Science China Materials最新文献

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Leaf vein-inspired transparent superhydrophobic coatings with high stability 叶脉启发透明超疏水涂层,具有高稳定性
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-10 DOI: 10.1007/s40843-024-3269-6
Hang Li  (, ), Zehao Wang  (, ), Hongyi Tu  (, ), Min Chen  (, ), Yi Wu  (, ), Limin Wu  (, )
{"title":"Leaf vein-inspired transparent superhydrophobic coatings with high stability","authors":"Hang Li \u0000 (,&nbsp;),&nbsp;Zehao Wang \u0000 (,&nbsp;),&nbsp;Hongyi Tu \u0000 (,&nbsp;),&nbsp;Min Chen \u0000 (,&nbsp;),&nbsp;Yi Wu \u0000 (,&nbsp;),&nbsp;Limin Wu \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3269-6","DOIUrl":"10.1007/s40843-024-3269-6","url":null,"abstract":"<div><p>Transparent superhydrophobic coatings hold significant potential for applications in architectural glass and optoelectronic devices. However, obtaining good compatibility between highly transparent, low haze and excellent mechanical stability in a superhydrophobicity coating remains a significant challenge. Inspired by the natural protection mechanism of the hierarchical structure of leaf veins, we have designed and fabricated transparent superhydrophobic coatings with highly detailed hierarchical vein-like ridges via a template-assisted multi-mask photolithography and inverted mold process combined with a spraying technique. The coated glass exhibited not only outstanding superhydrophobicity, with contact angle ⩾ 160° and sliding angle ⩽ 1.5° but also a high optical transmittance of 88.4% and a low haze of 8.1%, as well as remarkable mechanical durability and weather resistance.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1203 - 1211"},"PeriodicalIF":6.8,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bioinspired chiral photonic crystals 仿生手性光子晶体
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-07 DOI: 10.1007/s40843-024-3264-7
Jiawei Lv  (, ), Xiaoqing Gao  (, ), Zhiyong Tang  (, )
{"title":"Bioinspired chiral photonic crystals","authors":"Jiawei Lv \u0000 (,&nbsp;),&nbsp;Xiaoqing Gao \u0000 (,&nbsp;),&nbsp;Zhiyong Tang \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3264-7","DOIUrl":"10.1007/s40843-024-3264-7","url":null,"abstract":"<div><p>Structural coloration strategies are widely adopted in the living world to manipulate light, offering great inspiration for humans to address the challenges in creating advanced photonic materials with desired performance. Among the vast photonic structures in nature, chiral photonic crystals have drawn special attention owing to their intricate 3D structure, unique chiroptical properties, and potential applications in chiral optics, pigments, information storage, and so on. In this review, we focus on the research progress in clarifying the hierarchical structures and unique optical properties of chiral photonic crystal structures found in animals and plants, including cholesteric-like one-dimensional photonic crystals and chiral gyroid structures. We summarize various top-down and bottom-up methods to mimic the biological strategy to fabricate chiral photonic crystals with comparable or better performances than their bio-counterparts. The emerging applications in sustainable photonic pigments, polarized luminescence and lasers, information storage, chiroptical devices, sensors, and radiative cooling are highlighted. We hope this review will be helpful in the design and fabrication of multifunctional chiral photonic materials inspired by nature.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"979 - 997"},"PeriodicalIF":6.8,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking electrochemical potential: amorphous NaFePO4 as a high-capacity and cycle-stable cathode material for advanced sodium-ion batteries 解锁电化学电位:无定形NaFePO4作为高容量和循环稳定的先进钠离子电池正极材料
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-07 DOI: 10.1007/s40843-024-3260-1
Lixiao Han  (, ), Shuxuan Liao  (, ), Shihao Zhang  (, ), Kean Chen  (, ), Xumiao Chen  (, ), Mengyi Li  (, ), Qiang Li  (, ), Xinping Ai  (, ), Yuliang Cao  (, ), Yongjin Fang  (, )
{"title":"Unlocking electrochemical potential: amorphous NaFePO4 as a high-capacity and cycle-stable cathode material for advanced sodium-ion batteries","authors":"Lixiao Han \u0000 (,&nbsp;),&nbsp;Shuxuan Liao \u0000 (,&nbsp;),&nbsp;Shihao Zhang \u0000 (,&nbsp;),&nbsp;Kean Chen \u0000 (,&nbsp;),&nbsp;Xumiao Chen \u0000 (,&nbsp;),&nbsp;Mengyi Li \u0000 (,&nbsp;),&nbsp;Qiang Li \u0000 (,&nbsp;),&nbsp;Xinping Ai \u0000 (,&nbsp;),&nbsp;Yuliang Cao \u0000 (,&nbsp;),&nbsp;Yongjin Fang \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3260-1","DOIUrl":"10.1007/s40843-024-3260-1","url":null,"abstract":"<div><p>Traditional cathode materials are well-defined high crystalline structures, but the repeated ion insertion/extraction with high lattice stress and volume change during the charge/discharge will cause structural degradation and diminish electrochemical performance. Herein we identify an amorphous iron phosphate electrode, NaFePO<sub>4</sub>, which can be rechargeable and show excellent electrochemical properties. The amorphous NaFePO<sub>4</sub> electrode delivers a reversible capacity of 160.5 mAh g<sup>−1</sup> at 20 mA g<sup>−1</sup>, accompanied by remarkable rate capability and cycling stability. Unlike conventional crystalline materials, the excellent electrochemical performance of the amorphous NaFePO<sub>4</sub> electrode stems from the absence of lattice limitation in the amorphous structure, which allows for the accommodation of local stress and volume change during the long-term sodiation/desodiation processes. Further experimental characterizations and theoretical simulation reveal the underlying redox characteristics. This research offers some insights for the development of innovative amorphous electrode materials with low cost and attractive electrochemical properties for wide energy storage applications.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1109 - 1116"},"PeriodicalIF":6.8,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance deep ultraviolet light detectors composed of MXene/GaN heterostructures enabled by p-type doping of MXenes 由MXene/GaN异质结构组成的高性能深紫外光探测器
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-06 DOI: 10.1007/s40843-024-3253-3
Liangpan Yang  (, ), Yu Cheng  (, ), Deng Ke  (, ), Shijie Xu  (, ), Chao Xie  (, ), Wenhua Yang  (, ), Pengbin Gui  (, ), Zhixiang Huang  (, )
{"title":"High-performance deep ultraviolet light detectors composed of MXene/GaN heterostructures enabled by p-type doping of MXenes","authors":"Liangpan Yang \u0000 (,&nbsp;),&nbsp;Yu Cheng \u0000 (,&nbsp;),&nbsp;Deng Ke \u0000 (,&nbsp;),&nbsp;Shijie Xu \u0000 (,&nbsp;),&nbsp;Chao Xie \u0000 (,&nbsp;),&nbsp;Wenhua Yang \u0000 (,&nbsp;),&nbsp;Pengbin Gui \u0000 (,&nbsp;),&nbsp;Zhixiang Huang \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3253-3","DOIUrl":"10.1007/s40843-024-3253-3","url":null,"abstract":"<div><p>The performance enhancement of MXene/semiconductor heterostructure-based light detectors is greatly restricted by the relatively small junction barrier due to the limited work function of MXenes. The work function of MXenes can be largely adjusted to approach 600 meV through simple incorporation of V<sub>2</sub>O<sub>5</sub> via a charge transfer doping mechanism. Exploiting this strategy, the performance of MXene/GaN heterostructure-based deep ultraviolet (DUV) photodetectors has been greatly improved. Specifically, the photocurrent is enhanced by nearly 3 times, and the dark current is suppressed at the lowest order of magnitude, resulting in improved responsivity and specific detectivity of 121.6 mA/W and 2.23×10<sup>13</sup> Jones, respectively, at 265 nm. The device also displays an ultralow dark current of 10<sup>−14</sup> A, a fast response speed of 0.4 ms/15.1 ms, a large linear dynamic range exceeding 150 dB, and a high DUV/near ultraviolet rejection ratio of 2.41×10<sup>5</sup>. Owing to its good device performance, the detector is capable of sensing weak photon signals produced by a fire flame and functions as an optical receiver to transmit a text signal in a DUV light communication system. The proposed MXene doping method is expected to help develop MXene-based electronic/optoelectronic devices, and the present DUV photodetectors will find potential applications in DUV optoelectronic systems.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1012 - 1021"},"PeriodicalIF":6.8,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Color-tunable supramolecular luminescent materials for information anticounterfeiting 用于信息防伪的可调色超分子发光材料
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-06 DOI: 10.1007/s40843-024-3265-2
Zhen Qi  (, ), Qian Wang  (, ), Da-Hui Qu  (, )
{"title":"Color-tunable supramolecular luminescent materials for information anticounterfeiting","authors":"Zhen Qi \u0000 (,&nbsp;),&nbsp;Qian Wang \u0000 (,&nbsp;),&nbsp;Da-Hui Qu \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3265-2","DOIUrl":"10.1007/s40843-024-3265-2","url":null,"abstract":"<div><p>Counterfeiting-related crimes pose a serious threat to the economic interests, security, and health of governments, businesses, and consumers. The urgent need for advanced anticounterfeiting materials with multilevel security for information encryption and decryption has driven significant research in this area. Supramolecular luminescent materials are potential for anticounterfeiting owing to their dynamic and controllable optical properties. In this review, the strategies adopted for fabricating supramolecular fluorescent materials and their corresponding anticounterfeiting technologies have been discussed. Especially, the time-dependent luminescent materials, which were created by non-equilibrium supramolecular assemblies and exhibited significant changes in fluorescence intensity and wavelength over time, were highlighted for their unique dynamic feature. This feature endowed materials programmable properties on time dimension, allowing for automatic and spontaneous behavior. Consequently, a series of information encryption materials have been developed, including self-erasing fluorescence hydrogels and 4D codes, demonstrating an enhanced level of security.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"962 - 978"},"PeriodicalIF":6.8,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pillararene based supramolecular nanoplatform for endoplasmic reticulum-targeting type I photodynamic and NO gas therapy 基于柱芳烃的内质网靶向I型光动力和NO气体治疗超分子纳米平台
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-05 DOI: 10.1007/s40843-024-3268-6
Shaoqi Xie  (, ), Chang Liu  (, ), Yue Cao  (, ), Jiachen Xia  (, ), Bing Lu  (, )
{"title":"Pillararene based supramolecular nanoplatform for endoplasmic reticulum-targeting type I photodynamic and NO gas therapy","authors":"Shaoqi Xie \u0000 (,&nbsp;),&nbsp;Chang Liu \u0000 (,&nbsp;),&nbsp;Yue Cao \u0000 (,&nbsp;),&nbsp;Jiachen Xia \u0000 (,&nbsp;),&nbsp;Bing Lu \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3268-6","DOIUrl":"10.1007/s40843-024-3268-6","url":null,"abstract":"<div><p>The development of tumor-targeted multimodality therapy is an important strategy to improve the curative effects of cancer treatment. It is critical to construct such a platform that can perfectly integrate these functional entities into one. Herein, we designed a phenyl sulfonamide-modified pillararene WP5-PEG-BSA. WP5-PEG-BSA can be used to construct endoplasmic reticulum (ER)-targeting nanocarriers. Then NO donor <i>S</i>-nitroso-<i>N</i>-acetyl-<i>D</i>-penicillamine (SNAP) and the newly designed photosensitizer DPP-DMATPE were loaded into the nanocarriers via different paths. Under laser irradiation, DPP-DMATPE exhibited excellent type I photodynamic activity, while SNAP can release NO under the action of glutathione. The formed nanodrugs BSA-DPP/SNAP exhibited outstanding ER-targeting and high lethality towards tumor cells as well as biocompability. What’s even more worth saying is that BSA-DPP/SNAP performed well even in hypoxic tumor cells. The final experimental results <i>in vivo</i> again confirmed the good therapeutic effects of BSA-DPP/SNAP. As a result, a supramolecular nanoplatform that realizes highly efficient ER-targeting type I photodynamic and NO gas cancer therapy was constructed.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1285 - 1291"},"PeriodicalIF":6.8,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible polyvinylidene fluoride/multiwall carbon nanotube-based thermoelectric composite films with excellent environmental stability and enhanced power factor from ferroelectric polarization 柔性聚偏氟乙烯/多壁碳纳米管热电复合薄膜具有优异的环境稳定性和增强的铁电极化功率因数
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-05 DOI: 10.1007/s40843-024-3240-9
Qinghui Jiang  (, ), Zhenxiang Yu  (, ), Xinyue Zhang  (, ), Shanliang Chen  (, ), Jitao Yi  (, ), Yong Liu  (, )
{"title":"Flexible polyvinylidene fluoride/multiwall carbon nanotube-based thermoelectric composite films with excellent environmental stability and enhanced power factor from ferroelectric polarization","authors":"Qinghui Jiang \u0000 (,&nbsp;),&nbsp;Zhenxiang Yu \u0000 (,&nbsp;),&nbsp;Xinyue Zhang \u0000 (,&nbsp;),&nbsp;Shanliang Chen \u0000 (,&nbsp;),&nbsp;Jitao Yi \u0000 (,&nbsp;),&nbsp;Yong Liu \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3240-9","DOIUrl":"10.1007/s40843-024-3240-9","url":null,"abstract":"<div><p>Flexible thermoelectric (TE) films and devices have potential applications in wearable technology and the Internet of Things. One of the main challenges is how to simultaneously achieve good TE performance and high chemical/thermal stability in air with low cost and large-scale production. To address this, we utilized tape casting to fabricate composite films of polyvinylidene fluoride (PVDF) and multi-walled carbon nanotubes (MWCNTs). In the composite, polar β-PVDF introduced by hot pressing can decouple the electrical conductivity and Seebeck coefficient and significantly lead to enhanced power factor of MWCNTs/PVDF composite film. As a result, the MWCNTs (60 wt%)/PVDF film has a power factor of 1.1–1.4 µW m<sup>−1</sup> K<sup>−2</sup> near room temperature. The film also has excellent flexibility and stability in the air. Its power factor is decreased by only 9% after 1000 bends and can keep stable in air for above 6 months, which is much longer than that (15 days) of Bi<sub>2</sub>Te<sub>3</sub>/PEDOT: PSS film. A demo TE device with 10 p-type legs has an output voltage of 11.5 mV and output power of 47.53 nW at a temperature difference of 60°C. The above descriptions make the MWCNTs/PVDF films have a significant advantage in the commercial application of flexible TE devices.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1240 - 1248"},"PeriodicalIF":6.8,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716628","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystal-phase engineering of ε-Ga2O3 for high-performance deep UV photodetectors via MOCVD MOCVD制备高性能深紫外光电探测器用ε-Ga2O3的晶相工程
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-04 DOI: 10.1007/s40843-024-3245-6
Zhiwei Wang  (, ), Hong Huang  (, ), Xiaohu Hou  (, ), Keju Han  (, ), Weiheng Zhong  (, ), Xiao Feng  (, ), Haoyan Zhan  (, ), Weizhen Liu  (, ), Xiaolong Zhao  (, ), Nan Gao  (, ), Shibing Long  (, )
{"title":"Crystal-phase engineering of ε-Ga2O3 for high-performance deep UV photodetectors via MOCVD","authors":"Zhiwei Wang \u0000 (,&nbsp;),&nbsp;Hong Huang \u0000 (,&nbsp;),&nbsp;Xiaohu Hou \u0000 (,&nbsp;),&nbsp;Keju Han \u0000 (,&nbsp;),&nbsp;Weiheng Zhong \u0000 (,&nbsp;),&nbsp;Xiao Feng \u0000 (,&nbsp;),&nbsp;Haoyan Zhan \u0000 (,&nbsp;),&nbsp;Weizhen Liu \u0000 (,&nbsp;),&nbsp;Xiaolong Zhao \u0000 (,&nbsp;),&nbsp;Nan Gao \u0000 (,&nbsp;),&nbsp;Shibing Long \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3245-6","DOIUrl":"10.1007/s40843-024-3245-6","url":null,"abstract":"<div><p>Gallium oxide (Ga<sub>2</sub>O<sub>3</sub>), with an ultrawide bandgap corresponding to the deep ultraviolet (DUV) spectra range, provides a potential subversive scheme for the filter-free DUV photodetection. Meanwhile, the various crystal phases of Ga<sub>2</sub>O<sub>3</sub> provide more substrate options for achieving heteroepitaxy, with the coupling of Ga<sub>2</sub>O<sub>3</sub> to SiC substrates conducive to developing integrated Ga<sub>2</sub>O<sub>3</sub> DUV photodetectors. Phase engineering of <i>β</i>-Ga<sub>2</sub>O<sub>3</sub> and <i>ε</i>-Ga<sub>2</sub>O<sub>3</sub> was achieved on the commercial 4H-SiC substrate via metal-organic chemical vapor deposition. According to the in-depth analysis of different Ga<sub>2</sub>O<sub>3</sub> growth stages, it was found that <i>β</i>-Ga<sub>2</sub>O<sub>3</sub> is easy to form under high-pressure growth conditions, while low-pressure conditions promote the formation of <i>ε</i>-Ga<sub>2</sub>O<sub>3</sub> at 500°C. Furthermore, the developed <i>ε</i>-phase dominated Ga<sub>2</sub>O<sub>3</sub> DUV photodetector exhibits obvious advantages in high responsivity (∼639 A/W), photo-to-dark current ratio (∼2.4×10<sup>7</sup>), external quantum efficiency (∼3.15×10<sup>5</sup>%), and specific detectivity (∼9.62×10<sup>13</sup> Jones) under 254 nm illumination. This work not only reveals the growth mechanism of Ga<sub>2</sub>O<sub>3</sub> films under various pressures but also ensures the great potential of <i>ε</i>-Ga<sub>2</sub>O<sub>3</sub> for highly sensitive DUV detection on the heterogeneous substrate, which is expected to expand the application of Ga<sub>2</sub>O<sub>3</sub> optoelectronic devices.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1174 - 1183"},"PeriodicalIF":6.8,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitigating Li2S agglomeration in lithium-sulfur batteries with hierarchically structured CNT/Ni-Ni0.85Se sulfur hosts 层次化碳纳米管/Ni-Ni0.85Se硫载体减轻锂硫电池中Li2S团聚
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-04 DOI: 10.1007/s40843-024-3259-x
Yonghui Xie  (, ), Fan Wu  (, ), Wenrui Zheng  (, ), Hong Zhang  (, ), Xinghui Wang  (, )
{"title":"Mitigating Li2S agglomeration in lithium-sulfur batteries with hierarchically structured CNT/Ni-Ni0.85Se sulfur hosts","authors":"Yonghui Xie \u0000 (,&nbsp;),&nbsp;Fan Wu \u0000 (,&nbsp;),&nbsp;Wenrui Zheng \u0000 (,&nbsp;),&nbsp;Hong Zhang \u0000 (,&nbsp;),&nbsp;Xinghui Wang \u0000 (,&nbsp;)","doi":"10.1007/s40843-024-3259-x","DOIUrl":"10.1007/s40843-024-3259-x","url":null,"abstract":"<div><p>The development of sulfur host materials with high catalytic activity to tackle the shuttling effect of polysulfides and their slow conversion kinetics is a prospective strategy for improving the performance of lithium-sulfur batteries. However, it may result in excessively thick Li<sub>2</sub>S films that cover the entire electrode structure, consequently weakening the functionalization effect of the sulfur host. Herein, we developed a hierarchical structured sulfur host material composed of a three-dimensional composite conductive network of carbon nanotubes and Ni nanoparticles, along with Ni<sub>0.85</sub>Se nanosheets grown on its surface. The synergistic effects of hierarchical structure and conductive network accelerate the electron and ion transport, mitigate the volume expansion during lithiation, enhance the conversion kinetics of polysulfides, and importantly prevent the agglomeration of thick Li<sub>2</sub>S films, which results in a significant improvement in the electrochemical performance of the sulfur cathode. The developed CC@CNT/Ni-Ni<sub>0.85</sub>Se-S exhibits excellent rate performance and long-term stability, achieving a discharge-specific capacity of 965 mA h g<sup>−1</sup> at 3 C and maintaining a discharge-specific capacity of 789 mA h g<sup>−1</sup> even after 300 cycles at 1 C. Notably, the capacity retention rate is as high as 92.9% for 100 cycles at 0.1 C, even with a high sulfur loading of 4.0 mg mg<sup>−2</sup>. This work not only effectively mitigates the agglomeration of Li<sub>2</sub>S film but also offers a novel design approach for the practical application of high-energy-density lithium-sulfur batteries.\u0000</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":773,"journal":{"name":"Science China Materials","volume":"68 4","pages":"1100 - 1108"},"PeriodicalIF":6.8,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143716644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Near-infrared organic photodetectors outperform Si photodetectors: introducing an all-fused-ring acceptor into active layers for ultra-low trap density 近红外有机光电探测器优于硅光电探测器:在有源层中引入全熔环受体,实现超低陷阱密度
IF 6.8 2区 材料科学
Science China Materials Pub Date : 2025-03-04 DOI: 10.1007/s40843-024-3251-x
Wenliang Chen  (, ), Yingze Zhang  (, ), Xiaoyu Zhu  (, ), Junhui Miao  (, ), Jun Liu  (, ), Lixiang Wang  (, )
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