Russian Journal of Coordination Chemistry最新文献_第4页

Samarium(III) Complex Based on 5-Phenyl-2,2'-bipyridine with the Diethylenetriaminotetraacetic Acid Residue in the C6 Position: Synthesis, Crystal Structure, and Photophysical Properties 基于 5-苯基-2,2'-联吡啶且 C6 位有二乙烯三氨基四乙酸残基的钐(III)配合物：合成、晶体结构和光物理性质

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Russian Journal of Coordination Chemistry Pub Date : 2024-08-15 DOI: 10.1134/S1070328424600268

A. P. Krinochkin, S. E. Vatolina, V. S. Gaviko, I. A. Litvinov, M. I. Valieva, Ya. K. Shtaitz, S. S. Rybakova, D. S. Kopchuk, G. V. Zyryanov, V. L. Rusinov

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Versatile Electronic and Structural Properties of Ruthenium-Mediated 1,4-Diaza-1,3-butadiene Ligands: A Review 钌介导的 1,4-二氮杂-1,3-丁二烯配体的多功能电子和结构特性：综述

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-08-15 DOI: 10.1134/S1070328423601449

A. S. Roy

{"title":"Versatile Electronic and Structural Properties of Ruthenium-Mediated 1,4-Diaza-1,3-butadiene Ligands: A Review","authors":"A. S. Roy","doi":"10.1134/S1070328423601449","DOIUrl":"10.1134/S1070328423601449","url":null,"abstract":"Ruthenium α-diimine complexes are widely known for their unique low-lying excited states and potent light absorption capabilities in the visible and NIR regions. A few specially constructed Ru α-diimine complexes have also shown enormous potential in the biomedical field. Several Ru-diimine complexes are well known for their catalytic activity. In this context, the simplest α-diimine system is 1,4-diaza-1,3-butadiene, abbreviated as (DAB/DAD), which received the greatest attention from the research communities. DAB ligands are redox-active. DAB ligands typically function as effective electron donors by employing lone pairs of nitrogen atoms and the π-electrons of the C=N bonds while coordinating the metal ion. The structural, electronic, and photophysical properties of the metal-mediated (DAB) complexes largely depend on the substitution of the ligand backbone as well as metal precursors. A versatile ‘redox noninnocent’ 1,4-diaza-1,3-butadiene motif can stabilise different oxidation states of ruthenium metal depending on the reaction conditions and the presence of co-ligands. The comparative studies of the structural and electrical characteristics of diverse ruthenium-DAB compounds are intriguing, which opens up a new route for researchers to utilise them in a variety of application domains. It is challenging and fascinating to determine the precise electronic structure of redox noninnocent diimine complexes in the presence of a ‘redox active’ metal like ruthenium. In this concise review, we provided a brief overview of the structural and electrical features of various Ru DAB complexes that solely comprise (–N=CH–CH=N–) fragments in the skeleton.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142182845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Influence of the Coordination Environment on the EPR Spectra of Mononuclear Gd Thiocyanates 配位环境对单核硫氰酸钆 EPR 光谱的影响

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S1070328423601413

S. P. Petrosyants, A. B. Ilyukhin, K. A. Babeshkin, E. A. Ugolkova, V. V. Minin, P. S. Koroteev, N. N. Efimov

{"title":"Influence of the Coordination Environment on the EPR Spectra of Mononuclear Gd Thiocyanates","authors":"S. P. Petrosyants, A. B. Ilyukhin, K. A. Babeshkin, E. A. Ugolkova, V. V. Minin, P. S. Koroteev, N. N. Efimov","doi":"10.1134/S1070328423601413","DOIUrl":"10.1134/S1070328423601413","url":null,"abstract":"Using the synthesized salt Gd(NCS)3·6H2O, previously unknown mononuclear molecular complexes [Gd(H2O)(bpy)2(NCS)3]·0.5(bpy)·H2O, [Gd(H2O)(phen)2(NCS)3]·phen·0.5H2O as well as ionic ones [Hbpy][Gd(NCS)4(bpy)2]·H2O, [Hphen][Gd(NCS)4(phen)2] (bpy is 2,2'-bipyridine, phen is 1,10-phenanthroline) were prepared. Structural characteristics of the obtained compounds were determined using X-ray diffraction data. The magnetic susceptibility and EPR data of the new Gd complexes are considered taking into account the features of their composition and structure. Due to the peculiarities of the electronic structure, Gd complexes can serve as test systems for analyzing the field strength of ligands and the geometry of the local environment of the 4f-metal ion. It is shown that EPR spectroscopy is highly efficient method for determining the spin Hamiltonian parameters and, consequently, for characterizing the local environment of the gadolinium ion in complexes. However, the EPR method does not allow one to determine the sign of the splitting parameter in the zero field D, which requires additional studies.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141778729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Coordination Compounds of Cobalt(II) Nitrate and Perchlorate with Acetamide and Carbamide: Precursors for the Synthesis of Catalytically Active Tricobalt Tetraoxide 硝酸钴和高氯酸钴与乙酰胺和碳酰胺的配位化合物：催化活性四氧化三钴的合成前体

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S1070328424600049

R. A. Rodriguez Pineda, I. A. Karavaev, E. V. Savinkina, E. V. Volchkova, Zh. Yu. Pastukhova, L. G. Bruk, G. A. Buzanov, A. S. Kubasov, V. M. Retivov

{"title":"Coordination Compounds of Cobalt(II) Nitrate and Perchlorate with Acetamide and Carbamide: Precursors for the Synthesis of Catalytically Active Tricobalt Tetraoxide","authors":"R. A. Rodriguez Pineda, I. A. Karavaev, E. V. Savinkina, E. V. Volchkova, Zh. Yu. Pastukhova, L. G. Bruk, G. A. Buzanov, A. S. Kubasov, V. M. Retivov","doi":"10.1134/S1070328424600049","DOIUrl":"10.1134/S1070328424600049","url":null,"abstract":"The reactions of cobalt(II) nitrate or perchlorate with acetamide (AA) or carbamide (Ur) in an aqueous medium results in formation of coordination compounds [Co(Ur)4](NO3)2 (I), [Co(Ur)6](NO3)2 (II), [Co(AA)4(H2O)2](NO3)2 (III), [Co(AA)4(H2O)2](NO3)2∙2AA (IV), [Co(Ur)6](ClO4)2, (V), [Co(AA)4(H2O)2](ClO4)2 (VI), and [Co(AA)6](ClO4)2 (VII). The compositions of the isolated complexes are determined by physicochemical methods, and the crystal and molecular structures of compounds II, V, VI, and VII are solved. Specific features of the thermal behavior of all synthesized compounds in a wide temperature range are studied in detail. These compounds are shown to be used as precursors in the preparation of nanosized Co3O4 using self-propagating high-temperature synthesis. The catalytic activity of thus synthesized Co3O4 in the model epoxidation of allyl alcohol is studied.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141778832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis and Study of Mono(arylhydrazino)acenaphthenones and Nickel Complex Based on Pyridine-Substituted Derivative 单(芳基肼)苊酮和基于吡啶取代衍生物的镍配合物的合成与研究

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S1070328423601644

I. V. Bakaev, V. I. Komlyagina, N. F. Romashev, A. L. Gushchin

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Photoluminescent Lanthanide(III) Complexes Based on 2-[((4-Chlorophenyl)amino)methylene]-5,5-dimethylcyclohexane-1,3-dione 基于 2-[((4-氯苯基)氨基)亚甲基]-5,5-二甲基环己烷-1,3-二酮的光致发光镧系元素（III）配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S1070328423601450

K. S. Smirnova, E. A. Sanzhenakova, I. V. El’tsov, I. P. Pozdnyakov, A. A. Russkikh, V. V. Dotsenko, E. V. Lider

{"title":"Photoluminescent Lanthanide(III) Complexes Based on 2-[((4-Chlorophenyl)amino)methylene]-5,5-dimethylcyclohexane-1,3-dione","authors":"K. S. Smirnova, E. A. Sanzhenakova, I. V. El’tsov, I. P. Pozdnyakov, A. A. Russkikh, V. V. Dotsenko, E. V. Lider","doi":"10.1134/S1070328423601450","DOIUrl":"10.1134/S1070328423601450","url":null,"abstract":"Five coordination compounds of the general formula [LnL2(NO3)3]n (Ln3+ = Eu (I), Sm (II), Tb (III), Dy (IV), and Gd (V)) based on 2-[((4-chlorophenyl)amino)methylene]-5,5-dimethylcyclohexane-1,3-dione (L) are synthesized. The crystal structures of the ligand and complex III are determined by X-ray diffraction (XRD) analysis of single crystals (CIF files CCDC no. 2298715 (L) and 2298716 (III)). Complex III is polymeric due to the bidentate-bridging coordination of the ligand by the oxygen atoms of the cyclohexanedione fragment, and the coordination number of the central atom is ten. According to the powder XRD data, all synthesized polycrystalline compounds are isostructural to the single crystals of complex III. The photoluminescence properties of the ligand and coordination compounds in the polycrystalline state are studied. The energy transfer from the ligand to lanthanide(III) ion is shown to proceed via the “antenna” mechanism in the case of the europium(III), samarium(III), and terbium(III) compounds. Among the series of the complexes, the highest quantum yield is observed for compound I (21.9%), and the sensitization efficiency of the europium(III) complex is 43.5%.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141778730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis of Halogen-Substituted [12]Mercuracarborands-4. Crystal Structure of {[(9,12-I2-C2B10H8-1,2'-Hg)4]Cl}Na(H2O)n 卤素取代的 [12]Mercuracarborands-4 的合成。{[(9,12-I2-C2B10H8-1,2'-Hg)4]Cl}Na(H2O)n 的晶体结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S1070328423601620

K. Yu. Suponitskii, S. A. Anufriev, A. V. Shmal’ko, I. B. Sivaev

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Acyclic Diaminocarbene Platinum(IV) Complexes Synthesized by the Oxidative Addition of MeI and I2 通过 MeI 和 I2 的氧化加成合成的无环二氨基羰基铂（IV）络合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S107032842360153X

A. A. Karcheuski, M. A. Kinzhalov, S. A. Katkova

{"title":"Acyclic Diaminocarbene Platinum(IV) Complexes Synthesized by the Oxidative Addition of MeI and I2","authors":"A. A. Karcheuski, M. A. Kinzhalov, S. A. Katkova","doi":"10.1134/S107032842360153X","DOIUrl":"10.1134/S107032842360153X","url":null,"abstract":"The oxidative addition of methyl iodide or molecular iodine to the bis(С,N-chelate) deprotonated diaminocarbene platinum(II) complexes [Pt{C(N(H)Ar)(NC(N(H)Ph)N(Ph)}2] (Ar = C6H3-2,6-Me2 (Xyl), C6H2-2,4,6-Me3 (Mes), and C6H4-4-Me (pTol)) affords the corresponding platinum(IV) derivatives in a yield of 89–99%. The addition of CF3CO2H is accompanied by the protonation of the nitrogen atoms of the diaminocarbene fragment to form the cationic complexes [PtI(X)-{C(N(H)Ar)(NC-(N(H)Ph)N(Ph)}2]CF3CO2H (X = Me, I). The structures of the compounds are determined by elemental analysis; high resolution mass spectrometry with electrospray ionization (ESI HRMS); IR spectroscopy; 1H, 13C{1H}, 19F{1H}, and 195Pt{1H} NMR spectroscopy; 2D NMR spectroscopy (1H,1Н COSY, 1H,1Н NOESY, 1H,13C HSQC, 1H,13C HMBC, 1H,15N HSQC, 1H,15N HMBC), and X-ray diffraction (XRD) and thermogravimetric analyses. The synthesized platinum(IV) complexes are thermally stable to 200–260°C and are electroneutral molecules with the octahedral coordination sphere formed by two deprotonated diaminocarbene C,N‑chelate substituents and iodine and methyl or two iodine atoms localized in the apical positions.","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141785646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Lanthanide Complexes with 1,4,7-Trimethyl-1,4,7-triazacyclononane 镧系元素与 1,4,7-三甲基-1,4,7-三氮杂环壬烷的配合物

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-07-27 DOI: 10.1134/S1070328424600219

S. S. Degtyareva, D. A. Bardonov, K. A. Lysenko, M. E. Minyaev, I. E. Nifant’ev, D. M. Roitershtein

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Mononuclear Nickel(II) and Copper(II) Coordination Compounds with Ligands Based on Acetyl(benzoyl)acetone S-Methylisothiosemicarbazones and 8-Quinolinecarboxaldehyde. Synthesis and Crystal Structure 单核镍(II)和铜(II)配位化合物，配体基于乙酰基（苯甲酰）丙酮 S-甲基异硫代氨基脲和 8-喹啉甲醛。合成与晶体结构

IF 1.1 3区化学

Russian Journal of Coordination Chemistry Pub Date : 2024-05-16 DOI: 10.1134/S1070328423601267

M. A. Cocu, P. N. Bourosh, V. Ch. Kravtsov, O. S. Danilescu, I. I. Bulhac

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