Journal of the Indian Chemical Society最新文献

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Synthesis of p-trifluoromethylphenoxy substituted polyphosphazene / surface functionalized silica nanocomposites and characterization of their thermal, flame retardant & water uptake properties 对三氟甲基苯氧基取代聚磷腈/表面功能化二氧化硅纳米复合材料的合成及其热、阻燃和吸水性能的表征
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-03-01 Epub Date: 2026-02-10 DOI: 10.1016/j.jics.2026.102476
Nand Kumar , Nagmani Manikpuri , Om Prakash Gautam
{"title":"Synthesis of p-trifluoromethylphenoxy substituted polyphosphazene / surface functionalized silica nanocomposites and characterization of their thermal, flame retardant & water uptake properties","authors":"Nand Kumar ,&nbsp;Nagmani Manikpuri ,&nbsp;Om Prakash Gautam","doi":"10.1016/j.jics.2026.102476","DOIUrl":"10.1016/j.jics.2026.102476","url":null,"abstract":"<div><div>Poly[(aryloxy)phosphazene]s are attractive polymers for high-performance applications due to their thermal stability, flame retardancy, and chemical resistance. However, their intrinsic hydrophobicity and limited reinforcement restrict broader use in coatings and electronic materials. In this study, poly(bis(4-trifluoromethylphenoxy)phosphazene) (PBTP) was synthesized via nucleophilic substitution of polydichlorophosphazene (PDCP), obtained by thermal ring-opening polymerization of hexachlorophosphazene. To enhance performance, mesoporous SiO<sub>2</sub> nanoparticles were surface-functionalized with N-phenyl-3-aminopropyltrimethoxysilane (NP-3-APTMS) to introduce hydrophobic phenyl groups and improve compatibility with the PBTP matrix. A series of novel PBTP/silica nanocomposites with silica loadings of 1–10 phr were prepared using a solution-casting method. Structural characterization by NMR (<sup>1</sup>H, <sup>13</sup>C, <sup>31</sup>P) and FTIR confirmed successful polymer synthesis and substitution. BET analysis demonstrated successful surface functionalization of SiO<sub>2</sub> nanoparticles, evidenced by a significant reduction in surface area and pore volume after modification. SEM showed uniform nanoparticle dispersion at low loadings, while higher loadings led to agglomeration. Thermal analysis indicated improved stability, with T<sub>5%</sub> increasing from 351.1 °C (neat PBTP) to 386.3 °C (PBTP–δ). Heat resistance index and char yield also increased with silica content. Flame-retardant testing confirmed UL-94 V-0 ratings and rising limiting oxygen index values up to 46.6%. Char analysis revealed dense phosphorus- and silica-rich layers, promoting synergistic gas- and condensed-phase flame retardancy. Water uptake and contact angle measurements indicated reduced moisture absorption and enhanced hydrophobicity, with contact angles increasing from 121.1° to 135.4°. These results demonstrate that surface-functionalized silica nanoparticles effectively reinforce PBTP, enhancing thermal stability, flame retardancy, and hydrophobicity. The nanocomposites are promising candidates for high-performance flame-resistant coatings and advanced electronic insulation materials.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 3","pages":"Article 102476"},"PeriodicalIF":3.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design of gold nanoparticle based colorimetric sensor for detection of biogenic amines in micelles with improved sensitivity 基于金纳米粒子的胶束生物胺比色传感器的设计
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-03-01 Epub Date: 2026-02-08 DOI: 10.1016/j.jics.2026.102477
Saima Ameen Ghoto , Muhammad Yar Khuhawar , Taj Muhammad Jahangir Khuhawar , Muhammad Farooque Lanjwani
{"title":"Design of gold nanoparticle based colorimetric sensor for detection of biogenic amines in micelles with improved sensitivity","authors":"Saima Ameen Ghoto ,&nbsp;Muhammad Yar Khuhawar ,&nbsp;Taj Muhammad Jahangir Khuhawar ,&nbsp;Muhammad Farooque Lanjwani","doi":"10.1016/j.jics.2026.102477","DOIUrl":"10.1016/j.jics.2026.102477","url":null,"abstract":"<div><div>A rapid, highly sensitive colorimetric nanosensor based on citrate-capped gold nanoparticles (Cit-AuNPs) is presented for screening total biogenic amines (TBAs) as a practical indicator of food quality and safety. Individual BAs like putrescine (PUT), histamine (HTM), spermine (SPM), and spermidine (SPD) were first investigated in aqueous and micellar media to elucidate the sensing mechanism, evaluate sensitivity, optimization of parameters and confirm uniform optical responses. Electrostatic and hydrogen-bonding interactions between the amines and Cit-AuNPs induce nanoparticle aggregation, triggering a distinct color change from burgundy red to dark grey accompanied by a surface plasmon resonance shift from 520 to 700 nm. The nanosensor was comprehensively characterized by UV–Vis spectroscopy, FTIR, SEM-EDX, dynamic light scattering, and zeta potential, validating surface chemistry, size, morphology, and colloidal stability. Detection limits of 0.842–2.018 μg/mL in aqueous medium were enhanced nearly tenfold (0.008–0.067 μg/mL) in a micellar environment. The method was applied to <em>Labeo rohita</em> fish muscle, TBAs (as HTM equivalents) ranging from 141.99 to 654.33 mg/kg, with excellent precision (RSD &lt;0.1%) were calculated. Further the method's practical applicability was confirmed using HTM spiked samples, which demonstrated high accuracy and precision with recoveries of 96.26–101.65%, low standard deviations (0.002–0.006 mg/kg), and %RSD below 0.4%, highlighting the sensor as a fast, reliable, and cost-effective tool for food freshness and safety screening<strong>.</strong></div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 3","pages":"Article 102477"},"PeriodicalIF":3.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171973","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green approach based on Micellar -Modified Kalonji seeds waste for removal of hexavalent chromium ions and methyl orange dye from aqua 胶束改性卡龙鸡种子废弃物去除水中六价铬离子和甲基橙染料的绿色方法研究
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-03-01 Epub Date: 2026-02-03 DOI: 10.1016/j.jics.2026.102470
Yonis Ahmed Ismael , Dhufr Abdulghani Omer , Saja Saad Ibrahim , Doha Neithal Saad
{"title":"Green approach based on Micellar -Modified Kalonji seeds waste for removal of hexavalent chromium ions and methyl orange dye from aqua","authors":"Yonis Ahmed Ismael ,&nbsp;Dhufr Abdulghani Omer ,&nbsp;Saja Saad Ibrahim ,&nbsp;Doha Neithal Saad","doi":"10.1016/j.jics.2026.102470","DOIUrl":"10.1016/j.jics.2026.102470","url":null,"abstract":"<div><div>This study focuses on utilizing de-oiled Kalonji seed waste (KS) as a green approach, transforming it into sustainability adsorbent for removal methyl orange dye (MO) and Cr (VI)ions from aqua The adsorbent performance was enhanced by modification of surface using Cetyltrimethylammonium bromide (CTAB) micelles were used to produce M-MKS adsorbent, the adsorbent was characterized by (FT-IR, SEM-EDX, XRD, Zeta potential, and BET analysis). Additionally, the ideal parameters pH solution, initial concentration, adsorbent dosage, contact time, and temperature were examined. BET analysis found that M-MKS has an appropriate surface area of around (27m<sup>2</sup>/g), with an average pore diameter of (11.17) nm. The removal efficiencies for MO dye and Cr (VI) ions were determined to be (95.90 and 99.04%), respectively, at starting concentrations of (200 and 70 mg/L). The Temkin model was shown to be more appropriate for the experimental adsorption data than the other isotherm models. while, the P–SO model was better matched than the other kinetic models. Thermodynamic analysis demonstrated spontaneous and exothermic adsorption events. According to regeneration demonstrated that M-MKS adsorbent could sustain around (73.70 and 84.93%) for dye and Cr (VI) at the fifth consecutive cycle of regeneration. The proposed mechanism for dye and Cr (VI) removal involves electrostatic reactions, hydrogen bonding, ion exchange, and π-π reactions between the cationic surface of the adsorbent and anionic molecules of the pollutants. Furthermore, M-MKS was applied to actual water samples, where the adsorbent its efficiency in water samples, confirming its applicability on an industrial scale. Finally, M-MKS adsorbent represents a sustainable, low-cost, highly efficient green solution for treating polluted water, and is a promising option for large-scale environmental applications.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 3","pages":"Article 102470"},"PeriodicalIF":3.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization, geometrical structural, optical properties and electrical conductivity, and effect of type of derivatives of azo Schiff base quinoline on the optical energies gap and theoretical parameters 偶氮席夫碱喹啉的表征、几何结构、光学性质和电导率,以及衍生物类型对其能隙和理论参数的影响
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-03-01 Epub Date: 2026-01-31 DOI: 10.1016/j.jics.2026.102459
Sh.M. Morgan , A.Z. El-Sonbati , N.A. El-Ghamaz , S.G. Nozha , M.A. Diab , M.A. El-Mogazy
{"title":"Characterization, geometrical structural, optical properties and electrical conductivity, and effect of type of derivatives of azo Schiff base quinoline on the optical energies gap and theoretical parameters","authors":"Sh.M. Morgan ,&nbsp;A.Z. El-Sonbati ,&nbsp;N.A. El-Ghamaz ,&nbsp;S.G. Nozha ,&nbsp;M.A. Diab ,&nbsp;M.A. El-Mogazy","doi":"10.1016/j.jics.2026.102459","DOIUrl":"10.1016/j.jics.2026.102459","url":null,"abstract":"<div><div>This study investigates the optical properties, electrical conductivity and dielectric behavior of a series of azo Schiff base quinoline ligands 4-{[5-(4- derivatives-phenylazo)-8-hydroxy-quinolin-7-ylmethylene]-amino}-1,5-dimethyl-2-phenyl-1,2-dihydro-pyrazol -3-one (HL<sub>1</sub> – HL<sub>5</sub>). Optimized molecular geometry and quantum chemical calculations indicate that the HL<sub>4</sub> ligand is more stable than the other ligands. The HOMO–LUMO energy gap of ligands is in the range 2.645–3.552 eV. The thermal activation energies for AC conductivity for ligands decrease with increasing frequency, and the AC conductivity is influenced by the variation of the substituent groups in the ligand structures. The AC electrical conductivity mechanism in HL<sub>1</sub>–HL<sub>5</sub> is found to follow the correlated barrier hopping model. The type of electronic transition found to be indirect allowed for all ligands. The optical energy gaps (E<sub>g</sub>) are calculated to be 0.613, 1.19, 1.658 and 1.753 eV, for the thermally evaporated thin films of the HL<sub>2-5</sub> ligands, respectively. The width of the band tail (E<sub>u</sub>) values is found in range from 0.713 to 1.000 eV for the ligands. All the ligands show good emission properties; especially HL<sub>1</sub> ligand demonstrates the highest values of emission intensity.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 3","pages":"Article 102459"},"PeriodicalIF":3.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Extra-heavy crude oil viscosity modifiers derived from common geranium extracts and their characterization 从普通天竺葵提取物中提取的特重质原油粘度改进剂及其表征
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-03-01 Epub Date: 2026-01-29 DOI: 10.1016/j.jics.2026.102456
Jessica I. Lozano-Navarro , Arturo Palacio-Pérez , Edgardo J. Suárez-Domínguez , Josué F. Pérez-Sánchez , Nancy P. Díaz-Zavala , Alejandro Rodríguez-Valdés , Jonathan Hernández-García , Laura I. Montoya Ortiz
{"title":"Extra-heavy crude oil viscosity modifiers derived from common geranium extracts and their characterization","authors":"Jessica I. Lozano-Navarro ,&nbsp;Arturo Palacio-Pérez ,&nbsp;Edgardo J. Suárez-Domínguez ,&nbsp;Josué F. Pérez-Sánchez ,&nbsp;Nancy P. Díaz-Zavala ,&nbsp;Alejandro Rodríguez-Valdés ,&nbsp;Jonathan Hernández-García ,&nbsp;Laura I. Montoya Ortiz","doi":"10.1016/j.jics.2026.102456","DOIUrl":"10.1016/j.jics.2026.102456","url":null,"abstract":"<div><div>Extra-heavy crude presents high viscosity and a considerable percentage of asphaltenes that cause problems during production and transportation, such as clogging pipes and superior requirements of pumping energy. In the last decades, its production was increased, and the use of substances that improve its flow was demanded. It is important to find new green/renewable/accessible compounds that allow viscosity reduction and substitute toxic modifiers such as toluene, naphtha, xylene, heptane, methanol, etc. This study synthesized new common geranium (<em>Pelargonium hortorum</em>) extracts using ethanol and the Soxhlet method. The extracts were used in concentrations of 10, 15, and 20 % (w/v), and their effects on the viscosity of a Mexican extra-heavy crude (Altamira 8° API blend) were analyzed through rheological tests. To understand the mechanisms implied in the viscosity reduction phenomena, GC-MS studies and phytochemical analyses of the extracts were carried out in order to know their main compounds. Also, asphaltenes flocculation, Fourier Transform Infrared Spectroscopy analysis (FTIR), hydrogen potential (pH), total dissolved solids (TDS), and electrical conductivity (EC) tests were performed. The research results propose further investigation with Pelargonium species to present brand-new alternative viscosity reducers with easy, cheap, and effective performance.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 3","pages":"Article 102456"},"PeriodicalIF":3.4,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable production of lignin-based surfactants from tropical wood waste via delignification–Sulfonation for enhanced oil recovery 通过脱木质素-磺化处理从热带木材废料中可持续生产木质素基表面活性剂以提高石油采收率
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-02-01 Epub Date: 2026-01-27 DOI: 10.1016/j.jics.2026.102449
Ahmad Shobib , Aminuddin , Nur Rokhati , Bambang Pramudono
{"title":"Sustainable production of lignin-based surfactants from tropical wood waste via delignification–Sulfonation for enhanced oil recovery","authors":"Ahmad Shobib ,&nbsp;Aminuddin ,&nbsp;Nur Rokhati ,&nbsp;Bambang Pramudono","doi":"10.1016/j.jics.2026.102449","DOIUrl":"10.1016/j.jics.2026.102449","url":null,"abstract":"<div><div>This study investigates the isolation and modification of lignin from tropical hardwoods, i.e: teak (<em>Tectona grandis</em>), mahogany (<em>Swietenia macrophylla</em>), and sengon (<em>Albizia chinensis</em>), for the production of surfactant-lignin sulfonate (SLS) used in enhanced oil recovery (EOR). Lignin was extracted using hydrogen peroxide and sodium hydroxide, followed by solvolysis. The biomass composition was analyzed, revealing significant variation in hemicellulose content, with sengon showing the highest content (41 %-wt) compared to teak and mahogany. Sulfonation was carried out at varying temperatures, showing that higher temperatures generally increased SLS yield and surfactant performance. FTIR analysis confirmed structural differences between the lignins from different biomass sources. The produced SLS demonstrated favorable properties for EOR applications, including good compatibility with synthetic brine, stability at elevated temperatures, and effective phase behavior. These findings suggest that biomass-derived SLS could be a sustainable and cost-effective alternative to conventional surfactants for EOR processes.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 2","pages":"Article 102449"},"PeriodicalIF":3.4,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of recycled fine aggregate admixture on the performance of seawater sea sand recycled concrete 再生细骨料外加剂对海水海砂再生混凝土性能的评价
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-02-01 Epub Date: 2026-01-16 DOI: 10.1016/j.jics.2026.102428
Yanmei Yu , Jun Shen , Juhua Luo
{"title":"Evaluation of recycled fine aggregate admixture on the performance of seawater sea sand recycled concrete","authors":"Yanmei Yu ,&nbsp;Jun Shen ,&nbsp;Juhua Luo","doi":"10.1016/j.jics.2026.102428","DOIUrl":"10.1016/j.jics.2026.102428","url":null,"abstract":"<div><div>Seawater sea sand recycled concrete (SSRAC) has a wide range of application prospects in relieving resource constraints and urban construction waste disposal. Theoretically, after being crushed, SSRAC can still be used as fine aggregate. However, the strength of recycled fine aggregates (RA) and the corrosion problem of chloride ions limited the application of SSRAC. Here, we designed the orthogonal experiment to evaluate the effects of recycled fine aggregate (RFA) admixture, water-glass admixture and sand-cement ratio on the compressive strength, and chloride curing ability of SSRAC. The hydration products and microscopic morphology of SSRAC were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS). The results showed that the RFA was the main factor to affect the compressive strength, and chloride curing ability of SSRAC. Especially, the amount of water glass admixture had an obvious effect on the compressive strength and chloride curing ability of SSRAC. With the increase of RFA admixture, the compressive strength of SSRAC firstly increased and then decreased, continues to decrease with the increase of water glass content. The chloride curing ability decreased and then increased with the increase of RFA content, and increased with the increase of water glass content. Therefore, when the RFA admixture was 60 % and the water glass admixture was 1.5 %, the compressive strength and chloride curing capacity of SSRAC were 31.2 MPa and 1.05, respectively, at which time the water-soluble chloride ion content was 0.218 %. The results and new findings can provide a basis for the preparation of SSRAC.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 2","pages":"Article 102428"},"PeriodicalIF":3.4,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146078623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tunable Copper-doped BaZrO3 for generation of hydrogen through photocatalytic water splitting 光催化水裂解制氢的可调铜掺杂BaZrO3
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-02-01 Epub Date: 2025-12-29 DOI: 10.1016/j.jics.2025.102386
Catalina Vega-Reyes , Iliana E. Medina-Ramírez , Luis A. Díaz-Torres , Eduardo Coutiño-González , Patricia M. Olmos-Moya , Carlos A. Pineda-Arellano
{"title":"Tunable Copper-doped BaZrO3 for generation of hydrogen through photocatalytic water splitting","authors":"Catalina Vega-Reyes ,&nbsp;Iliana E. Medina-Ramírez ,&nbsp;Luis A. Díaz-Torres ,&nbsp;Eduardo Coutiño-González ,&nbsp;Patricia M. Olmos-Moya ,&nbsp;Carlos A. Pineda-Arellano","doi":"10.1016/j.jics.2025.102386","DOIUrl":"10.1016/j.jics.2025.102386","url":null,"abstract":"<div><div>BaZrO<sub>3</sub>, a perovskite-type semiconductor, exhibits exceptional stability and tunable electronic properties, making it a promising candidate for photocatalytic applications. In this study, Cu-doped BaZrO<sub>3</sub> was synthesized by a hydrothermal method followed by thermal annealing at 1100 °C. The substitution of Cu within the BaZrO<sub>3</sub> lattice improves H<sub>2</sub> evolution efficiency. It enhances photosensitivity by introducing electronic defects, increasing the photogenerated electron lifetime (19.89 ns), increasing the specific surface area (19.35 m<sup>2</sup>/g), and narrowing the band gap (3.4 eV) of calcined BaZrO<sub>3</sub> containing 0.5 % Cu. The X-ray Photoelectron Spectroscopy study showed that Cu<sup>+</sup>/Cu<sup>2+</sup> was effectively incorporated into the BaZrO<sub>3</sub> structure by substituting for Zr<sup>3+</sup>/Zr<sup>4+</sup>, creating O vacancies, and thereby improving the optical performance of the doped materials. The materials exhibit photosensitivity that decreases with the highest Cu doping. However, the most beneficial H<sub>2</sub> evolution by photocatalysis occurs at an impurity level is 0.5 % Cu. The importance of the calcination treatment was evident, as it reduces the presence of unwanted species such as BaCO<sub>3</sub>. Inductively Coupled Plasma studies confirmed a good approximation of the expected Cu concentrations. Photocatalysis results showed the best hydrogen production (27.2 μmol g<sup>−1</sup> h<sup>−1</sup> and apparent quantum yield = 0.54 %) when BaZrO<sub>3</sub> was doped with 0.5 at% copper.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 2","pages":"Article 102386"},"PeriodicalIF":3.4,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145928412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of chlorination time and storage conditions on the aging resistance of AgCl electrodes for hyperhidrosis treatment 氯化时间和贮存条件对治疗多汗症用AgCl电极耐老化性能的影响
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-02-01 Epub Date: 2026-01-17 DOI: 10.1016/j.jics.2026.102427
Melike Çalık, İlyas Aktaş, Meltem Gör Bölen
{"title":"Influence of chlorination time and storage conditions on the aging resistance of AgCl electrodes for hyperhidrosis treatment","authors":"Melike Çalık,&nbsp;İlyas Aktaş,&nbsp;Meltem Gör Bölen","doi":"10.1016/j.jics.2026.102427","DOIUrl":"10.1016/j.jics.2026.102427","url":null,"abstract":"<div><div>In this study, AgCl electrodes used in the iontophoresis method to treat hyperhidrosis were produced for different chlorination times of Ag (5,10,15 and 30 min). This study aims to examine the performance of the produced electrodes against aging under two different storage conditions (KCl and NaCl solutions). For this purpose, the effects of aging and storage conditions on the electrodes aged for 5, 15, and 30 days were examined, and the potential differences between the produced electrodes and the reference electrode were measured. According to the results obtained, the electrodes stored in the NaCl solution were found to be more resistant to aging. In addition, the potential difference between these electrodes and the reference electrode was within acceptable limits and showed a high stability. This suggests that NaCl is the most suitable storage condition for the AgCl electrodes. After 5 days of aging in NaCl solution, the AgCl electrode was produced with a chlorination time of 5 min, and the potential difference with the reference electrode was measured as 8.40 mV. The potential difference between the AgCl electrodes produced and aged under the same conditions but stored in KCl solution during the aging period was measured as 100.10 mV. The chlorination times at which the potential difference between the AgCl electrodes and the reference electrode was the lowest were 15 min when stored in the NaCl solution and 30 min when stored in the KCl solution. The findings clarify the design principles of medical-grade electrodes and provide important outcomes for enhancing the reliability and consistency of iontophoresis-based therapies.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"103 2","pages":"Article 102427"},"PeriodicalIF":3.4,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ferrous hydroxide nanostructures as a stable electrode material for electrochemical supercapacitors 氢氧化铁纳米结构作为电化学超级电容器的稳定电极材料
IF 3.4 4区 化学
Journal of the Indian Chemical Society Pub Date : 2026-02-01 Epub Date: 2026-01-02 DOI: 10.1016/j.jics.2025.102378
Partha Pratim Sahu, Palash Phukan, Jagat Das, Mousumi Deori
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