Advanced Membranes最新文献_第4页

Ultrathin mineral interlayers regulate interfacial polymerization of polyamide nanofiltration membranes via multiple non-covalent and coordination bonding for rapid molecular separation 超薄矿物夹层通过多重非共价键和配位键调控聚酰胺纳滤膜的界面聚合，实现分子的快速分离

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-06-28 DOI: 10.1016/j.advmem.2025.100163

Yan Zhu, Danwei Huang, Hongbo Xie, Zheyuan Liu, Fei-Fei Chen, Yan Yu

{"title":"Ultrathin mineral interlayers regulate interfacial polymerization of polyamide nanofiltration membranes via multiple non-covalent and coordination bonding for rapid molecular separation","authors":"Yan Zhu, Danwei Huang, Hongbo Xie, Zheyuan Liu, Fei-Fei Chen, Yan Yu","doi":"10.1016/j.advmem.2025.100163","DOIUrl":"10.1016/j.advmem.2025.100163","url":null,"abstract":"<div><div>Polyamide (PA) nanofiltration membranes have raised considerable interest in the realm of water purification. However, balancing permeability and rejection remains a critical challenge in membrane science and technology. Herein, we report that weak non-covalent hydrogen bonds and strong coordination bonds between ultrathin calcium silicate (UCS) interlayers and piperazine (PIP) powerfully control its diffusion. Theoretical calculations reveal that coordination bonds dominate PIP binding on UCS with an adsorption energy of −443.83 kJ mol<sup>−1</sup>, thereby impeding its movement. The diffusion coefficient of PIP diminishes by 14 % upon the incorporation of UCS, as evidenced by molecular dynamics simulations. As a consequence, a superhydrophilic, smooth, loose, and ultrathin (∼18.9 nm) PA separation layer is created. The as-obtained UCS-interlayered PA possesses a remarkable water permeance of 31.7 L m<sup>−2</sup> h<sup>−1</sup> bar<sup>−1</sup> that is 2.2-fold higher than that of UCS-free PA, while dye rejection rates keep a high level. Furthermore, the UCS-interlayered PA demonstrates exceptional antifouling performance with a 95 % flux recovery ratio and long-term stability during 16-h filtration. The study highlights the pivotal role of mineral interlayers in tailoring amine monomer diffusion via multiple interfacial interactions for advanced water treatment applications.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100163"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Evaluating and advancing large language models for nanofiltration membrane knowledge tasks 评估和改进纳滤膜知识任务的大型语言模型

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-06-27 DOI: 10.1016/j.advmem.2025.100161

Xinchen Xiang , Zheng Cao , Yukun Qian , Dan Lu , Jiancong Lu , Jinyan Wang , Shiyu Zhou , Lijun Liang , Zhikan Yao , Lin Zhang

{"title":"Evaluating and advancing large language models for nanofiltration membrane knowledge tasks","authors":"Xinchen Xiang , Zheng Cao , Yukun Qian , Dan Lu , Jiancong Lu , Jinyan Wang , Shiyu Zhou , Lijun Liang , Zhikan Yao , Lin Zhang","doi":"10.1016/j.advmem.2025.100161","DOIUrl":"10.1016/j.advmem.2025.100161","url":null,"abstract":"<div><div>Nanofiltration (NF) is a rapidly growing field, resulting in a surge of publications with diverse focuses. It's challenging for researchers to quickly find key information from the vast amount of publications. Large language models (LLMs) have shown promise in analyzing article and reasoning about knowledge in some scientific fields, but their effectiveness in membrane research is unclear. Here, we introduced the first benchmark specifically designed for membrane studies and used it to systematically evaluate six general-purpose LLMs (i.e., Claude-3.5, Deepseek-R1, Gemini-2.0, GPT-4o-mini, Llama-3.2, and Mistral-small-3.1). Our findings revealed that the complexity and depth of NF knowledge pose a significant challenge for these LLMs, leading to poor performance, particularly in tasks involving membrane mechanisms. To enhance LLMs' using in this field, we developed a specialized NF database and integrated it with the LLMs using Retrieval-Augmented Generation (RAG). RAG significantly improved performance across all models, with average gains of 18.5 % on Question type tasks and 10.8 % on Reasoning type tasks. Moreover, in areas such as membrane fabrication and characterization, several models with RAG demonstrated performance exceeding that of human experts. These results suggested that RAG is a promising strategy for leveraging LLMs in NF research. This study introduced a new path for applying LLMs to membrane research and proposes a professional benchmark to ensure the reliable and effective use of LLMs.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100161"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144588192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chiral membrane with intrinsic microporosity for enantioselective electrochemical recognition of tryptophan enantiomers 具有固有微孔的手性膜，用于色氨酸对映体的对映选择性电化学识别

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-06-27 DOI: 10.1016/j.advmem.2025.100162

Wanshuang Zhou , Cong Yu , Qiang Chen , Shi-Peng Sun , Xinbo Wang

引用次数: 0

Outside Back Cover 外封底

IF 9.5

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-12-24 DOI: 10.1016/S2772-8234(25)00076-4

引用次数: 0

Mass transfer in membrane contactors for separating levulinic acid, formic acid, and furfural from biomass hydrolysate with physical organic solvents 用物理有机溶剂从生物质水解物中分离乙酰丙酸、甲酸和糠醛的膜接触器传质研究

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-05-08 DOI: 10.1016/j.advmem.2025.100151

Chatcha Saengsen , Laksamee Jeanmard , Litavadee Chuaboon , Wichitpan Rongwong

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Membranes with hollow bowl-shaped window for CO2 removal from natural gas 具有中空碗状窗口的膜，用于从天然气中去除二氧化碳

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-01-21 DOI: 10.1016/j.advmem.2025.100129

Weiwang Lim , Wen He , Ji Ma , Shabi Ul Hassan , Jingcheng Du , Qian Sun , Dong Cao , Jian Guan , Hongjun Zhang , Jiangtao Liu

{"title":"Membranes with hollow bowl-shaped window for CO2 removal from natural gas","authors":"Weiwang Lim , Wen He , Ji Ma , Shabi Ul Hassan , Jingcheng Du , Qian Sun , Dong Cao , Jian Guan , Hongjun Zhang , Jiangtao Liu","doi":"10.1016/j.advmem.2025.100129","DOIUrl":"10.1016/j.advmem.2025.100129","url":null,"abstract":"<div><div>Mixed matrix membranes (MMMs) are crucial for CO<sub>2</sub> separation and offer a potential solution to overcome conventional gas separation. Nevertheless, MMMs face challenges due to interfacial defects in membranes, which results in poor gas separation performance. In this study, γ-cyclodextrin (γ-CD) based MMMs were synthesized via a simple solution casting method. γ-CD could be molecularly dispersed in Matrimid matrix up to 3 wt% loading without defects at the interfaces in membranes. ATR-FTIR results showed that γ-CD based MMMs have significant peak with loading increases. Leveraging the high CO<sub>2</sub> solubility and high porosity of γ-CD, Matrimid/γ-CD based membranes exhibit improved CO<sub>2</sub>/CH<sub>4</sub> selectivity. Especially, the CO<sub>2</sub> permeability of Matrimid-3%-CD membrane increased by 40 % (from 13.35 to 18.71 Barrer) and CO<sub>2</sub>/CH<sub>4</sub> increased by 99 % (from 36.08 to 71.96), respectively compared to pristine Matrimid membrane. This demonstrates that the incorporation of γ-CD in Matrimid membrane significantly improves both permeability and selectivity. The Matrimid-γ-CD membrane also demonstrated superior long-term operation stability after aging 593 days. Thus, this study lays the foundation for the development of γ-CD-based membranes with high CO<sub>2</sub>/CH<sub>4</sub> selectivity, providing potential pathways for CO<sub>2</sub> separation processes in CO<sub>2</sub>/CH<sub>4</sub> separation.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100129"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143099935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Membrane technology for sterilization and virus elimination of biopharmaceuticals: Fouling matters 生物制药灭菌和病毒消除的膜技术：污染问题

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-03-28 DOI: 10.1016/j.advmem.2025.100143

Shilong Qi , Rong Fan , Xinwei Su , Hao Zhang , Yingzi Cui , Benkun Qi , Xiangrong Chen , Yinhua Wan , Jianquan Luo

{"title":"Membrane technology for sterilization and virus elimination of biopharmaceuticals: Fouling matters","authors":"Shilong Qi , Rong Fan , Xinwei Su , Hao Zhang , Yingzi Cui , Benkun Qi , Xiangrong Chen , Yinhua Wan , Jianquan Luo","doi":"10.1016/j.advmem.2025.100143","DOIUrl":"10.1016/j.advmem.2025.100143","url":null,"abstract":"<div><div>Membrane-based sterilization and virus removal have become an essential approach for Quality Control and Quality Assurance in biopharmaceutical manufacturing, offering significant advantages over traditional thermal and chemical methods. This green technology preserves drug integrity without chemical additives. However, the complex interactions between biomolecules and membrane surfaces often lead to membrane fouling and potential microbial breakthrough. This review first comprehensively interprets the physiochemical properties differences among four biopharmaceuticals (protein, nucleic acid, glycoconjugate vaccine and virus), and then, analyzed the major challenges facing in four biopharmaceuticals sterilization and virus removal. The separation mechanisms of sterilization and virus removal are discussed focusing on both physical (size exclusion) and chemical (electrostatic interactions, hydrophobic adsorption) properties. Particular attention is given to membrane fouling mechanisms and advanced mitigation strategies at the membrane-biomolecule interface. By integrating fundamental scientific principles with practical engineering considerations, this review offers valuable insights for optimizing downstream bioprocessing and advancing membrane technology in the biopharmaceutical industry.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100143"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Restricting ionic liquid in a network comprising of GO/CNT as a separation membrane for efficient CO2 capture 限制离子液体在由氧化石墨烯/碳纳米管组成的网络中作为有效捕获二氧化碳的分离膜

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-06-25 DOI: 10.1016/j.advmem.2025.100158

Dinesh K. Behera , Fan Wang , Bratin Sengupta , Qiaobei Dong , Weiwei Xu , Shiguang Li , Miao Yu

{"title":"Restricting ionic liquid in a network comprising of GO/CNT as a separation membrane for efficient CO2 capture","authors":"Dinesh K. Behera , Fan Wang , Bratin Sengupta , Qiaobei Dong , Weiwei Xu , Shiguang Li , Miao Yu","doi":"10.1016/j.advmem.2025.100158","DOIUrl":"10.1016/j.advmem.2025.100158","url":null,"abstract":"<div><div>The release of carbon dioxide (CO<sub>2</sub>) to the atmosphere remains a critical challenge in addressing climate change, with emissions from power plants being a primary contributor. Membrane-based separation processes offer cost-effective, robust, and energy efficient alternatives to CO<sub>2</sub> capture from power plants. Ionic liquids (IL), known for their high CO<sub>2</sub> affinity, low vapor pressure, and high thermal stability, are propitious materials for such separations. In this study, we try to address major challenges currently restricting IL-based membranes including the porous structure for loading IL and the loading procedure onto the porous structure. An ultrathin (∼230 nm) 2–dimensional composite network comprising of graphene oxide (GO) sheets intercalated carbon nanotubes (CNT) spatially confining IL targeting high CO<sub>2</sub> permeance was designed and fabricated. An IL, 1-ethyl-3 methylimidazolium tetrafluoroborate ([EMIM][BF<sub>4</sub>] was used as the active separating medium. This GO/CNT hybrid network not only stabilizes the IL within the nanochannels because of interactions between cations of IL and negatively charged functional groups on GO (carboxyl, hydroxyl and carboxy groups) but also facilitates faster transport (increased nanochannels because of CNT incorporation) yielding a CO<sub>2</sub> permeance of ∼600 GPU (one order of magnitude higher than reported membranes employing the same ionic liquid) and a CO<sub>2</sub>/N<sub>2</sub> selectivity of 62 under humid conditions and elevated temperatures (up to 80 °C). Our approach provides a modified strategy of using ionic liquids in the solution form as opposed to most studies using pure form for obtaining a scalable, ultrathin, stable supported IL membrane.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100158"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144518964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Eliminating lattice defects in UiO-66-NH2 membrane towards high-precision desalination 消除UiO-66-NH2膜的晶格缺陷，实现高精度脱盐

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-03-24 DOI: 10.1016/j.advmem.2025.100142

Wenwen Dong , Jiahui Yan , Taotao Ji , Mingming Wu , Kunpeng Yu , Yi Liu , Wenjing Hu , Yi Liu

{"title":"Eliminating lattice defects in UiO-66-NH2 membrane towards high-precision desalination","authors":"Wenwen Dong , Jiahui Yan , Taotao Ji , Mingming Wu , Kunpeng Yu , Yi Liu , Wenjing Hu , Yi Liu","doi":"10.1016/j.advmem.2025.100142","DOIUrl":"10.1016/j.advmem.2025.100142","url":null,"abstract":"<div><div>Zirconium-based MOF membranes exhibit significant potential in energy-efficient desalination. Nevertheless, framework defect elimination, which represents an effective protocol to enhance their molecular sieving capacity and operation stability, remains highly challenging to date. In this study, we proposed a framework defect patching strategy to prepare robust UiO-66-NH<sub>2</sub> membrane with Zr<sub>6</sub>O<sub>4</sub>(OH)<sub>4</sub>(OAc)<sub>12</sub> cluster source towards high-efficiency desalination. Ion sieving results indicated that increasing reaction temperature and ratio of ligand to Zr<sub>6</sub>O<sub>4</sub>(OH)<sub>4</sub>(OAc)<sub>12</sub> cluster contributed to framework defect elimination. UiO-66-NH<sub>2</sub> membranes prepared under optimized conditions exhibited superior metal ion rejection rate (Al<sup>3+</sup>: 97.7 %) and operation stability over 20 days. Particularly, their water/NaCl separation performance well exceeded majority of reported polycrystalline 3D membranes, offering promising prospects for modulating molecular diffusion kinetics in MOF pores.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100142"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143714301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Accurate separation and recovery of humic substances from landfill leachate concentrate by triethanolamine-based loose nanofiltration membranes 三乙醇胺基松散纳滤膜对垃圾渗滤液中腐殖质的精确分离和回收

Advanced Membranes Pub Date : 2025-01-01 Epub Date: 2025-02-25 DOI: 10.1016/j.advmem.2025.100137

Shihang Wei , Anqi Fu , Huaying Li , Wenyi Dong , Feiyun Sun , Hongjie Wang , Ding Yu Xing , Yuexing Wang

{"title":"Accurate separation and recovery of humic substances from landfill leachate concentrate by triethanolamine-based loose nanofiltration membranes","authors":"Shihang Wei , Anqi Fu , Huaying Li , Wenyi Dong , Feiyun Sun , Hongjie Wang , Ding Yu Xing , Yuexing Wang","doi":"10.1016/j.advmem.2025.100137","DOIUrl":"10.1016/j.advmem.2025.100137","url":null,"abstract":"<div><div>The treatment of landfill leachate concentrate poses significant environmental challenges, particularly in the separation and recovery of valuable humic substances from high salt concentrations. In this study, a novel loose nanofiltration (LNF) membrane was fabricated using 0.5 wt% triethanolamine (TEOA) and 0.1 wt% trimesoyl chloride (TMC) via interfacial polymerization for the accurate separation of humic substances from inorganic salts in landfill leachate concentrate. The optimized TEOA membrane exhibited high permeate flux about 67.6 L m<sup>−2</sup> h<sup>−1</sup>·bar<sup>−1</sup> and over 90 % transmission for ions, while achieving the rejection of humic substances above 92 %. The effects of operating conditions were investigated. Results showed that increasing inorganic salt concentration led to a notable decrease in inorganic salt rejection due to intensified concentration polarization and weakened electrostatic interactions. Rising humic substance concentration further intensified membrane fouling and concentration polarization, resulting in reduced flux and increased humic substance and inorganic salt rejections. Higher temperatures and alkaline pH increased flux and maintained stable rejections. In addition, a two-stage membrane filtration process was subsequently applied to actual landfill leachate concentrate samples. The humic substance concentration was enriched from 1.5 to 37.4 g L<sup>−1</sup>, achieving a recovery rate over 60 % at a concentration factor of 12.5. The recovered humic substances complied with the standards of water-soluble fertilizers containing humic-acids (NY1106-2010), highlighting the LNF membrane's potential in sustainable landfill leachate concentrate management and resource recovery.</div></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"5 ","pages":"Article 100137"},"PeriodicalIF":0.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143593665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0