{"title":"二维石墨烯薄膜转移到悬浮Si/SiO2结构上的器件性能增强","authors":"Ajay Kumar , Prashant Kumar , Mohan Lal , Radhapiyari Laishram , J.S. Rawat , Amit Jain","doi":"10.1016/j.chphi.2025.100852","DOIUrl":null,"url":null,"abstract":"<div><div>A large-area (2′’ x 2′’) single layer graphene film is grown on a 25μm thick copper foil substrate via Chemical Vapor Deposition technique. We further establish the transfer of graphene film from the copper foil to suspended structures fabricated on Si/SiO<sub>2</sub> substrate via a wet etching process utilizing ammonium persulfate solution, effectively removing the copper foil while preserving the structural integrity and quality of the graphene film. Fabrication of suspended structures on the Si/SiO<sub>2</sub> substrate involves a 3-level photolithography process, ensuring precise control over structural design. This approach enabled the creation of suspended platforms with depth of ∼1 µm. Characterization studies involving Raman analysis, scanning electron micrograph and electrical measurements confirm the high quality and integrity of the transferred graphene film onto suspended structures fabricated on Si/SiO<sub>2</sub> substrate. We observed significant improvement in graphene quality over suspended structure in respect of sheet resistance (∼400 Ω/□), carrier mobility (∼2800 cm<sup>2</sup>/v-s), mechanical flexibility and overall device performance. The transfer characteristics of the suspended back-gate Field Effect Transistor exhibited a shift in the Dirac point from approximately −5 V to near 0 V. This enhancement effectively reduces substrate interactions and enhances the intrinsic electronic properties of the graphene channel. Overall, this method presents a viable approach for the scalable production of large-area graphene films and their transfer onto diverse substrates, opening avenues for the integration of graphene into advanced technological devices and systems particularly in micro and nano electromechanical systems.</div></div>","PeriodicalId":9758,"journal":{"name":"Chemical Physics Impact","volume":"10 ","pages":"Article 100852"},"PeriodicalIF":3.8000,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhanced device performance of 2D graphene film transferred onto suspended Si/SiO2 structures\",\"authors\":\"Ajay Kumar , Prashant Kumar , Mohan Lal , Radhapiyari Laishram , J.S. Rawat , Amit Jain\",\"doi\":\"10.1016/j.chphi.2025.100852\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A large-area (2′’ x 2′’) single layer graphene film is grown on a 25μm thick copper foil substrate via Chemical Vapor Deposition technique. We further establish the transfer of graphene film from the copper foil to suspended structures fabricated on Si/SiO<sub>2</sub> substrate via a wet etching process utilizing ammonium persulfate solution, effectively removing the copper foil while preserving the structural integrity and quality of the graphene film. Fabrication of suspended structures on the Si/SiO<sub>2</sub> substrate involves a 3-level photolithography process, ensuring precise control over structural design. This approach enabled the creation of suspended platforms with depth of ∼1 µm. Characterization studies involving Raman analysis, scanning electron micrograph and electrical measurements confirm the high quality and integrity of the transferred graphene film onto suspended structures fabricated on Si/SiO<sub>2</sub> substrate. We observed significant improvement in graphene quality over suspended structure in respect of sheet resistance (∼400 Ω/□), carrier mobility (∼2800 cm<sup>2</sup>/v-s), mechanical flexibility and overall device performance. The transfer characteristics of the suspended back-gate Field Effect Transistor exhibited a shift in the Dirac point from approximately −5 V to near 0 V. This enhancement effectively reduces substrate interactions and enhances the intrinsic electronic properties of the graphene channel. Overall, this method presents a viable approach for the scalable production of large-area graphene films and their transfer onto diverse substrates, opening avenues for the integration of graphene into advanced technological devices and systems particularly in micro and nano electromechanical systems.</div></div>\",\"PeriodicalId\":9758,\"journal\":{\"name\":\"Chemical Physics Impact\",\"volume\":\"10 \",\"pages\":\"Article 100852\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2025-02-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Physics Impact\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667022425000404\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics Impact","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667022425000404","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Enhanced device performance of 2D graphene film transferred onto suspended Si/SiO2 structures
A large-area (2′’ x 2′’) single layer graphene film is grown on a 25μm thick copper foil substrate via Chemical Vapor Deposition technique. We further establish the transfer of graphene film from the copper foil to suspended structures fabricated on Si/SiO2 substrate via a wet etching process utilizing ammonium persulfate solution, effectively removing the copper foil while preserving the structural integrity and quality of the graphene film. Fabrication of suspended structures on the Si/SiO2 substrate involves a 3-level photolithography process, ensuring precise control over structural design. This approach enabled the creation of suspended platforms with depth of ∼1 µm. Characterization studies involving Raman analysis, scanning electron micrograph and electrical measurements confirm the high quality and integrity of the transferred graphene film onto suspended structures fabricated on Si/SiO2 substrate. We observed significant improvement in graphene quality over suspended structure in respect of sheet resistance (∼400 Ω/□), carrier mobility (∼2800 cm2/v-s), mechanical flexibility and overall device performance. The transfer characteristics of the suspended back-gate Field Effect Transistor exhibited a shift in the Dirac point from approximately −5 V to near 0 V. This enhancement effectively reduces substrate interactions and enhances the intrinsic electronic properties of the graphene channel. Overall, this method presents a viable approach for the scalable production of large-area graphene films and their transfer onto diverse substrates, opening avenues for the integration of graphene into advanced technological devices and systems particularly in micro and nano electromechanical systems.