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Recent progress on the use of lignin-based porous carbon in supercapacitors
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60955-3
Ding-chen ZHA , Jia-heng WANG , Rui-xiang Hao , Yun-feng Wu , Xiu-he LI , Jia-wen ZHAO , Wen LI , Wen-xiang PIAO , Nan-zhe JIANG
{"title":"Recent progress on the use of lignin-based porous carbon in supercapacitors","authors":"Ding-chen ZHA ,&nbsp;Jia-heng WANG ,&nbsp;Rui-xiang Hao ,&nbsp;Yun-feng Wu ,&nbsp;Xiu-he LI ,&nbsp;Jia-wen ZHAO ,&nbsp;Wen LI ,&nbsp;Wen-xiang PIAO ,&nbsp;Nan-zhe JIANG","doi":"10.1016/S1872-5805(25)60955-3","DOIUrl":"10.1016/S1872-5805(25)60955-3","url":null,"abstract":"<div><div>With the development of electronics and portable devices, there is a significant drive to develop electrode materials for supercapacitors that are lightweight, economical, and provide high energy and power densities. Lignin-based porous carbons have recently been extensively studied for energy storage applications because of their characteristics of large specific surface area, easy doping, and high conductivity. Significant progress in the synthesis of porous carbons derived from lignin, using different strategies for their preparation and modification with heteroatoms, metal oxides, metal sulfides, and conductive polymers is considered and their electrochemical performances and ion storage mechanisms are discussed. Considerable focus is directed towards the challenges encountered in using lignin-based porous carbons and the ways to optimize specific capacity and energy density for supercapacitor applications. Finally, the limitations of existing technologies and research directions for improving the performance of lignin-based carbons are discussed.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (109KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 50-80"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The low-temperature deposition of a zincophilic carbon layer on the Zn foil for long-life zinc metal batteries
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60947-4
Chun-yu LI, Ming-hui ZHANG, Xin-yue LANG, Ye CHEN, Yan-feng DONG
{"title":"The low-temperature deposition of a zincophilic carbon layer on the Zn foil for long-life zinc metal batteries","authors":"Chun-yu LI,&nbsp;Ming-hui ZHANG,&nbsp;Xin-yue LANG,&nbsp;Ye CHEN,&nbsp;Yan-feng DONG","doi":"10.1016/S1872-5805(25)60947-4","DOIUrl":"10.1016/S1872-5805(25)60947-4","url":null,"abstract":"<div><div>Aqueous zinc metal batteries (ZMBs) which are environmentally benign and cheap can be used for grid-scale energy storage, but have a short cycling life mainly due to the poor reversibility of zinc metal anodes in mild aqueous electrolytes. A zincophilic carbon (ZC) layer was deposited on a Zn metal foil at 450 °C by the up-stream pyrolysis of a hydrogen-bonded supramolecular substance framework, assembled from melamine (ME) and cyanuric acid (CA). The zincophilic groups (C=O and C=N) in the ZC layer guide uniform zinc plating/stripping and eliminate dendrites and side reactions. so that assembled symmetrical batteries (ZC@Zn//ZC@Zn) have a long-term service life of 2500 h at 1 mA cm<sup>−2</sup> and 1 mAh cm<sup>−2</sup>, which is much longer than that of bare Zn anodes (180 h). In addition, ZC@Zn//V<sub>2</sub>O<sub>5</sub> full batteries have a higher capacity of 174 mAh g<sup>−1</sup> after 1200 cycles at 2 A g<sup>−1</sup> than a Zn//V<sub>2</sub>O<sub>5</sub> counterpart (100 mAh g<sup>−1</sup>). The strategy developed for the low-temperature deposition of the ZC layer is a new way to construct advanced zinc metal anodes for ZMBs.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (157KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 178-187"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Near-infrared carbon dots: pioneering emerging frontiers in biomedical applications 近红外碳点:开拓生物医学应用的新领域
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60946-2
Qian HE , Yan-li YANG , Rui-jiao LI, Dan MA, Li-yun ZHANG
{"title":"Near-infrared carbon dots: pioneering emerging frontiers in biomedical applications","authors":"Qian HE ,&nbsp;Yan-li YANG ,&nbsp;Rui-jiao LI,&nbsp;Dan MA,&nbsp;Li-yun ZHANG","doi":"10.1016/S1872-5805(25)60946-2","DOIUrl":"10.1016/S1872-5805(25)60946-2","url":null,"abstract":"<div><div>Carbon dots (CDs) are fluorescent carbon-based nanomaterials with sizes smaller than 10 nm, that are renowned for their exceptional properties, including superior antiphotobleaching, excellent biocompatibility, and minimal toxicity, which have received significant interest. Near-infrared (NIR) light has emerged as an ideal light source in the biological field due to its advantages of minimal scattering and absorption, long wavelength emission, increased tissue penetration, and reduced interference from biological backgrounds. CDs with efficient absorption and/or emission characteristics in the NIR spectrum have shown remarkable promise in the biomedical uses. This study provides a comprehensive overview of the preparation methods and wavelength modulation strategies for near-infrared CDs and reviews research progress in their use in the areas of biosensing, bioimaging, and therapy. It also discusses current challenges and clinical prospects, aimed at deepening our understanding of the subject and promoting further advances in this field.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (53KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 131-153"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A B,N co-doped carbon nanotube array with anchored MnO2 nanosheets as a flexible cathode for aqueous zinc-ion batteries 锚定 MnO2 纳米片的 B、N 共掺杂碳纳米管阵列作为水性锌离子电池的柔性阴极
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60945-0
Yan-bing YUAN , Zong-bin ZHAO , Hong-hui BI , Run-meng ZHANG , Xu-zhen WANG , Jie-shan QIU
{"title":"A B,N co-doped carbon nanotube array with anchored MnO2 nanosheets as a flexible cathode for aqueous zinc-ion batteries","authors":"Yan-bing YUAN ,&nbsp;Zong-bin ZHAO ,&nbsp;Hong-hui BI ,&nbsp;Run-meng ZHANG ,&nbsp;Xu-zhen WANG ,&nbsp;Jie-shan QIU","doi":"10.1016/S1872-5805(25)60945-0","DOIUrl":"10.1016/S1872-5805(25)60945-0","url":null,"abstract":"<div><div>For rechargeable aqueous zinc-ion batteries (ZIBs), the design of nanocomposites comprised of electrochemically active materials and carbon materials with novel structures has great promise in addressing the issue of electrical conductivity and structural stability in the electrode materials during electrochemical cycling. We report the production of a novel flexible electrode material, by anchoring MnO<sub>2</sub> nanosheets on a B,N co-doped carbon nanotube array (BNCNTs) grown on carbon cloth (BNCNTs@MnO<sub>2</sub>), which was fabricated by in-situ pyrolysis and hydrothermal growth. The generated BNCNTs were strongly bonded to the surface of the carbon fibers in the carbon cloth which provides both excellent electron transport and ion diffusion, and improves the stability and durability of the cathode. Importantly, the BNCNTs offer more active sites for the hydrothermal growth of MnO<sub>2</sub>, ensuring a uniform distribution. Electrochemical tests show that BNCNTs@MnO<sub>2</sub> delivers a high specific capacity of 310.7 mAh g<sup>−1</sup> at 0.1 A g<sup>−1</sup>, along with excellent rate capability and outstanding cycling stability, with a 79.7% capacity retention after 8000 cycles at 3 A g<sup>−1</sup>.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (181KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 200-210"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in the use of biomass-derived carbons for sodium-ion batteries
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60953-X
Mei-ci SUN , Shuo-lin QI , Yun-he ZHAO , Chun-xia CHEN , Li-chao TAN , Zhong-li HU , Xiao-liang WU , Wen-li ZHANG
{"title":"Advances in the use of biomass-derived carbons for sodium-ion batteries","authors":"Mei-ci SUN ,&nbsp;Shuo-lin QI ,&nbsp;Yun-he ZHAO ,&nbsp;Chun-xia CHEN ,&nbsp;Li-chao TAN ,&nbsp;Zhong-li HU ,&nbsp;Xiao-liang WU ,&nbsp;Wen-li ZHANG","doi":"10.1016/S1872-5805(25)60953-X","DOIUrl":"10.1016/S1872-5805(25)60953-X","url":null,"abstract":"<div><div>Sodium-ion batteries (SIBs) have emerged as a promising alternative to commercial lithium-ion batteries because of the similar properties of Li and Na as well as the abundance and accessibility of sodium resources. The development of anode materials with a high capacity, excellent rate performance, and long cycle life is the key to the industrialization of SIBs. Biomass-derived carbon (BDC) anode materials synthesized from resource-rich, low-cost, and renewable biomass have been extensively researched and their excellent sodium storage performance has been proven, making them the most promising new low-cost and high-performance anode material for SIBs. This review first introduces the sources of BDCs, including waste biomass such as plants, animals, and microorganisms, and then describes several methods for preparing BDC anode materials, including carbonization, chemical activation, and template methods. The storage mechanism and kinetic process of Na<sup>+</sup> in BDCs are then considered as well as their structure control. The electrochemical properties of sodium-ion storage in BDCs with different structures are examined, and suggestions for future research are made.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (181KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 1-49"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The use of a ternary metal sulfide loading on carbon fibers as the sulfur host for high performance low-temperature lithium sulfur batteries
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(24)60942-X
Xin HE , Huai-yang ZUO , Ru XIAO , Zhuo-yan QU , Zhen-hua SUN , Bao WANG , Feng Li
{"title":"The use of a ternary metal sulfide loading on carbon fibers as the sulfur host for high performance low-temperature lithium sulfur batteries","authors":"Xin HE ,&nbsp;Huai-yang ZUO ,&nbsp;Ru XIAO ,&nbsp;Zhuo-yan QU ,&nbsp;Zhen-hua SUN ,&nbsp;Bao WANG ,&nbsp;Feng Li","doi":"10.1016/S1872-5805(24)60942-X","DOIUrl":"10.1016/S1872-5805(24)60942-X","url":null,"abstract":"<div><div>The use of lithium-sulfur (Li-S) batteries is limited by sulfur redox reactions involving multi-phase transformations, especially at low-temperatures. To address this issue, we report a material (FCNS@NCFs) consisting of nitrogen-doped carbon fibers loaded with a ternary metal sulfide ((Fe, Co, Ni)<sub>9</sub>S<sub>8</sub>) for use as the sulfur host in Li-S batteries. This material was prepared using transfer blot filter paper as the carbon precursor, thiourea as the source of nitrogen and sulfur, and FeCl<sub>3</sub>·6H<sub>2</sub>O, CoCl<sub>2</sub>·6H<sub>2</sub>O and NiCl<sub>2</sub>·6H<sub>2</sub>O as the metal ion sources. It was synthesized by an impregnation method followed by calcination. The nitrogen doping significantly increased the conductivity of the host, and the metal sulfides have excellent catalytic activities. Theoretical calculations, and adsorption and deposition experiments show that active sites on the surface of FCNS@NCFs selectively adsorb polysulfides, facilitate rapid adsorption and conversion, prevent cathode passivation and inhibit the polysulfide shuttling. The FCNS@NCFs used as the sulfur host has excellent electrochemical properties. Its initial discharge capacity is 1639.0 mAh g<sup>−1</sup> at 0.2 C and room temperature, and it remains a capacity of 1255.1 mAh g<sup>−1</sup> after 100 cycles. At −20 ~C, it has an initial discharge capacity of 1578.5 mAh g<sup>−1</sup> at 0.2 C, with a capacity of 867.5 mAh g<sup>−1</sup> after 100 cycles. Its excellent performance at both ambient and low temperatures suggests a new way to produce high-performance low-temperature Li-S batteries.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (82KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 167-177"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultra-stable lithium-sulfur batteries using nitrogen-doped porous carbon nanosheets implanted with both Fe and Ni
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60944-9
Reddeppa Nadimicherla , You-chen TANG , Yu-heng LU , Ru-liang LIU
{"title":"Ultra-stable lithium-sulfur batteries using nitrogen-doped porous carbon nanosheets implanted with both Fe and Ni","authors":"Reddeppa Nadimicherla ,&nbsp;You-chen TANG ,&nbsp;Yu-heng LU ,&nbsp;Ru-liang LIU","doi":"10.1016/S1872-5805(25)60944-9","DOIUrl":"10.1016/S1872-5805(25)60944-9","url":null,"abstract":"<div><div>The major problem with lithium-sulfur (Li-S) batteries is their poor cycling stability because of slow redox kinetics in the cathode and the growth of lithium dendrites on the anode. We report the production of 2D porous carbon nanosheets doped with both Fe and Ni (Fe/Ni-N-PCNSs) by an easy and template-free approach that solve this problem. Because of their ultrathin porous 2D structure and uniform distribution of Fe and Ni dopants, they capture polysulfides, speed up the sulfur redox reaction, and improve the material’s lithiophilicity, greatly suppressing the shuttling of polysulfides and dendrite growth on the lithium anode. As a result, it has an exceptional performance as a stable host for elemental sulfur and metallic lithium, producing a record long life of 1000 cycles with a very small capacity decay of 0.00025% per cycle in a Li-S battery and an excellent cycling stability of over 850 h with a small overpotential of &gt;72 mV in a lithium metal battery. This work suggests the use of multifunctional-based 2D porous carbon nanosheets as a stable host for both elemental sulfur and metallic lithium to improve the Li-S battery performance.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (65KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 188-198"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of high thermal conductivity carbon-based materials for microwave absorption materials
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60948-6
Zheng-xuan LI , Xi WU , Bo JIANG , Wang YANG , Jun-yan DONG , Zhong-zhen DING , Chen ZHANG , Shao-xiong DU , Si-yuan LI , Ruo-yao FENG , Yong-feng LI
{"title":"A review of high thermal conductivity carbon-based materials for microwave absorption materials","authors":"Zheng-xuan LI ,&nbsp;Xi WU ,&nbsp;Bo JIANG ,&nbsp;Wang YANG ,&nbsp;Jun-yan DONG ,&nbsp;Zhong-zhen DING ,&nbsp;Chen ZHANG ,&nbsp;Shao-xiong DU ,&nbsp;Si-yuan LI ,&nbsp;Ruo-yao FENG ,&nbsp;Yong-feng LI","doi":"10.1016/S1872-5805(25)60948-6","DOIUrl":"10.1016/S1872-5805(25)60948-6","url":null,"abstract":"<div><div>The ever-increasing integration of electronic devices has inevitably caused electromagnetic interference and heat accumulation problems, and dual-function materials with both a high thermal conductivity and high electromagnetic wave absorption (EWA) are regarded as an effective strategy for solving these problems. Carbon materials are widely used as thermal and EWA fillers due to their excellent conductivity and outstanding thermal conduction properties, and have become a research hotspot in the field of high thermal conductivity, microwave absorbing materials in recent years. The status of current research progress on carbon-based high thermalconduction microwave absorption materials, including carbon fibers, carbon nanotubes, graphene and amorphous carbon, is reviewed, and the influence of the structure of the materials on their absorption and thermal conductivity properties, such as core-shell structure, three-dimensional network structure, and heteroatom doping, is also elaborated. Feasible solutions for the current problems with these materials are proposed, with the aim of providing valuable guidance for the future design of carbon-based high thermal conduction microwave absorbing materials.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (119KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 111-130"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The use of an oxidized carbon nanotube film to control Zn deposition and eliminate dendrite formation in a Zn ion battery
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60950-4
Pin-xiang LI , Zhe-han YI , Ye-xing WANG , Chang HE , Ji LIANG , Feng HOU
{"title":"The use of an oxidized carbon nanotube film to control Zn deposition and eliminate dendrite formation in a Zn ion battery","authors":"Pin-xiang LI ,&nbsp;Zhe-han YI ,&nbsp;Ye-xing WANG ,&nbsp;Chang HE ,&nbsp;Ji LIANG ,&nbsp;Feng HOU","doi":"10.1016/S1872-5805(25)60950-4","DOIUrl":"10.1016/S1872-5805(25)60950-4","url":null,"abstract":"<div><div>Aqueous zinc ion batteries are regarded as one of the most promising candidates for large-scale energy storage due to their high safety, cost-effectiveness, and environmental friendliness. However, uncontrolled zinc dendrite growth and side reactions of the zinc anode decrease the stability of Zn batteries. We report the synthesis of an air-oxidized carbon nanotube (O-CNT) film by chemical vapor deposition followed by heat treatment in air which is used as a protective layer on the Zn foil to suppress zinc dendrite growth. The increase in the hydrophilicity of the O-CNT film caused by air oxidation facilitates zinc deposition between the film and the anode instead of deposition on the film surface. The porous structure of the O-CNT film homogenizes the Zn<sup>2+</sup> ion flux and the electric field on the surface of the Zn foil, leading to the uniform deposition of Zn. As a result, a O-CNT@Zn symmetric cell has a much better cycling stability with a life of more than 3000 h at 1 mA cm<sup>−2</sup> with a capacity of 1 mAh cm<sup>−2</sup>, and values of more than 2000 h and 1 mAh cm<sup>−2</sup> at 5 mA cm<sup>−2</sup>. In addition, a O-CNT@Zn || Mn<sup>2+</sup> inserted hydrated vanadium pentoxide (MnVOH) full cell has a better rate performance than a Zn || MnVOH cell, achieving a high discharge capacity of 194 mAh g<sup>−1</sup> at a high current density of 8 A g<sup>−1</sup>. In a long-term cycling test, the O-CNT@Zn || MnVOH full cell has a capacity retention of 58.8% after 2000 cycles at a current density of 5 A·g<sup>−1</sup>.</div><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (102KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":19719,"journal":{"name":"New Carbon Materials","volume":"40 1","pages":"Pages 154-166"},"PeriodicalIF":5.7,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143610525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
N/O co-doped microporous carbon as a high-performance electrode for supercapacitors
IF 5.7 3区 材料科学
New Carbon Materials Pub Date : 2025-02-01 DOI: 10.1016/S1872-5805(25)60951-6
Jing-jing YAN , Xiao-hao FANG , De-zhou YAO , Cheng-wei ZHU , Jian-jun SHI , Shan-shan QIAN
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