (CB[6]). According to X-ray diffraction data, compound I is formed by packing of cationic cobalt aqua complexes, terephthalate anions, and CB[6] molecules linked together by hydrogen bonds with crystallization water molecules into a supramolecular cage. The structure of compound II represents a packing of CB[6] molecules, dimethylammonium cations, and anionic cobalt chloro complexes. Compound III contains tetranuclear cationic cobalt chloro aqua complexes with CB[6], with chloride anions acting as counter-ions. The crystal structure of IV is a packing of cationic cobalt aqua complexes, anionic cobalt chloro complexes, and CB[6] molecules linked by hydrogen bonds with crystallization water molecules into a supramolecular cage. The resulting compounds are characterized by IR spectra and elemental analysis data.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 7","pages":"586 - 594"},"PeriodicalIF":1.1,"publicationDate":"2025-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145327534","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0