New Carbon Materials最新文献_第2页

A review of carbon-based hybrid materials for supercapacitors 超级电容器用碳基混合材料综述

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60943-7

Theodore Azemtsop Manfo , Hannu Laaksonen

{"title":"A review of carbon-based hybrid materials for supercapacitors","authors":"Theodore Azemtsop Manfo , Hannu Laaksonen","doi":"10.1016/S1872-5805(25)60943-7","DOIUrl":"10.1016/S1872-5805(25)60943-7","url":null,"abstract":"<div><div>Supercapacitors are gaining popularity due to their high cycling stability, power density, and fast charge and discharge rates. Researchers are exploring electrode materials, electrolytes, and separators for cost-effective energy storage systems. Advances in materials science have led to the development of hybrid nanomaterials, such as combining filamentous carbon forms with inorganic nanoparticles, to create new charge and energy transfer processes. Notable materials for electrochemical energy-storage applications include MXenes, 2D transition metal carbides, and nitrides, carbon black, carbon aerogels, activated carbon, carbon nanotubes, conducting polymers, carbon fibers, and nanofibers, and graphene, because of their thermal, electrical, and mechanical properties. Carbon materials mixed with conducting polymers, ceramics, metal oxides, transition metal oxides, metal hydroxides, transition metal sulfides, transition metal dichalcogenide, metal sulfides, carbides, nitrides, and biomass materials have received widespread attention due to their remarkable performance, eco-friendliness, cost-effectiveness, and renewability. This article explores the development of carbon-based hybrid materials for future supercapacitors, including electric double-layer capacitors, pseudocapacitors, and hybrid supercapacitors. It investigates the difficulties that influence structural design, manufacturing (electrospinning, hydrothermal/ solvothermal, template-assisted synthesis, electrodeposition, electrospray, 3D printing) techniques and the latest carbon-based hybrid materials research offer practical solutions for producing high-performance, next-generation supercapacitors.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (158KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 81-110"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

P, N co-doped hollow carbon nanospheres prepared by micellar copolymerization for increased hydrogen evolution in alkaline water

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60949-8

Yi-meng HAN, Hao XIONG, Jia-ying YANG, Jian-gan WANG, Fei XU

{"title":"P, N co-doped hollow carbon nanospheres prepared by micellar copolymerization for increased hydrogen evolution in alkaline water","authors":"Yi-meng HAN, Hao XIONG, Jia-ying YANG, Jian-gan WANG, Fei XU","doi":"10.1016/S1872-5805(25)60949-8","DOIUrl":"10.1016/S1872-5805(25)60949-8","url":null,"abstract":"<div><div>The design of cost-effective and efficient metal-free carbon-based catalysts for the hydrogen evolution reaction (HER) is of great significance for increasing the production of clean hydrogen by the electrolysis of alkaline water. Precise control of the electronic structure by heteroatom doping has proven to be efficient for increasing catalytic activity. Nevertheless, both the structural characteristics and the underlying mechanism are not well understood, especially for doping with two different atoms, thus limiting the use of these catalysts. We report the production of phosphorus and nitrogen co-doped hollow carbon nanospheres (HCNs) by the copolymerization of pyrrole and aniline at a Triton X-100 micelle-interface, followed by doping with phytic acid and carbonization. The unique pore structure and defect-rich framework of the HCNs expose numerous active sites. Crucially, the combined effect of graphitic nitrogen and phosphorus-carbon bonds modulate the local electronic structure of adjacent C atoms and facilitates electron transfer. As a result, the HCN carbonized at 1100 °C exhibited superior HER activity and an outstanding stability (70 h at a current density of 10 mA cm<sup>−2</sup>) in alkaline water, because of the large number of graphitic nitrogen and phosphorus-carbon bonds.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (98KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 211-221"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Porous nitrogen-doped carbon nanosheets derived from oil palm petioles for use as the sulfur host material in high-rate and durable Li-S batteries

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60952-8

Yu-si LIU , Xing-he ZHAO , Kai-xue WANG

{"title":"Porous nitrogen-doped carbon nanosheets derived from oil palm petioles for use as the sulfur host material in high-rate and durable Li-S batteries","authors":"Yu-si LIU , Xing-he ZHAO , Kai-xue WANG","doi":"10.1016/S1872-5805(25)60952-8","DOIUrl":"10.1016/S1872-5805(25)60952-8","url":null,"abstract":"<div><div>The composition and structure of the sulfur host material in lithium-sulfur batteries are the main reasons for differences in battery performance, and one that is both economical and environmentally friendly is needed for producing practical batteries. We have used an innovative method to prepare nitrogen-doped porous carbon nanosheets (N-PPCNs) from the petioles of palm trees. A nitrogen dopped material consisting of stacks of these nano-sheets was synthesized by soaking the petioles in urea followed by chemical activation. The porous carbon materials were uniformly doped with nitrogen and were used as the sulfur host material, which increased the adsorption energy of polysulfides and accelerated the conversion from long-chain polysulfides to short-chain polysulfides. The porous structure and nitrogen doping work together to suppress the “shuttle effect”, enabling the electrode to achieve a high specific capacity of 1257 mAh g<sup>−1</sup>, and still maintain a specific capacity of 490 mAh g<sup>−1</sup> after 500 cycles at a rate of 1 C. This work demonstrates the potential reuse of waste biomass.</div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 222-230"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Progress in the research of carbon aerogel in photothermal conversion

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60865-6

Yan-ting Lang , Yu He , Huai-he Song , Li-ming Yi , Hai-jun Deng , Xiao-hong Chen

引用次数: 0

Defect-rich N/O-co-doped porous carbon frameworks as anodes for superior potassium and sodium-ion batteries

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60892-9

Ling Bai , Qian Liu , Tao Hong , Hao-ran Li , Fang-yuan Zhu , Hai-gang Liu , Zi-quan Li , Zhen-dong Huang

{"title":"Defect-rich N/O-co-doped porous carbon frameworks as anodes for superior potassium and sodium-ion batteries","authors":"Ling Bai , Qian Liu , Tao Hong , Hao-ran Li , Fang-yuan Zhu , Hai-gang Liu , Zi-quan Li , Zhen-dong Huang","doi":"10.1016/S1872-5805(24)60892-9","DOIUrl":"10.1016/S1872-5805(24)60892-9","url":null,"abstract":"<div><div>Carbon with its high electrical conductivity, excellent chemical stability, and structure ability is the most promising anode material for sodium and potassium ion batteries. We developed a defect-rich porous carbon framework (DRPCF) built with N/O-co-doped mesoporous nanosheets and containing many defects using porous g-C<sub>3</sub>N<sub>4</sub> (PCN) and dopamine (DA) as raw materials. We prepared samples with PCN/DA mass ratios of 1/1, 2/1 and 3/1 and found that the one with a mass ratio of 2/1 and a carbonization temperature of 700 °C in an Ar atmosphere (DRPCF-2/1-700), had a large specific surface area with an enormous pore volume and a large number of N/O heteroatom active defect sites. Because of this, it had the best pseudocapacitive sodium and potassium ion storage performance. A half battery of Na//DRPCF-2/1-700 maintained a capacity of 328.2 mAh g<sup>−1</sup> after being cycled at 1 A g<sup>−1</sup> for 900 cycles, and a half battery of K//DRPC-2/1-700 maintained a capacity of 321.5 mAh g<sup>−1</sup> after being cycled at 1 A g<sup>−1</sup> for 1 200 cycles. The rate capability and cycling stability achieved by DRPCF-2/1-700 outperforms most reported carbon materials. Finally, ex-situ Raman spectroscopy analysis result confirms that the filling and removing of K<sup>+</sup> and Na<sup>+</sup> from the electrochemically active defects are responsible for the high capacity, superior rate and cycling performance of the DRPCF-2/1-700 sample.</div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"39 6","pages":"Pages 1144-1156"},"PeriodicalIF":5.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143312582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis of pitch-derived carbon anodes for high-performance potassium-ion batteries

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60868-1

Ming-chi Jiang, Ning Sun, Jia-xu Yu, Ti-zheng Wang, Razium Ali Somoro, Meng-qiu Jia, Bin Xu

{"title":"Synthesis of pitch-derived carbon anodes for high-performance potassium-ion batteries","authors":"Ming-chi Jiang, Ning Sun, Jia-xu Yu, Ti-zheng Wang, Razium Ali Somoro, Meng-qiu Jia, Bin Xu","doi":"10.1016/S1872-5805(24)60868-1","DOIUrl":"10.1016/S1872-5805(24)60868-1","url":null,"abstract":"<div><div>Potassium-ion batteries (PIBs) hold promise for large-scale energy storage, necessitating the development of high-performance anode materials. Carbons with the advantage of structural versatility, are recognized as the most promising anode materials for their commercialization, however the relationship between the carbon anode structure and its electrochemical performance remains unclear. A series of pitch-based soft carbons with different structures were fabricated using carbonization temperatures in the range 600–1400 °C, and their changes in carbon configuration and K-storage performance as a function of carbonization temperature were investigated. Correlations between the carbon crystal size and the low-potential plateau region capacity and between the degree of structural disorder of the carbons with their sloping region capacity were revealed. Among all samples, that obtained by carbonization at 700 °C had a relatively high degree of disorder and a large interlayer spacing, and had a high reversible capacity of 329.4 mAh g<sup>−1</sup> with a high initial coulombic efficiency of 72.81%, and maintained a high capacity of 144.2 mAh g<sup>−1</sup> at the current rate of 5 C. These findings improve our fundamental understanding of the K-storage process in carbon anodes, and thus facilitate the advance of PIBs.</div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"39 6","pages":"Pages 1117-1127"},"PeriodicalIF":5.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143312584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fluorescence color tuning of dual-emission carbon quantum dots produced from biomass and their use in Fe3+ and Cu2+ detection

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60869-3

Jia-jia Xue, Mei-heng Gan, Yong-gen Lu, Qi-lin Wu

引用次数: 0

Modeling of pyrolytic carbon deposition from propylene

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60893-0

Wen-fang Fang , Jing-chao Yuan , Meng-qian Wang , Yu-qing Peng , Dan Zhang , Ai-jun Li

引用次数: 0

Increasing both the electromagnetic shielding and thermal conductive properties of three-dimensional graphene-CNT-SiC hybrid materials

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60889-9

Fan Feng , Zhi-dong Han , Bing Wei , Yang Wang , Fei-zhou Wang , Yan-yan Jiao , Zhen-ting Wang

{"title":"Increasing both the electromagnetic shielding and thermal conductive properties of three-dimensional graphene-CNT-SiC hybrid materials","authors":"Fan Feng , Zhi-dong Han , Bing Wei , Yang Wang , Fei-zhou Wang , Yan-yan Jiao , Zhen-ting Wang","doi":"10.1016/S1872-5805(24)60889-9","DOIUrl":"10.1016/S1872-5805(24)60889-9","url":null,"abstract":"<div><div>During the operation of electronic devices, a considerable amount of heat and electromagnetic radiation is emitted. Therefore, the investigation of materials with electromagnetic shielding and thermal management abilities has significant importance. Hybrid materials of three-dimensional graphene networks containing both carbon nanotubes (CNTs) and SiC whiskers (3D graphene-CNT-SiC) were synthesized. Using an aqueous-phase reduction method for the self-assembly of the graphene oxide, a three-dimensional porous graphene structure was fabricated. SiC whiskers, inserted between the graphene layers, formed a framework for longitudinal thermal conduction, while CNTs attached to the SiC surface, created a dendritic structure that increased the bonding between the SiC whiskers and graphene, improving dielectric loss and thermal conductivity. It was found that the thermal conductivity of the hybrid material reached 123 W·m<sup>–1</sup>·K<sup>–1</sup>, with a shielding effectiveness of 29.3 dB when the SiC addition was 2%. This result indicates that 3D Graphene-CNT-SiC has excellent thermal conductivity and electromagnetic shielding performance.</div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"39 6","pages":"Pages 1178-1190"},"PeriodicalIF":5.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143312581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A review of carbon nanotubes in modern electrochemical energy storage

IF 5.7 3区材料科学

New Carbon Materials Pub Date : 2024-12-01 DOI: 10.1016/S1872-5805(24)60878-4

Yao-ming Song , Shi-xin Qiu , Shu-xin Feng , Rui Zuo , Ya-ting Zhang , Ke Jia , Xue Xia , Ming-ming Chen , Ke-meng Ji , Cheng-yang Wang

{"title":"A review of carbon nanotubes in modern electrochemical energy storage","authors":"Yao-ming Song , Shi-xin Qiu , Shu-xin Feng , Rui Zuo , Ya-ting Zhang , Ke Jia , Xue Xia , Ming-ming Chen , Ke-meng Ji , Cheng-yang Wang","doi":"10.1016/S1872-5805(24)60878-4","DOIUrl":"10.1016/S1872-5805(24)60878-4","url":null,"abstract":"<div><div>The quest for sustainable energy storage solutions is more critical than ever, with the rise in global energy demand and the urgency of transition from fossil fuels to renewable sources. Carbon nanotubes (CNTs), with their exceptional electrical conductivity and structural integrity, are at the forefront of this endeavor, offering promising ways for the advance of electrochemical energy storage (EES) devices. This review provides an analysis of the synthesis, properties, and applications of CNTs in the context of EES. We explore the evolution of CNT synthesis methods, including arc discharge, laser ablation, and chemical vapor deposition, and highlight the recent developments in metal-organic framework-derived CNTs and a novel CNT aggregate with a three-dimensional ordered macroporous structure. We also examine the role of CNTs in improving the performance of various EES devices such as lithium-ion, lithium-metal, lithium-sulfur, sodium, and flexible batteries as well as supercapacitors. We underscore the challenges that remain, including the scalability of CNT synthesis and the integration of CNTs in electrode materials, and propose potential solutions and future research directions. The review presents a forward-looking perspective on the pivotal role of CNTs in shaping the future of sustainable EES technologies.</div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"39 6","pages":"Pages 1037-1074"},"PeriodicalIF":5.7,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143312587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0