Bhart Kumar, Kamalesh Tripathy, Mitradip Bhattacharjee and Sanjit Konar
{"title":"Spin crossover-driven thermochromic temperature sensor for monitoring heat transfer via image analysis†","authors":"Bhart Kumar, Kamalesh Tripathy, Mitradip Bhattacharjee and Sanjit Konar","doi":"10.1039/D5TC01390A","DOIUrl":"https://doi.org/10.1039/D5TC01390A","url":null,"abstract":"<p >The thermochromic behaviour of spin crossover complexes is desirable for noninvasive thermometry technologies. In this work, we have developed an easy-to-use flexible temperature sensor based on color change accompanying the spin state switching. The sensor consists of an SCO complex, {Fe(Quin)<small><sub>2</sub></small>[Pt(CN)<small><sub>4</sub></small>]} (Quin = quinazoline), embedded in a transparent PDMS substrate using the mould casting method. The decomposition of the colors into individual RGB channels using image analysis provides a straightforward and accurate method for estimating temperature. The qualitative performance trials of the sensor demonstrate its versatility across various applications, including (a) heat transfer monitoring, (b) temperature mapping, and (c) hotspot detection. These trials establish the sensor's ability to operate effectively in a wide range of real-life scenarios.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 25","pages":" 12830-12836"},"PeriodicalIF":5.7,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc01390a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guang-Cheng Zhang, Jian-Qing Dai, Jin Yuan, Xin-Jian Zhu, Hao-Nan Liu and Cai-Dong Gu
{"title":"Phase transition-driven modulation of ferroelectricity and the photovoltaic effect in sol–gel-derived BiFeO3-based films†","authors":"Guang-Cheng Zhang, Jian-Qing Dai, Jin Yuan, Xin-Jian Zhu, Hao-Nan Liu and Cai-Dong Gu","doi":"10.1039/D5TC01118C","DOIUrl":"https://doi.org/10.1039/D5TC01118C","url":null,"abstract":"<p >BiFeO<small><sub>3</sub></small> films have attracted much attention because of their high polarization and relatively narrow bandgap. However, major challenges such as low remanent polarization and photovoltaic output have hindered their practical applications and further development. Here, enhanced ferroelectric polarization and photocurrent in Pt/Bi<small><sub>1−<em>x</em></sub></small>Pr<small><sub><em>x</em></sub></small>Fe<small><sub>0.95</sub></small>Cr<small><sub>0.05</sub></small>O<small><sub>3</sub></small>/FTO devices were achieved by Pr and Cr co-doped BiFeO<small><sub>3</sub></small> films. X-ray diffraction (XRD) and Raman spectroscopy analyses indicate that Bi<small><sub>1−<em>x</em></sub></small>Pr<small><sub><em>x</em></sub></small>Fe<small><sub>0.95</sub></small>Cr<small><sub>0.05</sub></small>O<small><sub>3</sub></small> films have a phase structure with coexisting rhombic (<em>R</em>3<em>c</em>) and tetragonal (<em>P</em>4<em>mm</em>) phases. By controlling the doping element content, dense and uniform films with few chemical defects were obtained. Notably, at the Pr doping level of 15%, a <em>P</em><small><sub>max</sub></small> of 137.1 μC cm<small><sup>−2</sup></small> and a <em>P</em><small><sub>r</sub></small> of 135.8 μC cm<small><sup>−2</sup></small> were achieved. The short-circuit current density (<em>J</em><small><sub>SC</sub></small>) and open-circuit voltage (<em>V</em><small><sub>OC</sub></small>) are −0.12 mA cm<small><sup>−2</sup></small> and 63.9 mV, respectively, under LED white light illumination. This work provides valuable information for the design and development of next-generation memory and photovoltaic devices.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 25","pages":" 12855-12869"},"PeriodicalIF":5.7,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Polarity from the bottom up: a computational framework for predicting spontaneous polar order","authors":"Jordan Hobbs, Calum J. Gibb and Richard J. Mandle","doi":"10.1039/D5TC01641J","DOIUrl":"https://doi.org/10.1039/D5TC01641J","url":null,"abstract":"<p >So-called polar liquid crystals possess spontaneous long-range mutual orientation of their electric dipole moments, conferring bulk polarity to fluid phases of matter. The combination of polarity and fluidity leads to complex phase behaviour, and rich new physics, yet the limited understanding around how specific molecular features generate long-range polar ordering in a fluid is a hindrance to the development of new materials. In this work, we introduce a computational framework that probes the bimolecular potential energy landscape of candidate molecules, enabling us to dissect the role of directional intermolecular interactions in establishing polar order. In closely related families of materials we find conflicting preferences for (anti)parallel ordering which can be accounted for by specific interactions between molecules. Thus, our results allow us to argue that the presence (or absence) of polar order is a product of specific molecular features and strong directional intermolecular interactions rather than being simply a product of dipole–dipole forces. The design principles established can be leveraged to developing new polar liquid crystalline materials.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 26","pages":" 13367-13375"},"PeriodicalIF":5.7,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc01641j?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144550789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jorge Labella, Elisa López-Serrano, Jorge Labrador-Santiago, Joaquín Barberá, César L. Folcia, Teresa Sierra and Tomás Torres
{"title":"Tuning the liquid crystal behavior of subphthalocyanines: effects of substitution, chirality, and hydrogen bonding†","authors":"Jorge Labella, Elisa López-Serrano, Jorge Labrador-Santiago, Joaquín Barberá, César L. Folcia, Teresa Sierra and Tomás Torres","doi":"10.1039/D5TC01417D","DOIUrl":"https://doi.org/10.1039/D5TC01417D","url":null,"abstract":"<p >Bowl-shaped aromatics that self-assemble into columnar liquid crystals (LCs) are key components for developing polarized semiconductors. However, progress in this field has been sluggish, as the limited set of available π-conjugated curved scaffolds has left structure–property relationships poorly understood. Herein the role that substitution pattern, substituent nature, and chirality play in the LC columnar organization of subphthalocyanines (SubPcs) is explored. Remarkably, it is revealed that enantiopure SubPcs exhibit a reduced tendency to form LC phases compared to their racemic counterparts, whereas higher substitution density increases flexibility within the columns, compromising coaxial alignment. Moreover, we find that the use of conformationally flexible, π-extended peripheral substituents enables efficient π–π stacking, and that the incorporation of hydrogen-bonding amide groups leads to highly stable mesophases with elevated melting points, although the mesophase remains at room temperature after thermal treatment. These trends are further rationalized through theoretical modeling. Overall, this work provides valuable synthetic and design guidelines for advancing bowl-shaped aromatics toward next-generation functional columnar liquid crystals.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 26","pages":" 13184-13189"},"PeriodicalIF":5.7,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc01417d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144550798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sampathkumar Prakasam, Giribabu Krishnan and Suresh Chinnathambi
{"title":"An oxygen-deficient tin oxide-modified electrode for nanomolar detection of chloramphenicol†","authors":"Sampathkumar Prakasam, Giribabu Krishnan and Suresh Chinnathambi","doi":"10.1039/D5TC01237F","DOIUrl":"https://doi.org/10.1039/D5TC01237F","url":null,"abstract":"<p >Chloramphenicol (CPL) is a broad-spectrum antibiotic belonging to the class of antimicrobials. The European Union and other countries have restricted the use of CPL in animal husbandry due to concerns about antibiotic resistance. Hence, monitoring CPL in animal food and environmental water samples is highly essential. In this context, we developed a low-cost sensing matrix of oxygen-deficient tin oxide (DSnO<small><sub>2</sub></small>) nanoparticles to determine CPL. The existence of oxygen deficiency was confirmed using various physicochemical characterization techniques. Electrochemical studies were performed by different voltammetry techniques, such as CV, LSV, and DPV, for CPL detection using DSnO<small><sub>2</sub></small>/GCE. The voltammetry results deduce that under optimal conditions, DSnO<small><sub>2</sub></small> can readily interact with the nitro group of the CPL molecule, which increases the sensitivity towards CPL detection. The designed sensor showed a wide linear range of 0.1–35 μM with an LOD value of 0.094 μM. The interference study results reveal that the proposed material exhibits good selectivity towards CPL even in the presence of higher concentrations of interfering species. The proposed DSnO<small><sub>2</sub></small> matrix has been successfully utilized for real sample analysis, such as water, milk, and honey samples, with acceptable recoveries. These results closely matched with the conventional high-performance liquid chromatography data, signifying its feasibility for real-time monitoring.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 25","pages":" 12911-12921"},"PeriodicalIF":5.7,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sijia Chang, Jiaying Mo, Beizhe Chang, Yiduo Huang, Lei Li, Zihong Zhao, Jiaheng Bi, Xiaozheng Ji, Ruirui Li, Zuankai Wang and Jijun Xiong
{"title":"Design of moisturizing and frost-resistant ionic hydrogels for multimodal sensing through water-stabilizing effects†","authors":"Sijia Chang, Jiaying Mo, Beizhe Chang, Yiduo Huang, Lei Li, Zihong Zhao, Jiaheng Bi, Xiaozheng Ji, Ruirui Li, Zuankai Wang and Jijun Xiong","doi":"10.1039/D5TC00805K","DOIUrl":"https://doi.org/10.1039/D5TC00805K","url":null,"abstract":"<p >Flexible hydrogel-based electronics have gained considerable attention in soft robotics, healthcare management, and electronic skins. However, engineering ionic hydrogel-based sensors capable of simultaneously detecting temperature and humidity is challenging because there is insufficient utilization of dynamic responses of the water matrix within the polymer network to these stimuli. Herein, we present a versatile moisturizing and frost-resistant ionic (MFI) hydrogel that exhibits multimodal sensing of strain, temperature, and humidity. This was achieved by designing a compact hydrogel skeleton that enables precise regulation of water states, such as free and bound water content, through dynamic ion–water interactions. The MFI hydrogel demonstrates impressive mechanical robustness with a toughness of 2.41 MJ m<small><sup>−3</sup></small> by regulating dynamic crosslinks for efficient energy dissipation. Distinct from its counterparts, the MFI hydrogel-based sensor demonstrates multimodal responsiveness by leveraging hydratable ions to stabilize water molecules. This water-stabilizing strategy enables excellent sensing performance, including a wide response range of 0–1300%, good strain linearity (>0.993), and a superior thermal sensitivity of 1.629%/°C with broad temperature (−60 to 80 °C) and humidity (25–70% RH) ranges for detection. Therefore, MFI hydrogels can serve as wearable strain sensors to accurately capture physiological signals such as body temperature, respiration, and pulse. Additionally, they can function as remote-control units for directing vehicle motion paths and vehicle navigation, paving fresh avenues for advanced artificial skins in next-generation smart electronics.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 25","pages":" 12922-12933"},"PeriodicalIF":5.7,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Minji Kim, Gergely Tarsoly, Dongyub Kwon and Seungmoon Pyo
{"title":"Interfacial spreading for rapid formation of uniform gate dielectric layers on flat and curved substrates for organic devices†","authors":"Minji Kim, Gergely Tarsoly, Dongyub Kwon and Seungmoon Pyo","doi":"10.1039/D5TC01546D","DOIUrl":"https://doi.org/10.1039/D5TC01546D","url":null,"abstract":"<p >Spin coating represents a mainstream method for depositing polymer gate dielectric layers in organic electronic devices. However, it encounters various challenges, including significant material waste, thickness variations from the center to edge of the substrate due to gradual changes in the centrifugal force, and substrate limitations. To address these drawbacks, this paper proposes an interfacial-spreading method based on the Marangoni effect, aimed at achieving highly uniform gate dielectrics on both flat and curved substrates. Using only ∼11 μL of the precursor solution, crosslinked poly(4-vinylphenol) (CL-PVP) films were successfully fabricated. The prepared films exhibited a thickness coefficient of variation of 0.04, four times lower than that of spin-coated films (0.17). Additionally, the CL-PVP gate dielectric could be mechanically patterned. The interfacial-spreading method minimized thickness variations and reduced material consumption by approximately tenfold in relation to spin coating. Organic-semiconductor-based transistors fabricated using the interfacial-spread CL-PVP gate dielectrics demonstrated performance comparable with those prepared using spin-coated films. Furthermore, a complementary-type inverter was fabricated to validate the functionality of the prepared films in electronic circuits. The CL-PVP gate dielectric could be successfully deposited on curved substrates (radius of curvature of up to 7.5 mm), displaying a thickness nearly identical to that on flat substrates and comparable with that on spin-coated films. Overall, the interfacial-spreading method represents a promising low-waste, and substrate-flexible alternative to spin coating for polymer gate dielectric formation, with potential adaptability to various polymer solutions.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 26","pages":" 13206-13213"},"PeriodicalIF":5.7,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144550802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qinhao Shi, Yijie Nai, Siqing He, Yitong Ji, Weikun Chen, Wei Liu, Wenchao Huang, Jun Yuan and Yingping Zou
{"title":"Effects of the number of methoxy groups in the thiophene π-bridges on the photovoltaic performance of the A–π–A type quasi-macromolecular acceptors†","authors":"Qinhao Shi, Yijie Nai, Siqing He, Yitong Ji, Weikun Chen, Wei Liu, Wenchao Huang, Jun Yuan and Yingping Zou","doi":"10.1039/D5TC01693B","DOIUrl":"https://doi.org/10.1039/D5TC01693B","url":null,"abstract":"<p > <strong>A</strong>–π–<strong>A</strong> type quasi-macromolecular (QM) acceptors have garnered significant research attention owing to their well-defined structural characteristics and excellent long-term stability. The π-bridge, serving as the core structural motif, plays a critical role in determining both the optoelectronic properties of the acceptor and the overall performance of the device. This work proposes a strategy of introducing methoxy groups into thiophene π-bridges to improve molecular planarity through non-covalent interactions, while leveraging its electron-donating capacity to enhance the open-circuit voltage (<em>V</em><small><sub>OC</sub></small>) and minimize voltage losses in devices, ultimately achieving excellent photovoltaic performance. Three <strong>A</strong>–π–<strong>A</strong> type QM acceptors, QM-T, QM-OT and QM-DOT were constructed by varying the number of methoxy groups in the thiophene π-bridge. Theoretical calculations and experiments revealed distinct geometry and structural features among the three molecules. Notably, QM-OT, featuring a 3-methoxythiophene π-bridge, showed optimal molecular planarity, which facilitated favorable π–π stacking and demonstrated superior compatibility with the polymer donor PM6. Therefore, the PM6:QM-OT-based active layer formed a nanoscale morphology with optimal phase separation, effectively mitigating voltage and charge recombination losses while promoting efficient exciton dissociation and charge transport. As a result, the PM6:QM-OT-based device achieved an impressive power conversion efficiency (PCE) of 18.15% with the highest <em>V</em><small><sub>OC</sub></small>, short-circuit current density (<em>J</em><small><sub>SC</sub></small>) and fill factor (FF). This work provides some guidance for further improving the performance of organic solar cells.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 25","pages":" 12699-12706"},"PeriodicalIF":5.7,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492508","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qiaoling Tian, Xuanyu Shan, Jingyao Bian, Yankun Cheng, Jiahui Zheng, Zhongqiang Wang, Xiaoning Zhao, Haiyang Xu and Yichun Liu
{"title":"Metal oxide-based resistive switching memristors for neuromorphic computing","authors":"Qiaoling Tian, Xuanyu Shan, Jingyao Bian, Yankun Cheng, Jiahui Zheng, Zhongqiang Wang, Xiaoning Zhao, Haiyang Xu and Yichun Liu","doi":"10.1039/D5TC01467K","DOIUrl":"https://doi.org/10.1039/D5TC01467K","url":null,"abstract":"<p >Brain-inspired neuromorphic computing has gained great interest considering its advantages of massive parallelism and high energy efficiency. Metal oxide-based resistive switching memristors are emerging as promising nanodevices for the hardware implementation of neuromorphic computing owing to their structural and functional resemblance to their biological counterparts and excellent compatibility with the advanced CMOS technique. In this article, we review the recent progress in metal oxide-based memristors and their application in neuromorphic computing. First, metal oxide-based memristive devices with different structural features are summarized, namely, two-terminal and three-terminal devices. Furthermore, various memristive mechanisms are systematically discussed, such as the formation of conductive filaments, Mott transition, and ferroelectric polarization. We examine the applications of different forms of memristive devices in artificial intelligence, such as electrical and optoelectronic synapses and neurons, and neuromorphic perception systems. Finally, we discuss the challenges and prospects of materials, devices, and integrations in this rapidly progressing field of research.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 24","pages":" 12046-12065"},"PeriodicalIF":5.7,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144323288","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Surface plasmon resonance modulation toward efficient transparent perovskite light-emitting diodes†","authors":"Zi-Yi Jin, Qi Sun, Wei He, Shuang-Qiao Sun, Guang-Li Li, Yue-Min Xie and Man-Keung Fung","doi":"10.1039/D5TC01216C","DOIUrl":"https://doi.org/10.1039/D5TC01216C","url":null,"abstract":"<p >Considerable progress has been achieved in perovskite light-emitting diodes (PeLEDs) in terms of efficiency and stability. However, transparent perovskite light-emitting diodes (TPeLEDs), which are crucial for high-end display applications, suffer from compromised device performance due to various photon loss channels, particularly the surface plasmon polariton (SPP) at the organic functional layer/transparent metal electrode interface. Herein, high-refractive-index capping layers (CPLs) and self-assembled silver nanoparticles (AgNPs) are adopted as light outcoupling layers to enhance the light outcoupling efficiency of TPeLEDs. By optimizing the CPL thickness, the transmittance and SPP loss of TPeLEDs can be effectively modulated. Moreover, by carefully modulating the vacuum deposition conditions, the size and distribution of AgNPs can be optimized, resulting in further reduction in SPP loss in the devices. As a result, high-performance green TPeLEDs with an average transmittance of over 66% in the visible light range are achieved, alongside a record total external quantum efficiency (EQE<small><sub>total</sub></small>) of 18.6%, with bottom and top EQE values of 11.1% and 7.5%, respectively. Moreover, the incorporation of AgNPs promotes a nearly 7-fold increase in device lifetime, which further illustrates the advantages of utilizing AgNPs for fabricating high-performance TPeLEDs.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 25","pages":" 13054-13060"},"PeriodicalIF":5.7,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144492537","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}