Journal of the Indian Chemical Society最新文献

{"title":"Using isopropanol as a liquid organic hydrogen carrier (LOHC) for the reduction nitroarenes employing Au/Ag decorated carbon aerogels","authors":"Zahra Yousefian-Jazi,&nbsp;Hossein Tavakol","doi":"10.1016/j.jics.2025.102116","DOIUrl":"10.1016/j.jics.2025.102116","url":null,"abstract":"<div><div>In this study, multi-walled carbon nanotubes functionalized with carboxylic acid/chitosan aerogel containing Ag/Au nanoparticles (NPs) (CNT/CS@Au/Ag aerogel) were synthesized using carboxylated multi-walled carbon nanotubes, deacetylated chitosan, AgNO₃, HAuCl_4, and their reduction by NaBH₄ using the sol-gel method, followed by freeze-drying. FE-SEM, EDS, XRD, BET, FT-IR, TGA, and Raman analyses confirmed the porous structure, NPs dispersion, pore size, functional groups, and thermal stability of the synthesized aerogel. Four different aerogels with different Au/Ag ratios or different preparation procedure were prepared. Then, the prepared catalysts were employed at different conditions for the mild reduction of nitroarenes by isopropanol, as an available and non-expensive Liquid Organic Hydrogen Carrier (LOHC). The optimal conditions for nitrobenzene reduction were determined as follows: 40 mg of mixed Ag/Au catalyst (containing 2.5 % Ag/2.5 % Au, reduced Ag and Au salts spontaneously), 3 equivalents of sodium hydroxide, and 5 mL of isopropanol as both solvent and reducing agent. The reaction was carried out at reflux temperature for 24 h. UV–Vis spectroscopy analysis revealed 100 % conversion and 78 % aniline yield. The high catalytic stability of the synthesized aerogel after 5 reuses demonstrated its high potential as a recyclable and economical catalyst. It was also used in the reduction of 15 different NB derivatives, and acceptable results were obtained.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102116"},"PeriodicalIF":3.4,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on the preparation and physicochemical property evolution of waste wood chips/bituminous coal-based composite fuel","authors":"Xinhang Yang ,&nbsp;Jiachen Man ,&nbsp;Zhijun He","doi":"10.1016/j.jics.2025.102125","DOIUrl":"10.1016/j.jics.2025.102125","url":null,"abstract":"<div><div>In response to the \"carbon peak and carbon neutrality\" demands of the steel industry, this study employs the co-micro carbonization of waste wood chips and bituminous coal to prepare carbon-based composite fuels. By regulating the mixing ratios (from 9:1 to 5:5) and carbonization temperatures (300–500 °C), the pyrolysis behavior, combustion characteristics, and physicochemical evolution are systematically analyzed. The results indicate that mixing waste wood chips with bituminous coal significantly improves the pyrolysis synergy. When the proportion of bituminous coal increases to 60 %, the activation energy of rapid pyrolysis decreases from 130.07 kJ mol⁻¹ to 46.94 kJ mol⁻¹. The solid yield increases from 28.81 % to 45.47 % as the proportion of bituminous coal increases, but when the carbonization temperature rises to 500 °C, the yield decreases to 41.03 % due to intensified volatile release. Carbonization at 500 °C promotes the formation of a porous structure in the composite fuel and enhances the condensation degree of the aromatic carbon network. The Raman spectroscopy I_D/I_G value increases to 2.793, indicating that the increase in defect sites is beneficial for the combustion reaction.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102125"},"PeriodicalIF":3.4,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient production of γ-valerolactone by transfer hydrogenation of levulinic acid using Cu–In2O3–Al2O3 prepared by combustion method","authors":"Sivudu Chiragoni ,&nbsp;Kumara Swamy Koppadi ,&nbsp;Saidulu Ganji ,&nbsp;Nagaraju Nekkala ,&nbsp;Kavitha Siddoju","doi":"10.1016/j.jics.2025.102128","DOIUrl":"10.1016/j.jics.2025.102128","url":null,"abstract":"<div><div>The catalytic transfer hydrogenation (CTH) process is a cost-effective, environmentally friendly, and efficient approach for hydrogenation, enabling the direct transfer of hydrogen from a donor to the substrate involved in the reaction. In this study, catalytic transfer hydrogenation (CTH) of biomass-derived levulinic acid (LA) into gamma-valerolactone (GVL), employing 2-propanol as the hydrogen donor, was carried out using In₂O₃-modified Cu/Al₂O₃ catalysts with varying In₂O₃ loadings synthesized via a combustion process. Various analytical techniques have been employed to investigate the structural and chemical properties of synthesized catalysts. The loading of In₂O₃ was a critical factor in determining the overall efficacy of the catalyst. Impressively, C10InA achieved a 100 % yield of GVL when tested at 200 °C for a period of 3 h at 1 MPa H₂ pressure. The C10InA catalyst demonstrated remarkable stability throughout a series of five consecutive trials, showcasing its resilience and durability in catalytic processes. This consistent performance is a crucial factor in industrial applications, where long-term stability and reusability of catalysts are essential for cost-effective and sustainable operations.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102128"},"PeriodicalIF":3.4,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental investigation and lumped kinetic modeling studies for upcycling of polyolefins","authors":"Omkar G. Kavade ,&nbsp;Paresh L. Dhepe ,&nbsp;Nandini R. Devi ,&nbsp;Satyam Naidu Vasireddy","doi":"10.1016/j.jics.2025.102127","DOIUrl":"10.1016/j.jics.2025.102127","url":null,"abstract":"<div><div>The present work discusses on comparative kinetic analysis of the pyrolysis of polypropylene (PP), high-density polyethylene (HDPE), and low-density polyethylene (LDPE) using sophisticated lumped models. Unlike many previous studies that focused on single-polymer kinetic models or employed simplified reaction schemes, this study develops an enhanced multistep reaction network that explicitly considers both primary decomposition and secondary cracking pathways, thereby improving the accuracy of product distribution predictions. By integrating this detailed reaction framework with a robust nonlinear regression approach using LSQNONLIN and ODE45 solvers in MATLAB, the study achieved greater accuracy in estimating kinetic parameters than traditional curve-fitting methods. The findings reveal that HDPE exhibits the highest activation energy (222.97 kJ mol⁻¹), indicating it is more thermally stable than LDPE (193.44 kJ mol⁻¹) and PP (62.16 kJ mol⁻¹). One of the highlights of the present work is that lower pyrolysis temperature (400 °C) is found to be optimum for liquid yield by reducing secondary cracking, which aligns with the sustainable fuel production principles. The study also emphasizes on the limitations of previous lumped models that overlooked wax decomposition pathways, which are crucial for optimizing the hydrocarbon distribution. Future research should investigate catalytic interventions and reactor design modifications to enhance the product selectivity and scalability. This study offers a more comprehensive kinetic framework for advancing the valorization of plastic waste through pyrolysis, aiding the development of efficient waste-to-fuel conversion strategies.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102127"},"PeriodicalIF":3.4,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Calcium lactate catalyzed tandem Michael addition-cyclization reaction: A green protocol to synthesize 2-amino-4H-chromene-3-carbonitriles","authors":"Sudipta Roy ,&nbsp;Nazir Uddin ,&nbsp;Chayanika Chakraborty ,&nbsp;Arun Kumar Sinha ,&nbsp;Naba K. Nath ,&nbsp;Paresh Nath Chatterjee","doi":"10.1016/j.jics.2025.102094","DOIUrl":"10.1016/j.jics.2025.102094","url":null,"abstract":"<div><div>An eco-friendly, green protocol catalyzed by non-toxic calcium lactate to synthesize 2-amino-4<em>H</em>-chromene-3-carbonitriles <em>via</em> a tandem Michael addition-cyclization reaction in green solvents is described here. The 2-amino-4<em>H</em>-chromene-3-carbonitriles are formed by the Michael addition reaction of malononitrile to 2-hydroxychalcones/2-(<em>E</em>)-2-nitrovinylphenols, followed by an intramolecular ring closure in aqueous ethanol (1:1 v/v). The present method can tolerate functional groups with different electronic properties and produce good to excellent yields of the desired chromenes.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102094"},"PeriodicalIF":3.4,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, in silico studies and in vitro evaluation of benzimidazole and benzotriazole derivatives as efflux pump inhibitors","authors":"Shivangi P. Sawant ,&nbsp;Sonali Mehendale-Munj ,&nbsp;Anand Chintakrindi ,&nbsp;Sanjivani Pathak ,&nbsp;Sadhana Sathaye ,&nbsp;Shreerang V. Joshi","doi":"10.1016/j.jics.2025.102112","DOIUrl":"10.1016/j.jics.2025.102112","url":null,"abstract":"<div><div>Multidrug resistance (MDR), primarily mediated by overexpression of ATP-binding cassette (ABC) transporters such as breast cancer resistance protein (BCRP) and P-glycoprotein (P-gp), pose a significant barrier to effective cancer chemotherapy. In this study, a series of benzimidazole (3a-3j) and benzotriazole (4a-4j) derivatives were rationally designed, synthesized, and characterised, aiming to develop efflux pump inhibitors with minimal intrinsic cytotoxicity. <em>In silico</em> docking studies against BCRP and P-gp revealed favourable binding profiles, with several compounds displaying key interactions with transporter residues. AutoQSAR-based predictive modelling further supported their potential, with disubstituted analogues emerging as promising candidates due to their superior predicted activity. Selected compounds were evaluated <em>in vitro</em> using MTT cytotoxicity assays and efflux inhibition studies in differentiated Caco-2 cells. Compounds 3c and 4c preferentially inhibited P-gp, while 3g showed higher BCRP inhibition, with compound 3c exhibiting dual activity and a favourable safety profile. Collectively, these findings suggest that the benzimidazole and benzotriazole scaffolds offer a viable strategy for the development of selective efflux pump modulators to combat MDR in cancer.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102112"},"PeriodicalIF":3.4,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145221499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Innovative valorization of ceramic waste by transforming it into high-performance heterogeneous catalysts for green and efficient benzothiazole derivatives synthesis","authors":"Imane Houmia ,&nbsp;Youssef Merroun ,&nbsp;Najwa Kaibous ,&nbsp;Soukaina Chehab ,&nbsp;Khadija Bazhar ,&nbsp;Achraf El Hallaoui ,&nbsp;Abdelaziz Souizi ,&nbsp;Rachida Ghailane ,&nbsp;Taoufiq Guedira","doi":"10.1016/j.jics.2025.102113","DOIUrl":"10.1016/j.jics.2025.102113","url":null,"abstract":"<div><div>This work introduces a sustainable strategy for catalyst development by repurposing ceramic waste—specifically kaolin–quartz residues—into efficient heterogeneous catalysts for the synthesis of benzothiazole derivatives, a class of compounds with significant pharmaceutical and agrochemical value. The two waste-derived catalysts were characterized using XRD, FT-IR, XRF, BET, SEM, and EDX techniques. Their catalytic activity was assessed in the condensation of 2-aminothiophenol with a variety of aldehydes, affording the target benzothiazole compounds in excellent yields (85–95 %) within 60 min. High turnover frequencies (TOF) confirmed the strong efficiency of the catalytic system.</div><div>The process exhibits multiple green chemistry advantages, including low catalyst loading, mild reaction conditions, straightforward work-up, and easy product separation. Both catalysts also showed remarkable recyclability, retaining their activity over at least five consecutive cycles with no significant structural degradation. Catalyst heterogeneity was confirmed via a hot filtration test, further supporting their applicability in sustainable heterogeneous catalysis.</div><div>To quantitatively assess environmental performance, several green chemistry metrics were calculated—including the Environmental Factor (E-factor), Atom Economy (AE), Reaction Mass Efficiency (RME), Carbon Efficiency (CE), and Optimum Efficiency (OE)—all of which indicated favorable ecological and material efficiency.</div><div>Overall, this study not only advances environmentally responsible synthetic methodologies but also promotes the circular use of industrial waste. The findings position ceramic waste-based catalysts as cost-effective, recyclable, and eco-friendly alternatives to conventional systems, aligning with current goals for sustainable and greener chemical practices.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102113"},"PeriodicalIF":3.4,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis, characterization, and antimicrobial evaluation of Fe(III) and Ni(II) complexes derived from azo-chalcone ligand: Spectroscopic, thermal, and molecular docking investigations","authors":"Mohammed A.O. Basubaih ,&nbsp;Hany M. Abd El-Lateef ,&nbsp;Faleh Z. Alqahtany ,&nbsp;Mai M. Khalaf ,&nbsp;Mohamed Gouda ,&nbsp;Antar A. Abdelhamid ,&nbsp;Raafat A. El-Eisawy ,&nbsp;Aly Abdou","doi":"10.1016/j.jics.2025.102120","DOIUrl":"10.1016/j.jics.2025.102120","url":null,"abstract":"<div><div>This study reports the design, synthesis, structural characterization, and antimicrobial evaluation of novel iron(III) and nickel(II) metal complexes derived from a newly developed azo-chalcone-based organic ligand. Comprehensive structural elucidation was performed using a range of spectroscopic and analytical techniques, including infrared spectroscopy, ultraviolet–visible spectroscopy, proton nuclear magnetic resonance spectroscopy, mass spectrometry, elemental analysis, molar conductivity measurements, and magnetic susceptibility analysis. The results confirmed coordination of the ligand to the metal centers through azo and phenolic functional groups, and indicated an octahedral geometry for both metal complexes. The non-electrolytic nature of the complexes was verified by conductivity studies, while elemental analysis established a metal-to-ligand stoichiometry of 1:1. Thermal analysis demonstrated high thermal stability and suggested the presence of coordinated water molecules. Biological assays revealed significantly enhanced antimicrobial activity of the metal complexes compared to the free ligand, with the nickel(II) complex showing the highest antibacterial effectiveness, particularly against <em>Pseudomonas aeruginosa</em>. This enhanced bioactivity is attributed to increased lipophilicity and improved interaction with microbial cell membranes. Furthermore, molecular docking studies demonstrated that metal coordination significantly improved the binding affinity of the complexes to bacterial target proteins, with the nickel(II) complex showing the strongest binding interaction. These findings suggest the potential of metal complexation as a strategy to enhance the pharmacological properties of bioactive ligands.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102120"},"PeriodicalIF":3.4,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable use of soybean meal in laccase production by Pleurotus ostreatus: Optimization of production and characterization of the enzyme","authors":"Thaís Santos Moraes Lima ,&nbsp;Alexsandra Nascimento Ferreira ,&nbsp;Márjorie Castro Pinto Porfirio ,&nbsp;Ivonéa Soares do Nascimento ,&nbsp;Luciana Carolina Bauer ,&nbsp;Jabson Meneses Teixeira ,&nbsp;Mateus Sousa Pereira ,&nbsp;Izabella de Carvalho Batista Muniz ,&nbsp;Paulo Bonomo ,&nbsp;Flávia Mariani Barros ,&nbsp;Renata Cristina Ferreira Bonomo","doi":"10.1016/j.jics.2025.102124","DOIUrl":"10.1016/j.jics.2025.102124","url":null,"abstract":"<div><div>Laccases are oxidoreductive enzymes found in animals, plants, and fungi. Due to their ability to catalyze the oxidation of different phenols and aromatic amines. These enzymes have been widely applied in several sectors, including pollutant degradation, cosmetics, food, and bioenergy industries, especially laccases of fungal origin. In this context, solid-state fermentation (SSF) emerges as a sustainable, economical, efficient, and environmentally friendly alternative for producing this enzyme, utilizing agro-industrial waste. This study aimed to produce, optimize, and characterize laccase by <em>Pleurotus ostreatus</em> cultivated in SSF using soybean meal. Enzyme production was monitored over 240 h to determine the optimal time, followed by a Central Composite Rotational Design (CCRD) to evaluate the parameters of moisture, pH, glucose, and copper sulfate. The characterization of the enzyme included optimal pH and temperature, determination of kinetic constants (K_m and V_max), molecular weight, and zymography. In optimizing enzyme production, pH and humidity were significant factors; the optimal condition was at pH 6.8 and 61.4 % humidity, resulting in an enzymatic activity of 12.85 U/mL and a recovery rate of 82.16 %. In the characterization, the laccase showed maximum activity at neutral pH and 30 °C (23.15 U/mL), with an estimated molecular weight of 65.0 kDa. The results indicate that the enzyme produced is viable for application in industrial and biotechnological processes. Furthermore, soybean meal proved to be a viable, sustainable, and cost-effective alternative for producing laccase by <em>P. ostreatus</em>.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102124"},"PeriodicalIF":3.4,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145096921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Non-ideal ion transport in moderately concentrated KCl solutions: Decoupling bulk and interfacial dynamics through impedance spectroscopy and equivalent circuit modeling","authors":"Meryem Bensemlali ,&nbsp;Halima Mortadi ,&nbsp;Abdellatif Aarfane ,&nbsp;Abdoullatif Baraket ,&nbsp;Abdelowahed Hajjaji ,&nbsp;Said Laasri ,&nbsp;Mina Bakasse ,&nbsp;Najoua Labjar ,&nbsp;Hamid Nasrellah","doi":"10.1016/j.jics.2025.102121","DOIUrl":"10.1016/j.jics.2025.102121","url":null,"abstract":"<div><div>This study investigates the concentration-dependent electrical and dynamic properties of KCl solutions (0.1–0.3 M) to elucidate ion transport mechanisms and validate classical electrolyte theory. Using AC conductivity analysis, we observed enhanced ionic conductivity with increasing concentration, evidenced by broadening Nyquist semicircles and rising CC plateaus, while equivalent circuit modeling decoupled bulk and interfacial processes, revealing decreasing resistances and shifting CPE parameters. Key results include a linear increase in conductivity (4.1–15.2 mS/cm) and opposing relaxation time trends (bulk τ₁ decreasing, interfacial τ₂ increasing), highlighting the interplay between ion mobility and electrode effects. The Debye screening length followed κ⁻¹ ∝ c⁻¹/² (A = 0.3036), confirming theoretical predictions, while derived ionic mobilities (4.25–5.25 × 10⁻⁸ m²/V·s) and diffusivities (1.09–1.35 × 10⁻⁹ m²/s) captured non-ideal behavior at moderate concentrations. This work provides a robust experimental framework linking macroscopic measurements to microscopic ion dynamics, offering insights for optimizing electrochemical systems.</div></div>","PeriodicalId":17276,"journal":{"name":"Journal of the Indian Chemical Society","volume":"102 11","pages":"Article 102121"},"PeriodicalIF":3.4,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}