Advanced MembranesPub Date : 2022-01-01DOI: 10.1016/j.advmem.2022.100038
Yao-Shen Guo , Qiaohong Liu , Yue Shen , Naixin Wang , Yan-li Ji , Mwema Wanjiya , Quan-Fu An , Cong-Jie Gao
{"title":"Preparation of anti-fouling zwitterionic nanofiltration membrane with tunable surface charge","authors":"Yao-Shen Guo , Qiaohong Liu , Yue Shen , Naixin Wang , Yan-li Ji , Mwema Wanjiya , Quan-Fu An , Cong-Jie Gao","doi":"10.1016/j.advmem.2022.100038","DOIUrl":"10.1016/j.advmem.2022.100038","url":null,"abstract":"<div><p>Anti-fouling property is of vital significance and remains a challenge in the membrane separation field. In this work, N-diethylethylenediamine (DEEDA) was incorporated into the polyamide matrix first. Then, an anti-fouling zwitterionic nanofiltration membrane with tunable surface charge was fabricated by the grafting of p-xylylene dichloride (XDC) on the membrane surface. The resulting nanofiltration membrane possessed zwitterionic groups of positively charged N<sup>+</sup> and negatively charged COO<sup>-</sup>. Meanwhile, the surface charge could be tuned precisely by the concentration of XDC. A neutrally charged nanofiltration membrane was obtained when the concentration of XDC was 1.0 wt% and the preparing membrane showed permeance of 9.1 L·m<sup>-2</sup>·h<sup>-1</sup>·bar<sup>-1</sup> with high rejection of CaCl<sub>2</sub> (90.8%) and Na<sub>2</sub>SO<sub>4</sub> (91.3%) at pH = 6.5. This membrane exhibited excellent anti-fouling properties towards not only negatively charged bovine serum albumin but also positively charged lysozyme. The optimum membrane, PA-XDC-1.0, had flux recovery rates of 95.0% and 94.0% for bovine serum albumin and lysozyme, respectively, which was higher than those of PA-DEEDA-0 (86.1% and 80.7%). This work offered a facile way to fabricate an anti-fouling zwitterionic nanofiltration membrane with tunable surface charge, which had wide applications in water purification.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"2 ","pages":"Article 100038"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823422000148/pdfft?md5=b2477c56ab22c2bd5863cca097ad4b01&pid=1-s2.0-S2772823422000148-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73742083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Advanced MembranesPub Date : 2022-01-01DOI: 10.1016/j.advmem.2022.100043
Hao Wang , Chongyang Yang , Shuo Wang , Sheng Hu
{"title":"Tunable ion transport through ultimately small channels","authors":"Hao Wang , Chongyang Yang , Shuo Wang , Sheng Hu","doi":"10.1016/j.advmem.2022.100043","DOIUrl":"10.1016/j.advmem.2022.100043","url":null,"abstract":"<div><p>Biological membranes allow not only fast and selective ion permeation but also tunable ion transport, passively or actively on demands, in response to external stimuli such as light, voltage, temperature, etc. At the core of the membrane is the ultimate small ion channels approaching the dimension of a single ion and water molecule in the angstrom scale. To mimic and better understand the functioning of biological ion channels, artificial systems of similar sizes are developed recently. As novel platforms, these systems provide insights into many important problems such as mechanisms of non-continuum ion transport that are difficult to be investigated in larger structures. The unique couplings among ions, channels and various external stimuli at this spatial scale further inspire potential technologies where efficient and tunable ion transport is required. We review the main concepts of creating angstrom-scale channels and focus on discussing the tunable ion transport behavior inside. Permeability and selectivity of ion permeation controlled by light, electric field and solution environment variation are highlighted.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"2 ","pages":"Article 100043"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823422000197/pdfft?md5=c80eea7e6f96aec5845668f072636417&pid=1-s2.0-S2772823422000197-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89272820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Advanced MembranesPub Date : 2022-01-01DOI: 10.1016/j.advmem.2022.100025
Guining Chen, Tianlei Wang, Guangru Zhang, Gongping Liu, Wanqin Jin
{"title":"Membrane materials targeting carbon capture and utilization","authors":"Guining Chen, Tianlei Wang, Guangru Zhang, Gongping Liu, Wanqin Jin","doi":"10.1016/j.advmem.2022.100025","DOIUrl":"10.1016/j.advmem.2022.100025","url":null,"abstract":"<div><p>Over the past decades, fossil fuel combustion has emitted large quantities of CO<sub>2</sub> into the atmosphere, resulting in global climate change. Nowadays, it's considered a feasible strategy to capture CO<sub>2</sub> from some significant point sources. Three main strategies have been developed, namely post-combustion, pre-combustion, and oxy-fuel combustion. Recent research indicates that the membrane technology for CO<sub>2</sub> capture has become competitive compared with conventional technologies because of the improved separation performance in materials and process designs. This paper mainly reviews the progress and breakthroughs of membrane materials for the three gas separation systems corresponding to the CO<sub>2</sub> capture strategies. Besides, the CO<sub>2</sub> utilization by the membrane process has also been highlighted.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"2 ","pages":"Article 100025"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S277282342200001X/pdfft?md5=7333d554c1bb9315ecaa5678987aac3f&pid=1-s2.0-S277282342200001X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83485364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Advanced MembranesPub Date : 2022-01-01DOI: 10.1016/j.advmem.2022.100032
Dan Lu , Zhikan Yao , Lei Jiao , Misbah Waheed , Zhilin Sun , Lin Zhang
{"title":"Separation mechanism, selectivity enhancement strategies and advanced materials for mono-/multivalent ion-selective nanofiltration membrane","authors":"Dan Lu , Zhikan Yao , Lei Jiao , Misbah Waheed , Zhilin Sun , Lin Zhang","doi":"10.1016/j.advmem.2022.100032","DOIUrl":"10.1016/j.advmem.2022.100032","url":null,"abstract":"<div><p>Mono-/multivalent ion-selective separation has become a common requirement at the water-energy nexus, including energy storage and conversion, water purification, and sustainable industrial processes. In this review, we summarize the theory of ion transport through membrane and mechanisms of selective ion separation in nanofiltration (NF) briefly. Recent advancing in improving the mono-/multivalent ion selectivity of thin-film composite (TFC) NF membrane via size sieving enhancement, electric charge property regulation and co-enhancement of size sieving and electric charge properties are concluded. What's more, three material classes—surface assembly materials, nanomaterials and biomimetic ion channels are highlighted as candidates for the preparation of ion-selective NF membranes. Lastly, design directions and critical challenges for developing high-selectivity nanofiltration membranes based on the ion-selective mechanisms are provided.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"2 ","pages":"Article 100032"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823422000082/pdfft?md5=38c45915f404ed4868bda388347ea70a&pid=1-s2.0-S2772823422000082-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77011786","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Advanced MembranesPub Date : 2022-01-01DOI: 10.1016/j.advmem.2022.100039
Panchan Dansawad , Yujie Yang , Xin Li , Xiaopeng Shang , Yanxiang Li , Zhiwei Guo , Yashi Qing , Shengyong Zhao , Siming You , Wangliang Li
{"title":"Smart membranes for oil/water emulsions separation: A review","authors":"Panchan Dansawad , Yujie Yang , Xin Li , Xiaopeng Shang , Yanxiang Li , Zhiwei Guo , Yashi Qing , Shengyong Zhao , Siming You , Wangliang Li","doi":"10.1016/j.advmem.2022.100039","DOIUrl":"10.1016/j.advmem.2022.100039","url":null,"abstract":"<div><p>Oily wastewater poses a significant impact on both environments and human societies. Especially, the treatment of oil/water emulsions for separating oil from water is challenging due to the high stability of oil/water emulsions. Smart membranes, known as stimuli-responsive membranes, are one of the emerging technologies that have been paid wide attention for separating oil/water emulsions in recent years. Smart membranes possess the unique features of switchable wettability between hydrophilicity and hydrophobicity after being triggered by external stimuli and have desired anti-fouling properties. This review summarizes the development of smart membranes for oil/water emulsions separation during the past five years (2018 – present). It was found that solvent stimuli-responsive membranes are the most popular type of smart membranes for oil/water emulsions separation. For multi-stimuli-responsive membranes that can respond to more than one stimulus, future research should focus on developing appropriate fabrication strategies to increase the separation and anti-fouling performances of the membranes. Additionally, surface coating, surface grafting, and copolymer blending are the most popular methods for smart membranes fabrication. However, these methods might not be universally applicable to the different types of stimuli-responsive membranes.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"2 ","pages":"Article 100039"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S277282342200015X/pdfft?md5=400b1b0d2183b636f845f952c82eb735&pid=1-s2.0-S277282342200015X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82209902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Advanced MembranesPub Date : 2022-01-01DOI: 10.1016/j.advmem.2022.100036
Muhammad Yazid Bin Zulkifli , Kun Su , Ruiqi Chen , Jingwei Hou , Vicki Chen
{"title":"Future perspective on MOF glass composite thin films as selective and functional membranes for molecular separation","authors":"Muhammad Yazid Bin Zulkifli , Kun Su , Ruiqi Chen , Jingwei Hou , Vicki Chen","doi":"10.1016/j.advmem.2022.100036","DOIUrl":"10.1016/j.advmem.2022.100036","url":null,"abstract":"<div><p>Metal Organic Frameworks (MOFs) have been recently found to exist in a more processible liquid and glassy phase. These glassy MOFs have been shown to exhibit functional properties either in their native glassy form or when composited with other functional materials. The capability of MOF glass to be easily tailored similar to its crystalline form, while being able to form a continuous film with limited intergrain boundaries makes it a promising candidate for a selective membrane material. However, even with its high processibility, limited studies have been performed on this material in a thin film format. This perspective highlights the properties of currently studied MOF glass and its composite, as well as existing studies on MOF glass membranes. Views on possible future exploration pathways for this material in the form of membrane thin films, such as possible new MOF glass composite membrane configuration and new applications, are also provided.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"2 ","pages":"Article 100036"},"PeriodicalIF":0.0,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823422000124/pdfft?md5=cbbbc9edb88ea3d508ff9588e1c5b47a&pid=1-s2.0-S2772823422000124-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89245797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Advanced MembranesPub Date : 2021-01-01DOI: 10.1016/j.advmem.2021.100014
Yanqiu Lu , Wei Liu , Jiangtao Liu , Xue Li , Sui Zhang
{"title":"A review on 2D porous organic polymers for membrane-based separations: Processing and engineering of transport channels","authors":"Yanqiu Lu , Wei Liu , Jiangtao Liu , Xue Li , Sui Zhang","doi":"10.1016/j.advmem.2021.100014","DOIUrl":"10.1016/j.advmem.2021.100014","url":null,"abstract":"<div><p>The expansion of separation demands at molecular and ionic levels has triggered extensive research to explore new materials as promising practical membranes for separations. Owing to their dimension-related properties of two-dimensional (2D) porous organic polymers (POPs), promising research on the construction of 2D POPs into membranes has emerged and progressed rapidly, offering membranes with highly tunable pores/channels, robust frameworks/networks, intrinsic flexibility, and light weight for multiple separation purposes. In this review, up-to-date strategies for processing of 2D POPs into diverse continuous membranes and engineering of their nanochannels are highlighted. The 2D POPs materials discussed include the examples of 2D covalent organic frameworks (COFs), 2D covalent triazine frameworks (CTFs) and 2D conjugated microporous polymers (CMPs). Case studies on these materials for potential membrane applications including gas separation, water treatment, organic solvent nanofiltration (OSN), pervaporation are summarized. Finally, the critical challenges and futuristic upgrades of research directions and opportunities of 2D POPs based advanced membranes are outlined.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"1 ","pages":"Article 100014"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823421000154/pdfft?md5=28e44cbcd366b7a85f0c4248a3586551&pid=1-s2.0-S2772823421000154-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78436683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Significantly improved pervaporation performance by relatively continuous and defect-free distribution of IL-modified ZIF-8 in PDMS membrane","authors":"Ao-Shuai Zhang, Shen-Hui Li, Heng Mao, Li-Hao Xu, Ming-Yu Lv, Zhi-Ping Zhao","doi":"10.1016/j.advmem.2021.100006","DOIUrl":"10.1016/j.advmem.2021.100006","url":null,"abstract":"<div><p>Organophilic pervaporation (PV) mixed matrix membranes (MMMs) possess huge potential in organic wastewater treatment with merits of environmentally friendly and high-efficiency. The filler dispersion structure inside MMMs is required to explore in depth to upgrade the PV performance. In this study, an ethoxysilyl functionalized ionic liquid (IL-PTES) modified ZIF-8 nanoparticles (IL-PTES@ZIF-8) were synthesized by one-pot method, and then incorporated into the PDMS matrix to prepare MMMs for PV separation of ethyl acetate (EtOAc) from its diluted aqueous solution. The preferential adsorption performances to EtOAc by IL-PTES, especially for the functions of specific chemical groups in IL-PTES, were researched via molecular dynamicssimulation approach. Furthermore, the IL-PTES covered on ZIF-8 surface could crosslink with PDMS chains, thereby enhancing the interfacial compatibility between ZIF-8 and PDMS. Importantly, the self-aggregated IL-PTES subtly “glued” the nanoparticles together to lead IL-PTES@ZIF-8 a relatively continuous and defect-free distribution state. This condition would lead to a high-efficiency molecular pathway with less polymer phase and much relatively continuous ZIF-8 phase with high selectivity. PV results suggested that the MMMs with 15% IL-PTES@ZIF-8 loading displayed an optimal separation performance with an ultra-high separation factor of 492 (158.7% more than that of pristine PDMS membrane) and normalized EtOAc flux of 4.98 kg μm m<sup>−2</sup>·h<sup>−1</sup> (2 times as much as that of pristine PDMS membrane) for separating 1 wt% EtOAc aqueous solution at 30 °C. These findings offered significant advancement toward developing high-performance MMMs enabled by the synergy of MOFs and ionic liquid.</p></div>","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"1 ","pages":"Article 100006"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823421000075/pdfft?md5=4f3beb6652c892acddff0bc9443c44df&pid=1-s2.0-S2772823421000075-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83562144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advanced membranes: The new era of membrane research","authors":"Weihong Xing , Huanting Wang , Nanping Xu , Congjie Gao","doi":"10.1016/j.advmem.2021.100004","DOIUrl":"10.1016/j.advmem.2021.100004","url":null,"abstract":"","PeriodicalId":100033,"journal":{"name":"Advanced Membranes","volume":"1 ","pages":"Article 100004"},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772823421000051/pdfft?md5=b96409a3fac22a6331ac90f23cc377aa&pid=1-s2.0-S2772823421000051-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83081174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}