含2,2'-二碘多联苯-4,4'-二羧酸阴离子的钠和钙金属有机框架的结构

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2025-07-10 DOI:10.1134/S1070328425600147

M. A. Bondarenko, N. A. Korobeinikov, A. S. Zaguzin, R. V. Red’kin, E. A. Pilyukova, A. V. Zaitsev, S. A. Adonin

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引用次数: 0

摘要

在n， n -二甲基甲酰胺（DMF）中，钠（NaOH）和氢氧化钙(Ca(OH)2分别与2,2′-二碘多联苯-4,4′-二羧酸（H2(Bpdc-I2)）反应得到了{[Na(μ2-DMF)(HBpdc-I2)]}n (I)和{[Ca(DMF)2(Bpdc-I2)]} （II）。用x射线衍射测定了产物的结构。这两种化合物分别具有二维和三维结构。在相邻的Bdc-I2配体之间的I中检测到卤素键。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions

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Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions

The heteroleptic metal-organic frameworks {[Na(μ₂-DMF)(HBpdc-I₂)]}_n (I) and {[Ca(DMF)₂(Bpdc-I₂)]} (II) were obtained by the reaction of sodium (NaOH) and calcium hydroxides (Ca(OH)₂), respectively, with 2,2'-diiodobiphenyl-4,4'-dicarboxylic acid (H₂(Bpdc-I₂)) in N,N-dimethylformamide (DMF). The product structures were determined by X-ray diffraction. The compounds had two- and three-dimensional structures, respectively. A halogen bond was detected in I between the neighboring Bdc-I₂ ligands.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.