New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin, N. T. Kuznetsov
{"title":"New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et","authors":"A. V. Nelyubin,&nbsp;N. A. Selivanov,&nbsp;A. Yu. Bykov,&nbsp;A. S. Kubasov,&nbsp;I. N. Klyukin,&nbsp;A. P. Zhdanov,&nbsp;K. Yu. Zhizhin,&nbsp;N. T. Kuznetsov","doi":"10.1134/S0036023624601910","DOIUrl":null,"url":null,"abstract":"<p>The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu<sub>4</sub>)[2-B<sub>10</sub>H<sub>9</sub>NH=C(C<sub>2</sub>H<sub>5</sub>)C(C(OH)CH<sub>3</sub>)C(O)CH<sub>3</sub>] has been established by single crystal X-ray analysis.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1469 - 1474"},"PeriodicalIF":1.8000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023624601910","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3] has been established by single crystal X-ray analysis.

Abstract Image

合成乙酰丙酮基近硼酸盐阴离子衍生物的新方法[BnHn - 1NH=C(R)C(C(OH)CH3)C(O)CH3] -,其中n = 10,12, R = Me,等
研究了亲核试剂乙酰丙酮在硼簇阴离子腈衍生物多键上的亲核加成过程。通过核磁共振谱、esi质谱和红外光谱对产物的结构进行了表征。用单晶x射线分析确定了化合物(NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3]的结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信