双核配合物[Zn2(Piv)4(Phen)2]在水的作用下单体化

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Coordination Chemistry Pub Date : 2024-12-08 DOI:10.1134/S1070328424601006

A. S. Samulionis, A. G. Medvedev, T. A. Tripol’skaya, M. A. Kiskin, P. V. Prikhodchenko, I. L. Eremenko, S. A. Nikolaevskii

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引用次数: 0

摘要

双核配合物[Zn2（Рiv）4（Рhen）2]与甲苯或乙腈中的水相互作用，使其单体化，形成化合物[Zn（Рiv）2(H2O)（Рhen）]，通过XRD （CIF文件CСDC no）测定其晶体结构。2374361)。粉末XRD证实了所形成晶相的独特性。提出以氧化锌/氢氧化锌纳米颗粒为水源，制备适合于XRD的[Zn（Рiv）2(H2O)（Рhen）]单晶。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Monomerization of Binuclear Complex [Zn2(Piv)4(Phen)2] under the Action of Water

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Monomerization of Binuclear Complex [Zn2(Piv)4(Phen)2] under the Action of Water

The interaction of the binuclear complex [Zn₂(Рiv)₄(Рhen)₂] with water in toluene or acetonitrile results in its monomerization with the formation of compound [Zn(Рiv)₂(H₂O)(Рhen)], the crystal structure of which is determined by XRD (CIF file CСDC no. 2374361). The individual character of the formed crystalline phase is confirmed by powder XRD. Nanoparticles of zinc peroxide/hydroxide are proposed to be used as a water source for the obtaining of single crystals of [Zn(Рiv)₂(H₂O)(Рhen)] suitable for XRD.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.