锰与N，N'-双[（2,4,6-三甲基苯基）亚胺]苊配合物的合成及结构

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424600578

Yu. A. Laricheva, Ch. Guan, N. V. Kuratieva, N. F. Romashev, A. L. Gushchin

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引用次数: 0

摘要

研究了N，N′-双[（2,4,6-三甲基苯基）亚氨基苊（tm -bian）， [Mn(tm -bian)Br2] (I), [Mn(tm -bian)(EtOH)Br2] (Ia), [Mn(tm -bian)Cl2] (II), [Mn(tm -bian)2(ClO4)2] (III), [Mn(tm -bian)2(OTs)2] （IV）等新型锰（II）配合物的合成方法。所得化合物通过元素分析和红外光谱进行了表征。通过x射线衍射（CCDC编号233510-233512）测定了I、I和III的分子结构。利用密度泛函理论（DFT）通过量子化学计算建立了I和III的电子结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

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Synthesis and Structure of Manganese Complexes with N,N'-bis[(2,4,6-trimethylphenyl)imino]acenaphthene

Methods for the synthesis of new manganese(II) complexes with N,N'-bis[(2,4,6-trimethylphenyl)iminoacenaphthene (Tmp-bian), [Mn(Tmp-bian)Br₂] (I), [Mn(Tmp-bian)(EtOH)Br₂] (Ia), [Mn(Tmp-bian)Cl₂] (II), [Mn(Tmp-bian)₂(ClO₄)₂] (III), and [Mn(Tmp-bian)₂(OTs)₂] (IV) were developed. The obtained compounds were characterized by elemental analysis and IR spectroscopy. The molecular structures of I, Iа, and III were determined by X-ray diffraction (CCDC nos. 233510–233512). The electronic structures of I and III were established by quantum chemical calculations using density functional theory (DFT).

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.