Russian Journal of Coordination Chemistry最新文献_第8页

Stereochemistry of the cis-Tetrafluoro Complexes of Titanium with 1-Ac-2-[Ph2P(O)]-Cyclohexane (1RS,2SR) Stereoisomers in СН2Сl2 钛与 1-Ac-2-[Ph2P(O)]-环己烷（1RS,2SR）立体异构体在 СН2Сl2 中的顺式四氟络合物的立体化学性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423700719

E. G. Il’in, A. S. Parshakov, V. I. Privalov, A. V. Churakov, G. V. Bodrin, E. I. Goryunov

{"title":"Stereochemistry of the cis-Tetrafluoro Complexes of Titanium with 1-Ac-2-[Ph2P(O)]-Cyclohexane (1RS,2SR) Stereoisomers in СН2Сl2","authors":"E. G. Il’in, A. S. Parshakov, V. I. Privalov, A. V. Churakov, G. V. Bodrin, E. I. Goryunov","doi":"10.1134/S1070328423700719","DOIUrl":"10.1134/S1070328423700719","url":null,"abstract":"The monodentate phosphoryl-containing ligand 1-Ac-2-[Ph2P(O)]-cyclohexane (L) bearing two asymmetric carbon atoms is synthesized. The study of its crystal structure shows that L is a racemic mixture of (1R,2S) and (1S,2R) stereoisomers. The complex formation of L with TiF4 in СН2Сl2 is studied by 19F{1Н} and 31Р{1Н} NMR spectroscopy. The compositions of the complexes formed in the solution are determined. Racemic and meso-diastereomers of the octahedral complex cis-TiF4L2 are formed in the solution as found by an analysis of the 19F and 31Р NMR spectra taking into account the concept of heterotropy of organic compounds. The influence of the optical configuration of stereoisomers of the monodentate ligand coexisting in the coordination sphere of the [MF4L2] octahedral tetrafluoro complexes of transition d0 metals on the chemical shifts of the fluorine atoms arranged in the trans positions relative to each other is shown. In the meso-diastereomer of cis-TiF4L2, this results in a nonequivalence of the fluorine atoms on the F–Ti–F' ordinate of the octahedron, and the spin-spin coupling constant JFF' = 286.1 Hz is observed in the 19F{1H} NMR spectrum.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Gold(I) Chloride Complexes with 4-Halo-Substituted Phenyl Isocyanide Ligands 具有 4-卤代苯基异氰酸配体的氯化金(I)配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423600596

G. A. Gavrilov, K. N. Davletbaeva, M. A. Kinzhalov

{"title":"Gold(I) Chloride Complexes with 4-Halo-Substituted Phenyl Isocyanide Ligands","authors":"G. A. Gavrilov, K. N. Davletbaeva, M. A. Kinzhalov","doi":"10.1134/S1070328423600596","DOIUrl":"10.1134/S1070328423600596","url":null,"abstract":"A series of gold(I) monoisocyanide [AuCl(CNC6H4-4-X)] (X = Cl (IIa), Br (IIb), I (IIc) and bis-isocyanide [Au(CNC6H4-4-X)2](PF6) (X = Cl (IIIa), Br (IIIb), I (IIIc) complexes were prepared by the reaction of [AuCl(Tht)] (Tht = tetrahydrothiophene) with the specified isocyanide. The molecular structure of IIa–IIc was established by X-ray diffraction (CCDC no. 2253450 (IIa), 2253447 (IIb), 2253448 (IIc)). The crystals of IIb and IIc are isostructural; they were found to have several types of intermolecular interactions, particularly, C–X⋯Cl–Au halogen bonds, π-hole (CCNR)···(~{{d}_{{{{z}^{2}}}}})(Au) interactions, and Au⋯Au aurophilic contacts, which form together a two-layer 2D supramolecular polymer. The crystals of IIb, IIc and IIIa, IIIb exhibit phosphorescence at room temperature; compounds IIa and IIIc do not possess luminescent properties; and mechanical grinding of IIa‒IIc and IIIa‒IIIc powders does not change the photophysical properties.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938567","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Modern Trends in the Synthesis of Disulfides: From Metal-Containing Catalysts to Nonmaterial Reagents (Review) 二硫化物合成的现代趋势：从含金属催化剂到非物质试剂（综述）

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-03-08 DOI: 10.1134/S1070328423600985

D. A. Burmistrova, I. V. Smolyaninov, N. T. Berberova

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Transition Metal (Zn(II), Co(II), Cu(II), Ni(II)) Complexes for the Removal of Acidic Sulfur Impurities from Hydrocarbon Fuel 过渡金属（Zn(II)、Co(II)、Cu(II)、Ni(II)络合物用于去除碳氢化合物燃料中的酸性硫杂质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-03-08 DOI: 10.1134/S1070328423600638

V. N. Storozhenko, A. S. Kamyshnikova, K. P. Pashchenko, A. O. Okhlobystin, I. L. Eremenko, N. T. Berberova

{"title":"Transition Metal (Zn(II), Co(II), Cu(II), Ni(II)) Complexes for the Removal of Acidic Sulfur Impurities from Hydrocarbon Fuel","authors":"V. N. Storozhenko, A. S. Kamyshnikova, K. P. Pashchenko, A. O. Okhlobystin, I. L. Eremenko, N. T. Berberova","doi":"10.1134/S1070328423600638","DOIUrl":"10.1134/S1070328423600638","url":null,"abstract":"The review addresses the main approaches to desulfurization of hydrocarbon products by adsorption methods. Examples of the use of various supports (metal-organic frameworks, various porous carbons, silica, and alumina) for the removal of acidic sulfur components from gas and liquid hydrocarbons are presented. Modification of the supports with transition metals, oxides, salts, and complex compounds to remove hydrogen sulfide and thiols from hydrocarbon raw materials is substantiated. The environmental friendliness and lower energy consumption for the use of silica gel modified with Zn(II), Co(II), Ni(II), and Cu(II) carboxylates to refine hydrocarbon fuel are demonstrated. A comparison of the theoretical calculations (DFT) with experimental results attests to good agreement between the data. The choice of the parameters for silica gel surface modification with metal carboxylates is discussed, including pore size of the support, time and power of the ultrasonic treatment for the support impregnation with solutions of complexes, optimal concentration of transition metal complexes, effect of the geometry of complexes on their adsorption and on the absorption of acidic sulfur components, and so on. According to quantum chemical calculations and experimental results, metal sulfides are formed as the final products of reactions of both hydrogen sulfide and thiols with metal carboxylates. Zinc pivalate is proposed as the most promising modifier for silica, which not only efficiently removes sulfur impurities, but also gives rise to nontoxic zinc sulfide supported on silica gel.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140076506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Metal Complexes with Redox-Active Ligands in the Indirect Electrosynthesis of Organic Sulfur Compounds 氧化还原活性配体金属配合物在有机硫化合物间接电合成中的应用

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-03-08 DOI: 10.1134/S107032842360122X

E. V. Shinkar’, I. V. Smolyaninov, N. T. Berberova

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Organic Sulfur Derivatives and Their Metal Complexes as Promising Pharmacologically Active Compounds 有望成为药理活性化合物的有机硫衍生物及其金属络合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-03-08 DOI: 10.1134/S1070328423600894

V. P. Osipova, N. T. Berberova

{"title":"Organic Sulfur Derivatives and Their Metal Complexes as Promising Pharmacologically Active Compounds","authors":"V. P. Osipova, N. T. Berberova","doi":"10.1134/S1070328423600894","DOIUrl":"10.1134/S1070328423600894","url":null,"abstract":"The mechanism of biological activity of various sulfur-containing compounds and sulfur fragments of both natural and synthetic origins is presented. Unique characteristics of organosulfur compounds that are present in natural plant products are considered to reveal the most efficient sulfur components of the natural origin. An insufficient efficiency of the pharmacological action of plant raw materials and undesirable effects indisputably confirm the topical character of research on the preparation of modified analogs of natural biologically active sulfur-containing compounds. The modern data on the development of new polytopic organosulfur compounds combining different redox-active functional groups in the structure, which should favor their efficiency and a decrease in side manifestations, are reviewed. Sulfur-containing metal complexes with antimicrobial, antiviral, and anticancer properties are among the most promising pharmacologically active compounds. In spite of the success achieved in this field of chemistry, the preparation of new target-oriented biodrugs based on bioessential metals (Cu, Zn, Se) and biomimetic organosulfur fragments remains to be an urgent problem. The developments in this direction should favor to understand mechanisms of the therapeutic action of new drugs and to prepare drugs of the new generation followed by their implementation in clinical practice.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140071402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Luminescent Metal Complexes of Polydentate Azomethine Ligands 多齿偶氮金属配体的发光金属配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-02-27 DOI: 10.1134/S1070328423600845

A. S. Burlov, V. G. Vlasenko, D. A. Garnovskii, A. I. Uraev, Yu. V. Koshchienko, E. I. Mal’tsev, D. A. Lypenko, A. V. Dmitriev

{"title":"Luminescent Metal Complexes of Polydentate Azomethine Ligands","authors":"A. S. Burlov, V. G. Vlasenko, D. A. Garnovskii, A. I. Uraev, Yu. V. Koshchienko, E. I. Mal’tsev, D. A. Lypenko, A. V. Dmitriev","doi":"10.1134/S1070328423600845","DOIUrl":"10.1134/S1070328423600845","url":null,"abstract":"The article represents a translated, revised, and updated Section 6.3 of the monograph by A.S. Burlov, V.G. Vlasenko, D.A. Garnovskiy, A.I. Uraev, E.I. Maltsev, D.A. Lypenko, and A.V. Vannikov, Electroluminescent Organic Light-Emitting Diodes Based on Metal Coordination Compounds, Rostov-on-Don: Yuzhn. Fed. Univ., 2015; ISBN 978-5-9275-1469-4 (see Additional Information). This section is dedicated to reviewing the photoluminescence and electroluminescence properties of metal complexes based on bi- and polydentate ligands of the azomethine type (Schiff bases). Many metal complexes of Schiff bases find wide use as luminescent materials. One of the applications of these compounds is the use as emissive layers or dopants for manufacturing OLED. The photo- and electroluminescence properties of a series of the metal complexes with the ligands based on the derivatives of hydroxybenzaldehyde, 2-(N-tosylamino)benzaldehyde, 1‑phenyl-3-methyl-4-formylpyrazol-5-one, and some others are reviewed. The systematic categorization of these compounds extends beyond their photophysical properties to consider the electroluminescence characteristics observed in OLED devices employing them as the basis. By modifying known azomethine-type ligand systems, one can obtain metal complex compounds with exceptional thermal stability, solubility, and quantum efficiency. These characteristics enable their use as luminescent materials in highly efficient OLED devices.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140008784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Luminescence Properties of the Iridium(III) Complexes 铱（III）配合物的发光特性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-02-27 DOI: 10.1134/S1070328423600857

A. S. Burlov, V. G. Vlasenko, D. A. Garnovskii, A. I. Uraev, Yu. V. Koshchienko, E. I. Mal’tsev, D. A. Lypenko, A. V. Dmitriev

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Photoluminescence and Electroluminescence of Metal Complexes of Quinoline Derivatives 喹啉衍生物金属络合物的光致发光和电致发光

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-02-27 DOI: 10.1134/S1070328423600821

A. S. Burlov, V. G. Vlasenko, D. A. Garnovskii, A. I. Uraev, Yu. V. Koshchienko, E. I. Mal’tsev, D. A. Lypenko, A. V. Dmitriev

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Electroluminescence and Organic Light-Emitting Diodes 电致发光和有机发光二极管

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-02-27 DOI: 10.1134/S107032842360078X

E. I. Mal’tsev, D. A. Lypenko, A. V. Dmitriev, A. V. Vannikov, A. S. Burlov, V. G. Vlasenko

引用次数: 0