基于Co（II）或Zn（II）和2,2′-二碘多联苯-4,4′-二羧酸盐的两种新型金属-有机配位聚合物的晶体结构

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2025-09-19 DOI:10.1134/S1070328425600664

A. S. Zaguzin, A. V. Zaitsev, M. A. Bondarenko, N. A. Korobeinikov, I. V. Korol’kov, I. A. Lystsov, I. F. Sakhapov, R. V. Red’kin, E. A. Pilyukova, P. E. Plyusnin, M. N. Sokolov, V. P. Fedin, S. A. Adonin

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引用次数: 0

摘要

以2,2′-二碘多联苯-4,4′-二羧酸盐为连接剂，制备了两种新型Co（II）和Zn（II）金属有机配位聚合物[Co2(bpdc-I2)2(bpp)(DMF)]·0.75DMF (I)和[zn40o (bpdc-I2)3]·7DMF (II) （bpdc-I2为2,2′-二碘多联苯-4,4′-二羧酸盐，bpp为1,3-双（4-吡啶基）丙烷）。通过x射线衍射确定了产物的结构。化合物II具有三维结构，计算可达体积为53.2%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Crystal Structures of Two New Metal-Organic Coordination Polymers Based on Co(II) or Zn(II) and 2,2'-Diiodobiphenyl-4,4'-dicarboxylate

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Crystal Structures of Two New Metal-Organic Coordination Polymers Based on Co(II) or Zn(II) and 2,2'-Diiodobiphenyl-4,4'-dicarboxylate

Two new Co(II) and Zn(II) metal-organic coordination polymers with 2,2'-diiodobiphenyl-4,4'-dicarboxylate linkers, [Co₂(bpdc-I₂)₂(bpp)(DMF)]·0.75DMF (I) and [Zn₄O(bpdc-I₂)₃]·7DMF (II), were prepared (bpdc-I₂ is 2,2'-diiodobiphenyl-4,4'-dicarboxylate, bpp is 1,3-bis(4-pyridyl)propane). The structure of the products was established by X-ray diffraction. Compound II has a three-dimensional structure with the calculated accessible volume of 53.2%.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.