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Paradigm of nanophotonics integrated smart contact lenses: A new frontier in wearable healthcare 纳米光子学集成智能隐形眼镜的范例:可穿戴医疗保健的新前沿
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-26 DOI: 10.1016/j.materresbull.2025.113511
Bakr Ahmed Taha , S.A. Abdulateef , Ali J. Addie , Suha. A. Muneam , Nada. A. Muneam , Adawiya J. Haider , Naser M. Ahmed , Vishal Chaudhary , Norhana Arsad
{"title":"Paradigm of nanophotonics integrated smart contact lenses: A new frontier in wearable healthcare","authors":"Bakr Ahmed Taha ,&nbsp;S.A. Abdulateef ,&nbsp;Ali J. Addie ,&nbsp;Suha. A. Muneam ,&nbsp;Nada. A. Muneam ,&nbsp;Adawiya J. Haider ,&nbsp;Naser M. Ahmed ,&nbsp;Vishal Chaudhary ,&nbsp;Norhana Arsad","doi":"10.1016/j.materresbull.2025.113511","DOIUrl":"10.1016/j.materresbull.2025.113511","url":null,"abstract":"<div><div>Nanophotonic contact lenses represent a revolutionary convergence of optics, electronics, and materials science, offering transformative solutions for personalized medicine and vision enhancement. These lenses integrate nanophotonic structures, biosensors, and wireless communication systems to enable real-time diagnostics, continuous health monitoring, and localized therapies. Key applications include non-invasive monitoring of blood glucose levels, intraocular pressure measurement for glaucoma management, and advanced drug delivery systems. Including innovative materials such as MXenes and plasmonic nanoparticles improves their functionality and provides unprecedented sensitivity and efficiency. In addition, synergy with artificial intelligence (AI) and the Internet of Things (IoT) enables predictive analytics, adaptive therapies and seamless integration into connected healthcare ecosystems. Despite remarkable progress, challenges remain in optimizing manufacturing techniques, ensuring long-term biocompatibility, and achieving scalable manufacturing. Overcoming these hurdles is critical to moving smart contact lenses from laboratory prototypes to commercially viable solutions. This manuscript provides a comprehensive overview of the current advances, challenges, and future directions in nanophotonic smart contact lenses, highlighting their potential to revolutionize personalized medicine and wearable technology. This work emphasizes the critical impact of smart contact lenses on redefining diagnostics, therapy, and beyond by highlighting multidisciplinary innovations and presenting a roadmap for future development. These changes herald a new era in healthcare, where real-time, non-invasive solutions become the norm, offering unprecedented benefits to patients and clinicians.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113511"},"PeriodicalIF":5.3,"publicationDate":"2025-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143898651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green emitting Sr2ZnGe2O7:Mn2+ phosphor: A dual function material for w- LEDs and YOLOv8x based latent fingerprint detection 绿色发光Sr2ZnGe2O7:Mn2+荧光粉:w- led和基于YOLOv8x的潜在指纹检测的双功能材料
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-24 DOI: 10.1016/j.materresbull.2025.113489
T.N. Megharaj , B.R. Radha Krushna , I.S. Pruthviraj , S.C. Sharma , Augustine George , Swati Mishra , K. Ponnazhagan , Lambodaran Ganesan , K. Manjunatha , Sheng Yun Wu , G. Ramakrishna , R. Arunakumar , H. Nagabhushana
{"title":"Green emitting Sr2ZnGe2O7:Mn2+ phosphor: A dual function material for w- LEDs and YOLOv8x based latent fingerprint detection","authors":"T.N. Megharaj ,&nbsp;B.R. Radha Krushna ,&nbsp;I.S. Pruthviraj ,&nbsp;S.C. Sharma ,&nbsp;Augustine George ,&nbsp;Swati Mishra ,&nbsp;K. Ponnazhagan ,&nbsp;Lambodaran Ganesan ,&nbsp;K. Manjunatha ,&nbsp;Sheng Yun Wu ,&nbsp;G. Ramakrishna ,&nbsp;R. Arunakumar ,&nbsp;H. Nagabhushana","doi":"10.1016/j.materresbull.2025.113489","DOIUrl":"10.1016/j.materresbull.2025.113489","url":null,"abstract":"<div><div>Thermally robust, narrow-band green phosphors are vital for advancing white light emitting diodes (w-LEDs). In this study, we examined Sr<sub>2</sub>ZnGe<sub>2</sub>O<sub>7</sub>:x% Mn<sup>2+</sup> (SZGO:x% Mn<sup>2+</sup>) phosphors, with Mn<sup>2+</sup> concentrations ranging from 0 to 6 mol %, synthesized via a solution combustion method using <em>Camellia sinensis</em> (<em>C.S.</em>) extract as the fuel. Upon monitoring the 539 nm emission, the excitation spectrum of the SZGO:4 %Mn<sup>2+</sup> phosphors revealed two distinct ultraviolet (UV) excitation bands. When exposed to UV light, the phosphor produces a brilliant green emission at 539 nm, which corresponds to the characteristic Mn<sup>2+</sup> transition (<sup>4</sup>T<sub>1</sub>→<sup>6</sup>A<sub>1</sub>). Moreover, the SZGO:4% Mn<sup>2+</sup> phosphor achieved an internal quantum efficiency (<em>I<sub>QE</sub></em>) of 86.57 % and maintained a thermal stability of 90.73 % at 420 K. Thermometric analysis reveals that SZGO:4% Mn²⁺ phosphors achieve a maximum relative sensitivity (<em>S<sub>r</sub></em>) of 0.2112 % <em>K</em><sup>−1</sup> at 300 K. Ultimately, a high-performance w-LED is assembled by coating commercial blue and red phosphors with the SZGO:4% Mn<sup>2+</sup> phosphors on a 310 nm UV chip, yielding a correlated colour temperature (CCT) of 5391 K and an impressive colour rendering index (CRI) <em>R<sub>a</sub></em> of 93.7. In addition, the aging, thermal and continuous operation tests are conducted on w-LEDs to evaluate the stability of the devices. The results show that the phosphor can improve the operational stability of w-LEDs. These findings underscore the potential of SZGO:Mn<sup>2+</sup> as an effective green component in w-LED lighting applications. Additionally, the outstanding luminescence properties of SZGO:4% Mn<sup>2+</sup> phosphors are further leveraged for anti-counterfeiting (AC) purposes, enabling multi-level security features under UV-254 nm excitation. Its high-contrast fluorescence response also facilitated precise latent fingerprints (LFPs) detection and classification using You Only Look Once, version 8–Extra Large model (<em>YOLOv8x</em>), demonstrating significant promise for automated forensic analysis and secure authentication systems.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113489"},"PeriodicalIF":5.3,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring yellow emissive polyethylenimine functionalized carbon dots for sensing and removal of chromium ions in aqueous media 探索黄色发光聚乙烯亚胺功能化碳点对水介质中铬离子的传感和去除
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-23 DOI: 10.1016/j.materresbull.2025.113509
Z. Nawas Sherif, K. Anitha
{"title":"Exploring yellow emissive polyethylenimine functionalized carbon dots for sensing and removal of chromium ions in aqueous media","authors":"Z. Nawas Sherif,&nbsp;K. Anitha","doi":"10.1016/j.materresbull.2025.113509","DOIUrl":"10.1016/j.materresbull.2025.113509","url":null,"abstract":"<div><div>The present study addresses the yellow emissive polyethylenimine functionalized carbon dots (YPC) for recognizing and removing pernicious chromium (Cr<sup>3+)</sup> ions from aqueous solutions. To sense and remove the Cr<sup>3+</sup> ions in this case, YPC functions as both an adsorbent and a fluorescent sensor using the adsorption method and fluorescence quenching (Turn-Off), respectively. A successful optimization of the material YPCconcerning certain parameters, such as pH, time, YPC concentration, and metal ion concentration, has resulted in significant sensitivity and removal efficiency. The material has a high removal efficiency and a low detection limit of 0.04 ppm for Cr<sup>3+</sup>ions. Cr<sup>3+</sup> ions are selected based on their fluorescence reaction to the material. The structural, optical, elemental composition and vibrational properties of YPC are examined, and the adsorption isotherm, kinetics and its mechanism of detection and elimination are examined. Lastly, the material is used with actual ambient water samples to assess its practicality.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113509"},"PeriodicalIF":5.3,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143888087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic properties and magnetoimpedance in FINEMET/NdFeB composite ribbons FINEMET/NdFeB复合带的磁性和磁阻抗
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-23 DOI: 10.1016/j.materresbull.2025.113507
Yongbin Guo , Dao Wang , Renpeng Xing , Zhaoxia Xu , Yizhang Li , Xiuwei Yang , Zhongmin Wang , Zhenjie Zhao
{"title":"Magnetic properties and magnetoimpedance in FINEMET/NdFeB composite ribbons","authors":"Yongbin Guo ,&nbsp;Dao Wang ,&nbsp;Renpeng Xing ,&nbsp;Zhaoxia Xu ,&nbsp;Yizhang Li ,&nbsp;Xiuwei Yang ,&nbsp;Zhongmin Wang ,&nbsp;Zhenjie Zhao","doi":"10.1016/j.materresbull.2025.113507","DOIUrl":"10.1016/j.materresbull.2025.113507","url":null,"abstract":"<div><div>This study systematically investigates the giant magnetoimpedance effect (GMI), structure, surface topography and magnetic property of the samples as a function of film thickness. All composite ribbons exhibit soft magnetic characteristics with minimal variation in coercivity. Notably, the coercivity of the NdFeB film is significantly higher compared to that of the composite ribbons. The maximum GMI ratio observed for the composite ribbons reaches 90.4 %, with the peak potential field increasing to 6.0 Oe with the increase of film thickness to 100 nm. A detailed analysis of the peak potential field reveals a strong correlation between the film and ribbon properties. The magnetic interactions models have been developed to explain the variation of magnetoimpedance as a function of film thickness. This model not only enhances our understanding of the magnetic behavior within these composite materials but also provides a theoretical foundation for optimizing high-performance magnetic sensors.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113507"},"PeriodicalIF":5.3,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143890482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, magnetic, dielectric and electrical transport properties of CaCu3Ti2FeVO12 quadruple perovskite oxides synthesized at ambient pressure 常压合成cuu3ti2fevo12四重钙钛矿氧化物的结构、磁性、介电和电输运性质
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-22 DOI: 10.1016/j.materresbull.2025.113508
Jie Ding , Xinhua Zhu
{"title":"Structural, magnetic, dielectric and electrical transport properties of CaCu3Ti2FeVO12 quadruple perovskite oxides synthesized at ambient pressure","authors":"Jie Ding ,&nbsp;Xinhua Zhu","doi":"10.1016/j.materresbull.2025.113508","DOIUrl":"10.1016/j.materresbull.2025.113508","url":null,"abstract":"<div><div>Quadruple perovskite oxides (QPOs) of CaCu<sub>3</sub>Ti<sub>2</sub>FeVO<sub>12</sub> (CCTFVO) were synthesized at ambient pressure, and their structural, dielectric, magnetic and electrical transport properties were investigated. The CCTFVO compounds crystallize in a cubic crystal structure with space group of <em>Im</em><span><math><mover><mn>3</mn><mo>¯</mo></mover></math></span> and lattice parameter of <em>a</em> = 7.3903(8) Å. XPS spectra verify the coexistence of Ti<sup>3+</sup>/Ti<sup>4+</sup> and Fe<sup>2+</sup>/Fe<sup>3+</sup> pairs in this compound. The CCTFVO ceramics displayed pronounced frequency-dependent dielectric behaviour, and a relaxor-like dielectric response appeared between 173 K and 450 K. That was ascribed to the movement of double-ionized oxygen vacancies with thermal activation energy of 1.10 eV. At 100 kHz and 300 K, the CCTFVO ceramics had relative dielectric constant (<em>ε</em><sub>r</sub>) of ∼ 138 and dielectric loss (tan<em>δ</em>) of 0.56. A diffuse phase transition undergoes near 330 K under 1 kHz. The CCTFVO QPOs exhibit ferrimagnetism at 2 K with saturated magnetization of 1.11 <em>μ</em><sub>B</sub>/f.u. and magnetic <em>T</em><sub>C</sub> = 623 K. The Curie-Weiss fitting of the inverse magnetic susceptibility (<em>χ</em><sup>-1</sup>) versus temperature curve, yielded the positive <em>θ</em><sub>P</sub> value of 767 K, confirming the predominant ferromagnetic interactions in the CCTFVO powders. From the Curie constant (<em>C</em> = 0.199 emu⋅K⋅mol<sup>-1</sup>), the effective magnetic moment was calculated as <em>μ</em><sub>eff</sub> = 1.22 <em>μ</em><sub>B</sub>/f.u., which was smaller than the theoretical value of 6.60 <em>μ</em><sub>B</sub>/f.u. Below ∼ 166 K the zero-field cooling (ZFC) and field-cooling (FC) curves became bifurcated each other, and the ZFC curve decreased further upon cooling. This phenomenon is attributed to the presence of short-range spin clusters in the ferromagnetic background. It can be ascribed to the partial disorder of B-site ions, leading to local random potentials and consequently resulting in local competition between the ferromagnetic state driven by double-exchange interactions and antiferromagnetic state driven by superexchange interactions. The resistivity (<em>ρ</em>)-temperature (T) data confirm the semiconducting behaviour of the CCTFVO ceramics, which are fitted by Mott’s variable range hopping model, thermally activated semiconductor conductivity model, and small polaron hopping model, respectively.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113508"},"PeriodicalIF":5.3,"publicationDate":"2025-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143874885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Ni(OH)2/Ni3S2/NF composite electrode materials doped with rGO 掺还原氧化石墨烯Ni(OH)2/Ni3S2/NF复合电极材料的制备
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-21 DOI: 10.1016/j.materresbull.2025.113503
Kang Wei , Jun Li , Xiao Sun , Meng Shao , Jianguo Tang , Soowohn Lee
{"title":"Preparation of Ni(OH)2/Ni3S2/NF composite electrode materials doped with rGO","authors":"Kang Wei ,&nbsp;Jun Li ,&nbsp;Xiao Sun ,&nbsp;Meng Shao ,&nbsp;Jianguo Tang ,&nbsp;Soowohn Lee","doi":"10.1016/j.materresbull.2025.113503","DOIUrl":"10.1016/j.materresbull.2025.113503","url":null,"abstract":"<div><div>rGO/Ni(OH)<sub>2</sub>/Ni<sub>3</sub>S<sub>2</sub> composite electrode materials were successfully synthesized on Ni foam (NF) by a two-step hydrothermal process and subsequent alkalization treatment. To investigate the influence of reaction time in the secondary hydrothermal process, three different hydrothermal times (4 h, 6 h, 8 h) were set. The results showed that the electrode had the highest specific capacitance of 2260 F·g<sup>−1</sup> at 1 A·g<sup>−1</sup> at the hydrothermal reaction time of 6 h, (4 h: 1807.8 F·g<sup>−1</sup>, 8 h: 1358.3 F·g<sup>−1</sup>). In addition, it exhibited prominent rating capability and cycling stability, with 41.7 % retention at 10 A·g<sup>−1</sup> and 137.9 % retention after 5000 cycles at 50 mV⋅<em>s</em><sup>−1</sup>. Finally, the assembled hybrid supercapacitor (HSC) with rGO/Ni(OH)<sub>2</sub>/Ni<sub>3</sub>S<sub>2</sub>/NF (6 h) and active carbon displayed outstanding electrochemical performance. When the power density was 400.5 W⋅kg<sup>−1</sup>, it showed the energy density (25.2 Wh⋅kg<sup>−1</sup>), proving its potential as electrode materials for HSC devices.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113503"},"PeriodicalIF":5.3,"publicationDate":"2025-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143890480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Full-color emissive bidirectional needle-like nano-tips of the hybrid of Tb/Eu-Metal organic frameworks @ inorganic halide perovskite for multifunctional applications 用于多功能应用的 Tb/Eu-Metal 有机框架@无机卤化物过磷酸盐混合体全彩双向发射针状纳米尖端
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-19 DOI: 10.1016/j.materresbull.2025.113505
Santosh Kachhap , Akhilesh Kumar Singh , Sunil Kumar Singh
{"title":"Full-color emissive bidirectional needle-like nano-tips of the hybrid of Tb/Eu-Metal organic frameworks @ inorganic halide perovskite for multifunctional applications","authors":"Santosh Kachhap ,&nbsp;Akhilesh Kumar Singh ,&nbsp;Sunil Kumar Singh","doi":"10.1016/j.materresbull.2025.113505","DOIUrl":"10.1016/j.materresbull.2025.113505","url":null,"abstract":"<div><div>A multifunctional metal-organic framework (Tb/Eu-MOF) interfaced with an CsPbCl<sub>1.5</sub>Br<sub>1.5</sub> is developed. The self-assembled Tb/Eu-MOF has a bi-directional needle-like morphology. The successful formation of the CsPbCl<sub>1.5</sub>Br<sub>1.5</sub> inside the porous Tb/Eu-MOF is evidenced by the characteristic absorption edge and characteristic PL emission of CsPbCl<sub>1.5</sub>Br<sub>1.5</sub>. PL studies show the unilateral energy transfer from Tb<sup>3+</sup> to Eu<sup>3+</sup>. The CsPbCl<sub>1.5</sub>Br<sub>1.5</sub> does not show any optical interaction with the other two emitting centers (Eu<sup>3+</sup> and Tb<sup>3+</sup>) and emits only by its characteristic excitation. The cool white light emission is achieved by CsPbCl<sub>1.5</sub>Br<sub>1.5</sub>@ Tb/Eu-MOF in PMMA matrix-coated UV-LED chip. The CIE coordinate, CCT, CRI, Vis., and color purity are calculated. Further, the excitation wavelength-dependent emission spectrum spans from blue to yellowish-red region opens the potential of the material for anti-counterfeiting application. The letter \"W\" encrypted on four different substrates exhibit momentous color change under different excitation wavelengths and show excellent stability over time in ambient conditions.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113505"},"PeriodicalIF":5.3,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143877069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bi vacancy-induced Bi2O2S nanosheets for remarkably boosting piezocatalytic degradation of dyes and antibiotic 铋空位诱导的Bi2O2S纳米片可显著促进染料和抗生素的压催化降解
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-19 DOI: 10.1016/j.materresbull.2025.113483
Jing Wang , Jing Xie , Zhenjiang Lu, Suixin Yin, Aize Hao, Jindou Hu, Yali Cao
{"title":"Bi vacancy-induced Bi2O2S nanosheets for remarkably boosting piezocatalytic degradation of dyes and antibiotic","authors":"Jing Wang ,&nbsp;Jing Xie ,&nbsp;Zhenjiang Lu,&nbsp;Suixin Yin,&nbsp;Aize Hao,&nbsp;Jindou Hu,&nbsp;Yali Cao","doi":"10.1016/j.materresbull.2025.113483","DOIUrl":"10.1016/j.materresbull.2025.113483","url":null,"abstract":"<div><div>Defect engineering is an efficient strategy to address piezoelectric-catalyzed degradation, but metal cation defects introduced in crystals have rarely been reported, owing to the formation of cationic defects requiring higher energy than that of anionic defects. Herein, Bi vacancy-induced Bi<sub>2</sub>O<sub>2</sub>S (BOS) nanosheets were synthesized for the piezoelectric-catalyzed degradation of organic dyes and antibiotic, utilizing a low-temperature solid-state reduction method with the help of NaBH<sub>4</sub> for the first time. Astonishingly, Bi<sub>2</sub>O<sub>2</sub>S (BOS-4) with a large number of Bi vacancies exhibited an impressive 95.69 % degradation rate for rhodamine B (RhB) under ultrasound, approximately three times higher than that achieved by BOS. Additionally, BOS-4 also effectively degrades other dyes as well. This phenomenon is mainly ascribed to reduced band gap and facilitated the generation of charges by the introduced Bi vacancies, which can attract negative charges move in a definite direction and promote effective charge separation, thereby improving piezocatalytic efficiency.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113483"},"PeriodicalIF":5.3,"publicationDate":"2025-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143848206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A perspective of GaAs//Si tandem photovoltaic cell: Architecture, fabrication, and performance 砷化镓/硅串联光伏电池的结构、制造和性能研究
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-18 DOI: 10.1016/j.materresbull.2025.113504
Pranoy Abhay Makode, Sakti Prasanna Muduli, Paresh Kale
{"title":"A perspective of GaAs//Si tandem photovoltaic cell: Architecture, fabrication, and performance","authors":"Pranoy Abhay Makode,&nbsp;Sakti Prasanna Muduli,&nbsp;Paresh Kale","doi":"10.1016/j.materresbull.2025.113504","DOIUrl":"10.1016/j.materresbull.2025.113504","url":null,"abstract":"<div><div>Tandem solar cells utilize multiple semiconductor layers with complementary bandgaps to capture a broader solar spectrum, overcoming the efficiency limits of single-junction cells. The article reviews the architecture, fabrication, and performance of GaAs//Si tandem solar cells, emphasizing material developments, optical coupling, and electrical connections in tandem configurations. The fabrication section elaborates on active layer deposition, doping techniques, and interconnecting layers. Deposition techniques like chemical vapor deposition and molecular beam epitaxy are preferred for GaAs deposition to reduce the lattice mismatch between GaAs and Si. Zn and Si are the cost-effective doping elements for GaAs by metalorganic chemical vapor deposition and ion implantation. AlGaP, InGaP, and ZnO are the typical window layers, acting as front passivation for the GaAs top cell. The graded composition of III-V compounds acts as the buffer layer to connect the GaAs top cell to the Si bottom cell in two terminal monolithic configurations.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"190 ","pages":"Article 113504"},"PeriodicalIF":5.3,"publicationDate":"2025-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143864536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Amine-functionalized sulfur quantum dots (NH2-SQDs) for detection of tetracycline in food samples 胺功能化硫量子点(NH2-SQDs)检测食品样品中四环素
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-04-18 DOI: 10.1016/j.materresbull.2025.113506
Jothi Vinoth Kumar , Jong-Whan Rhim
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