{"title":"化学掺杂和溶剂对制备荧光油墨用杯块碳点光学性能的影响","authors":"Dusadee Tumnantong , Supitsara Janseemai , Sirilux Poompradub","doi":"10.1016/j.materresbull.2025.113713","DOIUrl":null,"url":null,"abstract":"<div><div>Carbon dots (CDs) were prepared from cup lump (natural rubber) as a carbon resource using hydrothermal treatment at 200 °C for 18 h. In order to improve the optical properties of CDs, ammonium persulfate was used for chemical doping. Two kinds of solvent were evaluated (deionized water and formamide) for CD synthesis to enhance the solubility of cup lump. The particle size of CDs obtained using formamide (FCDs) was larger than that obtained using deionized water (ACDs). Formamide could facilitate electron transfer during the reaction, resulting in an enhanced hydrothermal treatment and improved optical properties to achieve the quantum yield. Finally, the FCDs could be applied as a fluorescent ink with a high stability fluorescence.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113713"},"PeriodicalIF":5.7000,"publicationDate":"2025-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of chemical doping and solvent on the optical properties of carbon dots from cup lump for making fluorescent ink\",\"authors\":\"Dusadee Tumnantong , Supitsara Janseemai , Sirilux Poompradub\",\"doi\":\"10.1016/j.materresbull.2025.113713\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Carbon dots (CDs) were prepared from cup lump (natural rubber) as a carbon resource using hydrothermal treatment at 200 °C for 18 h. In order to improve the optical properties of CDs, ammonium persulfate was used for chemical doping. Two kinds of solvent were evaluated (deionized water and formamide) for CD synthesis to enhance the solubility of cup lump. The particle size of CDs obtained using formamide (FCDs) was larger than that obtained using deionized water (ACDs). Formamide could facilitate electron transfer during the reaction, resulting in an enhanced hydrothermal treatment and improved optical properties to achieve the quantum yield. Finally, the FCDs could be applied as a fluorescent ink with a high stability fluorescence.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"193 \",\"pages\":\"Article 113713\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2025-08-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540825004209\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825004209","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of chemical doping and solvent on the optical properties of carbon dots from cup lump for making fluorescent ink
Carbon dots (CDs) were prepared from cup lump (natural rubber) as a carbon resource using hydrothermal treatment at 200 °C for 18 h. In order to improve the optical properties of CDs, ammonium persulfate was used for chemical doping. Two kinds of solvent were evaluated (deionized water and formamide) for CD synthesis to enhance the solubility of cup lump. The particle size of CDs obtained using formamide (FCDs) was larger than that obtained using deionized water (ACDs). Formamide could facilitate electron transfer during the reaction, resulting in an enhanced hydrothermal treatment and improved optical properties to achieve the quantum yield. Finally, the FCDs could be applied as a fluorescent ink with a high stability fluorescence.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.