A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin, N. T. Kuznetsov
{"title":"New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et","authors":"A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin, N. T. Kuznetsov","doi":"10.1134/S0036023624601910","DOIUrl":null,"url":null,"abstract":"<p>The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu<sub>4</sub>)[2-B<sub>10</sub>H<sub>9</sub>NH=C(C<sub>2</sub>H<sub>5</sub>)C(C(OH)CH<sub>3</sub>)C(O)CH<sub>3</sub>] has been established by single crystal X-ray analysis.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1469 - 1474"},"PeriodicalIF":1.8000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023624601910","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3] has been established by single crystal X-ray analysis.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.