Synthesis and X-ray Structures of Polymeric Calcium Carboxylates

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424601043

A. S. Samulionis, J. K. Voronina, S. N. Melnikov, A. S. Gavronova, D. A. Utepova, N. V. Gogoleva, A. S. Goloveshkin, D. S. Yambulatov, S. A. Nikolaevskii, M. A. Kiskin, I. L. Eremenko

{"title":"Synthesis and X-ray Structures of Polymeric Calcium Carboxylates","authors":"A. S. Samulionis, J. K. Voronina, S. N. Melnikov, A. S. Gavronova, D. A. Utepova, N. V. Gogoleva, A. S. Goloveshkin, D. S. Yambulatov, S. A. Nikolaevskii, M. A. Kiskin, I. L. Eremenko","doi":"10.1134/S1070328424601043","DOIUrl":null,"url":null,"abstract":"The reactions of calcium hydroxide with pivalic, 1-naphthoic, and 2-furancarboxylic acids afford the corresponding polymeric calcium carboxylates. Depending on the crystallization conditions, calcium pivalate is isolated as two different coordination polymers: [Ca3(Piv)6(DMF)2]n·0.635nC6H6·0.365nDMF (I) and [Ca(Рiv)(H2O)2.333(DMF)0.666]n·nРiv·0.333H2O (II). The synthesized calcium 1-naphthoate contains coordinated water molecules [Сa(Naph)2(H2O)2]n (III), and calcium furoate [Ca(Fur)2]n (IV) contains no ancillary ligands. The structures of compounds I–IV are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2342790–2342793, respectively). The structures of compounds I–III are characterized by the 1D polymeric structure, and compound IV is the 3D polymer.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 9","pages":"757 - 767"},"PeriodicalIF":1.1000,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328424601043","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

Abstract

The reactions of calcium hydroxide with pivalic, 1-naphthoic, and 2-furancarboxylic acids afford the corresponding polymeric calcium carboxylates. Depending on the crystallization conditions, calcium pivalate is isolated as two different coordination polymers: [Ca₃(Piv)₆(DMF)₂]_n·0.635nC₆H₆·0.365nDMF (I) and [Ca(Рiv)(H₂O)_2.333(DMF)_0.666]_n·nРiv·0.333H₂O (II). The synthesized calcium 1-naphthoate contains coordinated water molecules [Сa(Naph)₂(H₂O)₂]_n (III), and calcium furoate [Ca(Fur)₂]_n (IV) contains no ancillary ligands. The structures of compounds I–IV are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2342790–2342793, respectively). The structures of compounds I–III are characterized by the 1D polymeric structure, and compound IV is the 3D polymer.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.