Layered Coordination Polymers Based on the Cluster Complexes [Re6Q8(CN)6]4– (Q = S or Se) and Dimeric Cations {(Ag(Dppe))2(µ-Dppe)}2+

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424600402

Yu. M. Litvinova, Ya. M. Gaifulin, T. S. Sukhikh, K. A. Brylev, Yu. V. Mironov

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引用次数: 0

Abstract

The reactions of salts of cluster anions [Re₆Q₈(CN)₆]^4– with the [Ag(CN)₂]^– dicyanoargentate anion in the presence of 1,2-bis(diphenylphosphino)ethane are studied. Two new coordination polymers, [{(Ag(Dppe))₂(µ-Dppe)}₂{Re₆S₈(CN)₆}]·H₂O (I) and [{(Ag(Dppe))₂(µ-Dppe)}₂{Re₆Se₈(CN)₆}]_0.85-[{(Ag(Dppe))(Ag(DppeSe))(µ-Dppe)}₂{Re₆Se₈(CN)₆}]_0.15 (II), are prepared by the solvothermal synthesis. The XRD study of single crystals of the compounds (CIF files CCDC nos. 2341356 (I) and 2341355 (II)) shows their layered structures. The XRD study of crystalline powders of the compounds shows that the synthesis of compound II leads to the formation of two crystalline phases, one of which is isostructural to compound I. The luminescence parameters of the solid-state compounds (quantum yields, emission lifetimes) resemble the parameters of other coordination polymers based on the [Re₆Q₈(CN)₆]^4– ions.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.