Russian Journal of Coordination Chemistry最新文献_第6页

Retraction Note: Two Heteroligand Cd(II)-coordination Polymers: Crystal Structures and Anti-Lung Cancer Activity Evaluation 撤稿说明：两种异配体镉（II）配位聚合物：晶体结构和抗肺癌活性评估

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-16 DOI: 10.1134/S1070328424030060

C. H. Ye, G. Chen, Y. L. Gong

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Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures 氧化还原活性靛酚配体的镉(II)配合物：合成与结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-16 DOI: 10.1134/S1070328423601309

E. P. Ivakhnenko, Yu. G. Vitkovskaya, N. I. Merezhko, P. A. Knyazev, G. S. Borodkin, K. A. Lysenko, V. I. Minkin

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Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion 含有新型银（I）阴离子的双三维伪聚合物[Au{S2CN(CH2)6}2]4[Ag5Cl9]的合成、超分子自组织和热行为

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423600572

E. V. Korneeva, O. V. Loseva, A. I. Smolentsev, A. V. Ivanov

{"title":"Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Double Three-Dimensional Pseudo-Polymer Complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] Comprising the New Type Silver(I) Anion","authors":"E. V. Korneeva, O. V. Loseva, A. I. Smolentsev, A. V. Ivanov","doi":"10.1134/S1070328423600572","DOIUrl":"10.1134/S1070328423600572","url":null,"abstract":"New crystalline pseudo-polymer complex [Au{S2CN(CH2)6}2]4[Ag5Cl9] (I) was obtained by binding gold(III) with silver(I) hexamethylenedithiocarbamate from an AuCl3/2.5 M NaCl solution. Complex I was isolated in a preparative yield and structurally characterized. The X-ray diffraction (XRD) data (CIF file CCDC no. 2205197) show that the isomeric cations of [Au{S2CN(CH2)6}2]+ (A : 2B : C) and complicated pentanuclear anion [Ag5Cl9]4– are the main structural units of the compound. The supramolecular self-organization of the ionic structural units in complex I occurs due to multiple secondary interactions Cl···S and Ag···S, hydrogen bonds C–H···Cl, and anagostic interactions C–H···Ag, resulting in the formation of the 3D pseudo-polymer framework. The thermal behavior of complex I is studied by simultaneous thermal analysis to find that the thermolysis of the double Au(III)–Ag(I) compound is accompanied by the quantitative regeneration of the bound metals under comparatively mild conditions.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938485","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties 嘧啶-2-硫醚的钯配合物：合成、结构和性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423600729

A. S. Kuzovlev, N. A. Gordeeva, Zh. Yu. Pastukhova, V. V. Chernyshev, G. A. Buzanov, S. F. Dunaev, L. G. Bruk

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Synthesis and Thermodynamic Characteristics of Molybdenum Carboxylates Мо2((СH3)3CCOO)4, Мо2(СF3COO)4, and МоО2((СH3)3CCOO)2 钼羧酸盐Мо2((СH3)3CCOO)4、Мо2(СF3COO)4 和МоО2((СH3)3CCOO)2 的合成与热力学特性

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423600924

D. B. Kayumova, I. P. Malkerova, D. S. Yambulatov, A. A. Sidorov, I. L. Eremenko, A. S. Alikhanyan

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New Cobalt Complex with Dihydroxycoumarin: Synthesis and Kinetics of Its Redox-Activated Dissociation 二羟基香豆素的新钴配合物：合成及其氧化还原激活解离动力学

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423600663

K. A. Spiridonov, I. A. Nikovskii, E. P. Antoshkina, E. A. Khakina, Yu. V. Nelyubina

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Reactions of Carbon Dioxide Bound to Aluminum Diimine Hydride with Borane Dimethyl Sulfide and Ammonia 二亚胺氢化铝结合的二氧化碳与二甲基硫化硼烷和氨的反应

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423600936

M. V. Moskalev, A. A. Skatova, A. A. Bazanov, E. V. Baranov, I. L. Fedushkin

{"title":"Reactions of Carbon Dioxide Bound to Aluminum Diimine Hydride with Borane Dimethyl Sulfide and Ammonia","authors":"M. V. Moskalev, A. A. Skatova, A. A. Bazanov, E. V. Baranov, I. L. Fedushkin","doi":"10.1134/S1070328423600936","DOIUrl":"10.1134/S1070328423600936","url":null,"abstract":"The reaction of aluminum bis-formate acenaphthene-1,2-diimine complex [(ArBIG-bian)Al(μ-OC(H)O)2Li(Thf)2] (I) (ArBIG-bian = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene), prepared by binding carbon dioxide by aluminum diimine hydride [(ArBIG-bian)Al(H)2]–[Li(Thf)4]+, with borane dimethyl sulfide and ammonia was studied. The reaction of I with BH3∙SMe2 (1 : 1) in toluene affords the product of hydroboration of one formate group [(ArBIG-bian)Al(μ-OC(H)O)(OB(H)OCH3)Li(Thf)]2 (II), while the reaction of I with BH3∙SMe2 (1 : 2) is accompanied by reduction of both formate groups and gives complex [(ArBIG-bian)Al(OBOCH3)2OLi2(Thf)2BH4]2 (III), methoxyboroxine (CH3OBO)3 and, presumably, compound [(ArBIG-bian)AlOCH3]. The reaction of I with one equivalent of ammonia in THF gives adduct [(ArBIG-bian)Al(NH3)(μ-OC(H)O)2Li(Thf)2] (IV), in which ammonia is coordinated to the aluminum atom, while the key bonds in I have not undergone ammonolysis. Compounds II–IV were characterized by IR and NMR spectroscopy, elemental analysis, and X-ray diffraction (CCDC no. 2255017 (II), 2255018 (III), 2255019 (IV)).","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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3D Coordination Polymers with N-Heterocyclic Ga(I) Moieties 含 N-杂环 Ga(I) 分子的三维配位聚合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423601127

T. S. Koptseva, E. V. Baranov, I. L. Fedushkin

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Syntheses, Crystal Structure, and Properties of Two New Coordination Polymers from a Triphenylamino-Based Ligand 基于三苯胺配体的两种新型配位聚合物的合成、晶体结构和性质

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423601085

Q. Cai, J. Su, W. B. Tang, X. H. You

{"title":"Syntheses, Crystal Structure, and Properties of Two New Coordination Polymers from a Triphenylamino-Based Ligand","authors":"Q. Cai, J. Su, W. B. Tang, X. H. You","doi":"10.1134/S1070328423601085","DOIUrl":"10.1134/S1070328423601085","url":null,"abstract":"Two new coordination polymers, namely, {[CdCl2(BIPAB)2]·H2O}n (I) (BIPAB = 4-(bis(4-(1H-imidazol-1-yl)phenyl)amino)benzonitrile) and {[NiCl2(HBIPABA)2]·2H2O}n (II) (HBIPABA = 4-(bis(4-(1H-imidazol-1-yl)phenyl)amino)benzoic acid), have been successfully synthesized by using a triphenylamino-based ligand BIPAB, as original reactant and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, TG, and luminescence. X-ray single crystal diffraction analysis (CCDC nos. 2283736 and 2283737 for I and II, respectively) shows that both compounds I and II crystallize in monoclinic crystal system with space groups are P2/c and P21, respectively. All of them exhibit one-dimensional (1D) ribbon coordination chain formula as [MCl2(L)2]n. However, the 1D chains were packing into different three-dimensional (3D) supramolecular frameworks mainly due to the uncoordinated additional functional groups on the ligand. For compound I, the 1D chains cross arrange to form a 3D supermolecule framework, in which the nitrile grouping showed as guest molecule to be accommodated by Cd2L2 ring on adjacent 1D chains; for compound II, the 1D chains were connected by the hydrogen bonds between in situ formed carboxyl groups to formed a two-dimensional (2D) hydrogen bonding network, and the 2D networks were further interpenetrated to forms a 3D supermolecule framework. Compounds I and II showed a thermal stability up to 380 and 280°C, respectively. Moreover, compound I exhibits an intense blue emission centered at 490 nm upon excitation at 370 nm.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Two- and Three-Dimensional Polymeric Co(II) Terephthalates with 3,3',5,5'-Tetrabromo-4,4'-bipyridine (3,3'5,5'-BrBipy) 含有 3,3',5,5'-四溴-4,4'-联吡啶 (3,3'5,5'-BrBipy) 的二维和三维聚合物对苯二甲酸钴 (II)

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-08 DOI: 10.1134/S1070328423700707

I. F. Sakhapov, A. A. Zagidullin, D. R. Islamov, V. V. Sharutin, D. G. Yakhvarov, D. A. Zherebtsov, V. A. Milyukov, A. S. Zaguzin, V. P. Fedin, S. A. Adonin

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