M. P. Davydova, A. M. Agafontsev, V. N. Yudin, M. I. Rakhmanova, A. V. Artem’ev
{"title":"基于薄荷醇修饰邻菲罗啉的羰基异腈铼配合物的合成及其发光性能","authors":"M. P. Davydova, A. M. Agafontsev, V. N. Yudin, M. I. Rakhmanova, A. V. Artem’ev","doi":"10.1134/S1070328425600524","DOIUrl":null,"url":null,"abstract":"<p>The carbonyl isonitrile complex [Re(CO)<sub>3</sub>(L)(<i>m</i>-XylylNC)]OTf (<i>m</i>-XylylNC is 2,6-dimethylphenyl isocyanide) based on the 1,10-phenanthroline ligand (L) containing the menthol fragment (MtO<sup>–</sup>) in position 2 is synthesized. In the cationic moiety of the complex, the Re(I) atom has a distorted octahedral environment formed by <i>N</i>,<i>N</i>'-chelate ligand L and one isonitrile and three CO ligands. At ambient temperature the synthesized compound exhibits bright green phosphorescence in the solid state and in the solution with quantum yields of 15 and 10%, respectively.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"414 - 419"},"PeriodicalIF":1.1000,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rhenium(I) Carbonyl Isonitrile Complex Based on Menthol-Modified Phenanthroline: Synthesis and Luminescence Properties\",\"authors\":\"M. P. Davydova, A. M. Agafontsev, V. N. Yudin, M. I. Rakhmanova, A. V. Artem’ev\",\"doi\":\"10.1134/S1070328425600524\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The carbonyl isonitrile complex [Re(CO)<sub>3</sub>(L)(<i>m</i>-XylylNC)]OTf (<i>m</i>-XylylNC is 2,6-dimethylphenyl isocyanide) based on the 1,10-phenanthroline ligand (L) containing the menthol fragment (MtO<sup>–</sup>) in position 2 is synthesized. In the cationic moiety of the complex, the Re(I) atom has a distorted octahedral environment formed by <i>N</i>,<i>N</i>'-chelate ligand L and one isonitrile and three CO ligands. At ambient temperature the synthesized compound exhibits bright green phosphorescence in the solid state and in the solution with quantum yields of 15 and 10%, respectively.</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"51 6\",\"pages\":\"414 - 419\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2025-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328425600524\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328425600524","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Rhenium(I) Carbonyl Isonitrile Complex Based on Menthol-Modified Phenanthroline: Synthesis and Luminescence Properties
The carbonyl isonitrile complex [Re(CO)3(L)(m-XylylNC)]OTf (m-XylylNC is 2,6-dimethylphenyl isocyanide) based on the 1,10-phenanthroline ligand (L) containing the menthol fragment (MtO–) in position 2 is synthesized. In the cationic moiety of the complex, the Re(I) atom has a distorted octahedral environment formed by N,N'-chelate ligand L and one isonitrile and three CO ligands. At ambient temperature the synthesized compound exhibits bright green phosphorescence in the solid state and in the solution with quantum yields of 15 and 10%, respectively.
期刊介绍:
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.