Nanoscale Horizons最新文献

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From structure prediction to catalyst design: 2D MoS3 as tunable platform for CO2 electroreduction. 从结构预测到催化剂设计:二维MoS3作为CO2电还原的可调平台。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-12 DOI: 10.1039/d6nh00098c
Huili Li, Chenxu Zhao, Jinrong Huo, Chaozheng He
{"title":"From structure prediction to catalyst design: 2D MoS<sub>3</sub> as tunable platform for CO<sub>2</sub> electroreduction.","authors":"Huili Li, Chenxu Zhao, Jinrong Huo, Chaozheng He","doi":"10.1039/d6nh00098c","DOIUrl":"10.1039/d6nh00098c","url":null,"abstract":"<p><p>Utilizing the advanced crystal structure prediction algorithm CBD-GM, this study reports the first prediction of a novel 2D MoS<sub>3</sub> configuration. The results demonstrate that the monolayer MoS<sub>3</sub> exhibits excellent structural and thermal stability, narrow-bandgap semiconductor behavior, high carrier mobility, and pronounced mechanical anisotropy, highlighting its potential for applications in flexible electronics. Building upon this foundation, we designed a series of single-atom catalysts by anchoring transition metal atoms at distinct sulfur coordination sites (S<sub>1</sub>, S<sub>2</sub>, S<sub>3</sub>) of the MoS<sub>3</sub> support. This work reveals that both the dopant element and its coordination site precisely regulate the catalytic activity and selectivity for the CO<sub>2</sub> reduction reaction (CO<sub>2</sub>RR). Theoretical screening identified three highly promising candidates: Sc<sub>S<sub>2</sub></sub>@MoS<sub>3</sub>, Sc<sub>S<sub>3</sub></sub>@MoS<sub>3</sub>, and Ni<sub>S<sub>3</sub></sub>@MoS<sub>3</sub>. Sc<sub>S<sub>2</sub></sub>@MoS<sub>3</sub> favors the formate pathway to HCOOH with a low limiting potential of -0.18 V. Sc<sub>S<sub>3</sub></sub>@MoS<sub>3</sub> exclusively produces CH<sub>3</sub>OH with a rate-determining step of *CHO → *OCHH (<i>U</i><sub>L</sub> = -0.58 V). Ni<sub>S<sub>3</sub></sub>@MoS<sub>3</sub> can generate both HCOOH (<i>U</i><sub>L</sub> = -0.55 V) and CH<sub>3</sub>OH (<i>U</i><sub>L</sub> = -0.72 V) under different potentials. Notably, Sc<sub>S<sub>3</sub></sub>@MoS<sub>3</sub> exhibits the lowest reaction energy for methanol formation. This study provides crucial theoretical guidance for developing efficient and tunable CO<sub>2</sub> electrocatalysts and expands the Mo-S material family by introducing a metastable but accessible 2D MoS<sub>3</sub> platform with unique coordination environments for single-atom catalysis, thereby broadening the application potential of 2D materials in energy conversion and environmental remediation.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":"2637-2653"},"PeriodicalIF":6.4,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148838587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ZnO-Pd nanobolts-based immunoanalytical detection of a pancreatic cancer biomarker and its software-assisted digital quantification. 基于ZnO-Pd纳米微球的胰腺癌生物标志物的免疫分析检测及其软件辅助数字定量。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-12 DOI: 10.1039/d6nh00197a
Akanksha Deshwal, Rajesh, Sang J Chung, Prashant Mishra, Ravi Mani Tripathi
{"title":"ZnO-Pd nanobolts-based immunoanalytical detection of a pancreatic cancer biomarker and its software-assisted digital quantification.","authors":"Akanksha Deshwal, Rajesh, Sang J Chung, Prashant Mishra, Ravi Mani Tripathi","doi":"10.1039/d6nh00197a","DOIUrl":"https://doi.org/10.1039/d6nh00197a","url":null,"abstract":"<p><p>Early and reliable detection of pancreatic cancer (PC) remains a formidable clinical challenge, largely owing to the limited sensitivity, operational unreliability, and enzyme dependence of existing carbohydrate antigen 19-9 (CA19-9) immunoassays. In this work, we determine for the first time that ZnO-Pd nanobolts show intrinsic oxidase-like activity. Furthermore, this attribute was used to fabricate a colorimetric immunoanalytical sensor based on nanozymes for the sensitive and specific detection of CA19-9, a biomarker for PC. In this research, immunoreagent optimization, smartphone-assisted signal analysis, and kinetic analysis of nanozyme catalytic activity were employed to enable highly sensitive detection of CA19-9. Enzyme-kinetic studies showed low Michaelis-Menten constants (<i>K</i><sub>M</sub>) of 0.99 mM, as well as high turnover numbers (<i>k</i><sub>cat</sub>) and catalytic efficiencies (<i>k</i><sub>cat</sub>/<i>K</i><sub>M</sub>) of 4.48 × 10<sup>-4</sup> s<sup>-1</sup> and 0.453 M<sup>-1</sup> s<sup>-1</sup>, respectively, indicating high substrate affinity. The optimized nanozyme was functionalized with Goat anti-mouse IgG (GAM IgG), thereby facilitating antigen recognition and signal transduction. The proposed immunoassay demonstrated high analytical sensitivity (LOD of 0.000159 U mL<sup>-1</sup> and LOQ of 0.000482 U mL<sup>-1</sup>) and exceptional selectivity even in complex biological matrices. Software-assisted signal processing enabled precise assessment of the limit of detection (LOD) of 0.000359 U mL<sup>-1</sup> and the limit of quantification (LOQ) of 0.00108 U mL<sup>-1</sup>. The practical utility of the fabricated immunoassay was further examined using human serum, with recovery rates ranging from 100.6% to 102%, indicating high accuracy and reproducibility. Furthermore, the successful digitalization of assay results into software-based readable data demonstrates the sensing approach's potential for portable, cost-effective, and point-of-care PC diagnostics.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":""},"PeriodicalIF":6.4,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149163990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid electrolyte of ionic liquid and functionalized nanofiller for energy storage: dynamic and thermodynamic properties under extreme temperature and pressure conditions. 离子液体和功能化纳米填料的储能混合电解质:极端温度和压力条件下的动力学和热力学性质。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-12 DOI: 10.1039/d6nh00170j
Soorya Koymeth, Marian Paluch, Riccardo Casalini, Aleksandra Nyga, Mateusz Dulski, Josh J Bailey, Pranav Sharda, Joanna Klimontko, Maciej Zubko, Zaneta Wojnarowska
{"title":"Hybrid electrolyte of ionic liquid and functionalized nanofiller for energy storage: dynamic and thermodynamic properties under extreme temperature and pressure conditions.","authors":"Soorya Koymeth, Marian Paluch, Riccardo Casalini, Aleksandra Nyga, Mateusz Dulski, Josh J Bailey, Pranav Sharda, Joanna Klimontko, Maciej Zubko, Zaneta Wojnarowska","doi":"10.1039/d6nh00170j","DOIUrl":"10.1039/d6nh00170j","url":null,"abstract":"<p><p>Hybrid electrolytes combining ionic liquids with nanoscale fillers offer a transformative route toward safe, high-performance energy storage; however, the lack of understanding of their charge transport over a broad range of temperature and pressure conditions limits their application. Herein, we address this issue by examining the structural, conducting, viscoelastic and thermodynamic properties of a model quasi-solid electrolyte composed of an ammonium ionic liquid and charged polyhedral oligomeric silsesquioxane (POSS) nanoparticles over an extended temperature (173-393 K) and pressure (0.1-600 MPa) range. We demonstrate that the rigid POSS scaffold creates excess free volume, reduces compressibility and thermal expansion, and introduces reversible shear-thinning viscoelasticity while maintaining efficient ion conduction. Furthermore, our high-pressure experiments reveal that ion dynamics is mostly thermally activated in this nano-hybrid electrolyte and satisfies the density-scaling concept, enabling accurate prediction of ionic conductivity over 12 decades across a wide <i>T</i>-<i>P</i> landscape. This work establishes a fundamental and predictive framework for designing next-generation nano-hybrid electrolytes for operation in extreme environments.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":"2602-2613"},"PeriodicalIF":6.4,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148756730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantum capacitance-induced transconductance anomalies in cryogenic quasi-ballistic transistors. 低温准弹道晶体管中量子电容诱导的跨导异常。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-12 DOI: 10.1039/d6nh00209a
Dokyoung Lee, Hyeonsik Ahn, Jusung Kim, Moon-Seok Kim, Sungho Kim
{"title":"Quantum capacitance-induced transconductance anomalies in cryogenic quasi-ballistic transistors.","authors":"Dokyoung Lee, Hyeonsik Ahn, Jusung Kim, Moon-Seok Kim, Sungho Kim","doi":"10.1039/d6nh00209a","DOIUrl":"10.1039/d6nh00209a","url":null,"abstract":"<p><p>Understanding the transconductance (<i>g</i><sub>m</sub>) at cryogenic temperature remains a major challenge in the physics-based modeling of nanoscale field-effect transistors. Although short-channel drain current (<i>I</i><sub>D</sub>)-gate voltage characteristics can often be described accurately within transport-based formalisms, the corresponding <i>g</i><sub>m</sub> commonly exhibits pronounced low-temperature anomalies that remain unexplained. Here, we investigate a 65 nm Si <i>n</i>-channel transistor measured from 250 K down to 12 K and show that a Landauer-consistent model provides an accurate quasi-ballistic transport baseline for the <i>I</i><sub>D</sub> across the full temperature range, but fails to reproduce the shoulder-like <i>g</i><sub>m</sub> feature that emerges at deep cryogenic temperature. We show that this residual discrepancy originates not from transport nonidealities but from quantum capacitance (<i>C</i><sub>q</sub>)-induced electrostatic renormalization of gate-induced charge modulation. By decomposing the <i>g</i><sub>m</sub> into transport and charge-response contributions, and introducing a gate-control factor governed primarily by the <i>C</i><sub>q</sub>, we derive a compact framework in which the corrected <i>g</i><sub>m</sub> consists of renormalized baseline and differential electrostatic terms. A two-crossover parameterization of <i>C</i><sub>q</sub> in the effective gate-overdrive domain enables simultaneous and self-consistent reproduction of both the <i>I</i><sub>D</sub> and <i>g</i><sub>m</sub>, including the cryogenic shoulder. These results identify anomalous cryogenic <i>g</i><sub>m</sub> as a <i>C</i><sub>q</sub>-induced signature of rapidly varying gate-to-charge coupling in quasi-ballistic transistors.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":"2548-2559"},"PeriodicalIF":6.4,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanoscale Horizons Emerging Investigator Series: Dr Jake McClements, Newcastle University, UK. 纳米尺度地平线新兴研究者系列:杰克·麦克克莱门茨博士,纽卡斯尔大学,英国。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-12 DOI: 10.1039/d6nh90036d
{"title":"<i>Nanoscale Horizons</i> Emerging Investigator Series: Dr Jake McClements, Newcastle University, UK.","authors":"","doi":"10.1039/d6nh90036d","DOIUrl":"10.1039/d6nh90036d","url":null,"abstract":"<p><p>Our Emerging Investigator Series features exceptional work by early-career nanoscience and nanotechnology researchers. Read Jake McClements's Emerging Investigator Series article 'Unlocking interstitial fluid for acute coronary syndrome diagnosis: ultrasensitive troponin I detection using imprinted polymer nanoparticles' (https://doi.org/10.1039/D5NH00441A) and read more about him in the interview below.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":"2476-2477"},"PeriodicalIF":6.4,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148628807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymer-derived bifunctional anchoring coatings for mechanically resilient Si-based nanocomposite anodes. 机械弹性硅基纳米复合阳极用聚合物衍生双功能锚定涂层。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-12 DOI: 10.1039/d6nh00243a
Yanzhe Yang, Weiang Yin, Jing Wang, Zhiguang Zhao, Hui Hu, Yifan Ding, Jingze Guo, Zhao Lv, Yufeng Luo, Guoqiang Tan
{"title":"Polymer-derived bifunctional anchoring coatings for mechanically resilient Si-based nanocomposite anodes.","authors":"Yanzhe Yang, Weiang Yin, Jing Wang, Zhiguang Zhao, Hui Hu, Yifan Ding, Jingze Guo, Zhao Lv, Yufeng Luo, Guoqiang Tan","doi":"10.1039/d6nh00243a","DOIUrl":"10.1039/d6nh00243a","url":null,"abstract":"<p><p>Enhancing electrical conductivity and structural stability of Si-based anodes is crucial to attaining efficient and stable capacity output, promoting their practical applications. Here, we developed a polymer-derived bifunctional coating of nano-Si, which simultaneously provides conductive networks and elastic encapsulation to facilitate electron/ion transport and accommodate Si volume expansion during repeated lithiation/delithiation. A covalent bonding SiOC coating was firstly build onto nano-Si by ball-milling micro-Si with polyvinyl alcohol (PVA), then a cyclized-polyacrylonitrile (cPAN) coating was wrapped onto the above composite through low-temperature pyrolysis of PAN, forming polymer-derived anchoring coatings of nano-Si. The covalent SiOC anchoring layer serves as a bridge for fast electrical conduction and efficient stress buffer, and the cyclized-PAN conformal coating further improves electrical conductivity and mechanical resilience of the whole nanostructure. The as-prepared nanocomposite exhibits excellent electrical and mechanical properties, enabling outstanding electrochemical performance in Li-ion batteries. It exhibits a high initial capacity of 3477 mAh g<sup>-1</sup> and retains 1660 mAh g<sup>-1</sup> after 300 cycles at 1 A g<sup>-1</sup>. The graphite-Si/SiOC@cPAN//NCM811 full-cell exhibited a high initial capacity of 180.6 mAh g<sup>-1</sup> and 89% capacity retention after 300 cycles at 1C. This work provides a facile and scalable way to fabricate high-performance Si-based anode materials for high-energy-density Li-ion batteries.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":"2582-2592"},"PeriodicalIF":6.4,"publicationDate":"2026-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148862712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Label-free Nb4C3, Mo2Ti2C3, and Ta4C3 MXenes reprogram monocyte and macrophage activation toward an anti-inflammatory state. 无标记的Nb4C3、Mo2Ti2C3和Ta4C3 MXenes重编程单核细胞和巨噬细胞激活,使其进入抗炎状态。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-07 DOI: 10.1039/d6nh00130k
Giorgia Longo, Linda Giro, Recep Uyar, Benjamin Chacon, Christopher E Shuck, Laura Fusco, Adil Ijaz, Natalya Resto-Trujillo, Mohammad Oliaeimotlagh, Amir Khan, Martina Zoccheddu, Valentina Palmieri, Acelya Yilmazer, Martina Pigazzi, Yury Gogotsi, Lucia Gemma Delogu, Klaus Ley, Marco Orecchioni
{"title":"Label-free Nb<sub>4</sub>C<sub>3</sub>, Mo<sub>2</sub>Ti<sub>2</sub>C<sub>3</sub>, and Ta<sub>4</sub>C<sub>3</sub> MXenes reprogram monocyte and macrophage activation toward an anti-inflammatory state.","authors":"Giorgia Longo, Linda Giro, Recep Uyar, Benjamin Chacon, Christopher E Shuck, Laura Fusco, Adil Ijaz, Natalya Resto-Trujillo, Mohammad Oliaeimotlagh, Amir Khan, Martina Zoccheddu, Valentina Palmieri, Acelya Yilmazer, Martina Pigazzi, Yury Gogotsi, Lucia Gemma Delogu, Klaus Ley, Marco Orecchioni","doi":"10.1039/d6nh00130k","DOIUrl":"10.1039/d6nh00130k","url":null,"abstract":"<p><p>Macrophages are central effectors of innate immunity whose plasticity supports both inflammation and resolution. However, their dysregulated activation underlies many inflammatory, infectious, and degenerative diseases. Here, we show that three two-dimensional MXene nanomaterials, Nb<sub>4</sub>C<sub>3</sub>, Mo<sub>2</sub>Ti<sub>2</sub>C<sub>3</sub>, and Ta<sub>4</sub>C<sub>3</sub>, are efficiently internalized by monocytes without compromising viability while reprogramming their activation and differentiation toward an anti-inflammatory macrophage state. Bulk RNA sequencing of murine monocytes treated with each MXene reveals a convergent transcriptional signature characterized by downregulation of proinflammatory genes (<i>e.g.</i>, <i>Cxcl9</i>, <i>Cxcl10</i>, <i>Ccl24</i>, <i>Il1b</i>, and <i>Il18</i>), downregulation of <i>Ccr2</i>, and consistent upregulation of genes like <i>Cd28</i> and <i>Bhlhe41</i> across MXene treatments. At the protein level, secretion of CXCL10 and CCL24 is significantly reduced. Following early exposure of bone marrow precursors, differentiated macrophage cultures contained a larger CD86<sup>-</sup>CD206<sup>-</sup> fraction, fewer CD86<sup>+</sup> and CD206<sup>+</sup> cells, and reduced basal and LPS-induced activation, consistent with a less polarized, low-activation phenotype. Single-cell mass cytometry (CyTOF) enabled simultaneous immune profiling and label-free detection of MXene-associated elemental signals in peritoneal macrophage populations. In a thioglycolate-induced peritonitis model, MXene co-administration partially attenuated inflammation-associated changes in macrophage subset distribution. These findings establish MXenes as traceable immunoregulatory nanomaterials, enabling simultaneous control and tracking of macrophage responses <i>in vivo</i>. This work introduces a new nanoscale concept of compositionally encoded intrinsically traceable immunomodulatory nanomaterials that couple immune regulation and single-cell tracking even without surface labelling or drug loading.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":""},"PeriodicalIF":6.4,"publicationDate":"2026-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC13647253/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149134143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sharpening the cut: physical origins of rejection-curve broadening and routes to precision ultrafiltration. 锐化切割:拒绝曲线展宽的物理起源和精密超滤的途径。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-10-05 DOI: 10.1039/d6nh00362a
Jamila G Eatman, Chaoqiuyu Wang, Paul F Nealey, Seth B Darling
{"title":"Sharpening the cut: physical origins of rejection-curve broadening and routes to precision ultrafiltration.","authors":"Jamila G Eatman, Chaoqiuyu Wang, Paul F Nealey, Seth B Darling","doi":"10.1039/d6nh00362a","DOIUrl":"https://doi.org/10.1039/d6nh00362a","url":null,"abstract":"<p><p>Sectors that require precise separation between solutes of comparable size often rely on ultrafiltration (UF) and loose nanofiltration (LNF) for a low-cost, scalable, selective separation. However, solute separations in this regime have stubbornly exhibited broad rejection curves where solutes with dimensions substantially smaller than the nominal pore size are rejected. The widened profile of these curves results from three distinct mechanisms. Pore-size heterogeneity convolves the single-pore response with a broad size distribution, and because Hagen-Poiseuille flow scales as the fourth power of radius, the largest pores dominate the permeate and disproportionately leak oversized solutes. Confined (hindered) transport leads to intrapore hydrodynamics, slowing a solute relative to the background solvent velocity and effectively rejecting solutes that would intuitively pass through based on size exclusion alone. Finally, the pore array presents only a limited open area to an approaching solute; under single-pass operation, a solute that does not encounter a pore mouth is recorded as rejected regardless of its size. Despite these challenges in achieving sharp separations, no fundamental phenomena preclude much narrower rejection curves in principle. Advancing toward an ideal \"step function\" rejection profile requires a systematic dissection of each broadening mechanism and a scaffolded approach where geometric, intrapore, and process architecture might collectively enable unprecedented precision in practical size-selective separations.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":""},"PeriodicalIF":6.4,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149101136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visualizing energy transfer across a hexagonal Cs4PbBr6 microdisk using single-particle spectroscopy. 利用单粒子光谱学可视化六边形Cs4PbBr6微磁盘上的能量传递。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-09-30 DOI: 10.1039/d6nh00287k
Soumik De, Mrinal Kanti Panda, Subhadip Ghosh
{"title":"Visualizing energy transfer across a hexagonal Cs<sub>4</sub>PbBr<sub>6</sub> microdisk using single-particle spectroscopy.","authors":"Soumik De, Mrinal Kanti Panda, Subhadip Ghosh","doi":"10.1039/d6nh00287k","DOIUrl":"https://doi.org/10.1039/d6nh00287k","url":null,"abstract":"<p><p>Micron-scale hexagonal Cs<sub>4</sub>PbBr<sub>6</sub> perovskite microdisks (MDs), comprising a zero-dimensional phase, act as efficient energy donors when interfaced with the organic dye 1,1'-dioctadecyl-3,3,3',3'-tetramethylindocarbocyanine-perchlorate (DiIC<sub>18</sub>). Upon dye binding and selective excitation of the MDs, efficient singlet energy transfer (ET) occurs, as evidenced by the quenching of MD photoluminescence (PL), enhanced dye emission, and the emergence of an ET-induced rise component in the dye lifetime profile. Single-particle measurements under donor-selective excitation show strong ET-induced donor-acceptor PL anticorrelation, marked by a pronounced zero-delay dip [<i>g</i><sup>2</sup>(0)] in the antibunching cross-correlation. Additional evidence for ET comes from single-particle PL trajectory analysis showing strong temporal correlation between donor and acceptor signals, and from simultaneous donor/acceptor-channel imaging under donor-only excitation, where spatially colocalized MD images confirm ET-mediated excitation of dye molecules distributed all over the MDs. Solution-phase ensemble measurements demonstrate relatively high ET efficiency (>50%) even at low bulk dye concentrations (∼1 µM). Spatially-resolved analysis further reveals ∼55% higher ET efficiency at the MD core compared to the edges, indicating preferential dye accumulation within the cavities located mostly in the core region. These results demonstrate that Cs<sub>4</sub>PbBr<sub>6</sub> MDs serve as efficient ET platforms with tunable ET efficiency, providing promising potential for applications in photocatalysis, sensing, and light-harvesting technologies.</p>","PeriodicalId":93,"journal":{"name":"Nanoscale Horizons","volume":" ","pages":""},"PeriodicalIF":6.4,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149078942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrospinning-based architectural engineering of multi-layered fibrous membranes with spatially defined wettability for solar desalination. 基于电纺丝的多层纤维膜建筑工程,具有空间定义的润湿性,用于太阳能脱盐。
IF 6.4 2区 材料科学
Nanoscale Horizons Pub Date : 2026-09-22 DOI: 10.1039/d6nh00279j
Dianming Li, Chuang Cheng, Yanxia Luo, Xi Yao, Libang Feng
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