Russian Journal of Coordination Chemistry最新文献_第2页

Design of an Asymmetric PCN Pincer Nickel(II) Complex Based on 2,3,4,5-Tetraphenyl-1-monophosphole 基于2,3,4,5-四苯基-1-单磷孔的非对称PCN钳形镍（II）配合物的设计

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600548

I. K. Mikhailov, Z. N. Gafurov, A. A. Kagilev, A. O. Kantyukov, I. F. Sakhapov, E. M. Zueva, A. A. Zagidullin, O. G. Sinyashin, D. G. Yakhvarov

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Crystal Structures of Two New Metal-Organic Coordination Polymers Based on Co(II) or Zn(II) and 2,2'-Diiodobiphenyl-4,4'-dicarboxylate 基于Co（II）或Zn（II）和2,2′-二碘多联苯-4,4′-二羧酸盐的两种新型金属-有机配位聚合物的晶体结构

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Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600664

A. S. Zaguzin, A. V. Zaitsev, M. A. Bondarenko, N. A. Korobeinikov, I. V. Korol’kov, I. A. Lystsov, I. F. Sakhapov, R. V. Red’kin, E. A. Pilyukova, P. E. Plyusnin, M. N. Sokolov, V. P. Fedin, S. A. Adonin

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New Stannandiamines Containing Photoactive Fragments 含光活性片段的新锡二胺

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Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600585

A. G. Demkin, E. P. Latushko, B. Yu. Savkov, T. S. Sukhikh, S. N. Konchenko

{"title":"New Stannandiamines Containing Photoactive Fragments","authors":"A. G. Demkin, E. P. Latushko, B. Yu. Savkov, T. S. Sukhikh, S. N. Konchenko","doi":"10.1134/S1070328425600585","DOIUrl":"10.1134/S1070328425600585","url":null,"abstract":"Reactions of dibutyltin dichloride with potassium amides KNH-pap, KNH-4pbt, and KNH-2pbt (pap = 4-(phenylazo)phenyl; 4pbt = 1,3-benzothiazol-2-yl-4-phenyl; 2pbt = 1,3-benzothiazol-2-yl-2-phenyl) were studied. It was found that KNH-pap and KNH-4pbt yield only the stannandiamines nBu2Sn(NH-pap)2 (I) and nBu2Sn(NH-4pbt)2 (II), respectively. However, the reaction with KNH-2pbt gives an inseparable mixture of the stannandiamine nBu2Sn(NH-2pbt)2 (III) and the cyclodistannadiazane [nBu2Sn(N-2pbt)]2 (IV). The molecular structures of compounds I–IV were determined by single-crystal X-ray diffraction of phases I·0.5C7H8, II·0.5THF, III, and IV (CCDC nos. 2367378 (I·0.5C7H8), 2367379 (II·0.5THF), 2367380 (III), and 2367378 (IV)).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"420 - 429"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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New Manganese(II) Coordination Compounds with 4-((1H-Pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole 锰（II）与4-（（1h -吡咯-2-基）亚甲基-氨基）- 4h -1,2,4-三唑的新配位化合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600500

A. A. Bovkunova, E. S. Bazhina, M. A. Shmelev, N. V. Gogoleva, A. A. Anisimov, S. Yu. Kottsov, K. A. Babeshkin, N. N. Efimov, M. T. Metlin, I. V. Taydakov, L. N. Fetisov, A. E. Svyatogorova, A. A. Zubenko, M. A. Kiskin, I. L. Eremenko

{"title":"New Manganese(II) Coordination Compounds with 4-((1H-Pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole","authors":"A. A. Bovkunova, E. S. Bazhina, M. A. Shmelev, N. V. Gogoleva, A. A. Anisimov, S. Yu. Kottsov, K. A. Babeshkin, N. N. Efimov, M. T. Metlin, I. V. Taydakov, L. N. Fetisov, A. E. Svyatogorova, A. A. Zubenko, M. A. Kiskin, I. L. Eremenko","doi":"10.1134/S1070328425600500","DOIUrl":"10.1134/S1070328425600500","url":null,"abstract":"The reaction of manganese(II) chloride with the azomethine ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (HPyrtrz) affords crystals of 1D polymeric compound [MnII(HPy-rtrz)(H2O)Cl2]n (I). The addition of the coligand 1,10-phenanthroline (Phen) to the synthesis of compound I results in the sequential crystallization of two products: 1D polymeric compound [MnII(Phen)Cl2]n (II) and mononuclear complex [MnII(Phen)2Cl2]·HPyrtrz (III). Complex III is isolated as the single product in the reaction of compound I with Phen or in the reaction of the known complex [MnII(Phen)2Cl2] with HPyrtrz, respectively. The crystal structures of compounds I–III are determined by single-crystal X-ray diffraction (XRD) (CIF files CCDC nos. 2339139 (I), 2344064 (II), and 2339140 (III)). The antimicrobial properties toward bacterial strains E. coli and S. aureus and mold fungus Penicillium italicum Wehmer are studied for compounds I and III. The measurements of the temperature dependence of the magnetic susceptibility show antiferromagnetic exchange interactions between the Mn2+ ions (J = –2.69 cm–1) in compound I. The spectral luminescence studies show that HPyrtrz, I, and III exhibit blue luminescence in the solid phase.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"472 - 487"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Influence of the Synthesis and Crystallization Conditions on the Compositions and Structures of Mixed-Carboxylate Europium(III) Benzoate‒Pentafluorobenzoate Complexes 合成和结晶条件对混合羧酸型苯甲酸铕-五氟苯甲酸配合物组成和结构的影响

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600214

M. A. Shmelev, D. S. Lebedev, A. S. Chistyakov, Yu. K. Voronina, L. M. Efromeev, A. V. Rogachev, A. A. Sidorov, I. L. Eremenko

{"title":"Influence of the Synthesis and Crystallization Conditions on the Compositions and Structures of Mixed-Carboxylate Europium(III) Benzoate‒Pentafluorobenzoate Complexes","authors":"M. A. Shmelev, D. S. Lebedev, A. S. Chistyakov, Yu. K. Voronina, L. M. Efromeev, A. V. Rogachev, A. A. Sidorov, I. L. Eremenko","doi":"10.1134/S1070328425600214","DOIUrl":"10.1134/S1070328425600214","url":null,"abstract":"The influence of the nature of solvate molecules and N-donor ligands on the structure of the europium benzoate‒pentafluorobenzoate complexes is studied. The reactions of europium benzoate (Bz) and pentafluorobenzoate (Pfb) with 1,10-phenanthroline (Phen) in acetonitrile with toluene, o-xylene, or dichloromethane afford compounds of similar structures: [Eu2(Phen)2(Pfb)4(Bz)2]·4C6H5CH3 (I), [Eu2(Phen)2(Pfb)4(Bz)2]·4С6Н4(CH3)2 (II), and [Eu2(Phen)2(Pfb)4(Bz)2]·2.898CH2Cl2 (III), respectively. The use of quinoline (Quin) allows one to isolate crystals of mixed-carboxylate coordination polymer [Eu(H2O)(Pfb)2(Bz)]n·2n(Quin) (IV). The synthesized compounds are characterized by X-ray diffraction (XRD), IR spectroscopy, and CHN analysis. Noncovalent interactions are analyzed using Hirshfeld surface analysis.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"500 - 513"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Terephthalate and Isonicotinate N-Oxide Complexes of the {Mo6I8}4+ Cluster {Mo6I8}4+簇的对苯二甲酸盐和异烟酸盐n -氧化物配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI: 10.1134/S1070328425600949

M. A. Mikhaylov, T. S. Sukhikh, D. G. Sheven’, E. Kh. Sadykov, M. N. Sokolov, A. S. Berezin, K. A. Tagil’tsev

{"title":"Terephthalate and Isonicotinate N-Oxide Complexes of the {Mo6I8}4+ Cluster","authors":"M. A. Mikhaylov, T. S. Sukhikh, D. G. Sheven’, E. Kh. Sadykov, M. N. Sokolov, A. S. Berezin, K. A. Tagil’tsev","doi":"10.1134/S1070328425600949","DOIUrl":"10.1134/S1070328425600949","url":null,"abstract":"New complexes, (TBA)2[Mo6I8(OOC–C6H4–COOH)6] (I) and (TBA)2[Mo6I8(OOC–C5H4NO)6] (II), were synthesized by the reaction of (TBA)2[Mo6I8(OAc)6] with terephthalic acid and isonicotinic N-oxide acid, respectively. The optimized synthesis of complex II involves microwave activation of the reaction mixture at 130°C in a Teflon reactor using an ETHOS UP Milestone microwave system. According to X-ray structural analysis, the molybdenum atoms in the cluster cores of I and II are coordinated by carboxylate ligands in a monodentate fashion. The cluster anions [Mo6I8(OOC–C6H4–COOH)6]2– of complex I are arranged into a three-dimensional framework, and the crystal structure contains solvate molecules. Complexes I and II were characterized by elemental analysis for C, H, and N, IR spectroscopy, electrospray mass spectrometry, and proton nuclear magnetic resonance. The powder samples of I and II exhibit intense phosphorescence with emission maxima at ~680 nm, φ = 15%, τ = 125 µs (I) and φ = 12%, τ = 137 µs (II) (under air at λexc = 440 nm).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"447 - 454"},"PeriodicalIF":1.1,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Coordination Polymer Based on Pentacopper Metallamacrocyclic Units Featured by 3-Hydroxy-4-pyridinone Ligands: Synthesis, Structure and Biological Activity 以3-羟基-4-吡啶酮为配体的五铜金属大环配位聚合物的合成、结构及生物活性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-08-11 DOI: 10.1134/S1070328425600615

M. A. Katkova, R. V. Rumyantcev, G. S. Zabrodina, I. G. Fomina, O. B. Bekker, S. Yu. Ketkov, G. K. Fukin, I. L. Eremenko

{"title":"Coordination Polymer Based on Pentacopper Metallamacrocyclic Units Featured by 3-Hydroxy-4-pyridinone Ligands: Synthesis, Structure and Biological Activity","authors":"M. A. Katkova, R. V. Rumyantcev, G. S. Zabrodina, I. G. Fomina, O. B. Bekker, S. Yu. Ketkov, G. K. Fukin, I. L. Eremenko","doi":"10.1134/S1070328425600615","DOIUrl":"10.1134/S1070328425600615","url":null,"abstract":"A novel complex {[Cu5(β-alaha)4](CuL2)(H2O)14}n (I) was successfully synthesized in the presence of (3-hydroxy-2-methyl-4-oxo-4H-pyridin-1-yl)acetic acid, Cu(Ac)2·H2O, and β-alaninehydroxamic acid (H2β-alaha), with the aim of exploring the potential for binding biologically active ligands of the pyridinone type with the β-alaninehydroximate 12-MC-4 metallacrown fragments. X-ray diffraction and topological studies of the complex I have been carried out. The geometrical characteristics indicate the presence of Cu–O interactions between a metallamacrocyclic cation [Cu5(β-alaha)4(H2O)4]2+ and two adjacent anions [Cu(L)2]2–. In the study of the experimental−theoretical electron density topology, it is found that the central and two peripheral copper atoms also increase their coordination number to 6 due to additional contacts with anions. This leads to the formation of a 1D coordination polymer. The energy of all cation-anion interactions in the chain was estimated. It has been demonstrated that 1D chains in the crystal are linked together by hydrogen bonds involving solvate water molecules with formation of 3D networks. Complex I exhibited antimycobacterial activity towards Mycolicibacterium smegmatis (M. smegmatis), as a model for Mycobacterium tuberculosis (M. tuberculosis).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 6","pages":"438 - 446"},"PeriodicalIF":1.1,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Cationic Complexes of Magnesium with Phenanthroline: Synthesis, Structural Features, and Antibacterial Activity 镁与菲罗啉的阳离子配合物：合成、结构特征及抗菌活性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-29 DOI: 10.1134/S107032842560024X

S. M. Potylitsyna, K. A. Koshenskova, M. E. Nikiforova, L. S. Razvorotneva, F. M. Dolgushin, O. B. Bekker, A. S. Zaeva, M. A. Kiskin, I. L. Eremenko, I. A. Lutsenko

{"title":"Cationic Complexes of Magnesium with Phenanthroline: Synthesis, Structural Features, and Antibacterial Activity","authors":"S. M. Potylitsyna, K. A. Koshenskova, M. E. Nikiforova, L. S. Razvorotneva, F. M. Dolgushin, O. B. Bekker, A. S. Zaeva, M. A. Kiskin, I. L. Eremenko, I. A. Lutsenko","doi":"10.1134/S107032842560024X","DOIUrl":"10.1134/S107032842560024X","url":null,"abstract":"The reaction of magnesium oxide/magnesium pivalate with aromatic heterocyclic acids (3-indolecarboxylic (HInd); 2-thiophenecarboxylic (HTph)) and 1,10-phenanthroline (Phen) gave cationic complexes [Mg(Phen)(Ind)(H2O)3]+⋅Ind–·2Phen·1.5H2O (I) and [Mg(Phen)(H2O)4(]_{3}^{{2 + }})·6Tph–·2Phen (II). The structures of I and II were established by direct X-ray diffraction analysis (CCDC nos. 2422043 (I) and 2422042 (II)). According to X-ray diffraction data, the central atom in I and II has a distorted octahedral environment {MgN2O4}, with the magnesium coordination number being six. In the crystal packing of I, stacking interactions between the Phen aromatic rings give rise to parallel stacks held together by hydrogen bonds. The outer-sphere Tph– in II form strong hydrogen bonds with the coordinated water molecules, thus forming 1D hydrogen-bonded framework. The antibacterial activity of I and II against a non-pathogenic Mycolicibacterium smegmatis strain and two lactobacillus strains, Lactobacillus brevis and Lactobacillus fermentum, was evaluated. The antiproliferative activity of I was determined against the human ovarian adenocarcinoma (SKOV3), breast adenocarcinoma (MCF7), and glioblastoma (A172) cells.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 5","pages":"311 - 320"},"PeriodicalIF":1.1,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S107032842560024X.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Complexes of Fe(III), Co(III), and Cu(II) with Acylhydrazones Containing a Triphenylphosphonium Fragment: Synthesis, Crystal Structure, and Antibacterial Activity 铁（III）、钴（III）和铜（II）与含三苯基磷片段的酰基腙的配合物：合成、晶体结构和抗菌活性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-29 DOI: 10.1134/S1070328425600275

A. K. Matiukhina, E. N. Zorina-Tikhonova, N. V. Gogoleva, L. D. Popov, P. G. Morozov, V. A. Lazarenko, A. A. Zubenko, L. N. Fetisov, A. E. Svyatogorova, M. A. Kiskin, I. L. Eremenko

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Heterometallic Complex of Europium(III) Trifluoroacetate with Bis(diphenylphosphoryl)ferrocene (DppfO2): Synthesis, Structure, and Thermal Stability 三氟乙酸铕与二（二苯磷基）二茂铁（DppfO2）的异金属配合物：合成、结构和热稳定性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2025-07-29 DOI: 10.1134/S1070328425600445

M. A. Uvarova, M. A. Shmelev, V. A. Eliseenkova, I. A. Lutsenko, I. L. Eremenko

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