Monomerization of Binuclear Complex [Zn2(Piv)4(Phen)2] under the Action of Water

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424601006

A. S. Samulionis, A. G. Medvedev, T. A. Tripol’skaya, M. A. Kiskin, P. V. Prikhodchenko, I. L. Eremenko, S. A. Nikolaevskii

引用次数: 0

Abstract

The interaction of the binuclear complex [Zn₂(Рiv)₄(Рhen)₂] with water in toluene or acetonitrile results in its monomerization with the formation of compound [Zn(Рiv)₂(H₂O)(Рhen)], the crystal structure of which is determined by XRD (CIF file CСDC no. 2374361). The individual character of the formed crystalline phase is confirmed by powder XRD. Nanoparticles of zinc peroxide/hydroxide are proposed to be used as a water source for the obtaining of single crystals of [Zn(Рiv)₂(H₂O)(Рhen)] suitable for XRD.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.