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Tunable Blue-to-Orange-Red Emission in LaPO4: Sb3+/Mn2+ Phosphors: Multiple emission centers for LED applications LaPO4: Sb3+/Mn2+荧光粉中可调谐的蓝-橙红发射:LED应用的多个发射中心
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-07-03 DOI: 10.1016/j.materresbull.2025.113618
Oussama AitMellal , Mohamed Youssef Messous , Sara Ait Bouzid , Khalid Nouneh , Mihail Secu , Arpad Mihai Rostas
{"title":"Tunable Blue-to-Orange-Red Emission in LaPO4: Sb3+/Mn2+ Phosphors: Multiple emission centers for LED applications","authors":"Oussama AitMellal ,&nbsp;Mohamed Youssef Messous ,&nbsp;Sara Ait Bouzid ,&nbsp;Khalid Nouneh ,&nbsp;Mihail Secu ,&nbsp;Arpad Mihai Rostas","doi":"10.1016/j.materresbull.2025.113618","DOIUrl":"10.1016/j.materresbull.2025.113618","url":null,"abstract":"<div><div>This study explores synthesizing and characterizing LaPO<sub>4</sub>:Sb<sup>3+</sup>/ <figure><img></figure> (LSBMx) phosphors (x = 0%–5%) prepared via the co-precipitation method. Structural analysis and luminescence properties reveal that LSBM0 (without Mn<sup>2+</sup>) emits blue light under UV excitation, while Mn<sup>2+</sup>-doped samples exhibit tunable emission from blue to orange-red. Under UV excitation, LSBMx phosphors demonstrate a broad visible emission band with multiple peaks attributed to the <figure><img></figure> transition of Mn<sup>2+</sup>. The broad emission band (520–660 nm) can be deconvoluted into four Gaussian components centered at 564 nm (Mn-I), 595 nm and 616 nm (Mn-II), and 648 nm (Mn-III), corresponding to Mn<sup>2+</sup> in La<sup>3+</sup> sites due to charge inconsistency, crystal field modifications induced by Sb<sup>3+</sup> incorporation, and Mn<sup>2+</sup> - Mn<sup>2+</sup> dimers, respectively. Energy transfer efficiency calculations determine the optimal Mn<sup>2+</sup> concentration to be approximately 3%. This novel phosphor system demonstrates versatile green, orange, and red emission capabilities, establishing a valuable framework for developing Mn<sup>2+</sup>-doped luminescent materials with potential applications in LED lighting technology.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113618"},"PeriodicalIF":5.3,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of high-performance Ag2Se thermoelectric films and devices for wearable energy harvesting 可穿戴能量收集用高性能Ag2Se热电薄膜及器件的制备
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-07-02 DOI: 10.1016/j.materresbull.2025.113650
Wenjing Liu , Yao Lu , Jianmin Yang , Dasha Mao , Yi Huang , Fei Wang
{"title":"Preparation of high-performance Ag2Se thermoelectric films and devices for wearable energy harvesting","authors":"Wenjing Liu ,&nbsp;Yao Lu ,&nbsp;Jianmin Yang ,&nbsp;Dasha Mao ,&nbsp;Yi Huang ,&nbsp;Fei Wang","doi":"10.1016/j.materresbull.2025.113650","DOIUrl":"10.1016/j.materresbull.2025.113650","url":null,"abstract":"<div><div>Owing to the high thermoelectric (TE) performance near room temperature, Ag<sub>2</sub>Se has been recognized as a potential alternative to Bi<sub>2</sub>Te<sub>3</sub> for self-powered wearable electronics. Herein, we report a novel template-assisted approach using Ag NWs to synthesize Ag<sub>2</sub>Se nanowires (NWs), yielding more uniform morphology compared to Se NW-templated methods. This approach enables the fabrication of dense, thickness-controlled films with exceptional TE performance, reaching a power factor of 2011 μW/mK<sup>2</sup> at 390 K. Moreover, the film demonstrates excellent flexibility and stability. Specifically, the electrical conductivity remains 92 % after 2000 bending cycles, and 95 % after 360 days without encapsulation. This outstanding flexibility stems from the synergy between the nylon substrate and the Ag<sub>2</sub>Se porous nanostructured film. A flexible TE device assembled by the films achieves a high power density of 7.3 W/m<sup>2</sup> at a temperature difference of 32 K. We also explore potential applications of our flexible TE devices in solar-TE conversion.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113650"},"PeriodicalIF":5.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Manganese (III) oxide-infused poly(thiophene-co-pyrrole) nanocomposites for optical, dielectric, and photocatalytic applications 锰(III)氧化物注入聚(噻吩-共吡咯)纳米复合材料的光学,电介质和光催化应用
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-07-02 DOI: 10.1016/j.materresbull.2025.113649
S. Sankar, M.T. Ramesan
{"title":"Manganese (III) oxide-infused poly(thiophene-co-pyrrole) nanocomposites for optical, dielectric, and photocatalytic applications","authors":"S. Sankar,&nbsp;M.T. Ramesan","doi":"10.1016/j.materresbull.2025.113649","DOIUrl":"10.1016/j.materresbull.2025.113649","url":null,"abstract":"<div><div>Copolymer nanocomposites consisting of poly(thiophene-<em>co</em>-pyrrole) (PTh-<em>co</em>-PPy) and manganese (III) oxide (Mn<sub>2</sub>O<sub>3</sub>) nanofillers were synthesized via in-situ polymerization. FTIR confirmed the interfacial interactions between Mn<sub>2</sub>O<sub>3</sub> and the copolymer. UV–vis spectra revealed that the 5 wt % Mn<sub>2</sub>O<sub>3</sub> nanocomposites exhibited the highest absorption and refractive index, along with the lowest optical bandgap, indicating effective integration. PL spectra showed fluorescence quenching and red shift, indicating strong interfacial interactions and optoelectronic potential. XRD confirmed crystalline growth of Mn<sub>2</sub>O<sub>3</sub> in the copolymer, while FE-SEM and HR-TEM showed uniform dispersion of raspberry-like nanoparticles. DSC and TGA demonstrated an increased glass transition temperature and enhanced thermal stability. Electrical measurements revealed enhanced dielectric constant, electric modulus, and conductivity up to 5 wt % Mn<sub>2</sub>O<sub>3</sub>, followed by a decline at higher nanofiller concentrations. Photocatalytic activity with methylene blue confirmed maximum degradation efficiency for the 5 wt % nanocomposite. These findings highlight the promise of Mn<sub>2</sub>O<sub>3</sub>-reinforced PTh-<em>co</em>-PPy nanocomposites in optoelectronic and environmental applications.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113649"},"PeriodicalIF":5.3,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144563153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optical nonlinearity and laser protection potential of transition and rare earth doped YCrO4 nanoparticles 跃迁和稀土掺杂YCrO4纳米粒子的光学非线性和激光保护电位
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-07-01 DOI: 10.1016/j.materresbull.2025.113620
Y.S. Vidya , H.C. Manjunatha , R. Munirathnam , Vishwalinga Prasad B. , Nasir Ahamed N. , K.N. Sridhar , T.C. Sabari Girisun , T. Sharmila
{"title":"Optical nonlinearity and laser protection potential of transition and rare earth doped YCrO4 nanoparticles","authors":"Y.S. Vidya ,&nbsp;H.C. Manjunatha ,&nbsp;R. Munirathnam ,&nbsp;Vishwalinga Prasad B. ,&nbsp;Nasir Ahamed N. ,&nbsp;K.N. Sridhar ,&nbsp;T.C. Sabari Girisun ,&nbsp;T. Sharmila","doi":"10.1016/j.materresbull.2025.113620","DOIUrl":"10.1016/j.materresbull.2025.113620","url":null,"abstract":"<div><div>This study investigates the nonlinear optical (NLO) properties of YCrO<sub>4</sub> (YC), YCrO<sub>4</sub>:Zn (9 mol%) (YCZ), YCrO<sub>4</sub>:Ni (9 mol%) (YCN), YCrO<sub>4</sub>:Eu (9 mol%) (YCE), and YCrO<sub>4</sub>:Tb (9 mol%) (YCT) NPs. These NPs are synthesized by Aloe vera gel extract mediated solution combustion method. The X-ray diffraction patterns of YCrO<sub>4</sub> confirm the formation of tetragonal phase with the space group I 14<sub>1</sub>/amd. No other impurity related peaks were observed even after doping with transition/rare earth metal ions except the variation in intensity. Lattice distortion in the host lattice due to the addition of dopants leads to slight shifting of Bragg peaks towards lower angle side. The direct optical band gap of YC, YCZ, YCN, YCE and YCT were tuned to 3.08, 3.05, 2.96, 2.86 and 2.75 eV respectively. The nonlinear absorption coefficient and optical limiting behavior were analyzed using the Z-scan technique under high-intensity laser irradiation. The results reveal significant variations in the nonlinear absorption coefficient among the samples, indicating the influence of dopants on the material’s NLO performance. Among them, YCN exhibited the highest nonlinear absorption coefficient (14 m/W), demonstrating its strong reverse saturable absorption (RSA) characteristics. The optical limiting thresholds were also evaluated, showing that YCN had the lowest threshold (2.02 W/m<sup>2</sup>), making it a promising candidate for laser protection applications. These findings suggest that doping YCrO<sub>4</sub> with specific elements such as Ni<span><math><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></math></span> enhances its nonlinear optical response, making it suitable for advanced photonic and optoelectronic applications.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113620"},"PeriodicalIF":5.3,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144534622","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced photocatalytic oxidation through optimized CuFe2O4 distribution in MIL-125(Ti) heterostructures 通过优化MIL-125(Ti)异质结构中CuFe2O4的分布增强光催化氧化
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-06-30 DOI: 10.1016/j.materresbull.2025.113644
Junxian Hu , Yunxin Dai , Xiangxing Zhang , Zi Wan , Jiajun Ma , Yunxia Zhao
{"title":"Enhanced photocatalytic oxidation through optimized CuFe2O4 distribution in MIL-125(Ti) heterostructures","authors":"Junxian Hu ,&nbsp;Yunxin Dai ,&nbsp;Xiangxing Zhang ,&nbsp;Zi Wan ,&nbsp;Jiajun Ma ,&nbsp;Yunxia Zhao","doi":"10.1016/j.materresbull.2025.113644","DOIUrl":"10.1016/j.materresbull.2025.113644","url":null,"abstract":"<div><div>A novel ternary p-n heterojunction CuFe<sub>2</sub>O<sub>4</sub>/CNT/MIL-125(Ti) composite (CCM) was fabricated to enhance photocatalytic oxidation and enable magnetic recyclability for organic pollutants degradation. Pre-integration of CuFe<sub>2</sub>O<sub>4</sub>/CNT before MIL-125(Ti) assembly prevented magnetic nanoparticle aggregation and established electron transport bridges. Optimized CCMs (CCM-5, CCM-10, and CCM-20) exhibited bandgaps narrowed to 3.65, 3.58, and 3.47 eV, respectively, with increased photocurrent and reduced impedance, enhancing visible-light absorption and suppressing charge recombination. CCM-10 with proper CuFe<sub>2</sub>O<sub>4</sub>/CNT proportion achieved over 98.0 % Rhodamine (RhB) and 95.9 % Tetracycline Hydrochloride (TCH) removal within 60 min, with the reaction rate constant 86.7 % and 206.8 % higher than MIL-125(Ti), respectively. The composite can be easily separated magnetically and reused, showing only a 12.3 % decline in activity after five cycles of RhB degradation. The photocatalytic degradation mechanism was also explored, with superoxide anion radicals identified as the main contributors. This work highlights a rational interface-engineering approach to constructing a magnetically recoverable MIL-125(Ti)-based photocatalyst.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113644"},"PeriodicalIF":5.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Plasmonic Au-nanoparticles functionalized ultra-flexible Ga₂O₃ photodetector for enhanced broadband detection from UV-C to NIR on a paper substrate 等离子体au纳米粒子功能化的超柔性Ga₂O₃光电探测器,用于增强从UV-C到近红外在纸基上的宽带检测
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-06-30 DOI: 10.1016/j.materresbull.2025.113645
Urvashi Varshney , Anuj Sharma , Preetam Singh , Govind Gupta
{"title":"Plasmonic Au-nanoparticles functionalized ultra-flexible Ga₂O₃ photodetector for enhanced broadband detection from UV-C to NIR on a paper substrate","authors":"Urvashi Varshney ,&nbsp;Anuj Sharma ,&nbsp;Preetam Singh ,&nbsp;Govind Gupta","doi":"10.1016/j.materresbull.2025.113645","DOIUrl":"10.1016/j.materresbull.2025.113645","url":null,"abstract":"<div><div>With the rising demands of wearable electronics, Internet of Things (IoT) sensors, environmental monitoring, and biomedical diagnostics, there is an increased demand for ultra-flexible, self-powered broadband photodetectors with high sensitivity and fast response. Conventional photodetectors generally suffer from insufficient spectral response and low responsivity, which limits their efficiency in practical applications. To overcome these limitations, we have developed ultra-flexible Ga₂O₃-based photodetectors with plasmonic Au-nanoparticles (Au-NPs) on a paper substrate. Incorporating Au-NPs enhances light absorption through localized surface plasmon resonance, extending the detection range from UV-C to NIR. The pristine device exhibits a responsivity of 20.96 mA/W at 266 nm, while the Au-NP-functionalized device achieves 38.86 mA/W, demonstrating a ∼185 % enhancement due to efficient hot carrier generation and improved charge transfer. The device also shows maximum detectivity values of 1.92×10<sup>10</sup> Jones at 266 nm, 3.69×10<sup>9</sup> Jones at 532 nm, and 1.74×10<sup>9</sup> Jones at 1064 nm, respectively. Furthermore, the device reaches maximum responsivities of 7357 mA/W (266 nm), 163 mA/W (532 nm), and 6.31 mA/W (1064 nm) under a 5 V applied bias. This technique provides a pathway for developing nanoplasmonic-enhanced, flexible, self-powered photodetectors that provide high performance toward next-generation wearable optoelectronic devices.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113645"},"PeriodicalIF":5.3,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Near-infrared luminescence in titanate-germanate glasses co-doped with Cr3+/Ln3+ (Ln=Tm or Ho) 共掺杂Cr3+/Ln3+ (Ln=Tm或Ho)钛酸锗酸盐玻璃的近红外发光
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-06-29 DOI: 10.1016/j.materresbull.2025.113643
Wojciech A. Pisarski , Marta Kuwik , Joanna Pisarska , Dominik Dorosz , Diego Pugliese , Jan Dorosz , Piotr Miluski , Jacek Żmojda , Marcin Kochanowicz
{"title":"Near-infrared luminescence in titanate-germanate glasses co-doped with Cr3+/Ln3+ (Ln=Tm or Ho)","authors":"Wojciech A. Pisarski ,&nbsp;Marta Kuwik ,&nbsp;Joanna Pisarska ,&nbsp;Dominik Dorosz ,&nbsp;Diego Pugliese ,&nbsp;Jan Dorosz ,&nbsp;Piotr Miluski ,&nbsp;Jacek Żmojda ,&nbsp;Marcin Kochanowicz","doi":"10.1016/j.materresbull.2025.113643","DOIUrl":"10.1016/j.materresbull.2025.113643","url":null,"abstract":"<div><div>Near-infrared luminescence in titanate-germanate glasses co-doped with Cr<sup>3+</sup>/Ln<sup>3+</sup> (where Ln = Tm or Ho) have been investigated under different excitation wavelengths. Near-infrared emission spectra and their decays were analyzed for glass samples varying with TiO<sub>2</sub> content. Several emission bands in the 950–1570 nm and 1570–2200 nm spectral ranges are observed for glass samples excited directly at 600 nm (Cr<sup>3+</sup>), which correspond to characteristic transitions of Cr<sup>3+</sup> and Ln<sup>3+</sup> (Ln = Tm, Ho) ions. It suggests that the energy transfer processes Cr<sup>3+</sup> → Tm<sup>3+</sup> and Cr<sup>3+</sup> → Ho<sup>3+</sup> occur. It was also confirmed by the excitation spectra measurements. The experimental results indicate that titanate-germanate glasses co-doped with Cr<sup>3+</sup>/Ln<sup>3+</sup> (Ln = Tm or Ho) are promising for near-infrared luminescence applications.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113643"},"PeriodicalIF":5.3,"publicationDate":"2025-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultra-wideband and angular-stable Terahertz reflective cross-polarization converter integrated with highly sensitive biosensing 集成高灵敏度生物传感的超宽带角稳定太赫兹反射交叉极化变换器
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-06-27 DOI: 10.1016/j.materresbull.2025.113641
Bo Lv , Taha Sheheryar , Jacob Wekalao , Lei Gao
{"title":"Ultra-wideband and angular-stable Terahertz reflective cross-polarization converter integrated with highly sensitive biosensing","authors":"Bo Lv ,&nbsp;Taha Sheheryar ,&nbsp;Jacob Wekalao ,&nbsp;Lei Gao","doi":"10.1016/j.materresbull.2025.113641","DOIUrl":"10.1016/j.materresbull.2025.113641","url":null,"abstract":"<div><div>This paper presents a reflective metasurface device that simultaneously achieves ultra-wideband polarization conversion and high-sensitivity biosensing, overcoming major limitations in existing terahertz platforms. Unlike conventional approaches that rely on noble metals or provide narrow operational bandwidths, the presented design utilizes low-cost aluminum and polyimide while maintaining exceptional performance. It exhibits a polarization conversion ratio exceeding 90 % over a 3.044 THz bandwidth with peak efficiencies up to 99.9 % and strong angular stability up to 40° For biosensing, the design attains a sensitivity of up to 0.95 THz/RIU, allowing reliable detection of minute refractive index changes associated with several cancer types. The integration of wideband polarization conversion and biosensing in a cost-effective format provides strong potential for next-generation biomedical diagnostics and terahertz sensing.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113641"},"PeriodicalIF":5.3,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient and broadband near-infrared emitting Ca2YHf2Ga3O12: Cr3+ phosphor for anti-counterfeiting applications 高效,宽带近红外发射Ca2YHf2Ga3O12: Cr3+荧光粉防伪应用
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-06-26 DOI: 10.1016/j.materresbull.2025.113631
Linlin Wang , Yan-gai Liu , Juyu Yang , Ziyao Wang , Tonglu Sun , Lefu Mei , Hao Ding , Peishu Yang
{"title":"Efficient and broadband near-infrared emitting Ca2YHf2Ga3O12: Cr3+ phosphor for anti-counterfeiting applications","authors":"Linlin Wang ,&nbsp;Yan-gai Liu ,&nbsp;Juyu Yang ,&nbsp;Ziyao Wang ,&nbsp;Tonglu Sun ,&nbsp;Lefu Mei ,&nbsp;Hao Ding ,&nbsp;Peishu Yang","doi":"10.1016/j.materresbull.2025.113631","DOIUrl":"10.1016/j.materresbull.2025.113631","url":null,"abstract":"<div><div>Near-infrared (NIR) phosphor-converted light-emitting diodes (pc-LEDs) as efficient and compact light sources widely used in fields such as medicine, food safety, night vision, and more. However, most NIR phosphors manifest drawbacks, including relatively narrow FHWM, low photoluminescence quantum efficiency, and poor thermal and chemical stability, which limit their effectiveness in broadband applications. Therefore, a key challenge lies in designing an NIR phosphor combining a broad emission bandwidth with high quantum efficiency and excellent Thermal stability. A broadband NIR phosphor Ca<sub>2</sub>YHf<sub>2</sub>Ga<sub>3</sub>O<sub>12</sub>: Cr<sup>3+</sup> (CYHG: Cr<sup>3+</sup>) was explored. The peak emission of the material occurs at 794 nm, with an FWHM of 189 nm covering 700–1100 nm. The best-performing phosphor presents the internal and external quantum efficiencies (IQE/EQE) of 82 % and 22 %, respectively. At 423 K, its luminescence remains at roughly 60 % of its room-temperature intensity. Utilizing its superior optical properties, a prototype NIR pc-LED incorporating CYHG: Cr<sup>3+</sup> was developed to assess its practical feasibility. The resulting device, functioning as a compact and broadband NIR source, delivered 62 mW output at 380 mA, making it suitable for applications such as night vision, non-destructive testing, and anti-counterfeiting.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"193 ","pages":"Article 113631"},"PeriodicalIF":5.3,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in scalable 2D material synthesis: Flash Joule heating and beyond 可扩展二维材料合成的进展:闪光焦耳加热及其他
IF 5.3 3区 材料科学
Materials Research Bulletin Pub Date : 2025-06-26 DOI: 10.1016/j.materresbull.2025.113639
Muhammad Faizan, Mohammad Nahid Siddiqui
{"title":"Advances in scalable 2D material synthesis: Flash Joule heating and beyond","authors":"Muhammad Faizan,&nbsp;Mohammad Nahid Siddiqui","doi":"10.1016/j.materresbull.2025.113639","DOIUrl":"10.1016/j.materresbull.2025.113639","url":null,"abstract":"<div><div>Flash Joule Heating (FJH) utilizes a variety of carbonaceous waste, such as garbage, biomass, plastic, and coal, to produce high-quality 2D materials, such as turbostratic flash graphene, in a scalable, low-energy, and green route. Unlike conventional strategies, FJH produces instantaneous heating (up to 3000 K) in milliseconds, enabling carbon conversion directly without the need for catalysts, solvents, or any additional energy. The obtained graphene exhibits excellent structural, thermal, and electrochemical performance, with high purity defined as ≥95 at.% carbon, as determined by X-ray Photoelectron Spectroscopy, and with minimal heteroatom impurities (e.g., oxygen, nitrogen, sulfur). The approach also allows morphological adjustment as well as control over porosity, and therefore it can find application in energy storage, composites, electrocatalysis, and environmental clean-up. Life cycle and techno-economic evaluation confirms drastic greenhouse gas emission, water usage, and production cost savings in comparison with the traditional synthesis technique. Its coupling with machine learning has further encouraged process optimization and material quality, precisely predicting yield and crystallinity. FJH's capability to convert low-value waste into high-value nanomaterials means that it can become a central point in promoting sustainable nonmanufacturing and the circular economy. FJH-based manufacturing of graphene has been covered within this review which also discusses the trend toward industrialization and commercialization of green technology.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"192 ","pages":"Article 113639"},"PeriodicalIF":5.3,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144549895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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