Ph. Yu. Gorobtsov, N. P. Simonenko, T. L. Simonenko, E. P. Simonenko
{"title":"Preparation of V2O5 Thin Films Using Vanadyl Heteroligand Complexes and Their Electrochromic Properties","authors":"Ph. Yu. Gorobtsov, N. P. Simonenko, T. L. Simonenko, E. P. Simonenko","doi":"10.1134/S0036023624602277","DOIUrl":"10.1134/S0036023624602277","url":null,"abstract":"<p>Microstructural features, phase composition, and eletrochromic properties of V<sub>2</sub>O<sub>5</sub> film formed by spin-coating using vanadyl alkoxoacetylacetonate as a precursor have been studied. The obtained material possesses a significant amount of V<sup>4+</sup> ions, which is indicated both by the presence of the corresponding modes in the Raman spectra and the presence of the V<sub>7</sub>O<sub>16</sub> phase. As a result, the material exhibits anodic electrochromism; it colors upon oxidation, changing color from pale blue to a much less transparent orange-yellow. The optical contrast can reach 30% at a wavelength of 400 nm, and the coloration efficiency is 65.26 cm<sup>2</sup>/C. The results of the study clearly demonstrate the promising application of materials based on V<sub>2</sub>O<sub>5</sub>, obtained using heteroligand hydrolytically active vanadyl complexes, as functional components of devices that provide a change in optical properties when an electrical voltage is applied.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1580 - 1586"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. P. Zhdanov, A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, K. Yu. Zhizhin, N. T. Kuznetsov
{"title":"Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons","authors":"A. P. Zhdanov, A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, K. Yu. Zhizhin, N. T. Kuznetsov","doi":"10.1134/S0036023624601934","DOIUrl":"10.1134/S0036023624601934","url":null,"abstract":"<p>The reaction of nucleophilic addition of isomers of iodaniline to the nitrile derivative of the <i>closo</i>-decaborate anion has been studied. The structures of the products have been determined using multinuclear NMR and IR spectroscopy, as well as ESI mass spectrometry. The structure of compound (NBu<sub>4</sub>)[2-B<sub>10</sub>H<sub>9</sub>NHC(CH<sub>3</sub>)HN(2-C<sub>6</sub>H<sub>4</sub>I)] was determined by single-crystal X-ray diffraction.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1463 - 1468"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"On the Reaction of Gold(III) Complexes with Methionine","authors":"V. Yu. Kharlamova, I. V. Mironov","doi":"10.1134/S0036023624602253","DOIUrl":"10.1134/S0036023624602253","url":null,"abstract":"<p>The reactions of gold(III) complexes <span>({text{AuCl}}_{4}^{ - })</span>, Au(bipy)Cl<span>(_{2}^{ + })</span>, Au(en)<span>(_{2}^{{3 + }})</span>, and Au(C<sub>9</sub>H<sub>19</sub>N<sub>4</sub>)<sup>2+</sup> with methionine (HMet) were studied in aqueous solutions (pH 2.0 and 7.4; <i>I</i> = 0.2 M (NaCl), <i>C</i><sub>Au</sub> = (5–10) × 10<sup>–5</sup> mol/L, <i>C</i><sub>HMet</sub> < (6–50) × 10<sup>–5</sup> mol/L) at 25°C. Methionine reduces gold(III) to gold(I), but the reactions proceed much more slowly (by hundreds of times) than under the action of thiols. The rate of reactions with HMet markedly decreases with increasing denticity of ligands in the gold(III) complex.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1575 - 1579"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Phase Equilibria in the Li–V–O System (an Analytical Review)","authors":"G. D. Nipan, G. A. Buzanov","doi":"10.1134/S003602362460182X","DOIUrl":"10.1134/S003602362460182X","url":null,"abstract":"<p>We used topological modeling based on fragmentary experimental data on phase equilibria and phase transformations to construct for the first time <i>P</i>–<i>T</i>–<i>x</i> diagrams for Li–V, Li–O, and V–O binary systems and a complete isothermal concentration diagram of the Li–V–O system, the latter taking into account the formation of limited solid solutions and the presence of saturated vapor.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1544 - 1554"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"On Polymeric Gold(I) Complexes with Glutathione in Aqueous Solutions","authors":"I. V. Mironov, V. Yu. Kharlamova","doi":"10.1134/S0036023624601247","DOIUrl":"10.1134/S0036023624601247","url":null,"abstract":"<p>The study addresses reactions involving gold(I) glutathione complexes in aqueous solutions at <i>T</i> = 25°C and <i>I</i> = 0.2 M (NaCl) in the pH range of 7.20–6.06 (<i>C</i><sub>Au</sub> = (5–10) × 10<sup>–4</sup> M). Using mass spectrometry, it was shown that at <i>C</i><sub>GS</sub> > <i>C</i><sub>Au</sub>, polymeric species <span>({text{A}}{{{text{u}}}_{{text{4}}}}({text{GS}})_{4}^{*})</span> and <span>({text{A}}{{{text{u}}}_{n}}({text{GS}})_{{n + 1}}^{*})</span>, where <i>n</i> ≤ 4, can exist, together with monomeric <span>({text{Au}}({text{GS}})_{2}^{*})</span> (the symbol * means the sum of species with different degrees of protonation). According to UV spectroscopy data, in the range of 0.5 < <i>C</i><sub>GS</sub>/<i>C</i><sub>Au</sub> < 3, all spectra can be described, within the experimental error, as linear combinations of the spectra of four species, including <span>({text{Au}}({text{GS}})_{2}^{*})</span>. The proportion of <span>({text{Au}}({text{GS}})_{2}^{*})</span> decreases with decreasing pH. The equilibrium constant for 0.25 <span>({text{A}}{{{text{u}}}_{{text{4}}}}({text{GSH}})_{4}^{{4 - }})</span> + <span>({text{GSH}}_{2}^{ - })</span> = <span>({text{Au}}({text{GSH}})_{2}^{{3 - }})</span> + H<sup>+</sup> amounts to log <i>K</i> = –4.4 ± 0.1 (<i>I</i> = 0.2 M, NaCl).</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1567 - 1574"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. K. Bettels, M. S. Polukhin, I. A. Karavaev, E. V. Savinkina, G. A. Buzanov, A. S. Kubasov, V. M. Retivov
{"title":"Yttrium(III) Complexes with Carbamide and Dimethylacetamide: Composition, Structure, and Thermal Decomposition","authors":"E. K. Bettels, M. S. Polukhin, I. A. Karavaev, E. V. Savinkina, G. A. Buzanov, A. S. Kubasov, V. M. Retivov","doi":"10.1134/S0036023624602289","DOIUrl":"10.1134/S0036023624602289","url":null,"abstract":"<p>Yttrium(III) complexes with carbamide (Ur) and <i>N</i>,<i>N</i>-dimethylacetamide (DMAA) of composition [Y(H<sub>2</sub>O)(Ur)<sub>2</sub>(NO<sub>3</sub>)<sub>3</sub>] (<b>I</b>), [Y(Ur)<sub>3</sub>(NO<sub>3</sub>)<sub>3</sub>] (<b>II</b>), and [Y(DMAA)<sub>3</sub>(NO<sub>3</sub>)<sub>3</sub>] (<b>III</b>) have been synthesized. Their composition, structural features, and thermolysis processes in a wide temperature range have been determined using physicochemical methods (elemental analysis, IR spectroscopy, X-ray powder diffraction, single-crystal X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry). It has been shown that the isolated complexes can be used for the synthesis of nanosized yttrium oxide.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1510 - 1519"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. S. Kelbysheva, T. V. Strelkova, A. V. Babaytsev, A. V. Naumkin, L. N. Telegina
{"title":"Photolysis and Photodegradation of N-Substituted Phthalimides with a Cymantrenyl Moiety","authors":"E. S. Kelbysheva, T. V. Strelkova, A. V. Babaytsev, A. V. Naumkin, L. N. Telegina","doi":"10.1134/S0036023624602629","DOIUrl":"10.1134/S0036023624602629","url":null,"abstract":"<p>The photochemical behavior of substituted phthalimides with carboxylate groups associated with the cymantrenyl fragment is studied by infrared spectroscopy (IR), nuclear magnetic resonance (NMR) spectroscopy, UV-visible spectroscopy, and cyclic voltammetry (CV). During the formation of hemilabile dicarbonyl chelate complexes, a sharp change in the electronic, electrochemical, and optical properties of compounds is observed. According to the dynamic light scattering (DLS) method, further irradiation of solutions of these complexes leads to the formation of previously undescribed stable nanoparticles in liquid media containing manganese in two degrees of oxidation Mn<sup>2+</sup>/Mn<sup>+</sup> and a phthalimide fragment associated with a Cp-ring coordinated or uncoordinated with manganese(I).</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 12","pages":"1779 - 1788"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143554020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. P. Simonenko, A. S. Mokrushin, I. A. Nagornov, S. A. Dmitrieva, T. L. Simonenko, N. P. Simonenko, N. T. Kuznetsov
{"title":"Preparation and Chemosensory Properties of Composite Material Ti2CTx–10 mol % SnO2","authors":"E. P. Simonenko, A. S. Mokrushin, I. A. Nagornov, S. A. Dmitrieva, T. L. Simonenko, N. P. Simonenko, N. T. Kuznetsov","doi":"10.1134/S0036023624601727","DOIUrl":"10.1134/S0036023624601727","url":null,"abstract":"<p>A hybrid method for the preparation of Ti<sub>2</sub>CT<sub><i>x</i></sub><i>–</i>10 mol % SnO<sub>2</sub> composite material was developed, combining a deposition method in the presence of dispersed MXene accordion-like aggregates and subsequent hydrothermal treatment. As a result, the MXene multilayer was decorated by ~2<i>–</i>4 nm tin dioxide nanoparticles, and the interlayer spacing of the Ti<sub>2</sub>CT<sub><i>x</i></sub> MXene multilayer increased from 11.6 to 13.5 Å. For the obtained Ti<sub>2</sub>CT<sub><i>x</i></sub><i>–</i>SnO<sub>2</sub> composite material coated by microplotting, a high sensitivity of the receptor layer to 100 ppm ethanol, ammonia, and nitrogen dioxide was observed already at room temperature and under conditions of 23% relative humidity. The determined high response of the nanocomposite to humidity changes allows us to consider it as a promising receptor material for a humidity sensor.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1587 - 1595"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. V. Golikova, A. D. Yapryntsev, M. A. Teplonogova, K. A. Babeshkin, N. N. Efimov, A. E. Baranchikov, V. K. Ivanov
{"title":"Mixed Yttrium and Dysprosium Lactates as the First Example of Rare-Earth Hydrogen-Bonded Organic Framework Solid Solutions","authors":"M. V. Golikova, A. D. Yapryntsev, M. A. Teplonogova, K. A. Babeshkin, N. N. Efimov, A. E. Baranchikov, V. K. Ivanov","doi":"10.1134/S0036023624601946","DOIUrl":"10.1134/S0036023624601946","url":null,"abstract":"<p>Molecular solid solutions of yttrium and dysprosium lactates of composition [Y<sub>1–<i>x</i></sub>Dy<sub><i>x</i></sub>(C<sub>3</sub>H<sub>5</sub>O<sub>3</sub>)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>], where <i>x</i> = 0, 0.01, 0.1, 0.5, 0.8, and 1, have been obtained for the first time. These solutions can be considered as the first examples of REE coordination compounds formed due to hydrogen bonding. The obtained compounds have been analyzed by the set of physicochemical methods including XRD, energy dispersive X-ray (EDX), IR, and Raman spectroscopy. Unit cell volume of solid solutions shows linear dependence on cationic composition. It has been found that variation in the cationic composition of solid solutions leads to the monotonic shift of position of lines in Raman spectra corresponding to vibrations of Ln–O bonds (151–158 cm<sup>–1</sup>). It has been shown that the obtained compounds can behave as single-molecule magnets with magnetization barrier up to 108 K.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1475 - 1486"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin, N. T. Kuznetsov
{"title":"New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et","authors":"A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin, N. T. Kuznetsov","doi":"10.1134/S0036023624601910","DOIUrl":"10.1134/S0036023624601910","url":null,"abstract":"<p>The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu<sub>4</sub>)[2-B<sub>10</sub>H<sub>9</sub>NH=C(C<sub>2</sub>H<sub>5</sub>)C(C(OH)CH<sub>3</sub>)C(O)CH<sub>3</sub>] has been established by single crystal X-ray analysis.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1469 - 1474"},"PeriodicalIF":1.8,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143438588","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}