Chemical Physics Impact最新文献_第6页

A sol-gel fabrication, characterization, and boosted photocatalytic activity of a zinc-substituted nickel ferrite: RSM optimization study 锌取代镍铁氧体的溶胶-凝胶制备、表征和增强光催化活性：RSM优化研究

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-11-04 DOI: 10.1016/j.chphi.2025.100963

Safoura Sharafzadeh , Alireza Nezamzadeh–Ejhieh , Javad Zolgharnein

{"title":"A sol-gel fabrication, characterization, and boosted photocatalytic activity of a zinc-substituted nickel ferrite: RSM optimization study","authors":"Safoura Sharafzadeh , Alireza Nezamzadeh–Ejhieh , Javad Zolgharnein","doi":"10.1016/j.chphi.2025.100963","DOIUrl":"10.1016/j.chphi.2025.100963","url":null,"abstract":"<div><div>In the current project, to degrade metronidazole aqueous solution, NiFe2O4 and ZnFe2O4 nanophotocatalysts have been used individually and in combination. The sol-gel method was used for the synthesis of single and combined photocatalysts. To identify them, XRD, DRS, EDX, SEM, VSM, FT-IR and X-ray mapping methods were used. The Scherrer and Williamson-Hall models were used to calculate crystallite size. The values for the Scherrer formula are 20.5, 25.2 and 14.8 nm for zinc ferrite, nickel ferrite and zinc-substituted nickel ferrite, respectively, and 27.3, 26.5 and 20.4 nm by the Williamson-Hall formula. Band gap energies obtained from DRS are 1.59, 1.39 and 1.79 eV for Zn0.75Ni0.25Fe2O4, NiFe2O4 and ZnFe2O4, respectively. The proposed mechanism, due to the DRS result, is a p-n junction. EDX results showed that the distribution of components is homogeneous, also confirming the mole ratio of 1:3 for Zn: Ni in ZnxNi1-xFe2O4. VSM results confirm that all of the photocatalysts have magnetic properties. The magnetic properties, crystallite size, and lattice parameters were systematically analyzed, revealing that Zn substitution reduces saturation magnetization while influencing microstructural features. Among the photocatalysts tested, Zn0.75Ni0.25Fe2O4 showed the highest MZ degradation efficiency, attributed to enhanced e−/h+ separation. An acceptable value of R2 (0.9816) for the quadratic model indicates good regression for the plot of predicted and experimental data. The highest degradation rate of metronidazole solution (86.4 %) was achieved under the following conditions: irradiation time: 70 min, pH: 5, metronidazole concentration: 5 mg/L, and dose of catalyst: 0.8 g/L.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100963"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145462998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Evolution of surface architectures in sol-gel spin coated multilayered ZnO thin films 溶胶-凝胶自旋涂覆多层ZnO薄膜表面结构的演变

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-11-17 DOI: 10.1016/j.chphi.2025.100974

Mahesh Malpani , Saikat Chattopadhyay , R.D.K. Misra , Kamakhya Prakash Misra

{"title":"Evolution of surface architectures in sol-gel spin coated multilayered ZnO thin films","authors":"Mahesh Malpani , Saikat Chattopadhyay , R.D.K. Misra , Kamakhya Prakash Misra","doi":"10.1016/j.chphi.2025.100974","DOIUrl":"10.1016/j.chphi.2025.100974","url":null,"abstract":"<div><div>Multilayered zinc oxide (ZnO) thin films were successfully deposited by spin coating technique on glass substrates. The number of layers were kept as 5, 10, 15, 20, 25, and 30 and their structural, morphological, elemental, and optical properties were studied. X-ray diffraction (XRD) study confirmed the wurtzite phase. The calculations revealed that the anion-cation bond length increased from 3.79 to 3.91 Å with number of layers. The crystallite size was ∼7–8 nm. Scanning electron microscope (SEM) indicated small cuboidal structure on the surface which led to clustered particles and eventually into a rod-like structures, with the increase in the number of layers. Energy-dispersive X-ray spectroscopy (EDX) revealed information on the elemental composition in which the content of Zn was increased monotonically from 5.5 to 9.9 at.% with increase in layers. Chemical bonds and functional groups were identified using Fourier transform infrared (FTIR) spectroscopy. Additionally, measurements of optical contact angles were performed to evaluate the ZnO thin films' surface wettability which showed that all the thin films were hydrophilic. Comprehensive evolution of properties indicated that spin-coated ZnO thin films can lead to variety of surface architectures, with potential for optical ability.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100974"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145619889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

DFT investigation of adsorptions of C2×2 and C2×4 (X=H, F) molecules on Ni-decorated Mg4O4 nanoclusters C2×2和C2×4 （X=H， F）分子在ni修饰的Mg4O4纳米簇上吸附的DFT研究

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-07-30 DOI: 10.1016/j.chphi.2025.100924

Shahin Abasaltian , Reza Ghiasi , Sahar Baniyaghoob

{"title":"DFT investigation of adsorptions of C2×2 and C2×4 (X=H, F) molecules on Ni-decorated Mg4O4 nanoclusters","authors":"Shahin Abasaltian , Reza Ghiasi , Sahar Baniyaghoob","doi":"10.1016/j.chphi.2025.100924","DOIUrl":"10.1016/j.chphi.2025.100924","url":null,"abstract":"<div><div>In this research, adsorptions of C2×2 and C2×4 (X = H, F) molecules on the Mg4O4 cluster and Ni-decorated Mg4O4 nanoclusters was inspected at the LC-ωPBE/6–311G(d,p) level of theory. Energetic aspects of adsorption process were exemplified. Structural parameters and polarity changes in the studied systems were explored. Molecular orbital analysis of the Mg4O4…C2×2, Mg4O4… C2×4, (X = H, F) and corresponding Ni-decorated molecules was provided. Charge decomposition analysis (CDA) was used to illustration charge transfer between two fragments. Characterizations of NiC bonds were studied by Quantum theory of atoms in molecules (QTAIM) analysis. Also, interactions between cluster with C2×2 and C2×4 molecules were explored with interacting quantum atoms (IQA) approach. Noncovalent interaction (NCI) analysis provided useful information about interactions between fragments.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100924"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144781005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced antibacterial and wound healing properties for Ni-Zn-Co ferrite nanoparticles 镍锌钴铁氧体纳米颗粒增强抗菌和伤口愈合性能

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-11-21 DOI: 10.1016/j.chphi.2025.100980

Dhivya Bharathi S , Radhakrishnan Vidya , Rajan Babu D

{"title":"Enhanced antibacterial and wound healing properties for Ni-Zn-Co ferrite nanoparticles","authors":"Dhivya Bharathi S , Radhakrishnan Vidya , Rajan Babu D","doi":"10.1016/j.chphi.2025.100980","DOIUrl":"10.1016/j.chphi.2025.100980","url":null,"abstract":"<div><div>The antimicrobial and wound healing properties of Zn0.2Co0.8-xNixFe2O4 (x = 0.2, 0.4, 0.6, and 0.8) nanoparticles, prepared through the sol-gel auto-combustion technique, were examined in this investigation. The physical and chemical characteristics of the obtained materials were studied using XRD, FTIR, XPS, FESEM, EDS, BET, and VSM. When tested for antibacterial action against both Gram-positive and Gram-negative bacteria, the nanoparticles exhibited inhibition against both types of bacteria within the 10 mg/mL dosage range. No significant antifungal activity was observed. The PANC1 and L929 cell line was used in the cytotoxicity test for the synthesized nanoparticles. Fibroblast migration and proliferation were confirmed using a wound healing assay, which involves artificial wound shrinking. For all biological experiments, Zn0.2Co0.8-xNixFe2O4 (x = 0.8) exhibited better responses than other Zn0.2Co0.8-xNixFe2O4 concentrations (x = 0.2, 0.4, and 0.6). These findings demonstrate that employing a combination of doping on the synthesized nanoparticles enhances their biological activity.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100980"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145619884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced solar energy harvest in dye-sensitized solar cells using silver-doped TiO2 Photoelectrodes via Spray Pyrolysis 通过喷雾热解方法利用掺杂银的TiO2光电极增强染料敏化太阳能电池的太阳能收获

IF 3.8

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-07-03 DOI: 10.1016/j.chphi.2025.100910

Piranave Sritharan , Meena Senthilnanthanan , Punniamoorthy Ravirajan , Dhayalan Velauthapillai , Gamaralalage Rajanya Asoka Kumara , Balraju Palanisamy

{"title":"Enhanced solar energy harvest in dye-sensitized solar cells using silver-doped TiO2 Photoelectrodes via Spray Pyrolysis","authors":"Piranave Sritharan , Meena Senthilnanthanan , Punniamoorthy Ravirajan , Dhayalan Velauthapillai , Gamaralalage Rajanya Asoka Kumara , Balraju Palanisamy","doi":"10.1016/j.chphi.2025.100910","DOIUrl":"10.1016/j.chphi.2025.100910","url":null,"abstract":"<div><div>This study focuses on doping TiO2 with trace amounts of Ag⁺ ions, employing spray pyrolysis to prepare the Ag-doped TiO2 photoelectrode for application in Dye-Sensitized Solar Cells (DSSCs). In this regard, Ag-doped TiO2 nanomaterials were initially synthesized from Titanium(IV) isopropoxide (TTIP) with varying concentrations of Silver nitrate (AgNO3). The structural and optical characterizations of the synthesized nanomaterials confirmed the presence of TiO2 in pure anatase phase and enhanced light absorption, respectively. The morphological characterization of Ag-doped TiO2 nanomaterials revealed spherical shaped particles. Subsequently, the DSSCs were fabricated using Ruthenium-based N719 dye and imidazolium iodide/ triiodide redox couple as the sensitizer and electrolyte, respectively. Photovoltaic performances were evaluated under simulated solar irradiation (100 mW cm−2, 1 sun, AM 1.5). The optimized device with 3 mmol % Ag-doped TiO2 photoelectrode exhibited PCE (η) of 8.32 %, which was about 13 % greater than the device with un-doped TiO2 (η = 7.35 %). The observed upsurge in PCE is due to the 10 % increase in short-circuit current density (JSC) value resulting from enhancement in visible light absorption which was confirmed by UV–Visible spectroscopic analysis. Moreover, an improved electron transport in the Ag-doped TiO2 based device was confirmed by electrochemical impedance spectroscopic study which is ascribed to the significant reduction in charge recombination. These findings demonstrate the potential of Ag-doped TiO2 for enhanced DSSC performance, offering a viable pathway for improving solar energy conversion efficiency.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100910"},"PeriodicalIF":3.8,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144588753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced optical and gamma-ray shielding behavior of Bi2O3-doped molybdenum iron borosilicate glasses 掺bi2o3钼铁硼硅酸盐玻璃的先进光学和伽马射线屏蔽性能

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-11-01 DOI: 10.1016/j.chphi.2025.100962

Asmae Mimouni , Dalal Abdullah Aloraini , Ateyyah M. AlBaradi , Kh.S. Shaaban

{"title":"Advanced optical and gamma-ray shielding behavior of Bi2O3-doped molybdenum iron borosilicate glasses","authors":"Asmae Mimouni , Dalal Abdullah Aloraini , Ateyyah M. AlBaradi , Kh.S. Shaaban","doi":"10.1016/j.chphi.2025.100962","DOIUrl":"10.1016/j.chphi.2025.100962","url":null,"abstract":"<div><div>Glasses with the structure 18SiO2–42B2O3–13MoO3–2Fe2O3-(25-x)Li2O-xBi2O3, where x=(0, 2, 4, 8, and 10 mol. %) were synthesized. The density (ρ) increased systematically from 2.88 to 3.69 g/cm3 with the rise in Bi2O3 content. Their optical absorption properties were systematically investigated. In addition, the effect of structural modifications within the glass network was analyzed in detail, revealing how these changes contribute to the enhancement of the optical performance of the prepared glasses. The red shift in the absorption edge, along with the increased proportion of (NBOs), is considered the primary cause for the reduction in the optical band gap. Calculations of the optical band gap revealed a decreasing trend with increasing Bi2O3 content, indicating an increase in structural disorder. In the studied glass samples, the elastic moduli exhibit a decreasing trend with increasing Bi2O3 concentration. The shielding parameters against radiation were assessed. Results showed that the half-value layer (HVL) and mean free path (MFP) decreased progressively. The higher Bi2O3 content is responsible for its superior shielding performance. These findings demonstrate that the samples are effective radiation shielding materials.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100962"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145462999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Revealing optical, mechanical and radiation shielding behavior of ZnO-PbO2-SiO2 Glasses 揭示ZnO-PbO2-SiO2玻璃的光学、机械和辐射屏蔽性能

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-10-06 DOI: 10.1016/j.chphi.2025.100949

M.I. Sayyed , J.S. Ashwajeet , M.N. Raghavendra , K.A. Mahmoud , Yasser Maghrbi

{"title":"Revealing optical, mechanical and radiation shielding behavior of ZnO-PbO2-SiO2 Glasses","authors":"M.I. Sayyed , J.S. Ashwajeet , M.N. Raghavendra , K.A. Mahmoud , Yasser Maghrbi","doi":"10.1016/j.chphi.2025.100949","DOIUrl":"10.1016/j.chphi.2025.100949","url":null,"abstract":"<div><div>A four zinc lead silicate glass series was fabricated for the optical and radiation shielding applications. To measure the prepared glasses' density, the Archimedes method was used, whereby the measurements showed that a 39–45 mol% PbO2 increase raises the prepared glasses' density from 5.699 to 6.106 g/cm3. Furthermore, the prepared glasses' absorption spectra were detected via a UV-visible spectrophotometer (UV-T-7200 model) within the 190–1100 nm spectral range. With increasing PbO₂ concentration, the energy band gap of the prepared glasses decreases, while the refractive index increases. Also, to investigate the prepared glasses' mechanical properties, the Makishima-Makinzie theory was applied. The investigation revealed that all the mechanical properties slightly decreased due to the increased concentration of PbO2. Additionally, across the 0.015–15 MeV energy range, Monte Carlo simulation was applied to evaluate the prepared glasses' radiation shielding properties. Due to the increase in PbO2 concentration, the evaluations depict the radiation shielding properties' enhancement. The 39–45 mol% PbO2 concentration increase raises the linear attenuation coefficient (LAC) through 9.074–10.168 cm–1 (at 0.08 MeV), 0.460–0.498 cm–1 (at 0.8 MeV), and 0.218–0.238 cm–1 (at 8 MeV). The LACs of the currently manufactured PbSi glasses are higher than those of commercial glasses, including RS 253, RS 253 G18, RS 323 G19, RS 360, and RS 520.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100949"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145412495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Experimental and numerical insights into Co-doped ZnS buffer layers for high-efficiency solar cells 高效太阳能电池共掺杂ZnS缓冲层的实验与数值研究

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-09-14 DOI: 10.1016/j.chphi.2025.100942

Abdelali Talbi, Yassine Khaaissa, Fadoua Mansouri, Outman El Khouja, Ahmed Rmili, Khalid Nouneh

引用次数: 0

Eco-friendly synthesis and photocatalytic application of rGO-MgO nanocomposites for eosin Y dye degradation rGO-MgO纳米复合材料降解伊红Y染料的生态合成及光催化应用

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-09-03 DOI: 10.1016/j.chphi.2025.100939

Nethra Kuruthukulangara , D. Thirumalai , I.V. Asharani

{"title":"Eco-friendly synthesis and photocatalytic application of rGO-MgO nanocomposites for eosin Y dye degradation","authors":"Nethra Kuruthukulangara , D. Thirumalai , I.V. Asharani","doi":"10.1016/j.chphi.2025.100939","DOIUrl":"10.1016/j.chphi.2025.100939","url":null,"abstract":"<div><div>Reduced graphene oxide-magnesium oxide nanocomposites (rGO-MgO NCs) were synthesized via a green and sustainable route using Saraca asoca leaf (Sa-leaf) extract as a natural reducing and capping agent. Graphene oxide, prepared using the modified Hummers method, was reduced and combined with MgO nanoparticles (MgO NPs) through a simple grinding technique. Structural and morphological characterizations confirmed the formation of a crystalline face-centered cubic MgO phase with nanorod and spherical morphologies uniformly distributed on rGO sheets. The nanocomposites exhibited an average particle size of 21.5 nm and a reduced band gap of 2.84 eV, enhancing charge separation and visible-light absorption. Under 500 W visible-light irradiation, the rGO-MgO NCs achieved 92.4% degradation of Eosin Y (EY) dye, following first-order kinetics, and demonstrated excellent stability and reusability across multiple cycles. Furthermore, ECOSAR-based toxicity predictions indicated that the degradation byproducts were environmentally benign. These findings highlight the potential of Sa-leaf-mediated rGO-MgO NCs as efficient, sustainable, and eco-friendly photocatalysts for wastewater remediation.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100939"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145026346","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Facile green synthesis of Co3O4 nanoparticles using turmeric extract: In vitro biomedical activities 使用姜黄提取物的Co3O4纳米颗粒的绿色合成：体外生物医学活性

IF 4.3

Chemical Physics Impact Pub Date : 2025-12-01 Epub Date: 2025-10-19 DOI: 10.1016/j.chphi.2025.100954

Mais Mazin Al-Hamdani , Basima A.A. Saleem , Mohammed Ihsan Majeed , Mohamed Ahmed , Helal F. Hetta , Mohammed S. Saddik , Stefan Bräse , Mostafa F. Al-Hakkani

{"title":"Facile green synthesis of Co3O4 nanoparticles using turmeric extract: In vitro biomedical activities","authors":"Mais Mazin Al-Hamdani , Basima A.A. Saleem , Mohammed Ihsan Majeed , Mohamed Ahmed , Helal F. Hetta , Mohammed S. Saddik , Stefan Bräse , Mostafa F. Al-Hakkani","doi":"10.1016/j.chphi.2025.100954","DOIUrl":"10.1016/j.chphi.2025.100954","url":null,"abstract":"<div><div>This research investigates the eco-friendly synthesis and comprehensive characterization of cobalt oxide nanoparticles (CoO<img>NPs) using turmeric ethanolic extract. Fourier transform infrared spectroscopy confirmed the presence of functional groups in the extract and their involvement in nanoparticle stabilization. Ultraviolet-visible spectroscopy revealed an absorption peak at 417 nm, with bandgap energies of 3.45 eV and 3.21 eV for direct and indirect transitions, respectively, as determined by Tauc's plot. X-ray diffraction analysis yielded an average crystallite size of 31.2 nm, while energy-dispersive X-ray spectroscopy verified the elemental composition. The nanoparticles displayed a zeta potential of -21.66 mV, and dynamic light scattering indicated a hydrodynamic diameter of 86.29 nm with a polydispersity index of 0.38. Transmission and scanning electron microscopy demonstrated an average particle size of 26.3 nm, featuring cubic structures and diverse surface morphologies. Antioxidant activity was evaluated using the DPPH assay, resulting in IC50 values of 3.82 mg/mL for the turmeric extract and 1.171 mg/mL for the CoO<img>NPs, compared to 0.42 mg/mL for BHT. The antibacterial efficacy of the CoO<img>NPs was assessed against Gram-positive Bacillus subtilis and Gram-negative Escherichia coli, with minimum inhibitory concentrations of 25.3 mg/L and 22.8 mg/L, respectively. Furthermore, the nanoparticles exhibited substantial anti-cancer effects, with IC50 values of 26.4 µg/mL against Caco-2 cells and 43.6 µg/mL against MCF-7 cells. This work advances green nanotechnology by integrating scientific innovation with environmental sustainability, thereby opening avenues for further research in materials science and biomedical applications.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"11 ","pages":"Article 100954"},"PeriodicalIF":4.3,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145358184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0