3,6-二吡啶-1,2,4,5-四嗪在含苯甲酸型配体的锌和镉金属有机骨架合成中的应用

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424700726

O. Yu. Trofimova, D. S. Kolevatov, N. O. Druzhkov, A. V. Maleeva, I. A. Yakushev, P. V. Dorovatovskii, A. V. Piskunov

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引用次数: 0

摘要

采用两段合成方法制备了锌（3D MOF）和镉（2D MOF）的新型杂电性金属有机骨架（MOF）： [Zn(pQ)(DPT)]·2DMF (I)和[Cd2(NO3)2-(pQ)(DPT)3]·2DMF·2MeOH (II)，其中pQ为2,5-二羟基-3,6-二叔丁基对苯醌二离子，DPT为3,6-二（吡啶-4-基）-1,2,4,5-四嗪，DMF为N，N-二甲基甲酰胺（DMF）。用XRD (CIF文件CCDC no . 2332754 （I)和2332755 (II)）研究了化合物的结构。用热重法研究了MOF的热稳定性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

3,6-Dipyridyl-1,2,4,5-tetrazine in the Synthesis of Zinc and Cadmium Metal-Organic Frameworks with Anilate-Type Ligands

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3,6-Dipyridyl-1,2,4,5-tetrazine in the Synthesis of Zinc and Cadmium Metal-Organic Frameworks with Anilate-Type Ligands

New heteroleptic metal-organic frameworks (MOF) of zinc (3D MOF) and cadmium (2D MOF) are prepared by the two-stage synthesis: [Zn(pQ)(DPT)]·2DMF (I) and [Cd₂(NO₃)₂-(pQ)(DPT)₃]·2DMF·2MeOH (II), where pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion, DPT is 3,6-di(pyridin-4-yl)-1,2,4,5-tetrazine, and DMF is N,N-dimethylformamide (DMF). The structures of the compounds are studied by XRD (CIF files CCDC nos. 2332754 (I) and 2332755 (II)). The thermal stability of the MOF is studied by thermogravimetry.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.