Electronic Materials Letters最新文献

筛选
英文 中文
Investigation and Comparative Studies on Charge Storage Performance in Nanostructured RuO2, NiO and Co3O4 Nanoparticles for High Dense Energy Storage 用于高密度储能的纳米结构 RuO2、NiO 和 Co3O4 纳米粒子的电荷存储性能调查与比较研究
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-05-24 DOI: 10.1007/s13391-024-00500-4
C. Sambathkumar, K. R. Nagavenkatesh, R. Thangavel, N. Nallamuthu, P. Devendran, K. Rajesh
{"title":"Investigation and Comparative Studies on Charge Storage Performance in Nanostructured RuO2, NiO and Co3O4 Nanoparticles for High Dense Energy Storage","authors":"C. Sambathkumar,&nbsp;K. R. Nagavenkatesh,&nbsp;R. Thangavel,&nbsp;N. Nallamuthu,&nbsp;P. Devendran,&nbsp;K. Rajesh","doi":"10.1007/s13391-024-00500-4","DOIUrl":"10.1007/s13391-024-00500-4","url":null,"abstract":"<div><p>Increasing energy requirement and over energy consumption and further upgrading of energy transfer and storage mechanisms are the critical problem. The supercapacitor is a good candidate for applications requiring high power delivery or uptake. Metal oxides can be effective electrode materials for energy storage devices due to their multiple oxidation states, high theoretical specific capacitance, wide potential window and eco-friendliness. In this connection, here report that electrodes made of notable nanosized transition metal oxides such as Ruthenium oxide (RuO<sub>2</sub>), Nickel oxide (NiO) and Cobalt oxide (Co<sub>3</sub>O<sub>4</sub>) were prepared by simple hydrothermal route and the prepared samples were confirmed through structural, vibrational, morphological, and elemental composition analysis. The modified working electrodes were then examined for electrochemical behavior, including CV, GCD, and EIS studies, using a 1 M KOH electrolyte solution after successive coating of the working material on empty Ni foil. Among them, RuO<sub>2</sub> has high integral area, a low sweep rate and remarkable specific capacitance value of 447.1 Fg<sup>-1</sup> at 5 mVs<sup>-1</sup> in CV analysis. In addition, the GCD curve has good charge-discharge cyclic stability with a maximum specific capacitance of 412.1 Fg<sup>-1</sup> at 0.5 Ag<sup>-1</sup> compared to NiO and Co<sub>3</sub>O<sub>4</sub>. RuO<sub>2</sub> has long charge-discharge stability and only 6.8% loss in capacitive retention compared to the other systems, NiO (11.2%) and Co<sub>3</sub>O<sub>4</sub> (9.3%), even after 10,000 cycles. We except that use of nanosized metal oxide electrodes to enhance electrochemical activity will lead to further improvement in the supercapacitors.</p></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"571 - 583"},"PeriodicalIF":2.1,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141101975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ZIF-Derived Cobalt Sulfides Embedded on Nitrogen-Doped Carbon Frameworks for Efficient Hydrogen Evolution Reaction 嵌入掺氮碳框架的 ZIF 衍生硫化钴,用于高效氢气进化反应
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-05-24 DOI: 10.1007/s13391-024-00502-2
Joon Soo Rhie, Ha Huu Do, Soo Young Kim
{"title":"ZIF-Derived Cobalt Sulfides Embedded on Nitrogen-Doped Carbon Frameworks for Efficient Hydrogen Evolution Reaction","authors":"Joon Soo Rhie,&nbsp;Ha Huu Do,&nbsp;Soo Young Kim","doi":"10.1007/s13391-024-00502-2","DOIUrl":"10.1007/s13391-024-00502-2","url":null,"abstract":"<div><p>The development of efficient and durable catalysts for the hydrogen evolution reaction (HER) is essential for sustainable energy research. Cobalt sulfides (CoS<sub>x</sub>) have attracted significant interest as prospective catalysts for the HER owing to their promising catalytic activity and high stability. In this study, CoS<sub>x</sub> nanocrystals embedded in nitrogen-doped carbon frameworks (NC) are fabricated using a zeolite imidazole framework precursor via a two-step pyrolysis-sulfurization process, followed by combination with carbon black (CB) to create CoS<sub>x</sub>-NC/CB as an efficient electrocatalyst for the HER. Interestingly, this catalyst displays a higher HER activity than that of the investigated materials, with an overpotential of 282 mV at a current density of 10 mA cm<sup>− 2</sup>, along with a Tafel slope of 57.6 mV dec<sup>− 1</sup> in an acidic solution. This performance is attributed to the synergistic effect of CoS<sub>x</sub> nanoparticles, nitrogen-doped carbon, and highly conductive CB, which improves the number of active sites, electron transfer, and electrochemical surface area. This outcome has significant potential for the development of economically viable catalysts for water splitting.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"639 - 647"},"PeriodicalIF":2.1,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141102659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Co2+ Doping on Electrochemical Properties of Nickel Metal Tungstate (NiWO4) Positive Material 掺杂 Co2+ 对金属钨酸镍(NiWO4)正极材料电化学特性的影响
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-05-15 DOI: 10.1007/s13391-024-00493-0
Jing Tang, Hui Xu, Yong Chen, Yuanqiang Zhu
{"title":"Effect of Co2+ Doping on Electrochemical Properties of Nickel Metal Tungstate (NiWO4) Positive Material","authors":"Jing Tang,&nbsp;Hui Xu,&nbsp;Yong Chen,&nbsp;Yuanqiang Zhu","doi":"10.1007/s13391-024-00493-0","DOIUrl":"10.1007/s13391-024-00493-0","url":null,"abstract":"<div><p>Currently, transition metal tungstates are emerging as electroactive materials for supercapacitors due to their excellent electrical conductivity and electrochemical properties. Small amounts of transition metal ions doping can affect the physical and electrical properties of transition metal tungstates. In this study, Co ion-doped NiWO<sub>4</sub> amorphous composites (CNWO) were synthesized using a simple and effective hydrothermal method and utilized as the cathode material for supercapacitors. The structure and electrochemical properties of NiWO<sub>4</sub> and CNWO composites were investigated using various testing techniques. Specifically, when the cobalt ion doping amount is 10%, the corresponding CNWO-10 electrode material exhibits a specific capacitance of 804 F g<sup>−1</sup> at 1 A g<sup>−1</sup>, and at a current density of 10 A g<sup>−1</sup>, the capacitance retention rate reaches 66.7%, demonstrating good rate performance. Additionally, an asymmetric supercapacitor device was constructed using CNWO-10 and activated carbon (AC) as positive and negative materials, respectively. Which could cycle reversibly under a potential window of 2.1 V. The device demonstrates a maximum specific capacitance of 76.5 F g<sup>−1</sup> at 0.5 A g<sup>−1</sup>, and a high energy density of 47 Wh kg<sup>−1</sup> at a power density of 527 W kg<sup>−1</sup>. Furthermore, 96% capacitance cycling stability is maintained after 5500 cycles at a trapezoidal current density. Moreover, the electrical conductivities of NiWO<sub>4</sub> and CNWO-10 samples are 9.01 × 10<sup>–8</sup> S m<sup>−1</sup> and 8.93 × 10<sup>–6</sup> S m<sup>−1</sup>, attributed to the Co ion-doping that can reduce the gap width of the forbidden band to enhance conductivity. These results suggest that CNWO composites can serve as promising high-capacity electrode materials for high-performance supercapacitors in alkaline electrolytes.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 4","pages":"459 - 473"},"PeriodicalIF":2.1,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140975608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Novel Sensor for the Detection of n-Butanol Based on CoMn2O4 Nanoparticles 基于 CoMn2O4 纳米粒子的新型正丁醇检测传感器
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-05-13 DOI: 10.1007/s13391-024-00498-9
Juan Pablo Morán-Lázaro, Maykel Courel-Piedrahita, Alex Guillén-Bonilla, Florentino López-Urías, Héctor Guillén-Bonilla, Víctor Manuel Soto-García, Aldo Palafox-Corona, David Alberto Hernández-Poot
{"title":"A Novel Sensor for the Detection of n-Butanol Based on CoMn2O4 Nanoparticles","authors":"Juan Pablo Morán-Lázaro,&nbsp;Maykel Courel-Piedrahita,&nbsp;Alex Guillén-Bonilla,&nbsp;Florentino López-Urías,&nbsp;Héctor Guillén-Bonilla,&nbsp;Víctor Manuel Soto-García,&nbsp;Aldo Palafox-Corona,&nbsp;David Alberto Hernández-Poot","doi":"10.1007/s13391-024-00498-9","DOIUrl":"10.1007/s13391-024-00498-9","url":null,"abstract":"<div><p>In this paper, we studied the alcohol-sensing properties of CoMn<sub>2</sub>O<sub>4</sub> nanoparticles for the first time. The CoMn<sub>2</sub>O<sub>4</sub> nanoparticles were prepared via a simple microwave-assisted colloidal method using cobalt nitrate, manganese nitrate, dioctyl sulfosuccinate sodium salt, and ethylene glycol as a solvent. Various techniques were used to characterize the structural, morphological, and optical properties of CoMn<sub>2</sub>O<sub>4</sub>. The crystal structure of CoMn<sub>2</sub>O<sub>4</sub> was found after calcination at a temperature of 400 °C. The Raman spectrum showed seven vibrational bands, while the optical absorption spectrum showed three bands, confirming the spinel CoMn<sub>2</sub>O<sub>4</sub>. Morphological analysis revealed that the porous microstructure of CoMn<sub>2</sub>O<sub>4</sub> was composed of nanoparticles with a size distribution of 16 to 58 nm. Gas sensors were fabricated with the CoMn<sub>2</sub>O<sub>4</sub> powders calcined at 400 °C using the brush-coating method, and experimental results showed that CoMn<sub>2</sub>O<sub>4</sub> nanoparticles were more sensitive to <i>n</i>-butanol than isopropanol and ethanol at an operating temperature of 185 °C. The CoMn<sub>2</sub>O<sub>4</sub> sensor showed a response of 6.6 at 50 ppm <i>n</i>-butanol with good stability, reproducibility, and repeatability. The present article provides a new sensing material that could be used as an <i>n</i>-butanol sensor with significant benefits for human health.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"610 - 620"},"PeriodicalIF":2.1,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Two-Dimensional Leafy Fe/N-Doped Carbon Nanomaterials Derived from Vitamin C-Modified ZIF-L for Efficient Oxygen Reduction Reaction 维生素 C 改性 ZIF-L 衍生的二维叶状 Fe/N 掺杂碳纳米材料用于高效氧还原反应
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-05-08 DOI: 10.1007/s13391-024-00496-x
Yating Zhang, Xiaobo Wang, Meng Chen, Pei He, Zhenghan Kong
{"title":"Two-Dimensional Leafy Fe/N-Doped Carbon Nanomaterials Derived from Vitamin C-Modified ZIF-L for Efficient Oxygen Reduction Reaction","authors":"Yating Zhang,&nbsp;Xiaobo Wang,&nbsp;Meng Chen,&nbsp;Pei He,&nbsp;Zhenghan Kong","doi":"10.1007/s13391-024-00496-x","DOIUrl":"10.1007/s13391-024-00496-x","url":null,"abstract":"<div><p>Oxygen reduction reaction (ORR) is an important half-reaction in various energy devices such as fuel cells. Here, 2D dendritic Fe/N co-doped carbon-based nanosheet composites (L-Fe-CNT@NCS-900) were obtained by high-temperature calcination using ZIF-L generated in the aqueous phase as a precursor and Vitamin C as a modifier. It is found that the catalysts calcined at 900℃ possessed the large specific surface area and the pore size distribution graphs showed a narrow micropore size distribution centered at about 1.8 nm. Furthermore, the Fe-N-C species was detected, which further improved the ORR performance as an active center. Thus, the L-Fe-CNT@NCS-900 calcined at 900 °C achieved the best ORR performance with a half-wave potential (E<sub>1/2</sub>) of 0.85 V, and the hydrogen peroxide yield is only about 4% during the ORR process. Meanwhile, L-Fe-CNT@NCS-900 exhibited outstanding methanol resistance. This work proposes a new strategy for constructing an efficient electrocatalysts for oxygen reduction reaction.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"592 - 602"},"PeriodicalIF":2.1,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140938206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tl3PbI5 Nanocrystals for Ultraviolet Photovoltaics 用于紫外线光伏的 Tl3PbI5 纳米晶体
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-05-04 DOI: 10.1007/s13391-024-00499-8
Wooyeon Kim, Bonkee Koo, Jaeyeon Kim, In Choi, Seongyeon Hwang, Min Jae Ko
{"title":"Tl3PbI5 Nanocrystals for Ultraviolet Photovoltaics","authors":"Wooyeon Kim,&nbsp;Bonkee Koo,&nbsp;Jaeyeon Kim,&nbsp;In Choi,&nbsp;Seongyeon Hwang,&nbsp;Min Jae Ko","doi":"10.1007/s13391-024-00499-8","DOIUrl":"10.1007/s13391-024-00499-8","url":null,"abstract":"<div><p>Tl<sub>3</sub>PbI<sub>5</sub> exhibits a bandgap energy suitable for absorbing visible and ultraviolet spectra along with a high absorption capability, rendering it a promising candidate for a broader range of solar energy applications. However, its applicability as a light absorber in solar cells is yet to be experimentally confirmed. In this study, we systemically investigate the synthesis process and the crystallographic and chemical properties of Tl<sub>3</sub>PbI<sub>5</sub> nanocrystals. These results enable the optimization of Tl<sub>3</sub>PbI<sub>5</sub> nanocrystals for use as a light absorber. In addition, a solid-state ligand exchange method employing methyl acetate (MeOAc) is introduced to construct a Tl<sub>3</sub>PbI<sub>5</sub> absorption layer for photovoltaic applications. This method facilitates the preparation of multilayer thin films with precise thickness control. The optimally designed Tl<sub>3</sub>PbI<sub>5</sub>-based solar cell achieves a power conversion efficiency (<i>PCE</i>) of 0.20%. Furthermore, the device retains over 90% of its <i>PCE</i> after 2000 h at 25 °C and 60% relative humidity, indicating the potential of Tl<sub>3</sub>PbI<sub>5</sub>-based photovoltaics for reliable solar energy harvesting.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"584 - 591"},"PeriodicalIF":2.1,"publicationDate":"2024-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140884163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phenyltrimethylammonium as an Interlayer Spacer for Stable Formamidinium-Based Quasi-2D Perovskite Solar Cells 苯基三甲基铵作为稳定的甲脒基准二维过氧化物太阳能电池的层间垫片
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-04-26 DOI: 10.1007/s13391-024-00497-w
Bumjin Gil, Jinhyun Kim, Byungwoo Park
{"title":"Phenyltrimethylammonium as an Interlayer Spacer for Stable Formamidinium-Based Quasi-2D Perovskite Solar Cells","authors":"Bumjin Gil,&nbsp;Jinhyun Kim,&nbsp;Byungwoo Park","doi":"10.1007/s13391-024-00497-w","DOIUrl":"10.1007/s13391-024-00497-w","url":null,"abstract":"<div><p>Quasi-2D perovskite materials possess great potential in improving the stability of perovskite solar cells due to their superior chemical and structural stableness compared to 3D counterparts. Here, commonly-used 3D formamidinum lead iodide (FAPbI<sub>3</sub>) perovskite is alloyed by addition of quaternary cation phenyltrimethylammonium (PTMA) up to 33% (<i>n</i> = 5), which forms quasi-2D perovskite phase that acts beneficial to charge transport and stability. Since the detailed structural analyses regarding this quaternary ammonium salt is still lacking, we attempt to provide how the presence of 2D perovskite affects the crystal structure based on x-ray diffraction techniques. It is shown that PTMA cations directs FAPbI<sub>3</sub> to have textured orientation and reduced strains. This led to enhanced extraction of photogenerated carriers and reduced defects, making it promising material for solar cell applications. The champion device remains stable under 60 °C or 1 sun for 700 h, demonstrating its potential for optoelectronic devices requiring long-term stability.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 6","pages":"791 - 798"},"PeriodicalIF":2.1,"publicationDate":"2024-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140799574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetite–Polyaniline Nanocomposite for Non-Volatile Memory and Neuromorphic Computing Applications 用于非易失性存储器和神经形态计算应用的磁铁矿-多苯胺纳米复合材料
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-04-16 DOI: 10.1007/s13391-024-00495-y
Ishika U. Shah, Snehal L. Patil, Sushilkumar A. Jadhav, Tukaram D. Dongale, Rajanish K. Kamat
{"title":"Magnetite–Polyaniline Nanocomposite for Non-Volatile Memory and Neuromorphic Computing Applications","authors":"Ishika U. Shah,&nbsp;Snehal L. Patil,&nbsp;Sushilkumar A. Jadhav,&nbsp;Tukaram D. Dongale,&nbsp;Rajanish K. Kamat","doi":"10.1007/s13391-024-00495-y","DOIUrl":"10.1007/s13391-024-00495-y","url":null,"abstract":"<div><p>Conducting polymers are proving to be useful for   construction of resistive switching devices. This work reports the fabrication of a resistive switching device using Magnetite-Polyaniline (Fe<sub>3</sub>O<sub>4</sub>-PANI) nanocomposite. The device showed good non-volatile memory properties and can mimic neuromorphic synaptic behavior. Initially, Fe<sub>3</sub>O<sub>4</sub> nanoparticles were synthesized using the co-precipitation method and PANI by oxidative polymerization and their nanocomposites of different compositions were prepared and fully characterized. The 10% Fe<sub>3</sub>O<sub>4</sub>-PANI-based RS device outperforms all others in terms of I–V switching performance. Furthermore, the optimized device (10% Fe<sub>3</sub>O<sub>4</sub>-PANI) has tuneable I–V characteristics. The device demonstrated excellent analog switching at ± 1.5 V and digital switching at ± 2.5 V. The memristive behavior of the Ag/10% Fe<sub>3</sub>O<sub>4</sub>-PANI/FTO device was confirmed by the pinched hysteresis loop in the I–V curves at different voltages, as well as the double-valued charged-flux characteristics. The device has good cycle-to-cycle reliability for switching voltages and switching currents, as demonstrated by the Weibull distribution and other statistical measures. Moreover, the device can retain memory states up to 6 × 10<sup>3</sup> s and shows a switching stability of 2 × 10<sup>4</sup> cycles. The device also showed linear potentiation and depression characteristics and mimicked excitatory post-synaptic current (EPSC) and paired-pulse facilitation (PPF) index properties similar to its biological counterpart. According to the charge transport model fitting results, the Ohmic and Child’s square laws dominated in both analog and digital switching processes, and RS occurs due to the filamentary process.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 4","pages":"381 - 392"},"PeriodicalIF":2.1,"publicationDate":"2024-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140609086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optoelectronic Synapse Behaviors of HfS2 Grown via Molten Salt Flux Method 熔盐通量法生长的 HfS2 的光电突触行为
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-04-13 DOI: 10.1007/s13391-024-00494-z
Mi Ji Kwon, Nguyen Vu Binh, Su-yeon Cho, Soo Bin Shim, So Hyun Ryu, Yong Jae Jung, Woo Hyun Nam, Jung Young Cho, Jun Hong Park
{"title":"Optoelectronic Synapse Behaviors of HfS2 Grown via Molten Salt Flux Method","authors":"Mi Ji Kwon,&nbsp;Nguyen Vu Binh,&nbsp;Su-yeon Cho,&nbsp;Soo Bin Shim,&nbsp;So Hyun Ryu,&nbsp;Yong Jae Jung,&nbsp;Woo Hyun Nam,&nbsp;Jung Young Cho,&nbsp;Jun Hong Park","doi":"10.1007/s13391-024-00494-z","DOIUrl":"10.1007/s13391-024-00494-z","url":null,"abstract":"<div><p>Layered two-dimensional materials are promising candidates for next-generation semiconductor platforms owing to their atomically thin bodies, and it is crucial to develop a method for their large-scale synthesis for integrating these materials into the fabrication process. Here, we report the synthesis of a centimeter-scale HfS<sub>2</sub> ingot using the molten salt flux method (MSFM). The structure, crystallinity, and uniformity of the synthesized HfS<sub>2</sub> sample were verified using X-ray diffraction and Raman spectroscopy. The chemical properties were investigated using X-ray photoelectron spectroscopy. A HfS<sub>2</sub> synaptic field effect transistor (FET) was fabricated to confirm its electrical uniformity and semiconducting nature, with an average mobility of 10.6 cm<sup>2</sup> V<sup>-1</sup> s<sup>-1</sup>. The synaptic plasticity of the HfS<sub>2</sub> synaptic FET was investigated by applying light pulses (405 nm) in different modulation configurations. Paired-pulse facilitation was achieved by applying a continuous light pulse with a negative gate bias voltage. The modulation of synaptic weight was demonstrated under different stimulation conditions, which emulates the human brain. Furthermore, the linearity of the HfS<sub>2</sub> synaptic device was optimized based on the frequency of the pulses to enhance learning accuracy. The approach reported here encourages the large-scaled production of transition metal dichalcogenides (TMDs) for use in artificial synaptic transistors.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"559 - 570"},"PeriodicalIF":2.1,"publicationDate":"2024-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588054","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Co-W and Co-Fe-W Diffusion Barriers on the Reliability of the Solder/Cu Interface during Reflow Conditions Co-W 和 Co-Fe-W 扩散屏障对回流条件下焊料/铜界面可靠性的影响
IF 2.1 4区 材料科学
Electronic Materials Letters Pub Date : 2024-04-13 DOI: 10.1007/s13391-024-00491-2
Yuexiao Liu, Chongyang Li, Peixin Chen, Jinyang Liu, Anmin Hu, Ming Li
{"title":"Effect of Co-W and Co-Fe-W Diffusion Barriers on the Reliability of the Solder/Cu Interface during Reflow Conditions","authors":"Yuexiao Liu,&nbsp;Chongyang Li,&nbsp;Peixin Chen,&nbsp;Jinyang Liu,&nbsp;Anmin Hu,&nbsp;Ming Li","doi":"10.1007/s13391-024-00491-2","DOIUrl":"10.1007/s13391-024-00491-2","url":null,"abstract":"<div><p>Efficient diffusion barriers are necessary to prevent the formation of copper-tin intermetallic compounds (IMCs) in advanced packaging for Sn/Cu micro-bumps. This study investigated the interfacial properties of solder and Ni, Co-9W, Co-20W, Co-20Fe-10W, and Co-36Fe-17W barriers and determined the thickness of IMCs formed between Sn and these barriers after up to 15 reflows. Among the five barriers, Co-36Fe-17W proved to be the most effective in inhibiting the reaction of liquid Sn solder. At the Sn/Co-W interface, CoSn<sub>3</sub> IMC was formed, while at the Sn/Co-Fe-W interface, CoSn<sub>3</sub> IMC and FeSn<sub>2</sub> IMC were observed. The contact angles of these layers were measured and found to be 18°, 22°, 25°, 29°, and 27°, respectively. The results showed that an increase in W content in Co-W led to an increase in the contact angle, while the intrinsic wettability of Co-Fe-W decreased with an increase in Fe content. The shear strengths of the five joints were 27 MPa, 31 MPa, 25 MPa, 25 MPa, and 26 MPa, respectively, with different fracture modes observed. The Co-Fe-W-Sn layer was partially peeling from the diffusion barriers in SAC305/Co-20Fe-10W, and the fracture surfaces exhibited an irregular and rough state, which was attributed to the increasing Fe and W contents. These findings offer valuable insights for enhancing the reliability of electronic packages.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":536,"journal":{"name":"Electronic Materials Letters","volume":"20 5","pages":"517 - 524"},"PeriodicalIF":2.1,"publicationDate":"2024-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588270","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信