含氰三烯基的n取代邻苯二甲酸亚胺的光解和光降解

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
E. S. Kelbysheva, T. V. Strelkova, A. V. Babaytsev, A. V. Naumkin, L. N. Telegina
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引用次数: 0

摘要

采用红外光谱(IR)、核磁共振(NMR)、紫外可见光谱(UV-visible spectroscopy)和循环伏安法(CV)研究了羧酸基取代邻苯二甲酸亚胺的光化学行为。在半可溶二羰基螯合物的形成过程中,观察到化合物的电子、电化学和光学性质发生了急剧变化。根据动态光散射(DLS)方法,进一步照射这些配合物的溶液会导致在含锰的液体介质中形成先前描述的稳定纳米颗粒,氧化程度为Mn2+/Mn+,并形成与cp环配位或不与锰配位(I)相关的邻苯二甲酸亚胺片段。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Photolysis and Photodegradation of N-Substituted Phthalimides with a Cymantrenyl Moiety

Photolysis and Photodegradation of N-Substituted Phthalimides with a Cymantrenyl Moiety

The photochemical behavior of substituted phthalimides with carboxylate groups associated with the cymantrenyl fragment is studied by infrared spectroscopy (IR), nuclear magnetic resonance (NMR) spectroscopy, UV-visible spectroscopy, and cyclic voltammetry (CV). During the formation of hemilabile dicarbonyl chelate complexes, a sharp change in the electronic, electrochemical, and optical properties of compounds is observed. According to the dynamic light scattering (DLS) method, further irradiation of solutions of these complexes leads to the formation of previously undescribed stable nanoparticles in liquid media containing manganese in two degrees of oxidation Mn2+/Mn+ and a phthalimide fragment associated with a Cp-ring coordinated or uncoordinated with manganese(I).

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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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