Russian Journal of Coordination Chemistry最新文献

{"title":"Spin States of the Cobalt(II) Complex with Bis(pyrazol-3-yl)pyridine and pH-Sensitive Functional Groups and Its Deprotonated Derivatives","authors":"E. S. Safiullina,&nbsp;I. A. Nikovskii,&nbsp;A. A. Dan’shina,&nbsp;Yu. V. Nelyubina","doi":"10.1134/S1070328424600682","DOIUrl":"10.1134/S1070328424600682","url":null,"abstract":"<p>The reaction of 2,6-bis(pyrazol-3-yl)pyridine H₂L bearing pH-sensitive imino groups with cobalt perchlorate hexahydrate followed by the addition of 1,8-diazabicyclo[5.4.0]undec-7-ene affords the cobalt(II) complex [Co(H₂L)₂](ClO₄)₂ (<b>I</b>) and its doubly deprotonated analog [Co(HL)₂]⁰ (<b>II</b>). The compounds are characterized by NMR spectroscopy, mass spectrometry, and XRD. The influence of the deprotonation of ligand H₂L with a chosen base on the spin state of the cobalt(II) ion in a solution is studied by in situ NMR spectroscopy. Complex <b>I</b> is shown to retain its high-spin state in the whole temperature range accessible in deuterated methanol (200–325 K) both before and after the deprotonation of all pH-sensitive imino groups. However, the doubly deprotonated form of complex <b>I</b> (complex <b>II</b>·2MeOH) exists in the crystal (CIF file CCDC no. 2351546) in the low-spin state, which is the first example of the pH-induced stabilization of this state for the cobalt(II) complexes with 2,6-bis(pyrazol-3-yl)pyridines.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 11","pages":"978 - 986"},"PeriodicalIF":1.1,"publicationDate":"2025-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143373228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Stabilisation of a μ2-Oxido Bridge Dinuclear VO3+ Core by Incorporating Redox-Active Tridentate (NNO)-Donor Ligands","authors":"A. S. Roy,&nbsp;S. Ghosh,&nbsp;S. Bera,&nbsp;S. Maity","doi":"10.1134/S1070328424600840","DOIUrl":"10.1134/S1070328424600840","url":null,"abstract":"<p>Two diamagnetic dinuclear μ₂-oxido bridged oxovanadium(V) complexes, [<span>({text{V}}_{2}^{{text{V}}})</span>O₄(L₁)₂] (<b>I</b>), (L₁H = (<i>E</i>)-1-(pyridin-2-yldiazenyl)naphthalen-2-ol, and [<span>({text{V}}_{2}^{{text{V}}})</span>O₄(L₂)₂] (<b>II</b>) L₂H = (<i>E</i>)-4-methyl-2-(thiazol-2-yldiazenyl)phenol) have been synthesised by using different “redox-active” tridentate NNO-donor ligands and VO(acac)₂. Both complexes have been well characterised by FT-IR, UV-vis, NMR, ESI-MS spectroscopy, and cyclic voltammetry data analysis. Geometries of <b>I</b> and <b>II</b> are confirmed by the single-crystal X-ray crystallography. Complexes have two symmetrical oxovanadium cores (in <i>anti</i>-angular configurations) held by two μ-O bridging ions. The bond angle between the central VO³⁺ unit and the oxido bridges V(1)−O(2)−V(1A) is 101.9(3)° and 100.11(12)°, respectively in <b>I</b> and <b>II</b>. In complex <b>II</b>, vanadium centres are separated from each other by 3.0672 (12) Å, whereas it is slightly higher in complex <b>I</b> (3.162 Å). The unsymmetrical bridge bond lengths, {V(1)–O(2) and V(1)–O(2A)}, are 1.660(6) and 2.371(7) in <b>I</b>, whereas 1.663(3) and 2.302(3) Å in <b>II</b>. Both complexes exhibit significant absorption peaks in the visible region due to (LMCT) ligand-to-metal as well as (ILCT) intra-ligand charge transfer. The cyclic voltammetry study shows the stepwise electron reduction for both <b>I</b> and <b>II</b>. The first reduction at –0.70 V is due to (<span>({{{text{L}}_{{{text{azo}}}}^{ - }} mathord{left/ {vphantom {{{text{L}}_{{{text{azo}}}}^{ - }} {{text{L}}_{{{text{azo}}}}^{{centerdot 2 - }}}}} right. kern-0em} {{text{L}}_{{{text{azo}}}}^{{centerdot 2 - }}}})</span>) (L = L₁ (<b>I</b>) and L = L₂ (<b>II</b>)), whereas the second reduction occurs at around –1.30 V and may be due to V^V/V^IV redox couple. Chemically generated in-situ mono-reduced analogues <b>I</b>^– and <b>II</b>^– produce single-line isotropic EPR spectra with ‘g’ values of 2.003 and 2.006, respectively. These signals indicate that organic radicals are present in the systems. Nevertheless, no further equivalent hyperfine splitting (HFS) of the magnetic nuclei of organic radicals was detected in any of the reduced species despite varying the concentration, sweep range, and modulation parameters. The Mulliken spin density plots of <b>I</b>^– and EPR spectra authenticate that mono-reduced analogues can be defined as azo-anion radical-coupled oxovanadium(V) of types [<span>({text{V}}_{2}^{{text{V}}})</span>O₄<span>(({text{L}}_{1}^{ - })_{2}^{{centerdot - }})</span>] (<b>I</b>^–) and [<span>({text{V}}_{2}^{{text{V}}})</span>O₄<span>(({text{L}}_{2}^{ - })_{2}^{{centerdot - }})</span>] (<b>II</b>^–).</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 11","pages":"987 - 1000"},"PeriodicalIF":1.1,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143373321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and Cytoprotective Properties of La(III), Ce(III) Complexes Possessing 2,6-Di-tert-butylphenol Moiety","authors":"E. A. Nikitin,&nbsp;A. A. Moiseeva,&nbsp;M. V. Svishcheva,&nbsp;S. D. Koldman,&nbsp;V. A. Koldman,&nbsp;S. A. Tsymbal,&nbsp;V. Yu. Tyurin,&nbsp;A. B. Alto,&nbsp;A. A. Shtil,&nbsp;E. R. Milaeva","doi":"10.1134/S1070328424601298","DOIUrl":"10.1134/S1070328424601298","url":null,"abstract":"<p>Novel complexes of lanthanum and cerium possessing antioxidant 2,6-di-<i>tert</i>-butylphenol moiety have been synthesized and characterized using NMR, IR spectroscopy, thermogravimetry and elemental analysis. Their redox properties have been investigated using cyclic voltammetry. Antioxidant activity has been evaluated in a series of model reactions in vitro. The affinity of the compounds for single electron transfer has been estimated in the CUPRAC test, while their radical scavenging capacity has been monitored in the DPPH test and their interaction with the superoxide radical anion has been investigated in the NBT test. It has been demonstrated that both complexes exhibit extraordinary antioxidant activity far surpassing that of known standards. The cerium complex appears to be 20 times more effective at scavenging superoxide radical anions than its lanthanum counterpart, which may be due to the unique +4 oxidation state of cerium. Biological activity has also been estimated in numerous in vitro assays. The ability of the complexes to inhibit lipoxygenase LOX-1B has been observed in a corresponding assay, showing mild inhibitory activity for both compounds. Cytotoxicity was evaluated using the common MTT assay, and the cytoprotective properties of the compounds were investigated using clonogenic analysis. Both compounds were found to be non-toxic at operating concentrations, and the cerium complex showed cytoprotective activity at radiation doses of about 2 Gy. These findings suggest that the synthesized complexes have the potential to be effective antioxidants and low-toxic cytoprotectors.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 11","pages":"969 - 977"},"PeriodicalIF":1.1,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143373331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Structural and Electronic Analysis of Sulfonamide Coordination with Platinum: A Density Functional Theory Study","authors":"Á. B. Cruz,&nbsp;A. K. dos Santos Pereira,&nbsp;D. H. Pereira","doi":"10.1134/S1070328424601109","DOIUrl":"10.1134/S1070328424601109","url":null,"abstract":"<p>Metallopharmaceuticals are compounds that contain metals and are designed for therapeutic purposes. They can be used as anticancer, antimicrobial or anti-inflammatory agents, as can sulfonamides and their complexes, which consist of a set of organic molecules containing the sulfonamide functional group (SO₂NH) and were pioneered as synthetic drugs with antibacterial activity. In this context, density functional theory was used to investigate possible descriptors for coordination and structural properties and stereoelectronic effects the of sulfonamides with Platinum. Some analyzes were carried out, including the analysis of the frontier molecular orbitals, the molecular electrostatic potential, the reactivity indices, and the evaluation of the structural and topological properties. Through analysis of the molecular electrostatic potential and frontier orbitals, it was agreed that the best region for platinum coordination is the nitrogen present in the functional amine group. The study of structural parameters prevented evaluating the behavior of sulfonamides before and after complexation with platinum, in which there was an increase in N–H and N–C bonds and a reduction in S=O and S–C bonds in the DMSO ligand, which could generate distortions in the structure of sulfonamide ligands. Based on topological properties, it was found that non-complexed sulfonamides (ligands) have stronger bonds (N–H and N–C) than in complexes. S=O and S–C bonds were stronger in complexes compared to DMSO isolated and the results obtained for the Pt–S, Pt–N, Pt–Cl and Pt–I bonds showed their partially covalent characters.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 11","pages":"1008 - 1028"},"PeriodicalIF":1.1,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143373330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fe(II), Zn(II), and Ni(II) Complexation of N-Substituted Esters of L-Amino Acids with Heterocyclic Carboxylic Acids as a Way to Prepare Aqueous-Soluble Forms Capable of Inhibiting the Reproduction of the Current Influenza A Strain","authors":"T. M. Garaev,&nbsp;I. I. Yudin,&nbsp;N. V. Breslav,&nbsp;T. V. Grebennikova,&nbsp;V. V. Avdeeva,&nbsp;L. V. Goeva,&nbsp;A. V. Golubev,&nbsp;S. E. Nikiforova,&nbsp;E. A. Malinina,&nbsp;N. T. Kuznetsov","doi":"10.1134/S1070328424601250","DOIUrl":"10.1134/S1070328424601250","url":null,"abstract":"<p>A series of N-substituted esters of L-amino acids with various heterocyclic and aromatic carboxylic acids were synthesized. To increase the water solubility of the synthesized compounds, they were used as organic ligands in iron(II), zinc(II), and nickel(II) complexation. The antiviral properties of the resulting aqueous solutions were tested against the influenza virus A/IIV-Orenburg/83/2012(H1N1)pdm09 in vitro. It was shown that complexation with iron(II) was the most successful in achieving a high level of viral reproduction suppression compared to nickel and zinc complexes.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 11","pages":"1037 - 1042"},"PeriodicalIF":1.1,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143373332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and Сrystal Structures of Nickel(II) Complexes Based on Tripodal Tetradentate Ligand","authors":"C. Q. Shen,&nbsp;J. N. Wang,&nbsp;Jin Liu,&nbsp;J. R. Liu,&nbsp;L. Y. Liu,&nbsp;Q. X. Ma","doi":"10.1134/S107032842460089X","DOIUrl":"10.1134/S107032842460089X","url":null,"abstract":"<p>Two novel nickel-based complexes [Ni(H₂O)LCl]Cl (<b>Ι</b>) and [(Ni₂L₂Cl₂)](NO₃)₂ (<b>ΙΙ</b>) were synthesized with the tripodal tetradentate ligand (tris((1-methyl-1<i>H</i>-benzo[<i>d</i>]imidazol-2-yl)methyl)amine, L). Two complexes show different nuclearity and coordination environment of nickel atoms: complex <b>Ι</b> is assembled from two mononuclear T-shaped building units, forming a binuclear complex through intermolecular π–π interactions; the building unit of complex <b>ΙΙ</b> resembles complex <b>Ι</b>, but it leads to a diverse centrosymmetric binuclear complex due to the two bridging chlorine atoms. The crystal structures of the two complexes were determined by single-crystal X-ray diffraction (CCDC nos. 2363616 (<b>Ι</b>) and 2363615 (<b>ΙΙ</b>)).</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 11","pages":"1001 - 1007"},"PeriodicalIF":1.1,"publicationDate":"2024-12-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143373333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Compounds of s-Metals with Spin-Labeled Nitrophenol","authors":"O. V. Kuznetsova,&nbsp;G. V. Romanenko,&nbsp;P. A. Chernavin,&nbsp;G. A. Letyagin,&nbsp;A. S. Bogomyakov","doi":"10.1134/S1070328424600487","DOIUrl":"10.1134/S1070328424600487","url":null,"abstract":"<p>A series of paramagnetic salts of <i>s</i>-elements (Li, Na, K, Rb, Cs) with deprotonated nitroxide radical, 2-(2-hydroxy-5-nitrophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1<i>H</i>-imidazol-1-oxyl 3-oxide (L), were synthesized and isolated as crystals. According to X-ray diffraction data, these compounds are polymers of different dimensionality (CCDC nos. 2342497–2342506). As indicated by the results of quantum chemical calculations and magnetic measurements, weak antiferromagnetic exchange interactions predominate in the paramagnetic salts, with the interaction energy decreasing with increasing radius of the alkali metal ion.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 9","pages":"721 - 733"},"PeriodicalIF":1.1,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142790290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Stabilization of an Aqueous Solution of a Liquid Micro Fertilizer Containing Trilon B as a Chelating Agent. Structure of the Molecular Crystal of Sodium Carbamide Ethylenediaminetetraacetate Hydrate NaH3L1·(H2N)2CO·H2O","authors":"V. V. Semenov,&nbsp;N. V. Zolotareva,&nbsp;B. I. Petrov,&nbsp;N. M. Lazarev,&nbsp;E. V. Baranov","doi":"10.1134/S1070328424600608","DOIUrl":"10.1134/S1070328424600608","url":null,"abstract":"<p>Chemical analysis methods were used to identify the causes for precipitation and fouling with a gray-green deposit of a vessel for the storage of liquid micro fertilizer consisting of ammonium heptamolybdate, potassium chloride, ammonium vanadate, boric acid, chromium trichloride, sodium selenate, and Trilon B as a chelating ligand. The precipitate represented the crystalline 1 : 1 complex of Trilon B with carbamide NaH₃L¹·(H₂N)₂CO·H₂O (H₄L¹ = ethylenediaminetetraacetic acid). The deposit on the vessel bottom and wall was formed upon transformation of the molybdenum complex Na₄(MoO₃)₂L¹·8H₂O into insoluble coordination polymer in an acid medium. Neutralization of the solution to pH 6–7 and a decrease in the concentration of Trilon B gave a violet micro fertilizer solution that was stable during storage. The molecular structure of the NaH₃L¹·(H₂N)₂CO·H₂O crystal was determined.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 10","pages":"817 - 826"},"PeriodicalIF":1.1,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142790351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Characteristic Features of the Synthesis of 2,1,3-Benzothiadiazole-Substituted 1,3-Iminophosphine and Platinum Complex of This Compound","authors":"R. M. Khisamov,&nbsp;S. N. Konchenko,&nbsp;T. S. Sukhikh","doi":"10.1134/S1070328424600360","DOIUrl":"10.1134/S1070328424600360","url":null,"abstract":"<p>In an attempt to synthesize a new iminomethylphosphine, ^<i>t</i>BuC(Ph₂P)=N-Btd (Btd = 2,1,3-benzothiadiazole) by a three-step procedure including (1) NH₂-Btd + ^<i>t</i>BuC(=O)Cl → ^<i>t</i>BuC(=O)NH-Btd, (2) ^<i>t</i>BuC(=O)NH-Btd + SOCl₂ → ^<i>t</i>BuC(Cl)=N-Btd, and (3) ^<i>t</i>BuC(Cl)=N-Btd + Ph₂PSiMe₃ → ^<i>t</i>BuC(Ph₂P)=N-Btd, it was found that the second step is accompanied by the chlorination of the carbocycle in the benzothiadiazole moiety. The reaction of the imidoyl chloride ^<i>t</i>BuC(Cl)=N-(7-Cl-Btd) formed in this reaction with Ph₂PSiMe₃ gave 1,3-iminomethylphosphine ^<i>t</i>BuC(Ph₂P)=N-(7-Cl-Btd) (PC=N). The by-products formed in this step include 1,3-aminomethylphosphine oxide ^<i>t</i>BuC{Ph₂P(O)}NH-(7-Cl-Btd) (POCN) and (Ph₂PO_<i>x</i>)₂, resulting from partial oxidation and hydrolysis. The reactions of PC=N and POCN with [Pt(COD)Cl₂] (COD = 1.3-cyclooctadiene) were studied. In the case of PC=N, the reaction affords the [Pt(PC=N)₂Cl₂] complex. In the latter case, cleavage of the P–C bond in POCN takes place, and [PtCl₂(Ph₂POH)₂](POCN) and [Pt(CH₃CN){^<i>t</i>BuC-NH-(7-Cl-Btd)}Cl] are isolated from the reaction mixture. The structures of the new compounds were established by single-crystal X-ray diffraction (CCDC nos 2335150 (^<i>t</i>BuC(Cl)N-(7-Cl-Btd)), 2335152 (POCN·Et₂O), 2335149 (Ph₂PO_<i>x</i>)₂, 2335153 ([Pt(PC=N)₂Cl₂]), 2335154 ([PtCl₂(Ph₂POH)₂](POCN)), and 2335151 ([Pt(CH₃CN)(^<i>t</i>BuC-NH-(7-Cl-Bbtd))Cl]).</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 9","pages":"705 - 714"},"PeriodicalIF":1.1,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142790387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3,6-Dipyridyl-1,2,4,5-tetrazine in the Synthesis of Zinc and Cadmium Metal-Organic Frameworks with Anilate-Type Ligands","authors":"O. Yu. Trofimova,&nbsp;D. S. Kolevatov,&nbsp;N. O. Druzhkov,&nbsp;A. V. Maleeva,&nbsp;I. A. Yakushev,&nbsp;P. V. Dorovatovskii,&nbsp;A. V. Piskunov","doi":"10.1134/S1070328424700726","DOIUrl":"10.1134/S1070328424700726","url":null,"abstract":"<p>New heteroleptic metal-organic frameworks (MOF) of zinc (3D MOF) and cadmium (2D MOF) are prepared by the two-stage synthesis: [Zn(pQ)(DPT)]·2DMF (<b>I</b>) and [Cd₂(NO₃)₂-(pQ)(DPT)₃]·2DMF·2MeOH (<b>II</b>), where pQ is the 2,5-dihydroxy-3,6-di-<i>tert</i>-butyl-<i>para-</i>benzoquinone dianion, DPT is 3,6-di(pyridin-4-yl)-1,2,4,5-tetrazine, and DMF is <i>N</i>,<i>N</i>-dimethylformamide (DMF). The structures of the compounds are studied by XRD (CIF files CCDC nos. 2332754 (<b>I</b>) and 2332755 (<b>II</b>)). The thermal stability of the MOF is studied by thermogravimetry.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 9","pages":"636 - 645"},"PeriodicalIF":1.1,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142790288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}