A. F. Rogozhin, V. A. Ilichev, L. I. Silantyeva, E. A. Kozlova, G. K. Fukin, M. N. Bochkarev
{"title":"异位中心对称巯基苯并噻唑二锂盐：从分子络合物到发光一维配位聚合物","authors":"A. F. Rogozhin, V. A. Ilichev, L. I. Silantyeva, E. A. Kozlova, G. K. Fukin, M. N. Bochkarev","doi":"10.1134/S1070328424600414","DOIUrl":null,"url":null,"abstract":"<p>The reaction of lithium amide LiN(Si(Me)<sub>3</sub>)<sub>2</sub> and ditopic heterocyclic ligand benzo[1,2-<i>d</i>:4,5-<i>d</i>′]bis(thiazole)-2,6(3<i>H</i>,7<i>H</i>)-dithione (H<sub>2</sub>L) in dimethoxyethane (DME) affords the binuclear molecular complex Li<sub>2</sub>L(DME)<sub>4</sub> (<b>I</b>). New compounds [Li<sub>2</sub>L(DMSO)<sub>4</sub>·(DMSO)<sub>2</sub>]<sub><i>n</i></sub> (<b>II</b>) and [Li<sub>2</sub>L(DMSO)<sub>4</sub>·(THF)<sub>2</sub>]<sub><i>n</i></sub> (<b>III</b>) are prepared by the recrystallization of compound <b>I</b> using a DMSO–diethyl ether or DMSO/THF mixture of solvents, respectively. According to the XRD data, these compounds are one-dimensional Coordination polymer (CPs) differed by the arrangement of the bis(thiazole) fragments relative to each other and the Li<sub>2</sub>O<sub>2</sub> fragment in the polymer chain, which affects the luminescence properties. The molecular structures of compounds <b>I</b>–<b>III</b> are determined by XRD (CIF files CCDC nos. 2334192 (<b>I</b>), 2334193 (<b>II</b>), and 2334194 (<b>III</b>)).</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 9","pages":"689 - 696"},"PeriodicalIF":1.1000,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1070328424600414.pdf","citationCount":"0","resultStr":"{\"title\":\"Ditopic Centrosymmetric Mercaptobenzothiazole Dilithium Salts: From the Molecular Complex to Luminescent 1D Coordination Polymers\",\"authors\":\"A. F. Rogozhin, V. A. Ilichev, L. I. Silantyeva, E. A. Kozlova, G. K. Fukin, M. N. Bochkarev\",\"doi\":\"10.1134/S1070328424600414\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of lithium amide LiN(Si(Me)<sub>3</sub>)<sub>2</sub> and ditopic heterocyclic ligand benzo[1,2-<i>d</i>:4,5-<i>d</i>′]bis(thiazole)-2,6(3<i>H</i>,7<i>H</i>)-dithione (H<sub>2</sub>L) in dimethoxyethane (DME) affords the binuclear molecular complex Li<sub>2</sub>L(DME)<sub>4</sub> (<b>I</b>). New compounds [Li<sub>2</sub>L(DMSO)<sub>4</sub>·(DMSO)<sub>2</sub>]<sub><i>n</i></sub> (<b>II</b>) and [Li<sub>2</sub>L(DMSO)<sub>4</sub>·(THF)<sub>2</sub>]<sub><i>n</i></sub> (<b>III</b>) are prepared by the recrystallization of compound <b>I</b> using a DMSO–diethyl ether or DMSO/THF mixture of solvents, respectively. According to the XRD data, these compounds are one-dimensional Coordination polymer (CPs) differed by the arrangement of the bis(thiazole) fragments relative to each other and the Li<sub>2</sub>O<sub>2</sub> fragment in the polymer chain, which affects the luminescence properties. The molecular structures of compounds <b>I</b>–<b>III</b> are determined by XRD (CIF files CCDC nos. 2334192 (<b>I</b>), 2334193 (<b>II</b>), and 2334194 (<b>III</b>)).</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"50 9\",\"pages\":\"689 - 696\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-12-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1134/S1070328424600414.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070328424600414\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328424600414","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Ditopic Centrosymmetric Mercaptobenzothiazole Dilithium Salts: From the Molecular Complex to Luminescent 1D Coordination Polymers
The reaction of lithium amide LiN(Si(Me)3)2 and ditopic heterocyclic ligand benzo[1,2-d:4,5-d′]bis(thiazole)-2,6(3H,7H)-dithione (H2L) in dimethoxyethane (DME) affords the binuclear molecular complex Li2L(DME)4 (I). New compounds [Li2L(DMSO)4·(DMSO)2]n (II) and [Li2L(DMSO)4·(THF)2]n (III) are prepared by the recrystallization of compound I using a DMSO–diethyl ether or DMSO/THF mixture of solvents, respectively. According to the XRD data, these compounds are one-dimensional Coordination polymer (CPs) differed by the arrangement of the bis(thiazole) fragments relative to each other and the Li2O2 fragment in the polymer chain, which affects the luminescence properties. The molecular structures of compounds I–III are determined by XRD (CIF files CCDC nos. 2334192 (I), 2334193 (II), and 2334194 (III)).
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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