Synthesis and X-ray Structures of Polymeric Calcium Carboxylates

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424601043

A. S. Samulionis, J. K. Voronina, S. N. Melnikov, A. S. Gavronova, D. A. Utepova, N. V. Gogoleva, A. S. Goloveshkin, D. S. Yambulatov, S. A. Nikolaevskii, M. A. Kiskin, I. L. Eremenko

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Abstract

The reactions of calcium hydroxide with pivalic, 1-naphthoic, and 2-furancarboxylic acids afford the corresponding polymeric calcium carboxylates. Depending on the crystallization conditions, calcium pivalate is isolated as two different coordination polymers: [Ca₃(Piv)₆(DMF)₂]_n·0.635nC₆H₆·0.365nDMF (I) and [Ca(Рiv)(H₂O)_2.333(DMF)_0.666]_n·nРiv·0.333H₂O (II). The synthesized calcium 1-naphthoate contains coordinated water molecules [Сa(Naph)₂(H₂O)₂]_n (III), and calcium furoate [Ca(Fur)₂]_n (IV) contains no ancillary ligands. The structures of compounds I–IV are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2342790–2342793, respectively). The structures of compounds I–III are characterized by the 1D polymeric structure, and compound IV is the 3D polymer.

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聚合羧酸钙的合成及x射线结构

氢氧化钙与戊酸、1-萘酸和2-呋喃羧酸反应生成相应的聚合羧酸钙。根据结晶条件的不同，分离得到两种不同的配位聚合物：[Ca3(Piv)6(DMF)2]n·0.635nC6H6·0.365nDMF (I)和[Ca（Рiv）（H2O）2.333(DMF)0.666]n·nРiv·0.333H2O （II）。合成的1-萘酸钙含有配位水分子[Сa(Naph)2(H2O)2]n (III)，而糠酸钙[Ca(Fur)2]n （IV）不含辅助配体。化合物I-IV的结构由x射线衍射（XRD）测定（CIF文件CCDC号分别为2342790-2342793）。化合物I-III的结构为一维聚合物结构，化合物IV为三维聚合物。

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.