Chloropentaammine- and Tris(ethylenediamine)cobalt(III) Oxalatocuprates(II): Synthesis, Crystal Structure, and Thermal Properties
IF 1.5
3区 化学
Q3 CHEMISTRY, INORGANIC & NUCLEAR
引用次数: 0
Abstract
New double complex salts [Co(NH3)5Cl][Cu(H2O)(C2O4)2] and [Co(en)3]2[Cu(H2O)(C2O4)2]2[Cu(H2O)2(C2O4)2]·10H2O (en is ethylenediamine) have been prepared and their thermal properties have been studied. The compounds have been characterized by physicochemical methods of analysis (single crystal and powder X-ray diffraction, IR spectroscopy and elemental analysis). It has been found using thermal analysis and powder X-ray diffraction that decomposition of the complex salts leads to formation of metastable CoxCu1–x solid solutions with high mutual solubility of metals. Formation of metastable solid solutions in Co–Cu system has been shown.
氯戊胺-和三（乙二胺）钴（III）草酸盐（II）：合成、晶体结构和热性能
制备了新型双络合盐[Co(NH3)5Cl][Cu(H2O)(C2O4)2]和[Co(en)3]2[Cu(H2O)(C2O4)2]2[Cu(H2O)2(C2O4)2]·10H2O （en为乙二胺），并对其热性能进行了研究。用物理化学分析方法（单晶和粉末x射线衍射、红外光谱和元素分析）对化合物进行了表征。通过热分析和粉末x射线衍射发现，配合盐的分解形成了具有高金属互溶性的亚稳CoxCu1-x固溶体。研究了Co-Cu体系中亚稳固溶体的形成。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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来源期刊
Russian Journal of Inorganic Chemistry
化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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