合成乙酰丙酮基近硼酸盐阴离子衍生物的新方法[BnHn - 1NH=C(R)C(C(OH)CH3)C(O)CH3] -，其中n = 10,12, R = Me，等

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Inorganic Chemistry Pub Date : 2024-10-29 DOI:10.1134/S0036023624601910

A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin, N. T. Kuznetsov

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引用次数: 0

摘要

研究了亲核试剂乙酰丙酮在硼簇阴离子腈衍生物多键上的亲核加成过程。通过核磁共振谱、esi质谱和红外光谱对产物的结构进行了表征。用单晶x射线分析确定了化合物（NBu4）[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3]的结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et

查看原文本刊更多论文

New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et

The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu₄)[2-B₁₀H₉NH=C(C₂H₅)C(C(OH)CH₃)C(O)CH₃] has been established by single crystal X-ray analysis.

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来源期刊

Russian Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

3.10

自引率

38.10%

发文量

237

审稿时长

3 months

期刊介绍： Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.