A review of strategies to produce a fast-charging graphite anode in lithium-ion batteries

IF 5.7 3区 材料科学 Q2 Materials Science
Jin LIANG , Ze QIN , Zhong QUAN , Jing HAO , Xian-ying QIN , Bao-hua LI , Fei-yu KANG
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Abstract

Lithium-ion batteries (LIBs) are an electrochemical energy storage technology that has been widely used for portable electrical devices, electric vehicles, and grid storage, etc. To satisfy the demand for user convenience especially for electric vehicles, the development of a fast-charging technology for LIBs has become a critical focus. In commercial LIBs, the slow kinetics of Li+ intercalation into the graphite anode from the electrolyte solution is known as the main restriction for fast-charging. We summarize the recent advances in obtaining fast-charging graphite-based anodes, mainly involving modifications of the electrolyte solution and graphite anode. Specifically, strategies for increasing the ionic conductivity and regulating the Li+ solvation/desolvation state in the electrolyte solution, as well as optimizing the fabrication and the intrinsic activity of graphite-based anodes are discussed in detail. This review considers practical ways to obtain fast Li+ intercalation kinetics into a graphite anode from the electrolyte as well as analysing progress in the commercialization of fast-charging LIBs.
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锂离子电池中快速充电石墨阳极生产策略综述
锂离子电池(LIBs)是一种电化学储能技术,已广泛应用于便携式电气设备、电动汽车、电网储能等领域。为了满足用户对便利性的需求,特别是对电动汽车的需求,锂电池快速充电技术的开发已成为人们关注的焦点。在商用锂电池中,锂离子从电解质溶液插入石墨阳极的缓慢动力学被认为是快速充电的主要限制。本文综述了制备快速充电石墨基阳极的最新进展,主要包括电解质溶液和石墨阳极的改性。详细讨论了提高离子电导率和调节电解质溶液中Li+溶剂化/脱溶状态的策略,以及优化石墨基阳极的制造和本征活性的策略。本文综述了从电解液中获得锂离子快速插入石墨阳极动力学的实际方法,并分析了快速充电锂离子电池商业化的进展。下载:下载高清图片(120KB)下载:下载全尺寸图片
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来源期刊
New Carbon Materials
New Carbon Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
6.10
自引率
8.80%
发文量
3245
审稿时长
5.5 months
期刊介绍: New Carbon Materials is a scholarly journal that publishes original research papers focusing on the physics, chemistry, and technology of organic substances that serve as precursors for creating carbonaceous solids with aromatic or tetrahedral bonding. The scope of materials covered by the journal extends from diamond and graphite to a variety of forms including chars, semicokes, mesophase substances, carbons, carbon fibers, carbynes, fullerenes, and carbon nanotubes. The journal's objective is to showcase the latest research findings and advancements in the areas of formation, structure, properties, behaviors, and technological applications of carbon materials. Additionally, the journal includes papers on the secondary production of new carbon and composite materials, such as carbon-carbon composites, derived from the aforementioned carbons. Research papers on organic substances will be considered for publication only if they have a direct relevance to the resulting carbon materials.
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