Russian Journal of Inorganic Chemistry最新文献_第8页

Extraction of Pb2+ Ions by Sodium Aluminosilicates Synthesized from Rice Straw 用稻草合成的铝硅酸钠萃取 Pb2+ 离子

IF 1.8 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/S0036023623603112

A. N. Kholomeydik, A. E. Panasenko

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Coordination, Equilibria, and Stability of Zn(II), Cu(II), Ni(II), Co(II), Pb(II), and Hg(II) Metal Complexes with 4-(2-Pyridylazo)resorcinol in Aqueous/Ethanol Solutions Zn(II)、Cu(II)、Ni(II)、Co(II)、Pb(II) 和 Hg(II) 与 4-(2-吡啶偶氮)间苯二酚的金属配合物在水溶液/乙醇溶液中的配位、平衡和稳定性

IF 2.1 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/s0036023623603458

A. Cihanbay, H. Sari, F. N. Al-Obaidi, H. Atabey

{"title":"Coordination, Equilibria, and Stability of Zn(II), Cu(II), Ni(II), Co(II), Pb(II), and Hg(II) Metal Complexes with 4-(2-Pyridylazo)resorcinol in Aqueous/Ethanol Solutions","authors":"A. Cihanbay, H. Sari, F. N. Al-Obaidi, H. Atabey","doi":"10.1134/s0036023623603458","DOIUrl":"https://doi.org/10.1134/s0036023623603458","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3>A potentiometric investigation has been undertaken to illustrate the coordination competence of 4-(2-pyridylazo) resorcinol through its reaction with particular metal ions Zn2+, Cu2+, Ni2+, Co2+, Pb2+, and Hg2+, where metal complexes are formed in the solution. The dissociation constants of the ligand PAR are calculated together with the stability constants of its complexes with the above metal ions. The experimental conditions are controlled to achieve all measurements required in the solution (ethyl alcohol (10%) and water (90%)) at (25 ± 0.1)°C and an ionic background of 0.1 mol dm–3 NaCl. The ligand acts as a tri-dentate, coordinating through the pyridine nitrogen, one of the azo group nitrogen and the ortho-hydroxy of the resorcinol moiety. Four dissociation constants were identified experimentally with values 2.40, 3.34, 5.63, and 10.84. It has been observed that several metal complexes originated in the solution, under the mentioned experimental conditions for each metal ion used. The values of the overall stability constants log ßn for all species and the dissociation constants of the PAR ligand are determined using the HYPERQUAD-2008 computer program. All species present in the solution are displayed with the use of speciation diagrams.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"25 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Interaction of Iron(III) with Succinic Acid and Certain Amino Acids 铁（III）与丁二酸和某些氨基酸的相互作用

IF 1.8 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/S0036023623602982

N. A. Skorik, O. A. Vasilyeva, A. P. Lakeev

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Alkaline Metal Fluorooxalatouranilates: Structures and Selected Properties 碱金属氟氧基戊二酸酯：结构和选定特性

IF 1.8 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/S0036023623602866

V. N. Serezhkin, M. S. Grigoriev, M. V. Sukacheva, V. Yu. Losev, L. B. Serezhkina

{"title":"Alkaline Metal Fluorooxalatouranilates: Structures and Selected Properties","authors":"V. N. Serezhkin, M. S. Grigoriev, M. V. Sukacheva, V. Yu. Losev, L. B. Serezhkina","doi":"10.1134/S0036023623602866","DOIUrl":"10.1134/S0036023623602866","url":null,"abstract":"The structures of crystals Na3[UO2(C2O4)F3]⋅4H2O (I), K3[UO2(C2O4)F3] (II), K3[UO2(C2O4)2F]⋅3H2O (III), and Cs[UO2(C2O4)F]⋅H2O (IV) were studied for the first time using X-ray diffraction. The uranium-containing structural units are complexes [UO2(C2O4)F3]3– (for I and II), [UO2(C2O4)2F]3– (III), and [UO2(C2O4)F]– (IV) with crystal chemical formulas А(В01)M(_{3}^{1}), А(В01)2M1, and А(Q02)M1 (A = ({text{UO}}_{{text{2}}}^{{{text{2 + }}}}); B01 or Q02 = ({{{text{C}}}_{{text{2}}}}{text{O}}_{{text{4}}}^{{2 - }}); M1 = F–), respectively. In all compounds, the U(VI) atoms implement a pentagonal-bipyramidal coordination; in I–II the uranyl complexes have a mononuclear structure, and in crystals IV they have a chain structure similar to that known for [UO2(C2O4)(H2O)]⋅2H2O. The results obtained suggest that the sharp increase in the solubility of uranyl oxalate trihydrate in aqueous solutions with the addition of fluorides is due to the effect of structural depolymerization of coordination polymers in the presence of fluoride ions. A semi-empirical calculation was performed and the calculated and experimental vibration frequencies in the IR spectra of II and IV were compared.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 2","pages":"178 - 187"},"PeriodicalIF":1.8,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Application of Energy-Dispersive X-ray Spectroscopy to Quantify the Chemical Composition of Igneous Rocks 应用能量色散 X 射线光谱法量化火成岩的化学成分

IF 1.8 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/S0036023623700365

E. N. Pechenkina, V. A. Krenev, S. V. Fomichev, D. F. Kondakov, E. I. Berbekova, A. A. Mikhailov

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Electronic, Structural, Elastic, and Thermodynamic Properties of X2TiBr6 (X = Li and Na) under Pressure: A DFT Investigation X2TiBr6（X = Li 和 Na）在压力下的电子、结构、弹性和热力学性质：DFT 研究

IF 2.1 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/s0036023624600722

R. Maizi, R. Ksouri, A. G. Boudjahem, M. Derdare, N. Cheghib, I. Djaghout

{"title":"Electronic, Structural, Elastic, and Thermodynamic Properties of X2TiBr6 (X = Li and Na) under Pressure: A DFT Investigation","authors":"R. Maizi, R. Ksouri, A. G. Boudjahem, M. Derdare, N. Cheghib, I. Djaghout","doi":"10.1134/s0036023624600722","DOIUrl":"https://doi.org/10.1134/s0036023624600722","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3>We investigate the electronic, structural, elastic, and thermodynamic properties of X2TiBr6 (X = Li and Na) under pressure using the DFT calculations as implemented in the Quantum Espresso code. Generalized gradient approximation in the Perdew–Burke–Ernzerhof (PBE) form is used in this work. The calculated lattice parameters are 9.864 and 9.959 Å for Li2TiBr6 and Na2TiBr6, respectively. The structure bands of the Li2TiBr6 and Na2TiBr6 compounds indicate energy band gaps of 0.92 and 1.0 eV, respectively. Their value increases with increasing ionic radius from Li to Na. The elastic constants, bulk modulus, shear modulus; Young’s modulus, Pugh’s ratio, and Poisson’s ratio have also been computed. The studied compounds are thermodynamically stable, and their stability decreased with the increase of atomic radius. Pugh’s and Poisson’s ratios that were calculated show that Li2TiBr6 and Na2TiBr6 are ductile compounds. The results also show that the heat capacity at high temperatures of the two compounds was found to be 224 J mol–1 K–1.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"21 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Polythermal Solubility of the Sodium Chlorate–Triethanolammonium Sulfate–Water System 氯酸钠-三乙醇胺硫酸盐-水体系的多热溶解度

IF 2.1 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/s0036023624600679

A. A. Sidikov, I. M. Miyassarov, A. S. Togasharov

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Synthesis and Doping of Zinc Sulfide in a Homogeneous System Based on Dodecane, Its Identification and Optical Properties 基于十二烷的均相体系中硫化锌的合成和掺杂及其鉴定和光学特性

IF 1.8 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/S0036023623602969

M. A. Zarudskikh, E. G. Ilina, A. S. Mankevich, V. P. Smagin

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Synthesis, Characterization, and Computational Studies of the Zinc Bromide Complex with 2-Amino-1,3,4-thiadiazole 2-Amino-1,3,4-thiadiazole 溴化锌络合物的合成、表征和计算研究

IF 2.1 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/s0036023624600941

K. Sh. Husenov, B. B. Umarov, K. K. Turgunov, B. Sh. Ganiev, U. M. Mardonov, B. T. Ibragimov, J. M. Ashurov, D. A. Safin

{"title":"Synthesis, Characterization, and Computational Studies of the Zinc Bromide Complex with 2-Amino-1,3,4-thiadiazole","authors":"K. Sh. Husenov, B. B. Umarov, K. K. Turgunov, B. Sh. Ganiev, U. M. Mardonov, B. T. Ibragimov, J. M. Ashurov, D. A. Safin","doi":"10.1134/s0036023624600941","DOIUrl":"https://doi.org/10.1134/s0036023624600941","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3>A new mononuclear heteroleptic complex bis(2-amino-1,3,4-thiadiazole-N)-dibromo zinc(II), [ZnBr2L2] (1), which was obtained from 2-amino-1,3,4-thiadiazole (L), is reported. Complex 1 was studied by elemental analysis, FT-IR spectroscopy and single crystal X-ray diffraction. Crystal packing of complex 1 was additionally studied using the Hirshfeld surface analysis. The DFT/B3LYP/6-31++G(d,p) based computations were additionally applied to reveal electronic features of the obtained complex 1. It was established that complex 1 contains two parent ligands L, which are monocoordinated through the thiadiazole 3-nitrogen atom and the coordination sphere of the metal cation is filled by two bromide anions. The molecular structure of complex 1 is stabilized by one N–H( cdots )N and one N–H( cdots )Br hydrogen bonds. Molecules of 1 are interlinked through a myriad of N–H( cdots )N and N–H( cdots )Br hydrogen bonds, and S( cdots )Br and π( cdots )π interactions, yielding a 3D supramolecular structure. Theoretical calculations revealed a strong electrophilic nature of the optimized structure of 1 with the most electro-rich and electron-deficient sites observed on the bromide anions and NH2 hydrogen atoms, which are not involved in the formation of intramolecular hydrogen bonds, respectively.","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"50 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Solid Solutions of Pyridinium Halobismuthates 吡啶鎓卤铋盐固溶体

IF 1.8 3区化学

Russian Journal of Inorganic Chemistry Pub Date : 2024-07-03 DOI: 10.1134/S003602362360288X

P. A. Buikin, A. S. Zhavoronkov, A. B. Ilyukhin, V. Yu. Kotov

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