碘苯胺与[2-B10H9NCCH3] -阴离子的亚氨基酰化反应制备新型含硼合成子

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Russian Journal of Inorganic Chemistry Pub Date : 2024-10-29 DOI:10.1134/S0036023624601934

A. P. Zhdanov, A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, A. S. Kubasov, I. N. Klyukin, K. Yu. Zhizhin, N. T. Kuznetsov

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引用次数: 0

摘要

研究了碘苯胺同分异构体与近癸酸阴离子的腈衍生物的亲核加成反应。用多核核磁共振、红外光谱和ESI质谱对产物的结构进行了测定。用单晶x射线衍射测定了化合物（NBu4）[2-B10H9NHC(CH3)HN(2-C6H4I)]的结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons

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Iminoacylation Reaction of Iodoaniline with [2-B10H9NCCH3]– Anion as a Route to the Preparation of New Boron-Containing Synthons

The reaction of nucleophilic addition of isomers of iodaniline to the nitrile derivative of the closo-decaborate anion has been studied. The structures of the products have been determined using multinuclear NMR and IR spectroscopy, as well as ESI mass spectrometry. The structure of compound (NBu₄)[2-B₁₀H₉NHC(CH₃)HN(2-C₆H₄I)] was determined by single-crystal X-ray diffraction.

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来源期刊

Russian Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

3.10

自引率

38.10%

发文量

237

审稿时长

3 months

期刊介绍： Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.