基于薄荷醇修饰邻菲罗啉的羰基异腈铼配合物的合成及其发光性能

IF 1.1 3区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
M. P. Davydova, A. M. Agafontsev, V. N. Yudin, M. I. Rakhmanova, A. V. Artem’ev
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引用次数: 0

摘要

以含有2位薄荷醇片段(MtO -)的1,10-菲罗啉配体(L)为基础合成了羰基异腈配合物[Re(CO)3(L)(m-XylylNC)]OTf (m-XylylNC为2,6-二甲基苯基异氰化物)。在配合物的阳离子部分,Re(I)原子具有由N,N'螯合配体L与1个异腈配体和3个CO配体组成的畸变八面体环境。在室温下,合成的化合物在固态和溶液中分别表现出亮绿色磷光,量子产率分别为15%和10%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Rhenium(I) Carbonyl Isonitrile Complex Based on Menthol-Modified Phenanthroline: Synthesis and Luminescence Properties

Rhenium(I) Carbonyl Isonitrile Complex Based on Menthol-Modified Phenanthroline: Synthesis and Luminescence Properties

Rhenium(I) Carbonyl Isonitrile Complex Based on Menthol-Modified Phenanthroline: Synthesis and Luminescence Properties

The carbonyl isonitrile complex [Re(CO)3(L)(m-XylylNC)]OTf (m-XylylNC is 2,6-dimethylphenyl isocyanide) based on the 1,10-phenanthroline ligand (L) containing the menthol fragment (MtO) in position 2 is synthesized. In the cationic moiety of the complex, the Re(I) atom has a distorted octahedral environment formed by N,N'-chelate ligand L and one isonitrile and three CO ligands. At ambient temperature the synthesized compound exhibits bright green phosphorescence in the solid state and in the solution with quantum yields of 15 and 10%, respectively.

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来源期刊
Russian Journal of Coordination Chemistry
Russian Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
2.40
自引率
15.80%
发文量
85
审稿时长
7.2 months
期刊介绍: Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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