Russian Journal of Inorganic Chemistry最新文献

Bismuth and Ytterbium Oxide Compounds: Preparation and Thermodynamics 铋和氧化镱化合物：制备和热力学

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625602120

N. I. Matskevich, E. R. Elbaev, A. N. Semerikova, A. Yu. Manakov, L. M. Levchenko, A. A. Shapovalova, V. P. Zaitsev, E. N. Tkachev

引用次数: 0

Binuclear Silver(I) Pyrazolate Complexes with Pyrazolyl-pyridine Derivatives: Association via Intramolecular Hydrogen Bonds and Ag···Ag Contacts 与吡唑基吡啶衍生物的双核吡唑酸银配合物：通过分子内氢键和银···银接触缔合

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625602193

G. B. Yakovlev, A. F. Smol’yakov, O. A. Filippov, A. A. Titov, E. S. Shubina

{"title":"Binuclear Silver(I) Pyrazolate Complexes with Pyrazolyl-pyridine Derivatives: Association via Intramolecular Hydrogen Bonds and Ag···Ag Contacts","authors":"G. B. Yakovlev, A. F. Smol’yakov, O. A. Filippov, A. A. Titov, E. S. Shubina","doi":"10.1134/S0036023625602193","DOIUrl":"10.1134/S0036023625602193","url":null,"abstract":"Cyclic trinuclear silver(I) complex, [AgPz]3 (Pz = 3,5-bis(trifluoromethyl)pyrazolate), serves as a versatile platform for binding to chelating N^N-donor aromatic ligands. In this work, we have proposed derivatives of pyrazolyl-1H-pyridine (L) as ligands of this type, including 2-(3-phenyl-1H-pyrazol-5-yl)pyridine (L1) and 2-methyl-6-(3-phenyl-1H-pyrazol-5-yl)pyridine (L2). It has been found that complex of the composition [AgPzL1] (1 : 1 : 1) forms in solution regardless of reactants stoichiometry. The crystallization of the prepared compounds from toluene results in binuclear complexes with the composition [AgPz2Ln]2 per one solvent molecule. The formation of these compounds is caused by hydrogen bonding between the NH groups of pyrazolylpyridines (Ln) and the unshared electron pair of the nitrogen atom of the pyrazolate ligand. Shortened Ag…Ag contacts (3.143–3.197 Å) have been observed in the complex, which leads to additional stabilization of the structure. The prepared compounds exhibit ligand-centered phosphorescence in solid state at ambient temperature.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 8","pages":"1172 - 1178"},"PeriodicalIF":1.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145190239","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Hexamethylenetetramine Polyoxotungstophosphate Copper Complexes 六亚甲基四胺多氧钨磷酸铜配合物

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625601989

Ya. A. Moroz, V. A. Shapovalov, N. S. Lozinskii, N. V. Tokii, T. V. Drokina, A. M. Vorotynov

{"title":"Hexamethylenetetramine Polyoxotungstophosphate Copper Complexes","authors":"Ya. A. Moroz, V. A. Shapovalov, N. S. Lozinskii, N. V. Tokii, T. V. Drokina, A. M. Vorotynov","doi":"10.1134/S0036023625601989","DOIUrl":"10.1134/S0036023625601989","url":null,"abstract":"Hitherto undescribed copper(II) hexamethylenetetramine (HMTA) complexes of tungstophosphate metalates Rb5[PW11O39Cu(H2O)]‧9H2O (I), Rb5[PW11O39Cu(C6H12N4)]‧10H2O (II), Rb5[PW11O39Zn0.95Cu0.05(H2O)]‧9H2O (III), and Rb5[PW11O39Zn0.95Cu0.05(C6H12N4)]‧10H2O (IV) were prepared and characterized by IR and electronic spectroscopies, X-ray powder diffraction, and electron paramagnetic resonance (EPR). The copper-ion absorption peak in the spectrum shifts to the longer wavelengths in going from [Cu(H2O)6]2+ through [PW11O39Cu(H2O)]5– [PW11O39Zn0.95Cu0.05(H2O)]5–, and [PW11O39Cu(C6H12N4)]5–, to [PW11O39Zn0.95Cu0.05(C6H12N4)]5– because of the changing ligand-field strength in the inner sphere of the complex. Electron paramagnetic resonance showed a significant difference between the magnitudes of the ligand field around the octahedrally coordinated Cu2+ ions in complexes (III) and (IV): the height of the crystal field potential barrier at the location of the Cu2+ ion differs more than twofold due to the replacement of a water molecule by an HMTA molecule C6H12N4. The results of the studies can be helpful in the preparation and structure determination of other tungstate polyoxometalates with inner-sphere paramagnetic ions.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 8","pages":"1150 - 1156"},"PeriodicalIF":1.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145190167","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Chloropentaammine- and Tris(ethylenediamine)cobalt(III) Oxalatocuprates(II): Synthesis, Crystal Structure, and Thermal Properties 氯戊胺-和三（乙二胺）钴（III）草酸盐（II）：合成、晶体结构和热性能

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S003602362560114X

V. I. Lagunova, E. Yu. Filatov, P. E. Plyusnin, N. V. Kuratieva, S. V. Korenev

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Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco] 金属-有机配位聚合物[Zn2(bdc)x(bdc- i)(2-x)dabco]的晶体结构与性能

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625601436

A. S. Zaguzin, Ya. A. Zaitsev, A. V. Zaitsev, N. A. Korobeynikov, M. A. Bondarenko, E. A. Maksimovskii, V. P. Fedin, S. A. Adonin

{"title":"Crystal Structures and Properties of Metal-Organic Coordination Polymers [Zn2(bdc)x(bdc-I)(2–x)dabco]","authors":"A. S. Zaguzin, Ya. A. Zaitsev, A. V. Zaitsev, N. A. Korobeynikov, M. A. Bondarenko, E. A. Maksimovskii, V. P. Fedin, S. A. Adonin","doi":"10.1134/S0036023625601436","DOIUrl":"10.1134/S0036023625601436","url":null,"abstract":"New mixed-ligand organometallic frameworks based on zinc terephthalate (bdc), 2‑iodoterephthalate (bdc-I), and 1,4-diazabicyclo[2.2.2]octane (dabco) were obtained: [Zn2(bdc)1.67(bdc-I)0.33dabco] (I), [Zn2(bdc)1.46(bdc-I)0.54dabco] (II), [Zn2(bdc)1.12(bdc-I)0.88dabco] (III), [Zn2(bdc)0.80(bdc-I)1.2dabco] (IV), [Zn2(bdc)0.46(bdc-I)1.54dabco] (V). Their structures and composition were determined by single-crystal and powder X-ray diffraction, as well as elemental analysis. Compounds I–V are isostructural with [Zn2(bdc)2(dabco)], but not with [Zn2(bdc-I)2(dabco)], which we have not described previously, which is confirmed by X-ray powder diffraction data. Experiments on the sorption of diiodine vapors are consistent with the idea that the presence of a larger amount of 2-iodoterephthalate in the MOF should lead to a decrease in pore volume: the greatest amount of I2 is absorbed by I, and the smallest by is absorbed V.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 8","pages":"1125 - 1131"},"PeriodicalIF":1.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145190200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis and Crystal Structures of Framework Tetrarhodanomercurate Mn(II), Fe(II), and Cd(II) Complexes with Nicotinamide 烟酰胺框架四聚氨基甲酸锰（II）、铁（II）和镉（II）配合物的合成和晶体结构

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625601357

D. A. Barantsev, N. V. Pervukhina, N. V. Kuratieva, T. G. Cherkasova

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Hydrothermal Synthesis of K2Ce(PO4)2·хH2O and Analysis of Its Photoprotective Properties 水热合成K2Ce(PO4)2·хH2O及其光防护性能分析

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625602223

T. O. Kozlova, D. N. Vasilyeva, I. V. Savintseva, A. L. Popov, N. P. Simonenko, D. A. Kozlov

{"title":"Hydrothermal Synthesis of K2Ce(PO4)2·хH2O and Analysis of Its Photoprotective Properties","authors":"T. O. Kozlova, D. N. Vasilyeva, I. V. Savintseva, A. L. Popov, N. P. Simonenko, D. A. Kozlov","doi":"10.1134/S0036023625602223","DOIUrl":"10.1134/S0036023625602223","url":null,"abstract":"A new method for obtaining K2Ce(PO4)2·xH2O (space group I41/amd, a = b = 6.8300(2) Å, c = 17.8488(4) Å, V = 832.63(4) Å3, Z = 4) under hydrothermal conditions has been developed. It has been established that the thermolysis of this compound proceeds through three stages of mass loss with the formation of CePO4 and K4P2O7 as intermediate products, which upon further heating form a mixture of CePO4 and K3Ce(PO4)2. The calculated values of the sun protection factor and UV-A protection factor for K2Ce(PO4)2·xH2O were 2.1 and 2.0, respectively. In relation to the human keratinocyte cell line (HaCaT), a photoprotective effect of K2Ce(PO4)2·xH2O was recorded. For the first time, the photoactive properties of KCe2(PO4)3 and K2Ce(PO4)2·хH2O in the decomposition reaction of methylene blue were evaluated. A significant slowdown in the decomposition reaction of an organic dye was demonstrated when using K2Ce(PO4)2·хH2O.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 8","pages":"1140 - 1149"},"PeriodicalIF":1.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145190165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Thermophysical Properties of Ceramics Produced from Nanocrystalline InFeZnO4 Powder 纳米晶infzno4粉末制备陶瓷的热物理性质

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625601758

O. N. Kondrat’eva, M. N. Smirnova, G. E. Nikiforova, A. V. Tyurin, V. A. Ketsko

{"title":"Thermophysical Properties of Ceramics Produced from Nanocrystalline InFeZnO4 Powder","authors":"O. N. Kondrat’eva, M. N. Smirnova, G. E. Nikiforova, A. V. Tyurin, V. A. Ketsko","doi":"10.1134/S0036023625601758","DOIUrl":"10.1134/S0036023625601758","url":null,"abstract":"The paper discusses the results of a study of the structural and thermophysical characteristics of polycrystalline ceramics produced from the InFeZnO4 nanoparticles. It was found that the bulk density of the resulting material is ~86% of the theoretical one. Scanning electron microscopy has shown that it has a dense microcrystalline structure consisting of randomly oriented grains with dimensions of 5–20 µm. The thermal diffusivity of InFeZnO4 ceramics was studied using the laser flash method. It was found that as the temperature increases from 299 to 1273 K, it decreases from 1.29 to 0.44 mm2/s. Using adiabatic and differential scanning calorimetry, the temperature dependence of the heat capacity of InFeZnO4 was studied for the first time. It was established that the measured curve has no signs of the existence of phase transitions in the range from 83 to 923 K. Using experimental data on thermal diffusivity, heat capacity, and density, an equation for the dependence describing the change in thermal conductivity of the material under study in the range from 299 to 1273 K was obtained. It was revealed that ceramics produced from InFeZnO4 nanoparticles obtained by the polymer-salt method have a higher thermal conductivity compared to those synthesized by standard ceramic technology from a mixture of In2O3, Fe2O3, and ZnO oxides. The results obtained allow us to recommend InFeZnO4 as a basis for the creation of thermally stable functional materials with low thermal conductivity at high temperatures.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"70 8","pages":"1157 - 1165"},"PeriodicalIF":1.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145190201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Aerosol Printing of Electrochromic Films Based on Nickel- or Tungsten-Doped V2O5 镍或钨掺杂V2O5电致变色薄膜的气溶胶印刷

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S003602362560220X

Ph. Yu. Gorobtsov, N. A. Fisenko, N. P. Simonenko, T. L. Simonenko, E. P. Simonenko

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Preparation and Investigation of Composite Based on Reduced Graphene Oxide and Fe3O4 Nanoparticles 还原性氧化石墨烯与纳米Fe3O4复合材料的制备与研究

IF 1.5 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2025-09-30 DOI: 10.1134/S0036023625602211

V. R. Ibragimova, I. V. Sapkov, E. I. Efremova, Z. A. Kudryashova, E. G. Rustamova, D. V. Korolev, E. I. Kunitsyna, Yu. V. Ioni

引用次数: 0