Journal of Materials Chemistry C最新文献

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High-performance bifunctional near-infrared diode enabled by intentional manipulation of energy transfer and carrier injection with a hetero-active-layer†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-20 DOI: 10.1039/D5TC00014A
Fanghao Ye, Guoliang Zhuang, Ting Zheng, Xi Lan, Junzi Li, Zhipeng Feng, Hangyu He, Siyang Liu, Ming Wang, Tingchao He, Ping Xu and Guijun Li
{"title":"High-performance bifunctional near-infrared diode enabled by intentional manipulation of energy transfer and carrier injection with a hetero-active-layer†","authors":"Fanghao Ye, Guoliang Zhuang, Ting Zheng, Xi Lan, Junzi Li, Zhipeng Feng, Hangyu He, Siyang Liu, Ming Wang, Tingchao He, Ping Xu and Guijun Li","doi":"10.1039/D5TC00014A","DOIUrl":"https://doi.org/10.1039/D5TC00014A","url":null,"abstract":"<p >The realization of integrating the generation and reception of optical signals into a single device in the near-infrared (NIR) region is of great value for biometric applications. However, existing semiconductors have limitations in material synthesis and device fabrication, which prevent the fabrication of high-performance integrated devices at low cost. Here, we proposed a bifunctional near-infrared hetero-diode based on FAPbI<small><sub>3</sub></small>/CdSe QDs. The QDs exhibited efficient Förster resonance energy transfer (FRET) to the perovskite, while the hole injection barrier, due to the deeper valence band of the QDs, regulated the number of injected holes, resulting in more balanced carrier injection. The hetero-diode improved its EQE from 16.9% to 21.6% as an emitter compared to the FAPbI<small><sub>3</sub></small> diode and achieved an improved on/off ratio from 2 × 10<small><sup>2</sup></small> to 3 × 10<small><sup>3</sup></small> as a sensing unit. This study opens up a new approach to improving the performance of bifunctional devices.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 11","pages":" 5483-5489"},"PeriodicalIF":5.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143611932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Influence of shape on crystal structure and optical properties of heterocyclic conjugated molecules
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-20 DOI: 10.1039/D5TC90023A
Elisa Guzmán, Yu Yan, Peter Müller, Justin Amengual, Chung-Hao Liu, Mu-Ping Nieh and Samuel W. Thomas, III
{"title":"Correction: Influence of shape on crystal structure and optical properties of heterocyclic conjugated molecules","authors":"Elisa Guzmán, Yu Yan, Peter Müller, Justin Amengual, Chung-Hao Liu, Mu-Ping Nieh and Samuel W. Thomas, III","doi":"10.1039/D5TC90023A","DOIUrl":"https://doi.org/10.1039/D5TC90023A","url":null,"abstract":"<p >Correction for ‘Influence of shape on crystal structure and optical properties of heterocyclic conjugated molecules’ by Elisa Guzmán <em>et al.</em>, <em>J. Mater. Chem. C</em>, 2025, <strong>13</strong>, 954–962, https://doi.org/10.1039/D4TC03509G.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 10","pages":" 5385-5385"},"PeriodicalIF":5.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d5tc90023a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143564251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boosting the long-term stability of all-polymer solar cells by using natural cellulose as an interlayer†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-20 DOI: 10.1039/D4TC05118A
Guan-Lin Chen, Po-Tuan Chen, Ching-I Huang and Leeyih Wang
{"title":"Boosting the long-term stability of all-polymer solar cells by using natural cellulose as an interlayer†","authors":"Guan-Lin Chen, Po-Tuan Chen, Ching-I Huang and Leeyih Wang","doi":"10.1039/D4TC05118A","DOIUrl":"https://doi.org/10.1039/D4TC05118A","url":null,"abstract":"<p >We conducted a thorough evaluation of the durability issues associated with organic/inorganic interfaces in inverted all-polymer solar cells (All-PSCs) and systematically investigated various interlayers, including polyethyleneimine (PEI), polyethylenimine ethoxylated (PEIE), and natural cellulose. Our findings reveal that natural cellulose stands out due to its exceptional water resistance, high adsorption energy, strong hydrogen bonding with ZnO, and a morphology that effectively prevents water molecules from penetrating the ZnO surface. Consequently, the ZnO/cellulose device retains 80% of its initial power conversion efficiency (<em>T</em><small><sub>80</sub></small> lifetime) for 2030 hours under humid aging conditions at 25 °C and 40% relative humidity (RH). Moreover, cellulose exhibits excellent interfacial compatibility with both the active layer and ZnO, leading to an impressive <em>T</em><small><sub>80</sub></small> lifetime of 2712 hours under thermal aging at 75 °C in N<small><sub>2</sub></small>. The ZnO/cellulose device also demonstrates remarkable resilience under harsher conditions, maintaining a <em>T</em><small><sub>80</sub></small> lifetime of 572 hours when stored at 75 °C and 50–60% RH. This study presents a sustainable and eco-friendly strategy to significantly enhance the long-term stability of All-PSCs.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 13","pages":" 6581-6587"},"PeriodicalIF":5.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Linear and non-linear optical properties of FeSnO(OH)5 oxyhydroxide perovskite†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC04040F
Abdelhadi El Hachmi, Goutam Biswas, Subhadeep Sen, Bouchaib Manoun, Khalid Draoui and Zouhair Sadoune
{"title":"Linear and non-linear optical properties of FeSnO(OH)5 oxyhydroxide perovskite†","authors":"Abdelhadi El Hachmi, Goutam Biswas, Subhadeep Sen, Bouchaib Manoun, Khalid Draoui and Zouhair Sadoune","doi":"10.1039/D4TC04040F","DOIUrl":"https://doi.org/10.1039/D4TC04040F","url":null,"abstract":"<p >FeSnO(OH)<small><sub>5</sub></small>, an oxyhydroxide perovskite also known as jeanbandyite, was prepared by a co-precipitation method and investigated using XRD, SEM, TEM and UV-Vis characterization techniques. The crystal structure of the title compound adopts a cubic system of space group <em>Pn</em><img> with unit-cell parameters <em>a</em> = 7.6381(5) Å and <em>V</em> = 445.61(5) Å<small><sup>3</sup></small>. The optical bandgap energy was estimated from diffuse reflectance data using a modified Kubelka–Munk function. The <em>E</em><small><sub>g</sub></small> value for the direct bandgap is 3.00 eV. The Urbach energy (<em>E</em><small><sub>U</sub></small>) was determined from the logarithmic absorption coefficient and found to be 1.256 ± 0.006 eV. The dependence of incident photon energy on optical parameters such as refractive index, extinction coefficient, real and imaginary parts of the dielectric function, real and imaginary parts of the complex conductivity, real and imaginary parts of the electrical modulus, dielectric loss and optical conductivity was investigated using UV-Vis spectrophotometer experiments. The obtained values for oscillator energy, dispersion energy, static refractive index, average oscillator strength and average oscillator wavelength were determined using the Wemple–DiDomenico model. The third-order nonlinear optical susceptibility <em>χ</em><small><sup>(3)</sup></small> and nonlinear refractive index (<em>n</em><small><sub>2</sub></small>) were calculated from linear optical parameters such as refractive index (<em>n</em>) and susceptibility <em>χ</em><small><sup>(1)</sup></small>.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 13","pages":" 6630-6640"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-bandgap oligothiophene-naphthalimide oligomeric semiconductors for thermoelectric applications†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC05383D
Matías J. Alonso-Navarro, Osnat Zapata-Arteaga, Sergi Riera-Galindo, Jiali Guo, Aleksandr-Peredeventsv, Edgar Gutiérrez-Fernández, Juan Sebastián Reparaz, Mar Ramos, Christian Müller, Jaime Martín, Marta Mas-Torrent, José L. Segura and Mariano Campoy-Quiles
{"title":"Low-bandgap oligothiophene-naphthalimide oligomeric semiconductors for thermoelectric applications†","authors":"Matías J. Alonso-Navarro, Osnat Zapata-Arteaga, Sergi Riera-Galindo, Jiali Guo, Aleksandr-Peredeventsv, Edgar Gutiérrez-Fernández, Juan Sebastián Reparaz, Mar Ramos, Christian Müller, Jaime Martín, Marta Mas-Torrent, José L. Segura and Mariano Campoy-Quiles","doi":"10.1039/D4TC05383D","DOIUrl":"https://doi.org/10.1039/D4TC05383D","url":null,"abstract":"<p >State-of-the-art p-type organic conjugated polymers are mostly thiophene-based semiconductors. Still, novel chemical design and a fresh perspective on different polymer backbones could pave the way for new high-performing materials and a deep understanding of donor–acceptor conjugated assemblies. Herein we designed and synthesized two novel electroactive oligomeric materials based on a donor terthiophene unit endowed with a strong electron-withdrawing naphthalimide unit. This molecular assembly has been polymerized using a palladium cross-coupling reaction with two different linkers, 1,1,1,2,2,2-hexabutyldistannane and (4,8-bis((2-ethylhexyl)oxy)benzo[1,2-<em>b</em>:4,5-<em>b</em>′]dithiophene-2,6-diyl)bis(trimethylstannane), to obtain the target polymers <strong>NIP3T-poly</strong> and <strong>NIP3T-BDT-poly</strong>, respectively. Both polymers exhibited an extended absorption up to 1000 nm and higher hole field-effect mobilities of up to 1.8 × 10<small><sup>−3</sup></small> cm<small><sup>2</sup></small> V<small><sup>−1</sup></small> s<small><sup>−1</sup></small>, in comparison to the molecular assembly <strong>NIP3T</strong>, and precisely tuned energy levels that make them compatible with common p-type dopants like 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F<small><sub>4</sub></small>TCNQ). After optimizing the doping level, we obtained a thermoelectric figure of merit up to <em>zT</em> = 0.02 for <strong>NIP3T-BDT-poly</strong>, comparable with benchmark F<small><sub>4</sub></small>TCNQ-vapor doped polythiophenes.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 13","pages":" 6922-6932"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/tc/d4tc05383d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A new helical InSeI polymorph: crystal structure and polarized Raman spectroscopy study†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC04902K
Lucía Olano-Vegas, Davide Spirito, Evgeny Modin, Pavlo Solokha, Sergio Marras, Marco Gobbi, Fèlix Casanova, Serena De Negri, Luis E. Hueso and Beatriz Martín-García
{"title":"A new helical InSeI polymorph: crystal structure and polarized Raman spectroscopy study†","authors":"Lucía Olano-Vegas, Davide Spirito, Evgeny Modin, Pavlo Solokha, Sergio Marras, Marco Gobbi, Fèlix Casanova, Serena De Negri, Luis E. Hueso and Beatriz Martín-García","doi":"10.1039/D4TC04902K","DOIUrl":"https://doi.org/10.1039/D4TC04902K","url":null,"abstract":"<p >Tetragonal InSeI is an interesting low-dimensional metal chalcohalide due to its composition and anisotropic crystal structure composed of helical chains, which give rise to optoelectronic properties with potential application in photodetectors, optical thermometers, and spintronic devices. However, there is a lack of experimental studies on its anisotropic or chiral behavior. Here we present the crystal structure of an unreported InSeI polymorph and study its lattice dynamics in bulk crystals and exfoliated nanowires by polarized Raman spectroscopy for two non-equivalent crystallographic planes. We determine the orientation of the helical chains and distinguish between crystallographic planes by linearly polarized measurements, evaluating the angle-dependent intensity of the modes, which allows assigning each mode to its representation. Circularly polarized Raman measurements do not reveal chiral phonons, despite the helical chains and anisotropic crystal structure. These results offer insight into the crystal structure of InSeI, which is fundamental for the fabrication of orientation-dependent optoelectronic and spintronic devices.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 14","pages":" 7102-7109"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coral-like porous tubular Ni doped g-C3N4 nanocomposites as bifunctional templates for photocatalytic degradation and fluorescence detection of sunset yellow in beverages†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC05391E
Yue Li, Ping Liu, Shisen Li, Yanting Ren, Wenzhen Du, Wenjing Yin, Haiyan Jiang, Qingli Yang and Yongchao Ma
{"title":"Coral-like porous tubular Ni doped g-C3N4 nanocomposites as bifunctional templates for photocatalytic degradation and fluorescence detection of sunset yellow in beverages†","authors":"Yue Li, Ping Liu, Shisen Li, Yanting Ren, Wenzhen Du, Wenjing Yin, Haiyan Jiang, Qingli Yang and Yongchao Ma","doi":"10.1039/D4TC05391E","DOIUrl":"https://doi.org/10.1039/D4TC05391E","url":null,"abstract":"<p >In this study, novel Ni-doped N-vacancy coral-like porous tubular g-C<small><sub>3</sub></small>N<small><sub>4</sub></small> (Ni–CN) nanocomposites were fabricated through a simple calcination strategy. The Ni–CN photocatalysts exhibited superior photocatalytic efficacy in the degradation of sunset yellow (SY) when exposed to visible light irradiation. The optimized Ni–CN nanocomposite contributed the highest SY removal efficiency of 96.87% after 120 min of irradiation, showing good reusability and structural stability. The as-prepared Ni–CN gel spheres had a high removal rate of SY from orange juice. In addition, Ni–CN nanosheets (Ni–CN NSs) obtained by ultrasonic stripping can be used as highly selective and sensitive fluorescent sensors for the detection of SY in beverages through dynamic or collisional fluorescence quenching mechanisms. The linear range of Ni–CN NSs for SY detection was 0–80 μM and the detection limit was 0.0397 μM. Here, the constructed Ni–CN nanocomposites provide a novel route for efficient removal and sensitive detection of SY in beverages.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 13","pages":" 6650-6659"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impacts of linking units of porphyrin dimer donors on the performance of organic solar cells†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC05390G
Hanping Wu, Jifa Wu, Feng Tang, Lin Yuan, Yinchun Guo, Yumeng Li and Xiaobin Peng
{"title":"Impacts of linking units of porphyrin dimer donors on the performance of organic solar cells†","authors":"Hanping Wu, Jifa Wu, Feng Tang, Lin Yuan, Yinchun Guo, Yumeng Li and Xiaobin Peng","doi":"10.1039/D4TC05390G","DOIUrl":"https://doi.org/10.1039/D4TC05390G","url":null,"abstract":"<p >Dimer photovoltaic materials have emerged as one of the most promising types of organic solar cell (OSC) materials due to their well-defined chemical structures and long-term device stability. However, current research on dimeric photovoltaic materials primarily focuses on acceptors, while the studies on dimer donors have been relatively limited. In this study, we designed and synthesized three porphyrin dimer donors E-ZnP<small><sub>2</sub></small>, BT-ZnP<small><sub>2</sub></small> and BDT-ZnP<small><sub>2</sub></small> by linking two functionalized D–A (D: electron donor unit and A: electron acceptor unit) porphyrins with ethynylene, diethynylene-benzothiadiazole (BT) and diethynylene-benzodithiophene (BDT), respectively. The impacts of the linking units on their energy levels, absorption properties, aggregation behaviors and photovoltaic performance are investigated. Among the three devices with porphyrins as the electron donors and Y6 as the electron acceptor, the E-ZnP<small><sub>2</sub></small>-based cells exhibit superior charge mobility and reduced charge recombination due to the stronger molecular aggregation of E-ZnP<small><sub>2</sub></small> and the improved miscibility with Y6, resulting in an impressive power conversion efficiency (PCE) of 9.64%. The findings offer valuable guidelines for developing dimer donor materials.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 13","pages":" 6880-6887"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tunable dielectric properties of a parylene dielectric layer through surface-modulation by click chemistry†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC04474F
Seong Cheol Jang, Gunoh Lee, Ilhoon Park, Byeongil Noh, Ji-Min Park, Jaewon Lee, Kyung Jin Lee and Hyun-Suk Kim
{"title":"Tunable dielectric properties of a parylene dielectric layer through surface-modulation by click chemistry†","authors":"Seong Cheol Jang, Gunoh Lee, Ilhoon Park, Byeongil Noh, Ji-Min Park, Jaewon Lee, Kyung Jin Lee and Hyun-Suk Kim","doi":"10.1039/D4TC04474F","DOIUrl":"https://doi.org/10.1039/D4TC04474F","url":null,"abstract":"<p >A dielectric serves as a separator between the semiconductor and the electrode in thin-film transistors (TFTs), playing a crucial role in attracting carriers through polarization by an electric field. In this study, copper-catalyzed azide/alkyne click reactions were adopted to modulate the dielectric and electrical properties of a polymer gate dielectric poly[(ethynyl-<em>p</em>-xylylene)-<em>co</em>-(<em>p</em>-xylylene)] (ethynyl parylene). A custom-synthesized ethynyl parylene dielectric layer is fabricated using chemical vapor polymerization, which yields smooth conformal films. Four types of azide materials – benzyl azide, aminopropyl azide, trimethylsilyl azide, and biotin-PEG3-azide – are utilized as dielectric constant modulators <em>via</em> click reactions. With only approximately 1% surface modulation, the dielectric constant of ethynyl parylene is nearly double that of pristine ethynyl parylene, whereas the leakage current density remains unchanged. Finally, IGZO TFTs are successfully fabricated using surface-modulated ethynyl parylene as the gate dielectric. Therefore, the click reaction of a polymer gate dielectric is an effective method to tune its properties while maintaining the interface properties of the front channel.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 13","pages":" 6614-6623"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Smart-responsive luminescence and VOC sensing application of a copper(i) cluster with a novel P2CuI2CuN2 core†
IF 5.7 2区 材料科学
Journal of Materials Chemistry C Pub Date : 2025-02-19 DOI: 10.1039/D4TC05038J
Ze-Qi Dai, Li Song, Jun-Er Chen, Ding-Feng Jin, Hong-Xiao Jin, Xiao-Lin Guo, Hang-Yan Shen and Wen-Xiang Chai
{"title":"Smart-responsive luminescence and VOC sensing application of a copper(i) cluster with a novel P2CuI2CuN2 core†","authors":"Ze-Qi Dai, Li Song, Jun-Er Chen, Ding-Feng Jin, Hong-Xiao Jin, Xiao-Lin Guo, Hang-Yan Shen and Wen-Xiang Chai","doi":"10.1039/D4TC05038J","DOIUrl":"https://doi.org/10.1039/D4TC05038J","url":null,"abstract":"<p >The detection of VOCs is of great significance due to their numerous applications in various fields, such as air quality assessment, environmental protection, and disease diagnosis. Herein, we report a smart-responsive luminescence device for detection of VOCs using a new CuI-cluster, (Xantphos)Cu<small><sub>2</sub></small>I<small><sub>2</sub></small>(4-PBO)<small><sub>2</sub></small> (<strong>1</strong>), as a probe. This cluster was characterized as a binuclear cluster structure with a novel P<small><sub>2</sub></small>CuI<small><sub>2</sub></small>CuN<small><sub>2</sub></small> core, which can be conveniently prepared using a ball-milling method. Owing to the high efficiency of the charge transfer transition from the cluster core to the peripheral 4-PBO ligand, the cluster emitted strong red light under both ultraviolet and visible light excitation. The luminescence mechanism was also elucidated through TD-DFT calculations. Furthermore, utilizing this cluster as a fluorescent probe, a paper-based sensor was successfully fabricated through a technical route involving polymer composite dispersion supported by a cellulose membrane. When exposed to a VOC atmosphere, the device demonstrated rapid and selective sensing responses, characterized by luminescence quenching (in the presence of cyclohexylamine) or enhancement, including vapochromic luminescence (in the presence of pyridine). A series of spectroscopic, structural, and theoretical investigations revealed that the fluorescence sensing operates through a reactive response mechanism.</p>","PeriodicalId":84,"journal":{"name":"Journal of Materials Chemistry C","volume":" 14","pages":" 7234-7244"},"PeriodicalIF":5.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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