Materials Research Bulletin最新文献_第10页

Advancing MXenes through green chemistry for sustainable future 通过绿色化学推进MXenes，实现可持续的未来

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-11 DOI: 10.1016/j.materresbull.2025.113720

Amarah Sultan Rana , Nadeem Raza , Muhammad Jamil Anwar , Muhammad Faizan Nazar

{"title":"Advancing MXenes through green chemistry for sustainable future","authors":"Amarah Sultan Rana , Nadeem Raza , Muhammad Jamil Anwar , Muhammad Faizan Nazar","doi":"10.1016/j.materresbull.2025.113720","DOIUrl":"10.1016/j.materresbull.2025.113720","url":null,"abstract":"<div><div>MXenes, an emerging class of two-dimensional transition metal carbides and nitrides, have attracted widespread attention owing to their unique physicochemical properties and optimistic applications in various fields from energy storage to environmental remediation. Traditionally, the production of MXenes involves approaches that typically involve energy-intensive, high-temperature solid-state reactions followed by selective etching, which indirectly rely significantly on hazardous chemicals, leading to substantial environmental and health safety concerns. To overcome these challenges, finding greener, safer, sustainable and environmentally friendly approaches to synthesize MXenes and commercialize them at a competitive price has always been of paramount importance. In particular, this review aims to highlight the integration of Green Chem. principles with MXenes and accentuating their potential to contribute to a sustainable future. By exploring green synthesis methods such as hydrothermal, solvothermal, electrochemical etching, molten salt, and microwave-assisted methods aligned with the use of green solvents, researchers can highlight how advances in MXene synthesis are consistent with the principles of Green Chem., i.e. reducing environmental impact while improving practice applications. Finally, this critical review ends with the comparative analysis of life cycle assessment for MXenes synthesis via both traditional and green approaches, highlighting the role of innovative research, development, and theoretical studies in advancing MXenes through Green Chem. for sustainable future.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113720"},"PeriodicalIF":5.7,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144830336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable silicon–carbon composite anodes from CO2-derived carbon for enhanced lithium-ion batteries 可持续的硅碳复合阳极，由二氧化碳衍生的碳制成，用于增强型锂离子电池

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-11 DOI: 10.1016/j.materresbull.2025.113707

S. Kishore Babu , Yu-Hsuan Li , Soorathep Kheawhom , Wei-Ren Liu

引用次数: 0

Effect of chemical doping and solvent on the optical properties of carbon dots from cup lump for making fluorescent ink 化学掺杂和溶剂对制备荧光油墨用杯块碳点光学性能的影响

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-10 DOI: 10.1016/j.materresbull.2025.113713

Dusadee Tumnantong , Supitsara Janseemai , Sirilux Poompradub

引用次数: 0

Ultralow lattice thermal conductivity and exceptional thermoelectric performance in the YbBi2 monolayer induced by strong four-phonon scattering 强四声子散射诱导的YbBi2单层的超低晶格热导率和优异的热电性能

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-09 DOI: 10.1016/j.materresbull.2025.113718

Meng-Yuan Yu , Chuan-Lu Yang , Xiaohu Li , Yuliang Liu , Wenkai Zhao , Feng Gao

{"title":"Ultralow lattice thermal conductivity and exceptional thermoelectric performance in the YbBi2 monolayer induced by strong four-phonon scattering","authors":"Meng-Yuan Yu , Chuan-Lu Yang , Xiaohu Li , Yuliang Liu , Wenkai Zhao , Feng Gao","doi":"10.1016/j.materresbull.2025.113718","DOIUrl":"10.1016/j.materresbull.2025.113718","url":null,"abstract":"<div><div>Achieving ultralow lattice thermal conductivity is crucial for high-performance thermoelectric materials and challengeable. Here, we investigate the YbBi<sub>2</sub> monolayer, a mechanically, dynamically, and thermodynamically stable material, and uncover an unprecedented reduction in lattice thermal conductivity <em>(κ<sub>l</sub></em>) driven by four-phonon scattering. Specifically, the <em>κ<sub>l</sub></em> values, calculated solely based on three-phonon scattering, are as low as 0.128 (0.377) Wm<sup>−1</sup>K<sup>−1</sup> in the <em>x</em> (<em>y</em>) directions at 300 K. Remarkably, four-phonon scattering further suppresses this by 95%, yielding ultralow values of 0.006 (0.022) Wm<sup>−1</sup>K<sup>−1</sup>. This extraordinary reduction originates from the interplay of the unique quadratic ZA phonon dispersion, pronounced anharmonicity, and reflection symmetry-imposed selection rules. Additionally, the YbBi<sub>2</sub> monolayer exhibits a peak power factor of 1.47 mWm<sup>−1</sup>K<sup>−2</sup> and an outstanding thermoelectric figure of merit (<em>ZT</em>) of 1.75 at 700 K under intrinsic carrier concentrations with the bipolar effect. These findings position the YbBi<sub>2</sub> monolayer as a promising candidate for thermoelectric applications, providing new insights into phonon scattering mechanisms in low-dimensional materials.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113718"},"PeriodicalIF":5.7,"publicationDate":"2025-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144810601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electromagnetic wave absorption performance of SiC/(NaAlSi3O8) and SiC/Al2O3 composites synthesized from high-alumina fly ash 高铝粉煤灰合成SiC/(NaAlSi3O8)和SiC/Al2O3复合材料的电磁波吸收性能

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-09 DOI: 10.1016/j.materresbull.2025.113717

Imrana Salisu , Xiaohui Wang , Shuhua Ma , Yanjun Ou , Helong Hui

{"title":"Electromagnetic wave absorption performance of SiC/(NaAlSi3O8) and SiC/Al2O3 composites synthesized from high-alumina fly ash","authors":"Imrana Salisu , Xiaohui Wang , Shuhua Ma , Yanjun Ou , Helong Hui","doi":"10.1016/j.materresbull.2025.113717","DOIUrl":"10.1016/j.materresbull.2025.113717","url":null,"abstract":"<div><div>In this work, SiC/(NaAlSi₃O₈) and SiC/Al₂O₃ composites were successfully synthesized from high-alumina fly ash (HAFA), an industrial byproduct of coal-fired power plants, through an environmentally friendly process involving alkaline activation and carbothermal reduction at 1250–1550°C. The SiC/(NaAlSi₃O₈) composite sintered at 1250°C for 4 hours exhibited a low density of 1.41 g/cm³ and high porosity of 62%, achieving a minimum reflection loss (RLₘᵢₙ) of −57.04 dB at 12.08 GHz and a maximum effective absorption bandwidth (EABₘₐₓ) of 4.11 GHz at 2.2 mm thickness. In comparison, the SiC/Al₂O₃ composite sintered at 1400°C for 3 hours demonstrated excellent performance at reduced thickness (1.5 mm), with an RLₘᵢₙ of −43.64 dB and an EABₘₐₓ of 4.28 GHz. The outstanding electromagnetic wave absorption performances are attributed to synergistic effects, including efficient impedance matching, strong dielectric loss, dipole and interfacial polarization, and enhanced attenuation capability of the composites.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113717"},"PeriodicalIF":5.7,"publicationDate":"2025-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144830339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation of ligand-functionalized UiO-66-X(X=H,NH2,Br)/PDINH composites for the photocatalytic degradation of tetracycline 配体功能化UiO-66-X(X=H,NH2,Br)/PDINH光催化降解四环素复合材料的制备

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-09 DOI: 10.1016/j.materresbull.2025.113715

Cheng Bu, Xinyu Yang, Fei Wang, Shihai Cui, Qinshu Zhu, Jing Yang

{"title":"Preparation of ligand-functionalized UiO-66-X(X=H,NH2,Br)/PDINH composites for the photocatalytic degradation of tetracycline","authors":"Cheng Bu, Xinyu Yang, Fei Wang, Shihai Cui, Qinshu Zhu, Jing Yang","doi":"10.1016/j.materresbull.2025.113715","DOIUrl":"10.1016/j.materresbull.2025.113715","url":null,"abstract":"<div><div>In this study, the heterojunction nanocomposites UiO-66-X(X=H,NH<sub>2</sub>,Br)/PDINH were prepared by acid-catalyzed amination and hydrothermal methods. In order to investigate the effect of ligand modification on the performance of the catalyst. Tetracycline (0.01 g/L) was chosen as the target pollutant, and the degradation effect of tetracycline by different materials at 0.3 g/L under simulated sun light was compared by the controlled variable method. All composites showed better performances compared to the monomers. Among them, UiO-66-Br/PDINH showed the highest photodegradation efficiency (97.8 %), which was superior to the UiO-66/PDINH and UiO-66-NH<sub>2</sub>/PDINH. This good photocatalytic activity is mainly attributed to two aspects: (1) The construction of Z-scheme heterojunction was conducive to promoting the separation of photogenerated carriers; (2) The target contaminant TC molecules and UiO-66-Br had strong intermolecular forces and were more tightly bound. Based on the energy band theory, the formation mechanism of Z-scheme heterojunction and photocatalytic degradation mechanism of TC were elucidated.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113715"},"PeriodicalIF":5.7,"publicationDate":"2025-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144830338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dynamic control of electromagnetically induced transparency based on symmetric and asymmetric phase-change metasurfaces 基于对称和非对称相变超表面的电致透明动态控制

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-08 DOI: 10.1016/j.materresbull.2025.113709

Yu-Jie Zhang , Zhe-Yu Liu , Dong-Qin Zhang , Zhong-Wei Jin , Bin Fang , Gui-Ming Pan , Yi-Jie Jin , Zhi Hong , Fang-Zhou Shu

{"title":"Dynamic control of electromagnetically induced transparency based on symmetric and asymmetric phase-change metasurfaces","authors":"Yu-Jie Zhang , Zhe-Yu Liu , Dong-Qin Zhang , Zhong-Wei Jin , Bin Fang , Gui-Ming Pan , Yi-Jie Jin , Zhi Hong , Fang-Zhou Shu","doi":"10.1016/j.materresbull.2025.113709","DOIUrl":"10.1016/j.materresbull.2025.113709","url":null,"abstract":"<div><div>Dynamic control of electromagnetically induced transparency (EIT) is realized in symmetric and asymmetric phase-change metasurfaces composed of periodic Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> (GST) nanoring array. The symmetric GST nanoring array supports the excitation of tunable magnetic dipole and toroidal dipole resonances. Significantly, the manipulation of either the outer or inner diameter of the GST nanoring enables the magnetic dipole resonance to interact with the toroidal dipole resonance, leading to the formation of EIT, which can be tuned by altering the phase of GST. Additionally, two high-Q quasibound states in the continuum (quasi-BICs) can be induced in the asymmetric GST nanoring array. Furthermore, a high-Q EIT resonance can be achieved through the interaction of a magnetic dipole resonance with a quasi-BIC resonance, or alternatively, through the interaction of a toroidal dipole resonance with another quasi-BIC resonance. The symmetric and asymmetric GST nanoring arrays hold promise for usage in slow-light systems, modulators and reconfigurable filters.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113709"},"PeriodicalIF":5.7,"publicationDate":"2025-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144830337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and photocatalytic performance of BiOI/ZnO composites for tetracycline degradation and antibacterial applications under visible light irradiation BiOI/ZnO复合材料的合成及其在四环素降解和抗菌中的光催化性能

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-08 DOI: 10.1016/j.materresbull.2025.113714

Jingwen Liu, Zirui Ding, Dengzheng Gao, Lihua Liu

{"title":"Synthesis and photocatalytic performance of BiOI/ZnO composites for tetracycline degradation and antibacterial applications under visible light irradiation","authors":"Jingwen Liu, Zirui Ding, Dengzheng Gao, Lihua Liu","doi":"10.1016/j.materresbull.2025.113714","DOIUrl":"10.1016/j.materresbull.2025.113714","url":null,"abstract":"<div><div>We employed the hydrothermal process to fabricate BiOI/ZnO, and <strong>its</strong> photocatalytic capacity to break down tetracycline (TC) in the presence of visible light was subsequently evaluated. To characterize the generated photocatalyst, analytical techniques such as SEM, EDS, TEM, XRD, XPS, and UV–vis were employed. When exposed to visible light, the photocatalyst showed superior TC removal capabilities <strong>compared to</strong> individual ZnO and BiOI. Recycling experiments indicated that the catalyst exhibited excellent cycling stability and reusability. Under visible light illumination, BiOI/ZnO composites exhibited nearly 100 % antibacterial removal <strong>efficiency</strong> against both <em>Escherichia coli</em> and <em>S. aureus</em>. <strong>Active species</strong> trapping studies were used to examine the role of the active species in the photodegradation process, which revealed that •O<sub>2</sub><sup>—</sup> assumed a pivotal function within this process. Finally, the electron transfer mechanism within ZnO/BiOI and the photocatalytic degradation and antimicrobial mechanisms was elucidated in comprehensive detail.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"194 ","pages":"Article 113714"},"PeriodicalIF":5.7,"publicationDate":"2025-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144867011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study on the performance and mechanism of NH2-MIL-101(Fe)/CQDs@UCN composite photocatalyst with self-Fenton effect 具有自fenton效应的NH2-MIL-101(Fe)/CQDs@UCN复合光催化剂的性能及机理研究

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-08 DOI: 10.1016/j.materresbull.2025.113716

Yan Huang , Zongxue Yu , Yuwen Huang , Wei Yan , Bo Xing , Fengyan Fan , Dingmei Han , Xia Liu , Chun Xu , Chao Tang , Zhedan Yang

{"title":"Study on the performance and mechanism of NH2-MIL-101(Fe)/CQDs@UCN composite photocatalyst with self-Fenton effect","authors":"Yan Huang , Zongxue Yu , Yuwen Huang , Wei Yan , Bo Xing , Fengyan Fan , Dingmei Han , Xia Liu , Chun Xu , Chao Tang , Zhedan Yang","doi":"10.1016/j.materresbull.2025.113716","DOIUrl":"10.1016/j.materresbull.2025.113716","url":null,"abstract":"<div><div>Monodisperse NH₂-MIL-101(Fe) and two-dimensional sheet-like UCN materials were synthesized using a one-pot solvothermal method and an acid treatment-ethanol intercalation-thermal exfoliation method, respectively. The heterojunction composite photocatalyst NM101/CQDs@UCN was then synthesized through electrostatic self-assembly. <strong>The heterojunction composite photocatalyst NM101/CQDs@UCN was then prepared via electrostatic self-assembly.</strong> Photocatalytic experiments and material characterization confirmed that the modified UCN and CQDs@UCN, after transitioning from the original bulk structure to a two-dimensional sheet-like structure, exhibited significantly increased BET surface area, enriched pore structure, and enhanced H₂O₂ production during photocatalytic processes. Notably, the catalyst also demonstrated excellent degradation performance for fracturing flowback fluid, achieving a COD removal rate of 72.7% under 180 minutes of visible light irradiation. <strong>Finally, capture experiments and ESR analysis revealed that the modified UCN selectively generated H₂O₂, which triggered the self-Fenton effect. This, in turn, coupled with NH₂-MIL-101(Fe) to form a surface heterojunction, promoting the directional migration and separation of photo-generated charge carriers, thus enhancing the photocatalytic degradation performance of the composite photocatalyst.</strong></div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"194 ","pages":"Article 113716"},"PeriodicalIF":5.7,"publicationDate":"2025-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144852729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Role of lipoic acid and gold nanomaterials and nanoclusters for biomedical and environmental applications 硫辛酸和金纳米材料和纳米团簇在生物医学和环境应用中的作用

IF 5.7 3区材料科学

Materials Research Bulletin Pub Date : 2025-08-07 DOI: 10.1016/j.materresbull.2025.113712

Ankita Doi , Mamta Sahu , Priyanka Sharma , Mainak Ganguly

引用次数: 0